Aiats Advanced-P1 2015 PDF

Test - 9 (Paper - I)_Code-A (Answers & Hints)
All India Aakash Test Series for JEE (Advanced) - 2015
All India Aakash Test Series for JEE (Advanced)-2015

Click here for Code-C Solution
Test Date : 12-04-2015
TEST - 9 (Paper-I) - Code-A

ANSWERS
PHYSICS
CHEMISTRY
MATHEMATICS
1.
(A, C)
21.
(C)
41.
(B, C)
2.
(A, C)
22.
(B)
42.
(A)
3.
(A, C)
23.
(A, B, C, D)
43.
(A, D)
4.
(A, C)
24.
(C, D)
44.
(A, B, C, D)
5.
(A, C)
25.
(A, C)
45.
(A, B, D)
6.
(B, C)
26.
(A, C)
46.
(A, D)
7.
(C, D)
27.
(A)
47.
(B, C, D)
8.
(B, D)
28.
(A, C)
48.
(B, C, D)
9.
(A, B, D)
29.
(A, B, C)
49.
(D)
10.
(B, C)
30.
(B, C)
50.
(B, C)
11.
(2)
31.
(5)
51.
(1)
12.
(5)
32.
(6)
52.
(6)
13.
(8)
33.
(5)
53.
(7)
14.
(2)
34.
(2)
54.
(4)
15.
(1)
35.
(8)
55.
(6)
16.
(1)
36.
(7)
56.
(1)
17.
(1)
37.
(3)
57.
(6)
18.
(9)
38.
(3)
58.
(5)
19.
(5)
39.
(5)
59.
(5)
20.
(4)
40.
(3)
60.
(4)
1/11
ANSWERS & HINTS

PART - I (PHYSICS)
1.
Answer (A, C)
3.
2
1 ml 2
1 ml 2 9 2 2
3l
m 2
ml
2 12
2 12 4
2
K total
Energy
The net field is zero at x =
Answer (A, C)
d
d
k dt
dt
2d
t
t 0
G(2M )m
kt
kt
0
2
2
dt
dt
4.
Answer (A, C)
0 k 40
2 0 k 2 80 0
2
0
k
12
2
k3
k
2 0
T( x )
2 3/2 2 3/2
2
0
3/2
0
0
3 k
k
2 0 k
2/11
k
2 0
3/2
0
0 .
k
3
M
G m
2
4r
3
1 GMm 1
9 GMm
5 GM
2
v
2 6 r 2 mv 8
r
2 3R
k
t
t
0 k
0 t
4 3
2
2 0
k
8
r
3
M
G m
1
2
mv 2
3r
2
G(2M )(m )
8r
3
k2 2
0
t 0 kt
4
infinity
Conservation of energy at (1) and equilibrium point
2
[ 0 ] t
k
and
2
1
8
x r
x
(4r x )
3
1 1
2 0
2
kt 2 0 kt t
1
k
1
2 0
(1)
M
G
1
2 4
As, G(2M )
x2
(4r x )2
x 2 (4r x )2
k dt
Again, [2 ] kt
0
at
13 GM
6
r
1
1
9
3l
KT mv 3 m ml 2
2
2
2
8
2.
conservation
M
G m
G(2M )m
1
2
mv 2 0
3r
2
r
7 2 2
ml
6
Answer (A, C)
m2 2
( l x 2 ) U ds
2l
A
2Y
m2 2
(l x 2 ) dx
0 2lA
m2 4l 3
.
15YA
1 stress2
A dx
Y

5.
11. Answer (2)
Answer (A, C)
I = I0sin2 dI = I0 2sincos.d
F sin
dI
2I0 sin cos
d
dI
1
100
100
2I0 sin cos
F cos
Area of PQ; A =
F
sin cos
A
Normal stress =
6.
A
sin
F cos
A / sin
Shear stress =
F sin F
sin2
A /sin A
Answer (B, C)
Energy conservation,
7
7
1
mv 02
mv 2 kx 2 0
10
10
2
7
dv k
dx
m 2v
2x
0
10
dt 2
dt
7 dv kx
0
5 dt m
5k
7m
7
1
7M
mv 02 kA2 A v 0
.
10
2
5k
Answer (C, D)
Gaussian surface can pass through continuous charge
distribution.
8.
Answer (B, D)

For equipotential surface, E ds .
9.
Answer (A, B, D)
10. Answer (B, C)

(I) The shortest path outside mud,
t=
PB BR
2 752 252 50 10 s
vg
(II) Straight path PACR, t
0.002 6
20 3
100
0.04 6 n 3
10 2
4 3
0.04 6
4 3 3 10 2
12. Answer (5)

During subsequent motion, separation increases.
13. Answer (8)
By decay through X only, N1
N0
1
N0
4
2
1
By decay through Y only, N2 N0
2
Again energy conservation,
7.
0.002
100
1 3
2 40

2 2 6
PA CR Al
1
v
25 2 2 50 2
1
50 2 1
1
v
v
For t t, vmin = 0.81 ms1.
1 1
1
By decay through both, N3 N2 T 2 N2
2
2
1 1
1
T1 4 6
hour
1 1 10
2
4 6
1
N3 N0
2
n = 8.
562
13
1
N0
2
14. Answer (2)
I
1
I I0 [2(1 cos )] 0 [1 cos c ]
2
4
I0
I
1
[1 1 sin2 c ] 0 1 1
2
2
2
I0
2
3 I0
1 1
4 2
1 I0 1
1 2 4 4 8
= 2 watt.
3/11
Cp = Cv + R = 4R
15. Answer (1)

