Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
M.SC. (CHEMISTRY)
(SEMESTER-WISE)
PAGE 1
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
FIRST SEMESTER
400 MARKS
075 MARKS
075 MARKS
075 MARKS
075 MARKS
100 MARKS
35 Marks
30 Marks
20 Marks
15 Marks
PAGE 2
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
SECOND SEMESTER
400 MARKS
075 MARKS
075 MARKS
075 MARKS
075 MARKS
100 MARKS
30 Marks
20 Marks
20 Marks
15 Marks
(E) Seminar
15 Marks
PAGE 3
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
THIRD SEMESTER
400 MARKS
075 MARKS
075 MARKS
075 MARKS
075 MARKS
100 MARKS
35 Marks
30 Marks
20 Marks
15 Marks
PAGE 4
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
FOURTH SEMESTER
400 MARKS
075 MARKS
075 MARKS
075 MARKS
075 MARKS
100 MARKS
60 Marks
(B) Seminar
20 Marks
20 Marks
PAGE 5
M.SC. (CHEMISTRY)
RULES & REGULATION
PAGE 6
Unit-II:
Unit-III:
Unit- IV:
Unit - V:
PAGE 7
Unit-II :
Nuclear Chemistry : Radioactive decay and equilibrium, Nuclear Reactions Types, Q value, Cross Section of reactions, Chemical effects of nuclear
transformation, Nuclear Fission - Fission Products, Fission Yield and Nuclear
Reactors, Nuclear Fusion and stellar energy,
Radioactive techniques:
(i) Tracer techniques (neutron activation analysis),
(ii) Countering Techniques such as G.M Ionization and Proportional
counters.
Unit -III :
Metallo-boranes
and
Metallocarboranes,
Classification,
PAGE 8
Unit -IV :
Polymerization
(step-growth,
chain-growth,
ring-opening,
Condensed
Phosphates,
Silicates,
and
sulphur-nitrogen
compounds, Isopoly and Hetropoly acid and Salts: Synthesis and structural
principles with reference to those of Mo and W.
Unit -V :
BOOKS RECOMMENDED
Chris J. Jones, d- and f- Block Chemistry , (2002), Wiely Interscience & RSC
V.S. Sastri, J.C.G. Bunzli, V.R. Rao, G.V.S. Rayudu, J.R. Perumareddi, Modern
Aspects of
rare earths and their complexes, (2003) Elsevier publication.
H.J. Arnikar, Essentials of Nuclear Chemistry, 4th Edition (1995), Wiely-Eastern
Ltd., New Delhi.
PAGE 9
PAGE 10
(a) Nature of bonding in organic molecules: Delocalised chemical bondingconjugation, cross conjugation, resonance, hyperconjugation, inductive
effect, electromeric effect, mesomeric effect, steric effect tautomerism.
(b) Fullerenes, annulenes, aromaticity, anti- aromaticity.
Unit II:
Unit III:
Substitution reactions:
(a) Electrophilic Substitution reaction: The SE1 and SE2 mechanisms, effect
of substrates, leaving group and the solvent polarity on the reactivity.
PAGE 11
(b) Nucleophilic Substitution reaction: The SN1, SN2 and SNi mechanisms,
effect of substrate structure, attacking nucleophile, leaving group and
reaction medium, ambedient nucleophile.
Unit IV:
Unit V:
correlation
diagram,
FMO,PMO
approach,
PAGE 12
Unit-II:
Unit-III:
Unit-IV:
Unit-V:
PAGE 14
35 Marks
30 Marks
20 Marks
15 Marks
(21 Marks)
Identification of seven radicals including insoluble residue and rare earth metal ions by
semi micro analysis.
