T

Ca
0
100
200
300
400

ln(Cao/Ca)
1000
500
333
250
200

0
0.69314718
1.09961279
1.38629436
1.60943791

1/Ca-1/Ca0
0
0.001
0.002003
0.003
0.004

Chart Title
0.0045
0.004

f(x) = 0.00001x + 6.00600600600822E-007

R = 0.9999992786

0.0035
0.003
0.0025
0.002
0.0015
0.001
0.0005
0

50

100

150

200

250

300

350

400

450

Chart Title
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0

400

450

50

100

150

200

250

300

350

400

450

Ca (mol/l)
1
2
4
6
7
9
12

ra (mol/lh)
ln (Ca)
ln (-ra)
0.06
0 -1.22184875
0.1
0.30103
-1
0.25 0.60205999 -0.60205999
1 0.77815125
0
2 0.84509804
0.30103
1 0.95424251
0
0.5 1.07918125
-0.30103

Chart Title
0.4
0.2
0
-0.2
-0.4
-0.6
-0.8
-1
-1.2
-1.4

f(x) = 1.7440570254x - 1.3857917021

0.1
0.2
0.3
0.4

0.5

0.6

0.7

0.8

0.9

.7

0.8

0.9

Ca
0
41
48
55
75
96
127
146
162
180
194
212
267
318
368
379
410

0
1.18
1.38
1.63
2.24
2.75
3.31
3.76
3.81
4.11
4.31
4.45
4.86
5.15
5.32
5.35
5.42

dCa/dt
0.0365
0.02947301
0.02834384
0.02723525
0.02418125
0.02115536
0.01702709
0.01469636
0.01285124
0.010904
0.00948356
0.00777824
0.00341069
0.00049604
-0.00130096
-0.00155539
-0.001999

-3.31044302
-3.52428035
-3.56334556
-3.60324319
-3.72217774
-3.85586198
-4.07294967
-4.22015543
-4.35431497
-4.51862558
-4.65819551
-4.85642519
-5.68084066
-7.60885399
Err:502
Err:502
Err:502

Chart Title
6

f(x)
5 = 7.34299063988585E-008x^3 - 8.643532111229
R = 0.9987518622
4
3
2
1
0

50

100

150

200

250

Chart Title

9063988585E-008x^3 - 8.6435321112295E-005x^2 + 0.0365358386x - 0.0879535259

18622

100

150

200

250

300

350

400

450

k
222
250
286
333
400
500

7.86E-014
1.349E-013
2.512E-013
4.266E-013
7.413E-013
1.413E-012

1/T
ln (k)
0.0045045 -30.1744047
0.004 -29.6342426
0.0034965 -29.012527
0.003003 -28.4829296
0.0025 -27.930371
0.002 -27.285306

ln (k) vs 1/t
-25.5
0.0015
-26

0.002

0.0025

0.003

0.0035

0.004

-26.5
-27
-27.5
-28
-28.5
-29
-29.5
-30
-30.5

f(x) = - 1146.7720163318x - 25.0255211427

R = 0.9993017942

0.0045

0.005

P
0
100
200
300
400
500

PA
82.7
71.1
64
60.4
56.7
54.8

82.7
59.5
45.3
38.1
30.7
26.9

K primer orden K segundo orden Orden 1.5

#DIV/0!
#DIV/0!
#DIV/0!
3.29E-03
4.71E-05
5.83E-05
3.01E-03
4.99E-05
6.12E-05
2.58E-03
4.72E-05
5.76E-05
2.48E-03
5.12E-05
6.20E-05
2.25E-03
5.02E-05
6.05E-05
n

P
0
1.2
1.95
2.9
4.14
5.7
8.1

1
0.8
0.7
0.6
0.5
0.4
0.3

0
0.11803399
0.19522861
0.29099445
0.41421356
0.58113883
0.82574186

Char
0.035
0.03

f(x) = 5.78946574456964E-005x - 0.
R = 0.9981981436

0.025
0.02
0.015
0.01
0.005
0

100

200

(Pa-Pa0)
-5.04303786
5.97318866
-7.77431443
2.45695364
3.69043206

PA (calculada)