1
1 E
H LI02 L
2
2 R1
r=
4
1
(3 103 ) 2 6 103
2
R1
34
R12
R1 1
26
16. Answer (1)
at watt
v
330
f
f
Hz
v
v
330 5
0
335
330 5
f
=325 325 =335 Hz
330
Beat frequency, f = f ~ f2 = 10 Hz.
17. Answer (1)

dQ = dU + PdV = d(a + bPV) + PdV = 0
PdV (b + 1) = bVdP
18. Answer (9)

At (1) (2)
loge V
b
loge P C
(b 1)
log (V )(P )1 b C
e
b
U = 2 + 3 RT
dU
3R Cv
dT
Cv = 3R
...(ii)
3 2 1 3 2
v
R1
R2
5 5 3 5 20 15 9 10
3 3 4 2 3
12 6
v1
10
10
10
10
5
1
1 1
52
7
10 12 60 24 60 120 120
2 5 = 2 10 h
10 10 = 20 h h = 5 meter.
20. Answer (4)
V3
constant
PV RT
1 b 1 3 4
b
3
3
...(i)
V3
P 2V 2
constant
P 2V constant PV
W dW
ALITER
U = 2 + 3PV
2 3 2
v
R2
At (1) + (2)
T2
(P )1 b V C1
constant
2A v = A 2gh
b
loge V
loge (P ) C
(b 1)
4/11
...(i)
19. Answer (5)
dV
b
dP
V
(b 1) P
1 b
b
4
3
3
7
180
v1
2v1 60
7 cm n = 9.
bPdV + bVdP + PdV = 0
PV
Cv
At (2) (3),
v v0
330 5
f1
f2 passenger = f1
330
v
Cp
2 1 2 1
2 1 2
v
4
R1
v
R1
f = 325 Hz
f1
600R
400R
3/2
n=4
1
2
constant
PV
R(T1 T2 )
1 1 P2V2
n 1
n 1
2R ( 300R )
1
1
2
PART - II (CHEMISTRY)
24. Answer (C, D)
21. Answer (C)

Let S1, S2 and S3 be the solubilies of MX, MX2 and M3X
respectively.
MX(S) M (aq) X (aq)
S1
S1
S1 =
K sp = (3.24 10 )
8 1/2
Ksp = 3.24 10 8
= 1.8 10 mol dm
= MX2(S) M (aq) 2X (aq)

S2
2S 2
K sp
S2 =
4
1/3
1.08 10
13
1
3
M3X(S) 3M (aq) X 3 (aq)

3S 3
S3
K sp
S3 =
27
1/4
4.32 10 14
27
Ksp = 1.08 10
13
Au3+ + 3e
+
Au +
Au + 2e
Au
Au+
G1 = 3F (1.50) = 4.50 F
G 2 = F (1.68) = 1.68 F
G 3 = 4.50F +1.68 F
2FE Au3 / Au = 2.82 F
= 3 105 mol dm3

Ksp = 4.32 1014
E Au 3 / Au = 1.41 V
2Fe 2 Au 3 2Fe 3 Au
= E Au 3 / Au E Fe 3 /Fe 2
E cell
1/4
= 2 104 mol dm
S3 > S1 > S2
RT
ln K = 1.41 0.77 = 0.64 V
2F
log K =
22. Answer (B)

Main hexagonal unit cell (Figure (A)) consists of three
identical smaller unit cells (Figure (B)). Lattice point
(I) of unit cell (B) is being shared by 6 unit cells and
lattice point (II) of unit cell (B) is being shared by 12
unit cells. Therefore, contributions of (I) and (II) per
unit cell are 1/6 and 1/12 respectively.
23. Answer (A, B, C, D)
H3C
H2C
HCl
CH2 +
Excess
CH3
+
Cl
I
(Meso)
Cl
Cl
+
Cl
CH3
0.64 2
22 ;
0.0591
K = 1022
Since E cell
is positive, the reaction is spontaneous.
25. Answer (A, C)

If PB and PB are the vapour pressures of pure solvent
and that of solution respectively, then
PB PB = 171 mm of Hg.
At the boiling point of solvent, PB = 760 mm Hg
Cl
H3C
3+
Au
H3C
Geometrical isomers
II
: I and II or III
III
Optical isomers
: I, II and III
Enantiomers
: II and III
Diastereisomers
: I and II; I and III
PB PB
PB
= XA
171
= XA ; XA = 0.225
760
CH3
Cl
Mole fraction of solute in solution = 0.225

Number of moles of solute in solution = 0.225 4 = 0.9
Number of moles of solvent in solution = 3.1
26. Answer (A, C)
P4O6 can show Lewis base character due to the
availability of lone pair of electrons on each P-atom.
The P O single bond length in P4O10 will be shorter
on account of partial double bond character due to
resonance.
5/11

27. Answer (A)

31. Answer (5)
P = KT3
...(1)
Fraction of molecules possessing energy equal to or
For an adiabatic process, PV = K'
greater than threshold energy = e
nRT
1
or, P
= K' ; P T = K";
P
P = K '''(T)
...(2)
From (1) and (2),
Cp
Cv
= e
3
= 3; =
1
2
18.424 10 3
8 10 3
e 2.303 0.1
Total number of molecules = 50

Number of molecules crossing over the energy barrier
= 0.1 50 = 5
32. Answer (6)
3
2
Binding energy of electrons in a metal = 250 103J
28. Answer (A, C)

