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Contents
1 Development of the Periodic Table
3 Electron Configurations
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References
References of these notes
General Chemistry, 10th ed, by Ralph H. Petrucci, F. Geoffrey Herring,
Jeffry D. Madura, and Carey Bisonnette.
Property
Atomic mass
Density, g/cm3
Molar volume, cm3 /mol
Specific heat capacity, J/g-K
Color
Density of oxide, g/cm3
Boiling point of chloride
Chloride density, g/cm3
Predicted
Eka-silicon
72
5.5
13
0.31
dirty gray
EsO2 , 4.7
EsCl4 , below 1000 C
EsCl4 , 1.9
Observed
Germanium
72.6
5.47
13.22
0.32
grayish white
GeO2 , 4.703
GeCl4 , 860 C
GeCl4 , 1.887
en.wikipedia.org/wiki/File:Medeleeff by repin.jpg
Properties of Germanium
Three elements predicted by Mendeleev were discovered shortly after the
appearance of his 1871 periodic tablegallium (1875), scandium (1879), and
germanium (1886).
3s
3p
3d
3d
4s
3p
2s
2p
Energy
Energy
3s
1s
2p
2s
1s
Klechkovski Rule
en.wikipedia.org/wiki/File:Klechkovski rule.svg
Hunds Rule
Hunds Rule states that for degenerate orbitals, the lowest energy is
attained when the number of electrons with the same spin is maximized.
also called Hunds Rule of Maximum Multiplicity.
Since electrons repel each other, the electrons attain the lowest energy
level by staying as far apart from each other by staying in different
sub-orbitals.
Orbital Energy Diagram
Hydrogen atom
4s
3s
3p
3d
3d
4s
3p
2s
2p
Energy
Energy
3s
1s
2p
2s
1s
correct
a.
1s
2s
2p
correct
b.
1s
2s
2p
c.
incorrect
1s
2s
2p
correct
d.
1s
2s
2p
commons.wikimedia.org/wiki/File:Hund%27s Rule.svg
3 Electron Configurations
Examples
Symbol
Li
Be
B
C
N
O
F
Ne
Ge
Au
# e
3
4
5
6
7
8
9
10
32
79
Electron configuration
1s2 2s1
1s2 2s2
1s2 2s2 2p1
1s2 2s2 2p2
1s2 2s2 2p3
1s2 2s2 2p4
1s2 2s2 2p5
1s2 2s2 2p6
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p2
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4 f 14 5d9
Group
Period
10
11
12
13
14
15
16
17
18
1
H
2
He
3
Li
4
Be
5
B
6
C
7
N
8
O
9
F
10
Ne
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
55
Cs
56
Ba
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
87
Fr
88
Ra
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Cn
113
Uut
114
Uuq
115
Uup
116
Uuh
117
Uus
118
Uuo
Lanthanides
57
La
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
Actinides
89
Ac
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
en.wikipedia.org/wiki/File:Periodic table.svg
P
Ni
[Ne]3s2 3p3
[Ar]4s2 3d8
s-block
p-block
1A
1s
2A
3A
2s
4A
5A
3B
4B
5B
6B
7B
7A
2p
d-block
3s
6A
8A
1s
8B
1B
3p
2B
4s
3d
4p
5s
4d
5p
6s
5d
6p
7s
6d
f-block
4f
5f
en.wikipedia.org/wiki/File:Periodic Table structure.svg
main group
1A
8A
1s
7A
1s
Noble gases
ns2np 1
ns2np 2
ns2np 3
ns2np 4
ns2np 5
ns2np 6
main group
Halogens
ns1
ns2
2A
3A
4A
5A
4s
5s
6s
Alkalai metals
3s
6A
2p
2s
transition elements
3B
4B
5B
6B
7s
7B
8B
1B
3p
2B
3d
4p
4d
5p
5d
6p
6d
inner transition elements
Lanthanide series
4f
Actinide series
5f
1A
2A
3A
3B
4B
5B
6B
7B
8B
1B
Ni
2B
4A
5A
6A
7A
Ne
Ar
Atomic Radius
The atomic radius of an element is a measure of the size of the atom, usually
the distance from the nucleus to the boundary of the surrounding cloud of
electrons.
