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energy
Concentration of technical gelatine by use of
a three-stage falling film evaporator with
mechanical vapour recompression (MVR)
Demonstration project
energy
Concentration of technical gelatine by use of
a three-stage falling film evaporator with
mechanical vapour recompression (MVR)
Demonstration project
A. M. B. Trommelen, A. J. M. Schellekens
Lijmfabriek Trabas BV
PO Box 14
5100 AA Dongen
The Netherlands
Contract No EE 349/85-NL
Final report
Directorate-General
Energy
1989
CL^EUR 12108 EN
Published by the
COMMISSION OF THE EUROPEAN COMMUNITIES
Directorate-General
Telecommunications, Information Industries and Innovation
L-2920 Luxembourg
LEGAL NOTICE
Neither the Commission of the European Communities nor any person
acting on behalf of the Commission is responsible for the use which might
be made of the following information.
C O N T E N T S
0.
Summary
1.
Introduction
2.
3.
3.1
3.1.1
3.1.2
Capacity Control
3.2
4.
5.
6.
Checking Measurements
6.1
Introduction
6.2
Measurements
6.3
10
6.4
12
7.
13
8.
17
0.
___SUMMARY
This report deals with the application of the technology of Mechanical Vapour
Recompression in the evaporation-process within the (technical) gelatine industry.
In the production process of technical gelatine a clarified solution of b%
protein in water, with a temperature of approximately 85
C. must be concentrated
INTRODUCTION
Trobas B.V. in Dongen - Holland produces hide qlue and technical qelatine from
hide-offals originating from tanneries, slaughter-houses and hide trading
companies. A simplified productionscheme is given below.
i Raw M a t e r i a l s
i
i
i
Liming
i
i
i
Washing
i
i
i
Extract ion
i
i
i
i
i
Clar] f i c a t i o n !
i
Evaporat ion
i
Cooling
i
i
i
i
i
i
i
Drying
Product
The hide-offals are plunged in a lime-milk solution and stored for a period of
about two months. During that period under influence of the lime, the insoluble
collagen is changed into water-soluble protein chains. The greater part of the
lime is eliminated by washing and the bound limerests are neutralised with acid.
The neutralised materials are rewashed several times. Afterwards the proteins
are extracted from the raw materials with water at temperatures between 70 and
100
C. After the extraction insoluble particles and grease are separated from
-1 -
2.
-2-
3.
DES
[ 0 i P I I O N _ 9 L M MVR-INSTAL L AION
On appendix 1 a flowchart of the original design of the MVR is drawn. From vessel
V-502 the protein solution of 85 C. is fed with P-532 through preheater E-541
to the first stage (E-538). This is a vertical tubular heatexchanger. The product
flows from the top to the bottom in the heatingtubes as a thin boiling film.
The heating medium is compressed process vapour from the third stage (E-540).
On the outside of the tubes the vapour condensates to supply the energy needed
for the evaporation. The generated vapour in stage one is separated from the
protein solution in a centrifugal vapour separator (S-530). The vapour is used
as heating medium on the second stage (E-539). The partly concentrated protein
solution from stage one is pumped to the second stage by pump P-533. The operation
of the following stages is in principle identical to the first stage.
The vacuum in the evaporator is maintained by vacuum pump P-541. The total amount
of the condensated vapour is removed from the installation by pump P-539. The
concentrated glue-liquor (average : 37 by weight, temperature 60
C.) is pumped
As to be explained in chapter 5 of this report, during the start-up of the MVRinstallation serious problems were met in order to reach even distribution of the
product-flow over the innerside of the heating tubes. These problems have been
solved by the application of product circulation on the three stages. As the
flowchart of the modified installation on appendix 2 shows, the product circulation
has been realized by installing extra pumps.
The product/vapour streams are equal to the above mentioned design situation.
The MVR installation has been engineered and designed by GEA Wiegand GmbH,
Ettlingen B.R.D. The compressor has been manufactured by Sulzer Escher Wyss,
Ravensburg B.R.D. and can be characterized as follows :
Type nr
Impellor diameter
: 0.315 m.
Flow
Installed power
: 160 kW
Rotation speed
: 27.154 1/min.
Compression ratio
: 1.65 - 1.95
3.1
C.
The control and measuring systems are indicated by numbers in the flow chart
on appendix 2. These numbers are explained in the form of tables on appendix 3.