Binding energy of one electron =
29. Answer (A, B, C)
Ag
CHCl3
HC
CH
h 0 =
Red hot
Fe tube
(Q)
(P)
O
C
H3C
N
H
CH3
b=
H
150C
COOH
C
C
6.023 6.627 10 34
6 10 14 sec 1
Pb
RT
atm 1
=
RT
492.6
RT
0.0821 300 10 3 3
m mol 1
492.6
492.6
= 5 10 4 m 3 mol 1
O
C
O
(X)
30. Answer (B, C)
25 10 19
Slope of a plot of Z vs P =
(R)
COOH
25 10 19
6.023
O
H
6.023 10 23
At very high pressure of a real gas, Z = 1
HCl(g)
250 10 3
33. Answer (5)
CH
CH
0 =
(NH4)2CO3
CH3 C CH2 CH2 C CH3
Ea
RT
4 3
r 6 10 23 5 10 4 m 3 mol 1 ;
3
r = 2.5 1010m = 2.5 A
Diameter = 5 A .
34. Answer (2)

Tf = iK f m
Methyl ketones of the type CH3 C R give positive
0.00558 = i 1.86 0.001;
haloform test and also form solid bisulphite addition

product. On the contrary ketones having two bulky
alkyl groups attached to carbonyl group do not give
both these tests.
The given complex has two chloride ions in the

ionisation sphere and its molecular formula is
[Pt(NH3)4Cl2] Cl2.
6/11
i=3
35. Answer (8)
CH2OH
H H
HO
CH2OH
OH
OH
H H
O
Moles of O2 formed in step (ii) =
OH
OH
Total moles of O2 formed =
OH
x
8
x x 5x

2 8
8
5x 60
; x = 3.
8
32
The structure of maltose is given above. One mole of

maltose has 8 moles of OH group. So, 8 moles of
acetyl chloride are needed to acetylate 1 mole of
maltose.
38. Answer (3)

Strontium, barium and radium have densities greater
than beryllium.
39. Answer (5)
36. Answer (7)

Hydrocarbon having molecular weight 70 which gives
only one monochloride is cyclopentane. Dichlorination
of cyclopentane gives.
Cl
Cl
H
Cl
Cl
Cl
Cl
+
S O CH CH CH3
CH3
Cl
+ 2Cl2
CH3
Cl
CH3
OAc CH3
CH3
CH3 CH CH CH3 + CH3 CH2 C CH3
Cl
Cl
OAc
+ CH2
CH CH CH3 + CH3 CH
CH3
CH3
37. Answer (3)

Let the moles of KClO3 required be x. Assuming 50%
yield in each step.
Moles of O2 formed in step (i) =
AcOH
75C
(SN1+E1)
x
2
CH 3
C CH3 + CH3 CH2 C
CH2
40. Answer (3)

The pH at isoelectric point of the given amino acid is
given by
Moles of each of K2 MnO4 and Cl2 formed in (i) =
x
4
p1 =
pK a1 pK a 2
2
24
=3
2
PART - III (MATHEMATICS)

41. Answer (B, C)
x=
b b 2 4ac
2c
42. Answer (A)

2
b
4ac b
i
2c
2c
b
4ac b2
i
2c
2c
(x ) (x ) + (y ') (y ')= 0
+ '' = 0
c c
0
a a
43. Answer (A, D)
Clearly | | = | |
1
1
|| || =
a <2
c
2.2c
( b 2 4 ac b 2 )
4.c
2 ac
k
3 sin x sin3 x
=
3sinx.cos2x sin3x = k
cos x cos3 x
cos3 x
3sinx(1 sin2x) sin3x = k
7/11
3sinx 4sin3x = k
sin3x = k
Consider three terms
sin3B = sin3C
A. M G. M
3B = 3C or
either B + C =
; clearly, A =
3
3

(C) P = (first 49 are non-red). (50th is red)
100 r
100
C49
C49
16 x22 x12
,
,
x12 2 x22
r
100 r 50. r
.
51 = 51 r 100
(D) Required Probability =
1
100
Cr
100 r ! r !
100 !
16 x2
2
x12
3
16
x12
2
x12
x22
16 x 2 x 2 3
2 s 2 12
2 x2
x1
x22 x12
2 6
2
x2
4 x 5 x 1
x 13
x 4 x 2
45. Answer (A, B, D)

Let P(x) = ax3 + bx2 + cx + d
1
P x dx =
ax 4 bx 3 cx 2
dx
4
3
2
a b c
a b c
= d d
4 3 2
4 3 2
2b
2d
3
2b
2d = a(x13 + x23) + b(x12 + x22) + c(x1 + x2) + 2d
3
2
Comparing the terms x13 + x23 = 0, x12 + x22 = ,
3
x1 + x2 = 0
46. Answer (A, D)
(2 n)x2 8x (n + 4) < 0
2n<0n>2
D<0
Integral value of x {1, 1}

wn = u2n +1 u2n
= (un +1 un) (un + 1 + un)
= d . (un + 1 + un)
where d is the common difference of the sequence
< un >
Clearly sum of two A.P' s is an A.P'
47. Answer (B, C, D)
g (f (x)) = sgn (x) (1 (sgn x)2) = 0xR
gof (x) = 0
fog (x) = sgn x(1x2)
= sgn x(1x) (1+x)
fog (x) =
B4 + 4(2 n) (n + 4) < 0
16 (n2 + 2n 8) < 0
1 x(, 1) (0, 1)
x(1x) (1+x) > 0
n2 2n + 24 < 0
n2 + 2n 24 > 0
0 x = 0, 1, 1
(n + 6) (n 4) > 0
n > 4 smallest n is 5
8/11
1 x(1, 0) (1, )

48. Answer (B, C, D)

51. Answer (1)
45
5
7
2
d=
5
2
A1 = 5
7 17
2 2
A2 = 12
A3 = 12 +
(3,0)
f (x) =
(2,0)
(2,0) (1,0)
7 31
=
2 2
(1,0)
(3,0)
A4 = 19
5
5
A1 2 , A2 , A3 2 (6, 12, 18)
A2 , A3 2 , A4 8 (12, 18, 27) G.P.
A4 1, A2 , A1 2 = (18, 12, 8) G.P.
49. Answer (D)
Apply Leibnitz rule, xlim