0
0.00553731
0.01163311
0.01640737
0.02357724
0.02874745

1.95

Chart Title

8946574456964E-005x - 0.0001565835
81981436

100

200

300

400

500

600

PA

0
2
3
5
6
8
9
11
12
14
15
17
18
20
21

173.5
187.3
193.4
205.3
211.3
222.9
228.6
239.6
244.4
254.5
259.2
268.7
273.9
282
286.8

173.5
166.6
163.55
157.6
154.6
148.8
145.95
140.45
138.05
133
130.65
125.9
123.3
119.25
116.85

K primer ordeK segundo or Orden 1.5

#DIV/0!
#DIV/0!
#DIV/0!
2.03E-02
1.19E-04
1.556E-03
1.97E-02
1.17E-04
1.517E-03
1.92E-02
1.16E-04
1.495E-03
1.92E-02
1.17E-04
1.502E-03
1.92E-02
1.20E-04
1.515E-03
1.92E-02
1.21E-04
1.524E-03
1.92E-02
1.23E-04
1.538E-03
1.90E-02
1.23E-04
1.532E-03
1.90E-02
1.25E-04
1.542E-03
1.89E-02
1.26E-04
1.542E-03
1.89E-02
1.28E-04
1.553E-03
1.90E-02
1.30E-04
1.571E-03
1.87E-02
1.31E-04
1.565E-03
1.88E-02
1.33E-04
1.580E-03

1.95

Chart Title
0.45
0.4

f(x) = 0.0187363362x + 0.0028595397

0.35
0.3

Chart Title

0.25
0.2
0.018
0.15
0.016

f(x) = 0.0007877107x - 0.0001487248

0.014
0.1
0.012
0.05
0.01
0
0
0.008

10

15

20

25

0.006
0.004
0.002
0

10

15

20

25

(Pa-Pa0)
2.52885171
1.43607032
-0.48201484
-0.83512295
-2.73199935
1.5

0
0.0015562
0.00227527
0.00373766
0.00450681
0.00605927
0.0068558
0.00846096
0.00919127
0.01079204
0.01156839
0.01320349
0.01413824
0.01565475
0.01659039

ln(Pao/Pa)
0
0.04058187
0.05905885
0.09611742
0.11533646
0.15357448
0.1729135
0.21132605
0.22856166
0.26582847
0.28365561
0.32068966
0.34155719
0.37495547
0.39528654

Pa-Pao
0
0.0015562
0.00227527
0.00373766
0.00450681
0.00605927
0.0068558
0.00846096
0.00919127
0.01079204
0.01156839
0.01320349
0.01413824
0.01565475
0.01659039

Pa orden 1 Pa orden 1.5

173.5
173.5
167.130944 166.411795
164.034636 163.029485
158.013046 156.567037
155.085658 153.478966
149.392579 147.570732
146.624896 144.743737
141.242405 139.328111
138.625714 136.733572
133.536867 131.757279
131.062931 129.370393
126.251708 124.787167
123.912739 122.586353
119.363994 118.355864
117.152628 116.322273

%desviacion 1 % desviacion 1.5

0
0.3186937175 0.11296828
0.2963227106 0.31826053
0.2620850403 0.6554333
0.3141387081 0.7251189
0.3982385696 0.82612109
0.4624160672 0.82649083
0.5641901754 0.79878155
0.4170332747 0.95358764
0.4036596362 0.93437667
0.3160591591 0.97941589
0.2793553054 0.88390203
0.4969496407 0.57878877
0.0955926225 0.74979983
0.2589886378 0.45162775

P
0

T (C)
70

80

90

100

Tiempo (h) Conversion %LN(1-x)