There is no precise outer boundary to an atom.
Thus we can describe an effective atomic radius as, the distance from the
nucleus within which 95% of all the electron charge density is found.
In fact, all that we can measure is the distance between the nuclei of
adjacent atoms (internuclear distance).
Definitions of Radii
Covalent radius is one-half the distance between the centers of two atoms
that are bonded covalently. It is the atomic radius associated with an element
in its covalent compounds.
Ionic radius is the radius of a spherical ion. It is the atomic radius associated
with an element in its ionic compounds.
Metallic radius is one-half the distance between the centers of adjacent
atoms in a solid metal.
The van der Waals radii are strictly hard sphere radii measured using
atomic distances in closest packed crystals.
solid sample of a noble gas
Trend of Atomic Radius
The atomic radius tends to decrease as one progresses across a period from
left to right
because the effective nuclear charge (Zeff ) increases, thereby attracting
the orbiting electrons and lessening the radius
The atomic radius usually increases while going down a group
due to the addition of a new energy level (shell).
The atomic radii of transition elements tend to be about the same across a
period but with a few unusual peaks.
Trend in Atomic Radius
Fr
He
Ionic Radius
Cations are smaller than the atoms from which they are formed.
For isoelectronic cations, the more positive the ionic charge, the smaller
the ionic radius.
Anions are larger than the atoms from which they are formed.
For isoelectronic anions, the more negative the charge, the larger the ionic
radius.
5.2
Ionization Energy
Ionization Energy
The ionization energy, I, is the quantity of energy a gaseous atom must
absorb to be able to expel an electron.
The first ionization energy I1 is the energy required to remove the most
loosely held electron from a gaseous atom.
The second ionization energy I2 is the energy required to remove an
electron from a gaseous unipositive ion.
Mg(g)
Mg+ (g)
Mg+ (g) + e
Mg2+ (g) + e
I1 = 738 kJ/mol
I2 = 1451 kJ/mol
5.3
2
Zeff
n2
Electron Affinity
Electron Affinity
Electron affinity is the energy change associated with the gain of an
electron by a neutral gaseous atom.
F(g) + e F (g)
5.4
Electronegativity
Electronegativity
Electronegativity (EN) is a measure of the ability of an atom to attract
electrons towards itself in the context of a chemical bond.
EN is related to IE and EA. In 1934, Robert S. Mulliken developed an
approach where
EN = IE EA2
Trend in Electronegativity
As one moves from left to right across a period in the periodic table, the
electronegativity increases
due to the stronger attraction that the atoms obtain as the nuclear charge
increases
Moving down a group, the electronegativity decreases
due to the longer distance between the nucleus and the valence electron
shell, thereby decreasing the attraction.
In general, EN is inversely related to atomic size.
Trend in Electronegativity
increasing electronegativity
Fr
decreasing electronegativity
en.wikipedia.org/wiki/Electronegativity
10
5.5
Magnetic Properties
Magnetic Properties
An important property related to the electron configurations of atoms and
ions is their behavior in a magnetic field. A spinning electron is an electric
charge in motion, which induces a magnetic field.
A diamagnetic substance has all its electrons paired and the individual
magnetic effects cancel out. It is slightly repelled by a magnetic field.
A paramagnetic substance has one or more unpaired electrons in its
atoms or molecules and the individual magnetic effects do not cancel
out. It is attracted into a magnetic field.
Paramagnetism in Manganese
The Mn atom ([Ar] 3d5 4s2 ) has a paramagnetism corresponding to 5
unpaired electrons
When a third electron is lost to produce Mn3+ , the ion has a paramagnetism
corresponding to 4 unpaired electrons.
11
F
nonmetals
metals
Fr
most
metallic
12