(i) Rare elements: Tl, W, Se, Mo, Ti, Zr, Ce, Th, V, U, Li
PAGE 15
(ii) Insolubles: PbSO4, SrSO4, Al2O3, Cr2O3, Fe2O3, SnO2, AgX, TiO2, ThO2,
WO2.xH2O
B. Preparations of Inorganic Complex Compounds
(14 Marks)
PAGE 16
Unit-I:
Unit-II:
Unit-III:
Unit-IV:
PAGE 17
Unit-V:
PAGE 18
Unit-II :
PAGE 19
Unit -III:
Unit -IV:
Unit -V:
BOOKS RECOMMENDED
Geoffrey A. Lawrance, Introduction to Coordination Chemistry, (2010), Wiley &
Sons.
PAGE 20
PAGE 21
Unit II:
Unit III:
Unit IV:
Unit V:
PAGE 22
Quantum Chemistry
Approximate Method: The Variation Theorem, linear variation principle,
Perturbation theory (first order & non degenerate). Application of variation
method & perturbation theory to the Helium atom.
Unit II:
Unit III:
PAGE 23
of
ethane),
photochemical
(hydrogen-bromine
and
Unit IV:
Unit V:
PAGE 24
30 Marks
20 Marks
20 Marks
15 Marks
(E) Seminar
15 Marks
(20 Marks)
Quantitative Separation and determination of two metal ions : Cu-Ni, Ni-Zn, Cu-Zn etc
using volumetric and gravimetric methods.
PAGE 25
B. Chromatography
(10 Marks)
1.
2.
3.
4.
5.
TLC separation and determination of the Rf values of Ni, Mn, Co and Zn ions.
6.
7.
PAGE 26
2.
3.
To compare the strength of two acids say hydrochloric acid and sulphuric acids
used in equal concentration for the hydrolysis of methyl acetate.
4.
PAGE 27
Unit-II:
Unit-III:
Unit-IV:
Unit-V:
Supramolecular
Chemistry:
Definition,
supramolecule
host-guest
BOOKS RECOMMENDED
Didier Astruc, Organometallic Chemistry and Catalysis, (2007), Springer.
Robert H Crabtree, The Organometallic Chemistry of the Transition Metals, 4th Ed
(2005), Wiley Interscience.
Helmut Werner, Landmarks in Organo-Transition Metal Chemistry, (2009),
Springer.
R.C. Mehrotra and A. Singh, Organometallic chemistry: A unified approach, (1991),
Wiley, New York.
Ayodhya Singh, R. Singh, Organometallic Chemistry, (2006) Campus Books
International.
R.H. Crabtree, The Organometallic Chemistry of the Transition Metals, 1st
Edn.(1988), John-Wiley & Sons, New York.
J. P. Collman, L. S. Hegedus, J. R. Norton and Richard G. Finke, Principles and
Applications of Organotransition Metal Chemistry, 1st Edn.(1987), University
Science Books, Mill Valley, California.
PAGE 29
PAGE 30
Unit II:
Unit III:
Unit IV:
PAGE 31
Unit V:
PAGE 32
SOLID STATE REACTIONS: general principle, experimental procedures, coprecipitation as a precursor to solid state reactions. Crystal defects and
non-stoichiometry, perfect and imperfect crystals, intrinsic and extrinsic
defects-point defects, line and plane defects, vacancies-Schottky defects
and Frenkle defects. Thermodynamics of Schottky defects and Frenkle
defect formation, Color centres, non-stoichiometry and defects.
Unit-II:
of
biopolymers
by
various
Sedimentation
equilibrium,
hydro
experimental
dynamic
methods,
techniques.
diffusion,
PAGE 33
Unit-III:
Unit-IV:
Unit-V:
PAGE 34
Unit-II:
Unit-III:
Unit-IV:
Unit-V:
PAGE 35
35 Marks
30 Marks
20 Marks
15 Marks
(25 Marks)
PAGE 36
PAGE 37
B. Flame photometry
(10 Marks)
1.
Benzene-benzophenone-benzophenone oxime-benzilide
2.
Aniline-acetanilide-p-nitro acetanilide-p-Nitroaniline
3.
Aniline-acetanilide-p-bromo acetanilide-p-bromoaniline
4.