0
cos t
lim x . sin x
= x 0
2 2cos 2 x
dt
x = 1, y = 2, z = 3
53. Answer (7)
E = nlim
sin x
1
x
= .
4 2 1 cos 2 x
2x 2
3 x 2y 3z 8
3 2 3 x 8
2 1 1 y 1 2 x y z 1
=
4 x 3 y 2z 4
4 3 2 z 4
On solving
2 x sin 2 x
So, only one extrema

52. Answer (6)
3
3
A1 2 , A3 2 , A4 9 = (7, 14, 28) G.P.
cos x
g (x) has extrema at x = 2
50. Answer (B, C)
x x 1 1 x
= nlim
n
n
2
2
( x 1 x x 1 x x x )dx
1 dx
= nlim
2
2
n
n
( x 1 x 1 x x x x )dx
= nlim
(x
4
9
=n
lim
1
=
4
k 1
1 x n 1
dx
x 1 x
= nlim

x
1
1
1 1
. . 2 1
4 2
Sk
= nlim
x
0
n2
1 2 x 1 x x 2 x )dx
x n 1 x 2 x dx
lim 1 1 1 1 1
=n
=
n 3 n 1 3 2 6
9/11
54. Answer (4)

7 sin3x 2(3 sin3x 4 sin33x) = 9 + (tan 2 cot)2
cos 30 =
2r
OD
OA =
OA
3
(sin3x + 8 sin3x) = 9 + (tan 2 cot)2

Only possibility is
sin3x = 1 and tan 2 cot = 0
3x =
x=
1
r
R=
+ r = 2 1
3
R
3
2r
3
,
2 2
(a + b + c)min = 6

,
6 2
58. Answer (5)
6
2
, = 6 = 4
6 2
3
Let E =
2 1
1
1
1
x
x
2 2 22 dx
55. Answer (6)
A1
An
x3 1
1 x2 1
1
E = 3 2 2 2 2 2 x

(2, 3)
(x0, y0)
7 7
,
2 2
x0 2
2
E =3
7
x0 = 5
2
3 1
1
3
3
2 2 2 2
2
3 2
3
3
2 2
2 2
2
= 3
y0 3
7
= y0 = 4
2
2
3 t 4 4t 3
3
3
2
=
2
2 4t 4t
2t
x0 + y0 3 = 6
56. Answer (1)
A3+2A2 11A 12I = 0
(where + = t2, = 2t)
12A1 = A2+2A 11I
1
So, 2014x + y + z 166 = 1
2
3 t 2 1 3
3
3 t2 1
3

=
2 4 t 4t 2 2t =
4 2 t 2
57. Answer (6)

2
= 3
C
r
r
3
r
A
3 t
1
3
1
3
.2.
Emin 3
2
4 2 t
4
4
2
30
r D r
9
8
B
a + b + c = 20
10/11
abc
=5
4
59. Answer (5)

f' (x) = f (x) +
3
1
ABC =
2
0
x
0
2 2
5 b
[3 5 1]
x 2 1
Let f (x) = y
dy
1
y = lnx
dx
x
bx 3
=
[3 5 1]
4 x 2
24
9b 9
=
12 x 2
which is L.D.E.
x 1
y.ex = e ln x dx
x
bx 3
4 x 2
40
5bx 15
20 5 x 2
y.ex = ex lnx + k
f (x).ex = ex ln(x) + k
at x = 1, f (1) = e, k = 1
tr (ABC) = 24 + 5bx 15 4 x2
f (x) = lnx + ex
x2 + 5bx 35 18
g (x) = x(lnx + ex ex)
x2 + 5bx 25 0 and D 0
g (x) = x lnx
25b2 4(1) (25) 0
25b2 100 0
I = x ln x dx
b [2, 2]
f (x) = e + (1 x) (lnx 1) + f t dt
f (1) = e
1 x2
. dx
x 2
0
2
2
lim x ln x x
I = x 0
2
4
1 x
II
x2
ln x
I=
2
60. Answer (4)
f' (x) = (lnx 1) +
1
lnx
x
A=
+ f (x)
=0
0
1
1
=
4
4
1
A1 = 4
4
11/11
Test - 9 (Paper - I)_Code-C (Answers & Hints)
All India Aakash Test Series for JEE (Advanced)-2015

Click here for Code-A Solution
Test Date : 12-04-2015
TEST - 9 (Paper-I) - Code-C

ANSWERS
PHYSICS
CHEMISTRY
MATHEMATICS
1.
(B, C)
21.
(B, C)
41.
(B, C)
2.
(A, B, D)
22.
(A, B, C)
42.
(D)
3.
(B, D)
23.
(A, C)
43.
(B, C, D)
4.
(C, D)
24.
(A)
44.
(B, C, D)
5.
(B, C)
25.
(A, C)
45.
(A, D)
6.
(A, C)
26.
(A, C)
46.
(A, B, D)
7.
(A, C)
27.
(C, D)
47.
(A, B, C, D)
8.
(A, C)
28.
(A, B, C, D)
48.
(A, D)
9.
(A, C)
29.
(B)
49.
(A)
10.
(A, C)
30.
(C)
50.
(B, C)
11.
(4)
31.
(3)
51.
(4)
12.
(5)
32.
(5)
52.
(5)
13.
(9)
33.
(3)
53.
(5)
14.
(1)
34.
(3)
54.
(6)
15.
(1)
35.
(7)
55.
(1)
16.
(1)
36.
(8)
56.
(6)
17.
(2)
37.
(2)
57.
(4)
18.
(8)
38.
(5)
58.
(7)
19.
(5)
39.
(6)
59.
(6)
20.
(2)
40.
(5)
60.
(1)
1/11
ANSWERS & HINTS