The most important process control systems are :
- heatbalance control
and
- capacity control
3.1.1
-4-
3.].2
Capacity Control
ad1_l
Depending on the desired water evaporation, the capacity of the compressor must
be adapted and consequently the total capacity of the installation is effected.
This can be reached by opening the throttle valve in the suction line of the
compressor, more or less.
ad^_2
By fully opened position of the throttle valve the desired concentration of the
end-product can be controlled by adjusting the feed rate.
3.2
When starting-up the MVR installation there is not any vapour available yet for
recompression. Therefore the compressor can not be used. The throttle valve in
the suction line of the compressor is completely closed. By means of live steam
the water evaporation is started. When a sufficient level of water evaporation
is reached, the live steam suppletion is closed and the generated steam can be
recompressed by starting the compressor and gradually opening the throttle valve.
In this way the installation reaches the operating equilibrium.
_ _IMPLEMENTATION OF T H E
PROJECT
The construction phase was executed according to plan and no real difficulties
were encountered.
The responsibilities were divided as follows :
- GEA Wiegand GmbH B.R.D., engineering, design and construction of the MUR
installation.
- Trobas B.V., implementation in the process.
The activities carried out have been :
1. Civil supplies :
- sewer system
- foundations on behalf of the MVR installation and compressor
- civil accommodation for the compressor
- adjustments to roof construction and accessibility
2. Construction of the installation :
- erect the supporting construction
- install the main components of the MVR such as heatexchangers, vapourseparators, compressor and pumps
- set up the operator platforms and the internal product-, condensate- and
vapourlines
3. Connect the MVR to the existing product- and utility systems.
4. Install and connect all measuring and controlling systems and other electronical
features.
5. Insulation of the plant.
6. Finish civil supplies.
7. Check the assembling activities.
8. General test of the alarm and signal systems.
9. Test run of the measuring and controlling systems.
The main suppliers of equipment are mentioned on appendix 4, in alphabatical order.
b._
99MMISSIONING_AND OPERATION
During the water-run the designed water evaporati on capaci ty could be reached.
However, the fi rst product-runs showed that the heat transfer was far below desi gn
value. It appeared that thi s was caused by i nfavourable flow conditions i n the
heating tubes. For that reason the total i nstalled heat transfer-surface was only
partly used and therefore the designed water evaporating capaci ty could not be met.
The compressor i s designed on a certain vapour quanti ty. Because of the bad flow
conditions the required vapour quanti ty was not reached and the compressor often
operated close to or i nto the critical surgi ng range.
This caused heavy mechanical load. A combination of this mechanical load and a
wrong choice of the impellor materi al resulted i n considerable damage to the
compressor. As a consequence the MVR was non-productive for about three months.
In order to reach better flow-condi ti ons and thus heatexchange, product ci rculati on
was i nstalled on the three stages. After these modifications the designed water
evaporation capaci ty has been achieved and the MVR evaporator operates since then
in a satisfying and reli able way.
Compressor
7-
6.
C H E C K I N G MEASUREMENTS
6.1
Introduction
The measurements have been carried out on the modified MVR installation. By
setting up a mass- and energy balance over the MVR it could be checked whether
the guaranteed and aimed energy saving and water evaporating capacity were
reached.
The inputs and outputs are visualized subjoined :
A
>
>
>
>
M.V.R.
> C
> E
Installation
> B
(kg/hr)
B : condensate
(kg/hr)
(kg/hr)
D : cooling water in
(kg/hr)
(kg/hr)
F : compressor energy in
(kW)
G : pumps energy in
(kW)
(C)
<C)
(C)
(C)
<C)
(% by weight)
(X by weight)
The measurements of mass streams and temperatures have been carried out in the
usual ways, except for the feed rate, which has been calculated by means of the
equation :
A = C * p(C)/C(A)
(kg/hr)
(1)
The feed concentration (=C(A) and end-concentration (=C(C) have been determined
by drying the samples on a laboratory scale. The power of the compressor and
pumps has been calculated by measuring the amperage and voltage.
6.2
Measurements
Measurement
Flow
FEED
CONCENTRATE
Temp.
Temp.
Cone.
kq/hr
wqht.%
Cone.