5.
Nitrobenzene-m-dinitrobenzene-m-nitroaniline-m-nitrophenol.
2.
3.
4.
PAGE 39
PAGE 40
Unit -II :
Unit -III :
PAGE 41
Unit -IV :
Unit -V:
BOOKS RECOMMENDED
Derek Sutton, Electronic spectra of transition metal complexes: An introductory
text (1968), McGraw-Hill.
R.L.Carlin, A. J. van Duyneveldt, Magenetic properties of transitional metals
Compounds (1979), Springer-Verlag.
PAGE 42
Rob Janes and Elaine Moore, Magnetism and the magnetic properties of
transition-metal complexes (2004), RSC.
G.W. Vanloon, S.J. Duffer, Environmental Chemistry - A Global Perspective, (2000)
Oxford University Press.
F.W. Fifield and W.P.J. Hairens, Environmental Analytical Chemistry, 2nd Edition
(2000), Black Well Science Ltd.
Colin Baird, Environmental Chemistry, (1995) W.H. Freeman and Company, New
York.
A.K. De, Environmental Chemistry, 4th Edition (2000), New Age International
Private Ltd., New Delhi.
Peter O. Warner, Analysis of Air Pollutants,1st Edition (1996), John Wiley, New
York.
S.M. Khopkar, Environmental Pollution Analysis, 1st Edition (1993), Wiley Estern
Ltd., New Delhi.
S.K. Banerji, Environmental Chemistry, 1st Edition (1993), Prentice-Hall of India,
New Delhi.
James H. Clark, Duncan J. Macquarrie, Handbook of Green Chemistry and
Technology, (2002) Wiley.
V. K. Ahluwalia, M. Kidwai, New Trends in Green Chemistry (2004), Springer.
R. L.Carlin, Magnetochemistry, Springer.
PAGE 43
PAGE 44
Unit II:
13
C NMR, FT-NMR,
Unit III:
Unit IV:
Unit V:
Chromatographic
techniques:
Introduction,
principle
types
of
PAGE 46
ANGULAR
MOMENTUM:
Angular
Momentum:
Ordinary
angular
Unit-II:
Unit-III:
ion
transport
through
cell
membrane,
irreversible
PAGE 47
Unit-IV:
Unit-V:
PAGE 48
C.
PAGE 49
Unit-II:
Nitrogenase Structure
and mechanism.
Molybdenum
Unit-III:
PAGE 50
Unit-IV:
Unit-V:
(a) Metal - Nuclic Acid Interactions : Metal ions and Nucleic Acids
Interactions (binding) - Types & suitable examples. Metal complexes (e.g.,
Cisplatin) interaction with DNA.
(b) Metals in Medicine: Metal Deficiency and disease. Toxic effects of
Metals. Metals used for diagnosis. Metals used in Chemotherapy with
particular reference to Anticancer drugs.
BOOKS RECOMMENDED
S. J. Lippard and J. M. Berg, Principles of Bioinorganic Chemistry, (1994),
University Science Books.
PAGE 51
Harry B. Gray, Edward I. Stiefel, Joan Selverstone Valentine and Ivano Bertini,
Biological Inorganic Chemistry: Structure and Reactivity, (2006),University Science
Books.
Robert Crichton, Biological Inorganic Chemistry: An Introduction (2008), Elsevier
Science.
M. N. Hughes, Inorganic Chemistry of Biological Processes, 2nd Ed.(1981), JohnWiley & Sons, New York.
W. Kaim and B. Schwederski, Bioinorganic Chemistry: Inorganic Elements in the
Chemistry of Life, An Introduction and Guide, (1995) Wiley, New York.
Nicholas V. Hud, Nucleic Acid - Metal Ion Interactions, (2009), Royal Society of
Chemistry.
Ivano Bertini, A.Sigel, H.Sigel (Editors), Handbook on Metalloproteins (2001),
Marcell Dekker,Inc,
James C. Dabrowiak, Metals in Medicine (2009), John Wiley & Sons, Ltd.