PART - I (PHYSICS)
1.
Answer (B, C)
(I) The shortest path outside mud,
t=
PB BR
2 752 252 50 10 s
vg
PA CR Al
(II) Straight path PACR, t

1
v
Normal stress =
7.
T( x )
25 2 2 50 2
1
50 2 1
1
v
v
1
For t t, vmin = 0.81 ms .
Answer (A, B, D)
3.
Answer (B, D)

For equipotential surface, E ds .
4.
Answer (C, D)
Gaussian surface can pass through continuous charge
distribution.
5.
Answer (B, C)
7
7
1
mv 02
mv 2 kx 2 0
10
10
2
Energy conservation,
m2 2
( l x 2 ) U ds
2l
A
2Y
m2 4l 3
.
15YA
Answer (A, C)
U
8.
Energy
conservation
G(2M )m
The net field is zero at x =
Answer (A, C)
F sin
P
A
Q
F cos
Area of PQ; A =
Shear stress =
2/11
A
sin
F cos
A / sin
and
infinity
8
r
3
M
G
1
2 4
As, G(2M )
x2
(4r x )2
x 2 (4r x )2
2
1
8
x r
x
(4r x )
3
Conservation of energy at (1) and equilibrium point
G(2M )m
(1)
13 GM
6
r
7 dv kx
0
5 dt m
7
1
7M
mv 02 kA2 A v 0
.
10
2
5k
at
M
G m
2 1 mv 2 0
3r
2
5k
7m
1 stress2
A dx
2
Y
m2 2
(l x 2 ) dx
0 2lA
7
dv k
dx
m 2v
2x
0
10
dt 2
dt
Again energy conservation,
6.
F sin F
sin2
A /sin A
Answer (A, C)
2.
F
sin cos
A
M
G m
1
2
mv 2
3r
2
M
G m
G(2M )(m )
2

8r
4r
3
3
1 GMm 1
9 GMm
5 GM
2
v
2 6 r 2 mv 8
r
2 3R

9.
Answer (A, C)
0
0
11. Answer (4)
d
d
k dt
dt
2
d
t
t 0
V3
T2
constant
PV RT
k dt
...(i)
V3
P 2V 2
constant
P 2V constant PV
1 1
2 0
2
kt 2 0 kt t
1
k
1
2 0
Again, [2 ] kt
0
2
[ 0 ] t
k
kt
kt
0
2
2
W dW
1
2
constant
PV
R(T1 T2 )
1 1 P2V2
n 1
n 1
2R ( 300R )
1
1
2
600R
400R
3/2
n=4
12. Answer (5)
k2 2
0
t 0 kt
4
k
k2 t3
t2
dt
t
k
0
4 3
2
dt 2 0
0 k 40
2 0 k 2 80 0
2
0
3
k
12
2
k
k
2 0
k
2 3/2 2 3/2
2
0
3/2
0
0
3 k
k
2 0 k
k
2 0
1 ml 2
3l
m
2 12
2
2 5 = 2 10 h
10 10 = 20 h h = 5 meter.
13. Answer (9)
At (1) (2)
2 1 2 1
2 1 2
v
4
R1
v
R1
...(i)
At (2) (3),
3
v
3/2
0
0 .
k
3
2 3 2
v
R2
...(ii)
At (1) + (2)
10. Answer (A, C)

K total
2A v = A 2gh
1 ml 2 9 2 2
ml
2
2 12 4
7 2 2
ml
6
3 2 1 3 2
v
R1
R2
5 5 3 5 20 15 9 10
3 3 4 2 3
12 6
v1
10
10
10
10
1
1
9
3l
KT mv 3 m ml 2
2
2
2
8
5
1
1 1
52
7
10 12 60 24 60 120 120
3
7
180
v1
2v1 60
7 cm n = 9.
3/11

14. Answer (1)

16. Answer (1)
dQ = dU + PdV = d(a + bPV) + PdV = 0

H
bPdV + bVdP + PdV = 0

PdV (b + 1) = bVdP
dV
b
dP
V
(b 1) P
loge V
loge V
b
loge P C
(b 1)
b
loge (P ) C
(b 1)
b
log (V )(P )1 b C
e
b
1
(P ) b
PV
1 b
b
V C1
constant
1 b 1 3 4
b
3
3
1 2 1 E
LI0 L
2
2 R1
4
1
(3 103 ) 2 6 103
2
R1
R12
34
R1 1
26
17. Answer (2)

I
1
I I0 [2(1 cos )] 0 [1 cos c ]
2
4
I0
I
1
[1 1 sin2 c ] 0 1 1
2
2
2
I0
2
3 I0 1 I0 1
1 1 1 8
4 2 2 4 4
= 2 watt.
18. Answer (8)
ALITER
U = 2 + 3PV
U = 2 + 3 RT
dU
3R Cv
dT
Cv = 3R
N
1
By decay through X only, N1 0 N0
4
2
1
By decay through Y only, N2 N0
2
Cp = Cv + R = 4R
Cp
r=
Cv 3
1 1
1
By decay through both, N3 N2 T 2 N2
2

2
15. Answer (1)

f = 325 Hz
f1
at watt
v
330
f
f
Hz
330 5
v v0
v v0
330 5
f1
f2 passenger = f1
330
v
335
330 5
f
=325
=335 Hz
325
330 5
Beat frequency, f = f ~ f2 = 10 Hz.
4/11
1 1
4
6 1 hour
T1
1 1 10
2
4 6
1
N3 N0
2
562
13
1
N0
2
n = 8.
19. Answer (5)
During subsequent motion, separation increases.
20. Answer (2)