Flow
wqht.?
kq/hr
Design
10,720
85.0
5.0
1,220
73.0
44.0
10,278
94.0
4.805
1,328
75.0
37.177
2
3
10,789
93.7
4.515
1,347
74.0
36.196
9,975
94.1
4.640
1,249
75.0
37.069
11,491
93.0
4.459
1,187
75.0
42.858
10,163
93.6
3.957
1,171
75.0
34.392
12,010
92.0
4.892
1,688
75.0
34.813
12,985
92.7
5.780
2,268
75.0
33.094
average
11,102
93.3
4.721
1,461
74.9
36.555
-9
Measurement
Flow
kq/hr
Design
Temp.
Temp.
D = E
E
Temp.
POWER
C00LINGWATER
CONDENSATE
Flow
kq/hr
Amp.
9,500 78.0
13,000
23.0
35.0
254.8
8,950
80.0
11,030
22.2
34.8
251.6
9,442
80.0
5,558
24.2
40.9
252.6
8,726
80.0
6,516
23.2
44.9
253.4
10,304
80.0
11,808
22.8
37.4
265.2
8,992
80.0
6,217
20.6
41.6
261.4
10,322
80.0
8,395
21.2
35.5
249.2
10,717
80.0
7,736
19.4
39.0
249.0
Average
9,641
80.0
8,172
21.8
39.2
254.6
The cumulated power of the pumps has been determined by measuring the amperages.
From the results it appeared that the difference between the measured values was
relatively small. Therefore the consumed amperage by the pumps is supposed to
be constant at a level of 77.9 ampere.
The average electrical efficiency of the pumps is 0.869, of the compressor 0.91.
6.3
Calculation of Enthalp^_and_Power
The quantity of evaporated water can be calculated by means of the mass balance.
(2)
A = B + C ===> B = A - C
The enthalpy of a liquid stream can be calculated by the equation.
(3)
h = Qm/3600 * Cp * T
in which :
h
: enthalpy
(kW)
Qm : mass stream
(kg/hr)
Cp : specific heat
(kJ/kgK)
(C)
: temperature
and with h = 0 by 0 C.
10-
In the temperature area concerned, the specific heat of the cooling water is
assumed to be constant at a value of 4.18 kJ/kgK.
The specific heat of a protein solution is a function of the protein concentration,
according to the equation.
Cp (protein sol.) = -0.0113 * (protein cone, by wght) +4.1966
(4)
4.1966 Is the average value of the specific heat from water in the temperature
range from 86-75
The power of the compressor and pumps can be calculated by using equation.
P =U* IVT
(5)
cosi
in which :
P
: power (W)
: voltage (V)
: currentstrength (A)
costi: e f f i c i e n c y
An example of the calculation is given on appendix 5. The results are listed below.
h(C)
kW
h(B)
kW
h(D)
kW
h(E)
kW
P(F)
kW
P(G)
kW
1,048.0
91.5
860.5
507.4
772.2
160.2
22.5
1,112.0
104.5
831.3
284.3
445.7
158.0
47.7
1,164.2
104.8
877.2
156.2
264.0
158.6
47.7
1,080.6
98.3
810.6
175.5
339.7
159.1
47.7
1,230.7
91.8
957.0
312.6
512.8
166.5
47.7
1,099.1
92.9
836.9
148.7
300.3
164.1
47.7
1,271.1
133.7
958.9
206.7
346.0
156.5
47.7
1,381.4
180.6
955.5
174.3
350.3
156.3
47.7
1,191.3
115.2
889.6
208.3
365.5
159.9
47.7
Measurement
Design
Average
h(A)
kW
-11
6.4
ENERGY OUT
Using the values of the first measurements the energy balance is as follows
ENERGY OUT
ENERGY IN
1112.0+284.3+158.0+47.7
831.3+104.5+445.7 + losses
1602.0
1381.5 + losses
Measurement
Energy IN
Energy OUT
(kW)
(kW)
losses
(kW)
1737.9
1602.0
1381.5
220.5
1526.7
1264.0
280.7
1462.9
1248.6
214.3
1757.5
1561.6
195.9
1459.6
1230.1
229.5
1682.0
1438.6
243.4
1759.7
1372.0
273.3
1607.2
1372.0
235.2
Design
MEAN VALUE
-12-
(6)
7^
I^yNICA
L _AND_ECONOMICA
L _RESU
L S
A comparison between the estimated and real investment costs for the project,
expressed in Dutch guilders and V.A.T. excluded, is given below :
Real costs
DESCRIPTION
1. Engineering
2. Construction/Basic order
3. Local assembly/modifications
4. Testing starting-up
5. Checking measurements
Total costs of the project :
Designed costs
(Dfl.)
(Dfl.)