Rosette M. Roat-Malone, Bioinorganic Chemistry - A Short Course, 2nd Edition,
(2007), Wiley.
H.B. Kraatz, N. Metzler-Nolte (Eds.), Concepts and Models in Bioinorganic
Chemistry (2006), Wiley-VCH.
L. Nelson and M.M. Cox, Lehninger Principles of Biochemistry, 3rd edition (2002)
McMillan North Publication.
PAGE 52
methods of
Steroids:
Introduction,occurance,
classification,
biological
role
and
Unit V:
PAGE 54
techniques,
evaporation/sputtering,
chemical
prcesses,
Unit-II:
Unit-III:
Theortical and computational treatment of atoms and molecules, hartreeFock theory, Review of the principles of quantum mechanics, Born-oppen
heimer approximation, staler condon rules, Hartree Fock equation,
Koopmans and Brilloning theories, Roothan Equation, Gaussian basis sets.
Unit-IV:
as
dense
gases,
liquids
as
disordered
solids,
some
PAGE 56
Unit-II:
PAGE 57
Unit-III:
Unit-IV:
Radiochemical
ray
spectrometry,
radiochemistry,
isotope
dilution,
Unit-V:
PAGE 58
60 Marks
(B) Seminar
20 Marks
20 Marks
(10 Marks)
PAGE 59
B. Soil Analysis
(10 Marks)
1. Determination of pH
2. Determination of conductivity
3. Determination of total alkalinity
4. Determination of chloride & sulphate
5. Determination of organic matter
6. Determination of phosphorus & total phosphorus
7. Determination of Na, K, Ca, Mg
(25 Marks)
4. Analysis of the given sample of dolomite (equimolar CaCO3+MgCO3) for its volatile
matter, insoluble matter, and its Ca & Mg contents by EDTA method.
5. Analyse the given five-rupee coin for its Cu content iodometrically, and Ni content
as Nidmg complex colorimetrically or gravimetrically.
(15 Marks)
SEMINAR
20
20
PAGE 61
OR
(B) ORGANIC PRACTICALS
1.
2.
3.
20
30
10
SEMINAR
20
20
OR
Thermodynamics:
PAGE 62
(i) Determination of partial molar volume of solute (KCl) and solvent in a binary
mixture.
(ii) Determination of temperature dependence of the solubility of a compound in to
solvents having inter molecular intraction (Benzoic acid in water and in DMSO
water mixture) and calculate the partial molar heat of solution.
Spectroscopy:
(i) Determination of pka of an indicator (e.g. Methyl Red) in (a) aqueous and (b)
micellar media.
(ii) Detremination of stoichometry and stability constant of inorganic (e.g. Ferricsalicylin acid) and organic (e.g. amine iodine) complexes.
(iii)
Polarography:
(i) Estimation of Pb+2 and Cd+2/Zn+2 and Ni+2 ions in a mixture of Pb+2 and Cd+2/Zn+2
and Ni+2 by Polarography.
(ii) Determination of dissolved oxygen in aqueous solution of organic solvents.
Electronics:
(i) Basic electronic experiments.
OR
PAGE 63
ANALYTICAL CHEMISTRY
1.
2.
Applied Electron Spectroscopy for Chemical Analysis Ed.H. Windai and F.L.Ho
Wiley Interscience
3.
NMR, NQR, EPR and Mossbauer Spectroscopy in Inorganic Chemistry, R.V. Parish,
Ellis Harwood.
4.
5.
6.
7.
8.
9.
PAGE 73
COMPUTERS
1. Computers and common sense, R. Hunt and J. Wiley, Prentice Hall.
2. Computational Chemistry, A.C. Norris
PAGE 74
PAGE 75
Gary L. Miessler, Donald A. Tarr, Inorganic Chemistry, 4th Ed. (2011), Prentice Hall,
Pearson.
PAGE 76