I = I0sin2 dI = I0 2sincos.d
dI
2I0 sin cos
d
dI
1
100
100
2I0 sin cos
0.002 6
100
20 3
0.04 6 n 3
10 2
4 3
0.002
100
1 3
2 40

2 2 6
0.04 6
4 3 3 10 2
PART - II (CHEMISTRY)
21. Answer (B, C)
24. Answer (A)

P = KT3
O
Methyl ketones of the type CH3 C R give positive
haloform test and also form solid bisulphite addition
product. On the contrary ketones having two bulky
alkyl groups attached to carbonyl group do not give
both these tests.
22. Answer (A, B, C)
Ag
CHCl3
HC
CH
Red hot
Fe tube
CH3 C CH2 CH2 C CH3
C
H3C
CH
N
H
O
H
H
H
C
C
...(2)
3
= 3; =
1
2
(R)
P4O6 can show Lewis base character due to the

availability of lone pair of electrons on each P-atom.
The P O single bond length in P4O10 will be shorter
on account of partial double bond character due to
resonance.
26. Answer (A, C)
If PB and PB are the vapour pressures of pure solvent
and that of solution respectively, then
PB PB = 171 mm of Hg.
H
150C
H
C
C
At the boiling point of solvent, PB = 760 mm Hg
PB PB
O
C
O
(X)
23. Answer (A, C)
CH3
COOH
COOH
HCl(g)
P = K '''(T)
25. Answer (A, C)
(NH4)2CO3
CH
nRT
1
or, P
= K' ; P T = K";
P
Cp 3
= C 2
v
(Q)
O
For an adiabatic process, PV = K'
From (1) and (2),
(P)
O
...(1)
PB
= XA
171
= XA ; XA = 0.225
760
Mole fraction of solute in solution = 0.225
Number of moles of solute in solution = 0.225 4 = 0.9
Number of moles of solvent in solution = 3.1
5/11

27. Answer (C, D)
3+
Au + 3e
+
Au +
30. Answer (C)

Let S1, S2 and S3 be the solubilies of MX, MX2 and M3X
respectively.
Au
Au
Au + 2e
Au
3+
MX(S) M (aq) X (aq)

S1
S1
G1 = 3F (1.50) = 4.50 F
Ksp = 3.24 10 8
K sp = (3.24 108)1/2 = 1.8 104 mol dm3
G 2 = F (1.68) = 1.68 F
S1 =
G 3 = 4.50F +1.68 F
= MX2(S) M 2 (aq) 2X (aq)

S2
2S 2
2FE Au3 / Au = 2.82 F
K sp
S2 =
4
E Au 3 / Au = 1.41 V
2Fe 2 Au 3 2Fe 3 Au
RT
ln K = 1.41 0.77 = 0.64 V
2F
0.64 2
22 ;
0.0591
K sp
S3 =
27
K = 1022
H3C
H2C
HCl
CH2 +
Excess
1/ 4
4.32 10 14
27
Ksp = 4.32 1014
1/ 4
= 2 104 mol dm 3
CH3
+
Cl
Cl
Cl
Cl
H3C
Geometrical isomers
CH3
II
: I and II or III
Optical isomers
: I, II and III
Enantiomers
: II and III
Diastereisomers
: I and II; I and III
p1 =
pK a1 pK a 2
2
24
=3
2
32. Answer (5)
I
(Meso)
Cl
31. Answer (3)

The pH at isoelectric point of the given amino acid is
given by
CH3
CH3
S O CH CH CH3
CH3
Cl
Main hexagonal unit cell (Figure (A)) consists of three

identical smaller unit cells (Figure (B)). Lattice point
(I) of unit cell (B) is being shared by 6 unit cells and
lattice point (II) of unit cell (B) is being shared by 12
unit cells. Therefore, contributions of (I) and (II) per
unit cell are 1/6 and 1/12 respectively.
CH3
OAc CH3
III
AcOH
75C
(SN1+E1)
CH3
CH3 CH CH CH3 + CH3 CH2 C CH3

OAc
+ CH2
CH CH CH3 + CH3 CH
CH3
29. Answer (B)
6/11
3
= 3 105 mol dm3
S3 > S1 > S2
Since E cell
is positive, the reaction is spontaneous.
H3C
1.08 10 13
M3X(S) 3M (aq) X 3 (aq)

3S 3
S3
= E Au 3 / Au E Fe 3 /Fe 2
E cell
log K =
1/3
Ksp = 1.08 1013
CH3
CH 3
C CH3 + CH3 CH2 C
CH2
33. Answer (3)

Strontium, barium and radium have densities greater
than beryllium.
34. Answer (3)
38. Answer (5)
Let the moles of KClO3 required be x. Assuming 50%

yield in each step.
Moles of O2 formed in step (i) =
x
2
x
Moles of each of K2 MnO4 and Cl2 formed in (i) =
4
Moles of O2 formed in step (ii) =

Total moles of O2 formed =
At very high pressure of a real gas, Z = 1
x
8
Slope of a plot of Z vs P =
b=
x x 5x

2 8
8
Pb
RT
atm 1
=
RT
492.6
RT
0.0821 300 10 3 3
m mol 1
492.6
492.6
= 5 10 4 m 3 mol 1
5x 60
; x = 3.
8
32
4 3
r 6 10 23 5 10 4 m 3 mol 1 ;
3
35. Answer (7)

