CHEM 112 - Z

Problem Set 1

CHEM 112 - Z
Problem Set 1

1.

The vapor pressure of benzene between 285 K and 310 K fits the expression:
log P = 10.086 1780.172 (1/T)
where: P is in Pa; T is in K
Calculate the molar enthalpy of vaporization and the normal boiling point of
benzene. Compare the normal boiling point with that of the boiling point obtained
from Troutons Rule.
= 34079.07 J/mol; normal Tb = 350.41 K; Tb = 387.26 (using
Answers:
Troutons rule)

1.

The vapor pressure of benzene between 285 K and 310 K fits the expression:
log P = 10.086 1780.172 (1/T)
where: P is in Pa; T is in K
Calculate the molar enthalpy of vaporization and the normal boiling point of
benzene. Compare the normal boiling point with that of the boiling point obtained
from Troutons Rule.
= 34079.07 J/mol; normal Tb = 350.41 K; Tb = 387.26 (using
Answers:
Troutons rule)

2.

At SATP, iodine boils at 183.0C. The vapor pressure of the liquid at 392 K is
4
1.35x10 Pa. If the molar enthalpy of fusion is 15.65 kJ/mol and the vapor pressure
of the solid is 1 Torr at 38.7C, calculate its
a. molar enthalpy of vaporization, molar entropy of vaporization and molar
enthalpy of sublimation.
b. triple point temperature and pressure, assuming that the equilibrium vapor
pressure with temperature for liquid and solid is in the vicinity of the triple
point.
= 198.23 J/mol-K;
= 46,711.18 J/mol;
= 62,096.98
Answers:
J/mol; T3 = 368.94 K; P3 = 5511.61 Pa

2.

At SATP, iodine boils at 183.0C. The vapor pressure of the liquid at 392 K is
4
1.35x10 Pa. If the molar enthalpy of fusion is 15.65 kJ/mol and the vapor pressure
of the solid is 1 Torr at 38.7C, calculate its
a. molar enthalpy of vaporization, molar entropy of vaporization and molar
enthalpy of sublimation.
b. triple point temperature and pressure, assuming that the equilibrium vapor
pressure with temperature for liquid and solid is in the vicinity of the triple
point.
= 198.23 J/mol-K;
= 46,711.18 J/mol;
= 62,096.98
Answers:
J/mol; T3 = 368.94 K; P3 = 5511.61 Pa

3.

The mole fraction of acetone (MM = 58.078 g/mol) in a binary solution of acetonechloroform is 0.4693. The partial molar volumes of acetone and chloroform (MM =
3
3
119.368 g/mol) are 74.166 cm /mol and 80.235 cm /mol, respectively. What is the
volume of solution of mass 1.245 kg?
3
Answer: 1063.37 cm

3.

The mole fraction of acetone (MM = 58.078 g/mol) in a binary solution of acetonechloroform is 0.4693. The partial molar volumes of acetone and chloroform (MM =
3
3
119.368 g/mol) are 74.166 cm /mol and 80.235 cm /mol, respectively. What is the
volume of solution of mass 1.245 kg?
3
Answer: 1063.37 cm

4.

Calculate the Gibbs energy, entropy and enthalpy of mixing when 2.75 g hexane
(C6H14) is mixed with 3.68 g of heptane (C7H16) at 298 K. Assume that the solution is
ideal. (MM: hexane = 86.17 g/mol; heptane = 100.2 g/mol)
Answers: = -117.46 J; = 0.394 J/K; = 0

4.

Calculate the Gibbs energy, entropy and enthalpy of mixing when 2.75 g hexane
(C6H14) is mixed with 3.68 g of heptane (C7H16) at 298 K. Assume that the solution is
ideal. (MM: hexane = 86.17 g/mol; heptane = 100.2 g/mol)
Answers: = -117.46 J; = 0.394 J/K; = 0

5.

Calculate the Henrys law constant of HCl at 350 K given the vapor pressure of
dilute solutions of HCl in liquid GeCl4.
HCl
0.005
0.012
0.019
PHCl (bar)
0.333
0.775
1.288
Answer: KHCl = 67.32 atm

5.

Calculate the Henrys law constant of HCl at 350 K given the vapor pressure of
dilute solutions of HCl in liquid GeCl4.
HCl
0.005
0.012
0.019
PHCl (bar)
0.333
0.775
1.288
Answer: KHCl = 67.32 atm

6.

A 4.25 g of a substance in 125 g CCl4 raises the boiling point by 0.75 K. Determine
the freezing point depression, relative vapor pressure lowering, osmotic pressure
at 25C, and molar mass of the substance.
3
For CCl4: = 1.59 g/cm (assume to be equal to the density of solution), MM =
153.82 g/mol, Kb = 5.03 K-kg/mol, Kf = 31.8 K-kg/mol
Answers: Tf = 4.738 K; = 0.02238; = 5.6 atm; MM = 228.2 g/mol

6.

A 4.25 g of a substance in 125 g CCl4 raises the boiling point by 0.75 K. Determine
the freezing point depression, relative vapor pressure lowering, osmotic pressure
at 25C, and molar mass of the substance.
3
For CCl4: = 1.59 g/cm (assume to be equal to the density of solution), MM =
153.82 g/mol, Kb = 5.03 K-kg/mol, Kf = 31.8 K-kg/mol
Answers: Tf = 4.738 K; = 0.02238; = 5.6 atm; MM = 228.2 g/mol