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Abstract
Structure and properties of a series of binary Ti}Mo alloys with molybdenum contents ranging from 6 to 20 wt% have been
investigated. Experimental results indicated that crystal structure and morphology of the cast alloys were sensitive to their
molybdenum contents. The hexagonal a phase c.p. Ti exhibited a feather-like morphology. When Mo content was 6 wt%, a "ne,
acicular martensitic structure of orthorhombic a phase was observed. When Mo content was 7.5 wt%, the entire alloy was dominated
by the martensitic a structure. When Mo content was increased to 10 wt% or higher, the retained b phase became the only dominant
phase. Among all Ti}Mo alloys, the a phase Ti}7.5Mo alloy had the lowest hardness. The bending strength of Ti}7.5Mo was similar
to that of Ti}15Mo and Ti}13Nb}13Zr, and higher than c.p. Ti by nearly 60%. The bending modulus of the a-dominated Ti}7.5Mo
alloy was lower than that of Ti}15Mo by 22%, of Ti}6Al}4V by 47%, of Ti}13Nb}13Zr by 17%, and of c.p. Ti by 40%. 1999
Elsevier Science Ltd. All rights reserved.
Keywords: Titanium}molybdenum alloy; Implant material; Structure; Mechanical properties
1. Introduction
There has been a concern from time to time regarding
the stress shielding phenomenon, i.e., insu$cient loading
of bone due to the large di!erence in modulus between
implant device and its surrounding bone. This phenomenon, more often observed in cementless hip and knee
prostheses [1], can potentially lead to bone resorption
[2] and eventual failure of the arthroplasty [1].
Both strain gauge analysis [3] and "nite element analysis [4] have demonstrated that lower modulus (more
#exible) femoral hip implant components result in
stresses and strains that are closer to those of the intact
femur, and a lower modulus hip prosthesis may better
simulate the natural femur in distributing stress to the
adjacent bone tissue [5,6]. Canine and sheep implantation studies have shown signi"cantly reduced bone resorption in animals with low modulus hip implants [7],
and the bone loss commonly experienced by hip prosthesis patients may be reduced by a prosthesis having
lower modulus [7,8].
0142-9612/99/$ - see front matter 1999 Elsevier Science Ltd. All rights reserved.
PII: S 0 1 4 2 - 9 6 1 2 ( 9 9 ) 0 0 1 1 4 - 3
2116
The metastable b phase Ti}15Mo alloy is being evaluated for orthopaedic implant applications by Synthes
USA. The rapidly quenched Ti}15Mo alloy was reported
to have a "ne-grained bcc structure with a lower modulus
(77.7 GPa) than that of 316L stainless steel, Grade IV Ti,
Ti}6Al}4V and Ti}6Al}7Nb [18]. According to Bania
[20], to stabilize b phase at room temperature in
a Ti}Mo alloy, a minimum of 10 wt% of this isomorphous b-stabilizing elememt is needed.
In the present study, the structure and properties of
a series of binary Ti}Mo alloys with Mo contents ranging
from 6 to 20 wt% were investigated. Emphasis of the
research was on the comparison of the properties of
b phase alloys with those of the orthorhombic a phase
alloy that seems to have great potential to be a new
candidate for implant material.
2. Experimental procedure
The molybdenum contents selected for this study include 6, 7.5, 9, 10, 12.5, 15, 17.5 and 20 wt%. The series of
the binary alloys were prepared from 99.9% pure titanium and 99.95% pure molybdenum using a commercial
arc-melting vacuum-pressure-type casting system (Castmatic, Iwatani Corp., Japan). The melting chamber was
"rst evacuated and purged with argon. An argon pressure of 1.5 kgf/cm was maintained during melting. Appropriate amounts of metals were melted in a U-shaped
copper hearth with a tungsten electrode. The ingots were
remelted thrice prior to casting to improve chemical
homogeneity.