K
114
10 0.10536052
208
19 0.21072103
404
38 0.4780358
0.0013
40
21 0.23572233
66
26 0.30110509
90
41 0.52763274
0.0058
42
10 0.10536052
65
19 0.21072103
89
38 0.4780358
0.008
24
37 0.46203546
40
61 0.94160854
44
65 1.04982212
63
77 1.46967597
0.0257

ln(k)

-6.64539101

-5.14989736

-4.82831374

-3.66126429

Chart Title
1.6
1.4

f(x) = 0.0257160269x - 0.1185746245

1.2
1
0.8
0.6
0.4
0.2
0
20

25

30

35

40

45

50

55

60

65

70

1/T

0.00291418

0.00283166

0.00275368

0.002914177
0.00267989

0
0.00265

0.0027

0.00275

0.0028

0.00285

-1
-2
-3
-4
-5
-6
-7

70

f(x) = - 11894.1123754472x + 28.1710609309

R = 0.9524082852

0.0029

0.00295

0.0029

0.00295

p+

Cb/Cbo
0
8000
14000
20000
30000
50000
90000

Cb
1
0.836
0.745
0.68
0.582
0.452
0.318

K1
0.002
0.001672
0.00149
0.00136
0.001164
0.000904
0.000636

k2

#DIV/0!
2.23908E-005
2.10265E-005
1.92831E-005
1.80428E-005
1.58815E-005
0.00001273

#DIV/0!
0.01226077
0.01222435
0.01176471
0.01197022
0.01212389
0.01191474

k orden n
#DIV/0!
0.0108078
0.01076232
0.01034714
0.01050904
0.01061126
0.01038027

Chart Title
1000
900

f(x) = 0.0102357148x

800
700
600
500
400
300
200
100
0

Cb/Cbo
0
8000
20000
50000
90000

Cb
1
0.901
0.787
0.593
0.453

Cb
0
8000
20000
50000
90000

10000 20000 30000 40000 50000 60000 70000 80000 90000 100000

0.002
0.001802
0.001574
0.001186
0.000906

K1
0.002
0.001802
0.001574
0.001186
0.000906

k2
k orden n
#DIV/0!
#DIV/0!
#DIV/0!
1.30313E-005 0.00686737 0.00118753
1.19764E-005 0.0067662 0.00114702
1.04512E-005 0.00686341 0.00111348
8.79848E-006 0.00670836 0.00104073

dcb/dt
ln(-dcb/dt)
ln(Cb)
-2.00E-08 -17.72753356 -6.2146081
-1.84E-08 -17.81091517 -6.31885812
-1.60E-08 -17.95067711 -6.45413513
-1.00E-08 -18.42068074 -6.73716898
-2.00E-09 -20.03011866 -7.00647125

0
84.7331463
147.659075
202.803997
308.965689
519.951614
915.539656
1.98

Chart Title
80
70
f(x) = 0.0007494147x + 0.9960325236

60
50
40
30

Ch

20

0.0025

10
0

000 80000 90000 100000

0.002
f(x) 70000
= 1.08527152525069E-013x^
10000 20000 30000 40000 50000 60000
80000 90000 100000
0.0015

0
6.84018855
16.5170543
40.0854435
67.4391379

1.72

0.001
0.0005
0

20000

4000

Chart Title

0025

.002
f(x) 70000
= 1.08527152525069E-013x^2
0000
80000 90000 100000 - 2.16728961870105E-008x + 0.0019816604

0015

.001

0005
0

20000

40000

60000

80000

100000

Presion total
420
363
290
225
184
121
60

385
420
492
572
665
820
1400

Ln(Pao)
Ln (Tmedia)
6.04E+00 5.95324333
5.89E+00 6.04025471
5.67E+00 6.19847872
5.42E+00 6.34913899
5.21E+00 6.49978704
4.80E+00 6.70930434
4.09E+00 7.24422752