Hydrocarbon having molecular weight 70 which gives
only one monochloride is cyclopentane. Dichlorination
of cyclopentane gives.
Cl
Cl
+ 2Cl2
Cl
Cl
Cl
Cl
Cl
Cl
Cl
+
Binding energy of electrons in a metal = 250 103J
h 0 =
CH2OH
HO
Binding energy of one electron =
Cl
36. Answer (8)
H H
Diameter = 5 A .
39. Answer (6)
r = 2.5 1010m = 2.5 A
OH
OH
CH2OH
H
H H
O
OH
OH
0 =
OH
The structure of maltose is given above. One mole of

maltose has 8 moles of OH group. So, 8 moles of
acetyl chloride are needed to acetylate 1 mole of
maltose.
0.00558 = i 1.86 0.001;
The given complex has two chloride ions in the

ionisation sphere and its molecular formula is
[Pt(NH3)4Cl2] Cl2.
25 10 19
6.023
25 10 19
6.023 6.627 10
34
6 10 14 sec 1
Fraction of molecules possessing energy equal to or

greater than threshold energy = e
= e
i=3
6.023 10 23
40. Answer (5)
37. Answer (2)

Tf = iK f m
250 10 3
Ea
RT
18.424 10 3
8 10 3
e 2.303 0.1
Total number of molecules = 50

Number of molecules crossing over the energy barrier
= 0.1 50 = 5
7/11
PART - III (MATHEMATICS)

41. Answer (B, C)
3
3
A1 2 , A3 2 , A4 9 = (7, 14, 28) G.P.
44. Answer: (B, C, D)
4
1
g (f (x)) = sgn (x) (1 (sgn x)2) = 0xR

gof (x) = 0
4
9
fog (x) = sgn x(1x2)
= sgn x(1x) (1+x)

fog (x) =
1 x(, 1) (0, 1)
x(1x) (1+x) > 0
42. Answer (D)
Apply Leibnitz rule, xlim

0
cos x
cos t
0 x = 0, 1, 1
2 x sin 2 x
lim x . sin x
2 2cos 2 x
x 0
sin x
1
x
= .
4 2 1 cos 2 x
2x 2
1 1
. . 2 1
4 2
1
=
4
43. Answer: (B, C, D)
45
5
7
2
d=
5
2
A1 = 5
7 17
2 2
7 31
=
2 2
A4 = 19
5
5
A1 2 , A2 , A3 2 (6, 12, 18)
A2 , A3 2 , A4 8 (12, 18, 27) G.P.
A4 1, A2 , A1 2 = (18, 12, 8) G.P.
8/11
1 x(1, 0) (1, )
45. Answer (A, D)

(2 n)x2 8x (n + 4) < 0
2n<0n>2
D<0
B4 + 4(2 n) (n + 4) < 0
16 (n2 + 2n 8) < 0
n2 2n + 24 < 0
n2 + 2n 24 > 0
(n + 6) (n 4) > 0
n > 4 smallest n is 5
Consider three terms
16 x22 x12
,
,
x12 2 x22
A. M G. M
A2 = 12
A3 = 12 +
dt
16 x22 x12 3
16 x22 x12
2 s
2 x22
2
x12
x22
x1
3
16
x12
2
x22 x12
2 6
2
x2
4 x 5 x 1
x 4 x 2
x 13

49. Answer (A)
(x ) (x ) + (y ') (y ')= 0
1
0
1
Integral value of x {1, 1}
wn = u2n +1 u2n
+ '' = 0
c c
0
a a
50. Answer (B, C)
= (un +1 un) (un + 1 + un)

= d . (un + 1 + un)
x=
where d is the common difference of the sequence

< un >
Clearly sum of two A.P' s is an A.P'
b b2 4ac
2c
b
4ac b2
i
2c
2c
b
4ac b2
i
2c
2c
46. Answer (A, B, D)

3
Let P(x) = ax + bx + cx + d
1
ax 4 bx 3 cx 2
P
x
dx
dx
4
3
2
1
Clearly | | = | |
1
1
|| || =
a b c
a b c
= d d
4 3 2
4 3 2
( b 4 ac b )
2b
2d = a(x13 + x23) + b(x12 + x22) + c(x1 + x2) + 2d
3
2
Comparing the terms x13 + x23 = 0, x12 + x22 = ,
3
x1 + x2 = 0
2 ac
a <2
c
x
f (x) = e + (1 x) (lnx 1) + f t dt
1
f (1) = e
f' (x) = (lnx 1) +
1 x
(C) P = (first 49 are non-red). (50th is red)

100 r
100
4.c
51. Answer (4)
2b
2d
=
3
2.2c
2
C49
C49
r
100 r 50. r
.
51 = 51 r 100
(D) Required Probability =
1
100
Cr
100 r ! r !
100 !
48. Answer (A, D)
k
3 sin x sin3 x
=
3sinx.cos2x sin3x = k
cos x cos3 x
cos3 x
f' (x) = f (x) +
1
lnx
x
Let f (x) = y
dy
1
y = lnx
dx
x
which is L.D.E.
3sinx(1 sin x) sin x = k
x 1
y.ex = e ln x dx
x
3sinx 4sin3x = k
y.ex = ex lnx + k
sin3x = k
f (x).ex = ex ln(x) + k
sin3B = sin3C
at x = 1, f (1) = e, k = 1
3B = 3C or
either B + C =
; clearly, A =
3
3
+ f (x)
f (x) = lnx + ex
g (x) = x(lnx + ex ex)
9/11
g (x) = x lnx
1
I = x ln x dx
0
II
x2
ln x
I=
2
3 t 4 4t 3
3
3
2
=
2
2 4t 4t
2t
1 x2
. dx
x 2
0
2
2
lim x ln x x
I = x 0
2
4
A=
3 2
3
3
2 2
2
2 2