Prior to casting, the ingots were melted once again in
an open-based copper hearth under an argon pressure of
1.5 kgf/cm. The di!erence in pressure between the two
chambers allowed the molten alloys to instantly drop
into the graphite mold when melted.
The cast alloys were sectioned using a Buehler Isomet low-speed diamond saw to obtain specimens
for various purposes. Surfaces of the alloys for
microstructural study were mechanically polished via
a standard metallographic procedure to a "nal level of
0.3 lm alumina powder and then etched in a solution
of water, nitric acid, and hydro#uoric acid (80 : 15 : 5
in volume). Microstructure of the etched alloys was
examined using an optical microscope (MC80, ZEISS,
Germany).
X-ray di!raction (XRD) for phase analysis was conducted using a Rigaku di!ractometer (Rigaku D-max
IIIV, Rigaku Co., Tokyo, Japan) operated at 30 kV and
20 mA. A Ni-"ltered CuK radiation was used for this
?
study. Phase was identi"ed by matching each characteristic peak with the JCPDS "les. The microhardness of
polished alloys was measured using a Matsuzawa
MXT70 microhardness tester with a load of 200 g for
15 s.
2117
Table 1
Phases and crystal structure of c.p. Ti and Ti}Mo alloys fabricated in
this study
wt% Mo
Phase
Crystal structure
c.p. Ti
3}5
6
7.5
9
10}20
a
a
a/a
a
a/b
b
Hexagonal
Hexagonal
Hexagonal/orthorhombic
Orthorhombic
Orthorhombic/bcc
bcc
2118
3.3. Microhardness
As shown in Fig. 6, all the Ti}Mo alloys (containing
6}20 wt% Mo) had much higher microhardness values
(270}340 HV) than that of c.p. Ti (160 HV). Among all
Ti}Mo alloys, the a phase alloy (Ti}7.5Mo) had the
lowest microhardness value (263 HV), while the b phase
alloy (especially those containing 10 and 12.5 wt% Mo)
had the highest hardness. The microhardness value of
Ti}7.5Mo was lower than that of as-cast Ti}6Al}4V
(294 HV) and of Ti}13Nb}13Zr (285 HV) by 10.5 and
7.7%, respectively.
One-way ANOVA statistical analysis and Sche!e multiple comparison indicated that the microhardness values
of all Ti alloys were signi"cantly higher than that of
c.p.Ti (P(0.001). Signi"cant di!erences (P(0.001)
were found among Ti}6Mo, Ti}7.5Mo and Ti}9Mo
alloys. The microhardness values of these three alloys
were signi"cantly lower than those of the alloys containing only b phase (Mo content ranging from 10 to 20
wt%).
Although the measurements were straightforward, the
interpretation of the measured microhardness values
could be quite complex. Such e!ects as solid solution
strengthening, precipitation hardening, strain aging,
grain size and crystal structure/phase (a, a, b) could all
a!ect the hardness of the alloy.
2119
4. Conclusions
1. The hexagonal a phase c.p. Ti exhibited a feather-like
morphology. When 6 wt% Mo was contained, a "ne,
acicular martensitic structure of orthorhombic a
2120
Fig. 5. (continued).
phase was observed. When 7.5 wt% Mo was contained, the entire alloy was dominated by the martensitic a structure. When the Mo content increased to
10 wt% or higher, retained b phase became the only
dominant phase.
2. Among all Ti}Mo alloys, the a phase Ti}7.5Mo alloy
had the lowest hardness, while the b phase alloys
containing 10 and 12.5 wt% Mo had the highest
hardness. The microhardness value of Ti}7.5Mo was
2121
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Table 2
Microhardness and bending properties of c.p. Ti and Ti alloys fabricated in this study
c.p. Ti
Ti}6Al}4V
Ti}13Nb}13Zr
Ti}15Mo
Ti}7.5Mo
Microhardness (HV)
156
294
285
307
263
884
1857
1471
1348
1395
92
105
66
71
55
7
27
29
26
40
2122
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