Chart Ti

0.3
8
7

f(x) = - 0.6535182614x +

6
5
4
3
2
1
0
3.50E+00

4.00E+00

4.50E+00

5.00E+0

Chart Title
f(x) = - 0.6535182614x + 9.8938234183

4.00E+00

4.50E+00

5.00E+00

5.50E+00

6.00E+00

6.50E+00

P
0
100
200
300
400
500

dP/dt
82.7
71.1
64
60.4
56.7
54.8

-0.1385
-0.0935
-0.0535
-0.0365
-0.028
-0.01

ln(-dp/dt)
ln(2P-Po)
dp/dt polino
-1.97688495 4.4152196
-0.1087
-2.36979384 4.08597631
-0.0987
-2.92807363 3.81330703
-0.0887
-3.31044302 3.64021428
-0.0787
-3.57555077 3.42426265
-0.0687
-4.60517019 3.29212629
-0.0587

ln(-dp/dt) poli
-2.21916348
-2.31567033
-2.42249539
-2.54211212
-2.67800608
-2.83531555

-1.976884953
0
3.2

3.4

3.6

3.8

-0.5
-1
-1.5
-2
-2.5
-3

f(x) = 0.5328582683x - 4.515541556

4.2

4.4

4.6

Ca
0
0.5
1
1.5
4
5
6

K1
0.2
0.125
0.08333
0.0625
0.02778
0.02273
0.01887

#DIV/0!
0.94000726
0.87550874
0.77543387
0.49350026
0.43492635
0.39345733

k2
#DIV/0!
6
7.00048002
7.33333333
7.74928006
7.79894413
7.99902844

k orden n
#DIV/0!
4.13533331
4.59588426
4.63807377
4.36122278
4.25415325
4.23548881

Chart Ti
25
20

f(x) = 3.3845448095x + 0.1825135486

15
10
5
0

0
1.65413332
3.6767074
5.56568852
13.9559129
17.016613
20.3303463
1.8

Chart Title

3.3845448095x + 0.1825135486

P
0
1.2
1.95
2.9
4.14
5.7
8.1

PA
1
1.1
1.15
1.2
1.25
1.3
1.35

1
0.8
0.7
0.6
0.5
0.4
0.3

K primer ordeK segundo or Orden 1.5

#DIV/0!
#DIV/0!
#DIV/0!
1.86E-01
2.08E-01
1.967E-01
1.83E-01
2.20E-01
2.002E-01
1.76E-01
2.30E-01
2.007E-01
1.67E-01
2.42E-01
2.001E-01
1.61E-01
2.63E-01
2.039E-01
1.49E-01
2.88E-01
2.039E-01

Chart Ti

1.5
0.9
0.8

f(x) = 0.1021970107x - 0.0037649983

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

(Pa-Pa0)
-1.78481973
-0.22541354
0.29033265
-1.90161465
3.52366465

ln(Pao/Pa)

0
0.11803399
0.19522861
0.29099445
0.41421356
0.58113883
0.82574186

Pa-Pao

0
0.22314355
0.35667494
0.51082562
0.69314718
0.91629073
1.2039728

0
0.11803399
0.19522861
0.29099445
0.41421356
0.58113883
0.82574186

Pa orden 1
1
0.9778099
0.96419184
0.94721422
0.92550291
0.89889414
0.85944367

Chart Title
0.1021970107x - 0.0037649983

Pa orden 1.5
1
0.99808276
0.99688729
0.9953761
0.99340876
0.990942
0.98716489

%desviacion % desviacion 1.5

0
22.226238 -24.7603452
37.7416914 -42.4124694
57.869037 -65.8960162
85.1005825 -98.6817527
124.723536 -147.735501
186.481222 -229.054964

xa
0
1110
2010
5052
11132

Ln
0
0.0642
0.1066
0.207
0.3085

k(M-L)Cao
0
0
-0.10444265 -9.40925E-005
-0.18932986 -0.000094194
-0.47376604 -9.37779E-005
-1.03541629 -9.30126E-005