31,350.==
14,300.==
1,463,368.==
1,460,500.==
726,825.==
496,400.==
88,965.==
43,800.==
8,761.==
40,000.==
2,319,269.==
2,055,000.==
Appendix 6 shows that the delay in realizing this project is fully caused by the
long starting-up period of the MVR-evaporator due to :
- required modifications of the original design
- time for repair of the damaged compressor
It is obvious that this also resulted in exceeding the budgeted costs for local
assembly/modifications and testing c.q. starting-up the installation.
The annual saving of energy and the difference in operating costs per mJ of
evaporated water is acquired by comparing the data from the MVR-installation
as built with the operational data of a conventional 3-stage falling film
evaporator equipped with steam jet-thermo vapour recompression (TVR). The
operating costs of the MVR are derived from the measured data, whereas the
energy consumption of the TVR-evaporator has been calculated on the basis of
design data from GEA Wiegand GmbH. It should be noted, however, that the latter
are fictitious though very realistic values.
-13-
The comparison in operating costs has been made under the following assumptions
natural gas
1 kWh electricity
1 m
Design value
1985
Actual value
1988
DESCRIPTION
cooling water
9,640 kg/hr
9,500 kg/hr
Dfl. 0.235
Dfl. 0.500
Dfl. 0.105
Dfl. 0.134
Dfl. 0.060
Dfl. 0.070
Dfl. 21.05
Dfl. 42.53
0.01 ton/m
0.01 ton/m3
5.760
5.760
Dfl. 42,000,==
Dfl. 42,000,==
57,142
56,308 (*)
Specific
energy consumption
Steam
M.V.R.
T.V.R.
Units
0.01
0.221
ton/m3
kW/m3
Power
- pumps
- compressor
4.81
16.12
3.02
m 3 /m 3
Cooling water
0.8238
11.09
Operating costs
(based on 1988-prices)
M.V.R.
T.V.R.
Steam
0.21
4.65
Dfl./m3
Power
2.20
0.32
Dfl./m3
Cooling water
0.06
0.78
Dfl./m3
Extra maintenance
0.10
Dfl./m3
Labour costs
0.74
0.74
Dfl./m3
3.31
6.49
Dfl./m3
Units
(mainly compressor)
14-
It appears that even at present low energy prices an annual saving in operating
costs of Dfl. 181,700.== is realized, by concentrating the technical gelatine
solution with a MVR-evaporator instead of a conventional 3-stage TVR-evaporator.
However, the savings calculated on the basis of the energy prices of 1985 amount
to Dfl. 400,500.==.
The simple pay-out time for the extra investment of the MVR in comparison with
the TUR is defined as :
extra investment
POT =
savings/year
Extra investment
: Dfl. 1,295,508.==
As stated before, the annual savings in operating costs amount to Dfl. 181,700.==
and thus holds :
POT =
1,295,508.==
181,700.==
=7.1 year
IN TVR
1.691 kW
Power
IN MVR
160 kW
Power-savings
1.531 kW
or relatively 90.5%
Because :
- 1 kW = 10 3 J/s
- 1 production year has 240*24*3,600 = 2.0736 * 10 7 s
- 1 TOE = A-1868 * 10 1 0 J
15-
It can be calculated that the achieved energy savings expressed in TOE are :
1531 * 10 3 * 2.0736 * 10 7
4.1868 * 10 1 0
758 TOE/year
The objective of the project was to reach an annual energy saving of 645 TOE/year
(relatively 80%). So the conclusion is, that from an energetical point of view
the project has been a complete success.
In order to calculate the overall energy saving, the 355o-efficiency for generating
electrical energy by the electricity works should be taken into account.
As a result the energy conservation in terms of the national energy balance
amounts to only 612 TOE/year.
-16-
8^
29NC
L USIONS_AND_gU
L OOK
The achieved annual saving of energy by Trobas B.V. amounts to 758 TOE/year.
This means an energy conservation of more than 90% in comparison with a
conventional 3-stage evaporator equipped with thermal vapour recompression.
17-
^J3
.IVE STEAM
(<>)p5u
w
,r
3J.
2.2 2.1.
w t w
5
32. l ?
COaiNG
-E5C2
-9-
-5
E52i
-E 541
WATER
-:i
5J9
E_5p.
E 537
tTT30
1521
00
FEED
tu
v
m
W
3531
/WvW^
PS0
P532
P533
P53
P535
K 550
P539
3 @
P536
P537
P538
PRCDUCT
LIVE STEAM
<?
