PARA GAS IDEAL, VAN DER WAALS, PENG ROBINSON Y SO

DATOS CONOCIDOS
CLCULOS

van der Waals

Para Peng- robinson y Soave

Para Peng- robinson y

Soave y Van der Waals

8.314

0.021

Tc
Pc
V (m3/mol)
T (K)

154.6 a
5.05E+06 b
1.43E-02
173

0.1381
3.18E-05

RESULTADOS

P (Pa)

DATOS
R
B(T) (m3/mol)
P (bar)
T (K)

GAS IDEAL
1.01E+05

EC. VIRIAL
RESULTADOS
8.314 V
-1.15E-04 Z
15 f
373.15

VAN DER
WAALS
1.0013E+05

206.8246067
1.00E+00
1.50E+01

PENG ROBINSON Y SOAVE

CLCULOS

DATOS

RedlichKwong and
Peng-Robinson
Soave
0.4069
0.5130
0.9535

0.9415

1.43E-01
1.98E-05

1.32E-01
2.21E-05

RESULTADOS
PENG-ROBINSON
1.0013E+05

REDLICHKWONG AND
SOAVE
1.0011E+05

T (K)
Tc (K)
Pc (Pa)
P (Pa)

ECUACIN CBICA
DATOS

CALCULOS
Peng-Robinson
van der Waals
8.314

0.4069

0.021

0.9535

173 a
154.6 b
5.05E+06 A
1.00E+05 B

0.9415 Z

0.1427
1.38E-01
1.32E-01 V (m3/mol)
1.98E-05
3.18E-05
2.21E-05
0.00690
0.00668 0.0063699442
0.00138
0.00221 0.0015343858
PARMETROS EC. CBICA
Peng-Robinson

Redlich-Kwong
and Soave
0.5130 RESULTADOS

Redlich-Kwong
van der Waals and Soave
-0.99862
-1.00221
-1
0.00413847
0.00668 0.004833204
-7.60576E-006 -1.47805E-005 0.000009774
3.115E-05
-0.0010039 -0.000623271

0.9945
1.43E-02

T (K)
Tc (K)
Pc (Pa)

DATOS
ETANO
BUTANO
8.31E+00
8.31E+00
0.098
0.193
373.15
373.15 a
305.4
425.2 b
4.88E+06
3.80E+06

CALCULOS
ETANO
BUTANO
0.5232
0.6622
0.8928
1.0855
0.5389
1.6322
4.04E-05
7.24E-05

RESULTADOS
ETANO
Z
Ln(f /P)
f (bar)
0.996 -0.00429598
9.96E+04
0.957 -0.04305450
9.58E+05
0.935 -0.06465694
1.41E+06

BUTANO
0.985
0.837
0.733

ETANO
P (bar)
1.00E+05
1.00E+06
1.50E+06

BUTANO
ETANO
BUTANO
A
B
0.005598690
0.016958806 0.0013037356 0.0023329520
0.055986898
0.169588057 0.0130373561 0.0233295204
0.083980348
0.254382086 0.0195560342 0.0349942806

S
BUTANO
Ln(f /P)
f (bar)
-0.01469152
9.85E+04
-0.15401679
8.57E+05
-0.23916078
1.18E+06

PARMETROS EC. CBICA

BUTANO
ETANO
BUTANO
ETANO

-0.998696264 -0.997667048 0.002986119 0.012276574 -5.59727E-006

-0.986962644 -0.976670480 0.029402268 0.121296217 -0.0005577325
-0.980443966 -0.965005719 0.043720964 0.180719726 -0.0012524051

ETANO

BICA
BUTANO
ETANO
BUTANO

-3.41087E-005
2.938E-04
-2.316E-04
-0.003399444
1.390E-04
2.767E-04
-0.0076344644
-1.016E-04
1.790E-04

T (K)
Tc (K)
Pc (Pa)
P (Pa)

DATOS
n-pentene
Benzene
8.31E+00
8.314
0.251
0.212
373.15
373.15 a
469.6
562.1 b
3.37E+06
4.89E+06 A
5.00E+06
5.00E+06 B

CLCULOS

PARMETROS EC. CBICA

CLCULOS
n-pentene
Benzene
0.7447
0.6895 Z
1.1683
1.2717 ln(f/P)
2.4134
2.5949 f (Pa)
9.00E-05
7.43E-05 f(bar)
1.25373
1.34804
0.14509
0.11973
PARMETROS EC. CBICA
-0.85491
-0.88027
0.9003887842 1.0655681
-0.157802268 -0.14535337
5.738E-06 -3.945E-05

RESULTADOS
n-pentene
Benzene
0.2058
0.1522
-2.08427846 -3.22690172
6.22E+05
1.98E+05
6.22
1.98

T (C)
hielo
Agua
R

DATOS
T (K)
P (mmHg)
-4
269.15
3.28
-2
271.15
3.88
2
275.15
5.294
4
277.15
6.101
8.314

RESULTADOS
sub (J/mol)
vap (J/mol)
fus (J/mol)
50965.0
44976.0
5988.9 PT
valorsub

PUNTO TRIPLE
4.627
50950.0

PUNTO TRIPLE
TT
valorvap

273.279
44995.4