Chart T
0
-0.2
-0.4
-0.6
-0.8
-1
-1.2

0 f(x) = - 9.29741124419265E-005x
2000
4000
- 600
0.00

Chart Title

2000
4000
8000
- 9.29741124419265E-005x
- 6000
0.0016365158

10000

12000

Cao

t
0.075
0.05
0.025
0.0133
0.01

1.3
1.96
4.1
7.7
9.8

ln(Ca0)
Ln(T)
-2.59026717 0.26236426
-2.99573227 0.67294447
-3.68887945 1.41098697
-4.31999124 2.04122033
-4.60517019 2.28238239

Chart Ti

f(x) = - 1.0128698439x - 2.35287

-5

-4.5

-4

-3.5

Chart Title
2.5
f(x) = - 1.0128698439x - 2.3528747148

2
1.5
1
0.5

-4.5

-4

-3.5

-3

-2.5

0
-2

CR

Ca

0
21
36
50
65
80
100
120
160
220

0
0.0241
0.0373
0.0499
0.061
0.0708
0.0811
0.096
0.1035
0.1155

0.1823
0.1582
0.145
0.1324
0.1213
0.1115
0.1012
0.0863
0.0788
0.0668

K primer orden K segundo orden K orden n

#DIV/0!
#DIV/0!
#DIV/0!
0.0067520774
0.0397928092 0.02790442
0.0063588872
0.0391968945 0.02723491
0.0063965208
0.0413481314 0.02844841
0.0062674902
0.0424393779 0.02891712
0.0061453636
0.0435393293 0.02938452
0.0058855492
0.043959594 0.02933624
0.0062318674
0.0508501833 0.03329329
0.0052421293
0.0450305738 0.02915409
0.0045634118
0.0431118016 0.02733224

Chart Title
n

6
5

1.8

f(x) = 0.0227345028x + 0.0490850019

R = 0.9881786151

4
3
2
1
0

50

CR
0
21
36
50
65
80
100
120
160
220

Ca
0
0.0241
0.0373
0.0499
0.061
0.0708
0.0811
0.096
0.1035
0.1155

100

dca/dt
0.1823
0.1582
0.145
0.1324
0.1213
0.1115
0.1012
0.0863
0.0788
0.0668

-0.0011
-0.000974
-0.000884
-0.0008
-0.00071
-0.00062
-0.0005
-0.00038
-0.00014
0.00022

150

200

250

ln(Ca)
-1.7021016
-1.84389522
-1.93102154
-2.02192764
-2.10948846
-2.19373069
-2.29065652
-2.44992568
-2.54084228
-2.7060522

Chart Title
0.2
0.18
f(x) = - 4.77829908889552E-009x^3 + 4.05646071456749E-006x^2 - 0.0011841506x + 0.1821363072
0.16

-2.6

-2.5

0.14
0.12
0.1
0.08
0.06

f(x) = 2.

0.18
f(x) = - 4.77829908889552E-009x^3 + 4.05646071456749E-006x^2 - 0.0011841506x + 0.1821363072
0.16

-2.6

-2.5

0.14
0.12
0.1
0.08
0.06

f(x) = 2.

0.04
0.02
0

50

100

150

200

250

1/Ca-1/cao
0
0.46879423
0.78436549
1.13793622
1.50369025
1.880609
2.34689908
3.19615559
3.73172295
4.81047362

250

ln(-dca/dt)
-6.8124451
-6.93409925
-7.0310535
-7.13089883
-7.25024559
-7.38579108
-7.60090246
-7.87533931
-8.87386814

0.04855782

Chart Title
-2.6

-2.5

-2.4

-2.3

-2.2

-2.1

-2

-1.9

-1.8

-1.7

0
-1.6
-1
-2
-3
-4
-5
-6

f(x) = 2.0784862592x - 3.0255182697

-7

-2.6

-2.5

-2.4

-2.3

-2.2

-2.1

-2

-1.9

-1.8

-1.7

-1.6
-1
-2
-3
-4
-5
-6

f(x) = 2.0784862592x - 3.0255182697

-7
-8
-9
-10