2
= 3
(where + = t2, = 2t)
=0
0
1
1
=
4
4
3 t 2 1 3
3
3 t2 1
= 3 2 4 t 2 2t = 3 4 2 2
t
4t
1
A1 = 4
4
= 3
52. Answer (5)

3
1
ABC =
2
0
x
0
2 2
5 b
[3 5 1]
x 2 1
40
5bx 15
20 5 x 2
9
8
a + b + c = 20
bx 3
=
[3 5 1]
4 x 2
24
9b 9
=
12 x 2
3 t
1
3
1
3
.2.
Emin 3
2
4 2 t
4
4
2
abc
=5
4
54. Answer (6)
C
r
bx 3
4 x 2
30
r D r
tr (ABC) = 24 + 5bx 15 4 x2
r
B
x2 + 5bx 35 18
x2 + 5bx 25 0 and D 0
25b2 4(1) (25) 0
25b2 100 0
cos 30 =
b [2, 2]
53. Answer (5)
Let E =
1
r
R=
+ r = 2 1
3
R
3
2r
1
1
1
1
2 2 x 2 2
dx

(a + b + c)min = 6
2
x3 1
1 x2 1
1
2 2
x
E= 3 2
2
1
E =3
10/11
3 1
1
3
3
2 2 2 2
2
2r
OD
OA =
OA
3
55. Answer (1)

A3+2A2 11A 12I = 0
12A1 = A2+2A 11I
So, 2014x +
1
y + z 166 = 1
2
56. Answer (6)
A1
An
(2, 3)
(x0, y0)
7 7
,
2 2
x0 2
2
7
x0 = 5
2
y0 3
7
= y0 = 4
2
2
= nlim
2
2
n
n
( x 1 x 1 x x x x )dx
= nlim
(x
= nlim
n2
1 2 x 1 x x 2 x )dx
x n 1 x 2 x dx
59. Answer (6)
57. Answer (4)
3 x 2y 3z 8
3 2 3 x 8
2 1 1 y 1 2 x y z 1
=
4 3 2 z 4
4 x 3 y 2z 4
7 sin3x 2(3 sin3x 4 sin33x) = 9 + (tan 2 cot)2

(sin3x + 8 sin3x) = 9 + (tan 2 cot)2
Only possibility is
On solving
sin3x = 1 and tan 2 cot = 0
x = 1, y = 2, z = 3
3
3x = ,
2 2
n
n
2
2
( x 1 x x 1 x x x )dx
lim 1 1 1 1 1
=n
=
n 3 n 1 3 2 6
x0 + y0 3 = 6
x=
= nlim
60. Answer (1)

,
6 2
6
2
,
= 6 = 4
6 2
3
58. Answer (7)

E = nlim
f (x) =
Sk
(3,0)
(2,0) (1,0)
(2,0)
(1,0)
(3,0)
k 1
1 x n 1
dx
x 1 x
= nlim

x
1
1
lim
=n
g (x) has extrema at x = 2
x x 1 1 x 1 dx
0
So, only one extrema
11/11

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Test - 9 (Paper - I)_Code-A (Answers & Hints)

All India Aakash Test Series for JEE (Advanced) - 2015

All India Aakash Test Series for JEE (Advanced)-2015

TEST - 9 (Paper-I) - Code-A

All India Aakash Test Series for JEE (Advanced) - 2015

Test - 9 (Paper - I)_Code-A (Answers & Hints)

ANSWERS & HINTS

The net field is zero at x =

Conservation of energy at (1) and equilibrium point

Test - 9 (Paper - I)_Code-A (Answers & Hints)

11. Answer (2)

All India Aakash Test Series for JEE (Advanced) - 2015

10. Answer (B, C)

(II) Straight path PACR, t

12. Answer (5)

Again energy conservation,

For t t, vmin = 0.81 ms1.

14. Answer (2)

All India Aakash Test Series for JEE (Advanced) - 2015

15. Answer (1)

Beat frequency, f = f ~ f2 = 10 Hz.

17. Answer (1)

18. Answer (9)

19. Answer (5)

bPdV + bVdP + PdV = 0

Test - 9 (Paper - I)_Code-A (Answers & Hints)

Test - 9 (Paper - I)_Code-A (Answers & Hints)

All India Aakash Test Series for JEE (Advanced) - 2015

21. Answer (C)

= MX2(S) M (aq) 2X (aq)

M3X(S) 3M (aq) X 3 (aq)

= 3 105 mol dm3

22. Answer (B)

25. Answer (A, C)

: I and II; I and III

Mole fraction of solute in solution = 0.225

All India Aakash Test Series for JEE (Advanced) - 2015

Test - 9 (Paper - I)_Code-A (Answers & Hints)

Fraction of molecules possessing energy equal to or

For an adiabatic process, PV = K'

greater than threshold energy = e

From (1) and (2),

Total number of molecules = 50

Binding energy of electrons in a metal = 250 103J

28. Answer (A, C)

30. Answer (B, C)

At very high pressure of a real gas, Z = 1

33. Answer (5)

CH3 C CH2 CH2 C CH3

r = 2.5 1010m = 2.5 A

34. Answer (2)

Methyl ketones of the type CH3 C R give positive

0.00558 = i 1.86 0.001;

haloform test and also form solid bisulphite addition

The given complex has two chloride ions in the

Test - 9 (Paper - I)_Code-A (Answers & Hints)

All India Aakash Test Series for JEE (Advanced) - 2015

35. Answer (8)

Moles of O2 formed in step (ii) =

Total moles of O2 formed =

The structure of maltose is given above. One mole of

38. Answer (3)

36. Answer (7)