C
w
2.2. 2.1.
33. 32.
* w
S)P5M
<40
COOLING
-EW2
>
^
-!
WATER
>
538
-E541
i 21
E50
li
^ > ,
I
Y
I
Js>
83
88 C
S>
79,
<'
E 537
5 C
1460 k g / H
TT3O
_^E>
11.100 kg/H
FEED
T531
3522.
fe
5% T.S.
tu
<t
ja
p
532
P531
P53I
m
P533
Pm
<9>37S T.S.
LF
PRODUCT
P50
Vapour 3100 k o / H
ir
-,
M.AJk
_3 f i l i 130
PO
35.
P37
Appendix 3
controIs/lockings/alarm6/local indicators
Number
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16/30
31
32
33
34
35
36
37
38
39
40
41
42
43
Description
Level Indicating Controlling Alarm
on feed vessel V-502.
Level Alarm first stage E-538.
Level Alarm second stage E-539.
Level Alarm third stage E-540.
Level Indicating Controlling Alarm
flash vessel E-537.
Level Alarm separator in suction line compressor.
The same as 6 on/off.
Temperature Indicating Controlling feed.
Thermal protection on/off MP-540.
Split-Range Pressure Indicating Recording
Controlling compressor suction 6ide.
Vacuum Control.
Hand Setting live steam (6tart-up).
Hand Control bypass compressor.
Hand Control throttle valve compressor
suction side.
Flow Control feed.
Several protections on the compressor for optimal
operation conditions e.g. mechanical vibrations,
indications, oil level/temperature.
Temperature Indicating feed from pre-heater.
Temperature Indicating vapour separator E-538.
Temperature Indicating vapour separator E-539.
Temperature Indicating vapour separator E-540.
Temperature Indicating Controlling E-537.
Temperature Indicating condensate after P-539.
Pressure Indicating E-538.
Pre66ure Indicating E-539.
Pressure Indicating E-540.
Presurre Indicating condensor E-542.
Pressure Indicating E-537.
Pressure Indicating suction side compressor.
Pressure Indicating pressure 6ide compressor.
-20-
Appendix 4
tEQUIPMENT
SUPPLIER
A.S.C.
Buveco
(Bleiswijk)
Dooren, van
(St. Willebrord)
Insulation activities
Eckhardt
(Rijswijk)
Kin
(Rijen)
Mechanical activities
Koning, de
(Eindhoven)
Electrical systems
O.B.R.
(Rijen)
Civil activities
Sandvik
(Schiedam)
Sulzer E-W
(Ravensburg) (*)
Compressor RT 28-1
GEA Wiegand
(Ettlingen)
Design / construction /
(*)
commissioning MVR
-21 -
Vi * 0 . 9 1 '
P ( F ) = 1 5 8 . 0 kWatt
Power pumps ( = G ) .
P(G) = 0 * 1 *
V 3 * cosv
P(G) = 3 8 0 * 7 7 . 9
V3 * 0 . 8 6 9 *
22-
Appendix 5
Appendix 6.
Table 7.
INITIAL TIMETABLE
s::iEEc:r:s:Et:s
1988
1987
I9S8
198S
PACE
1-
+-
+-
ENGIHEERItU
COHSTROCTIOH
LOCAL ASSEKBLT
TESTIHC/STARTIiW OF
CHECKING MEASUREMENTS
TABLE 8
REAL TIMETABLE
1985
FASE
1986
198T
1988
S
CHECKIHO M EASOHEHEM TS
1
1
23
A. M. B. Trommelen, A. J. M. Schellekens
Luxembourg: Office for Officia l Publica tions of the Europea n Communities
1989 - VI, 23 pp., tab., fig., ph. - 21.0 x 29.7 cm
Energy series
EN
ISBN 92-825-9675-3
Catalogue number: CD-NA-12108-EN-C
Price (excluding VAT) in Luxembourg: ECU 5
Major energy savings are demonstrated in the evaporation a nd concentration sta ges
of the gela tine ma nufa cturing process by the introduction of mecha nica l va pour
recompression techniques.
lllllllllllllllllllllllllll
25
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Casella postale 552
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Subagenti:
Libreria scientifica Lucio de Biasio -AEIOU
Via Meravigli. 16
20 123 Milano
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Herder Editrice e Libreria
Piazza Montecitorio. 117-120
0 0 186 Roma
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ISBN =12-025-^75-3