2012

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QUALIFYNC IXAMINATION IOR AP?LICANTSIOR JAPANESE
GOWRNMENT(MONBUKAGAKUSHO)SCHOLARSHIPSz(]Iz

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EXAMINATIONQUESTIONS

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COLLEGEOI TECENOLOGYSTUDENTS

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CIIXMTSTRY

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CHEMISTRY
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Ifnme$ary, nsethefollowiq daranr aswer lhe quesiions

below
Atomicweiehl:H=1.0,C=12.0,O=i6.0,Na=23.0.S=12.0.Cl=35.5,Cu=636
Ianday s onsrant F = 9.65x lO4C/nol
Molarvolme of gasat tne$.n&rd stat:22.4L/nol

w.ile lh hmher of you amwer in th box provided.

Cnooselhe one auemadvethat besl

Answer the followins questio.s.

(A) Wnat n lh oxidatior nunber of mSanese in KMrOa?

o - r(-2)

@ +n(+3)

@ +N(+4)

@ +v(+6)

(B) whici is . rdoxreodion?

O NaCl + AgNOr + AgCl + NaNOI
cacl? + 2Eo
@ca(oF), + 2Ecl O2NallCOr + Na,COr + H,O + Co,
@ HCI + NHr - NlIlrCl
@c,HjoH + 30: + 2co2 + 3H?o

6) +vn(+?)

(C) Which of lhe following elendrs hasthe g@t*i cleclronesalivitvvalue?

OAI

@ c

O F

@Na

oo

b -l'ealklre gmdp"
LD,wn'ch olr\e lollow'fg commud. belones

(E) Nlich ofthe followihg gaseshls fie higtest densitvat lhe Rr'nd'rd sbte?

o so:

o ct: @ o : O r ,

(FJWh(h or tnefollowing.ompoun[noplicallvacive?

O NHzcH:cooH @ cHrcF,clt(NHrcooH
O NH:(CH,),NII:
@ Hooc(cHrlcooH

O (CH lC(llHtCOOH

2. A nixtue of 6.0 nol of H: ga md 4 5 nol of Ir vtpor was heated al a c@stanl

Al th. equilibriun
tenperaluE in t radior vesselmd allowed lo each qnilibriun
Answe.lhe followingquestDns
rheanoutofHlws 8.0nol.

(A | ' alc' la,erh" \alLeofLheeqd,librm con tM' lor H rEl

O8

@16

Ol2

O64

Ol23

Ir(e)

2 HIG)

(B) A mixturcof 2.0 nol of H: s6 and2.0 mol of Ir vaporwasheated!t thesanc co.stanl

tententuie in lhe sanc rcaclionvcscl andallowcdto reachequilibdun Calculate

O ().4onol O l.2nol

O l.6mol O 2.5nol O:l2mol

by dissolviq 4.0sofNaOH in l000nL of walr.

3. Thesolutionwasprcparcd
(A) wrlal is lhc nolarityoltbis solulion?
C) O.050Dol/L O 0.10noUL

O 0.25nrol/L

@ l0 mol/L

O l.5nol/L

(B) what is thepH valueoflhissolution?

Or

aO4 @1

i l0

O13

(Cl Hownucbofa 0.10not/L HrSOa

solution
is requned
lo neullalize
20 nL of thisNaOH

i t 5 . 0m L

O 10mL

@ 20mL @ 25mL O 50mL

4. The rhffiochenical qn.lion Ior lhe combustionof propaneis sivn as follosj

LH: -222okl
CrHs(s)+ 5 O:(s)- 3 CO:G)+4Hio(4

(A) Eow nany kilojoulcs arc liberatedwhen 8.80 s of CrHs(s)!rcts rccordineto tnh

O) 111kJ

(D 222W

o 333kJ

) 444 kJ

fomtion of COld md E?O(l) &e 394 k mol and 286 kJ/nol,

Calculatethe bat of fodation of CrEsG).

O 106tj/mol @ 5021d/molO 610Ltmol @ 896U/nol O l040k mol

5, An aqueoussohtior of CISOI was electrcltzed wnh phtinnm electrodesfor 2.0 hous wi$

LAr\u1d' 's rhccold

-ombi0alionolelecuodeedCFnftredg^-

O o: aranode @ H2'r catnod

@ so, atetbode @ so: al anode

(B) How mny mulonbs wqe flowed in tbis electolysis?

O rooc

@ r 8 0c

((J Hoq mtryglmolt

@) 360C

c
@ 54oo

O ro8ooc

L weeJellortd on+epld' nur elrmde"

O 0890s @ l T a E

G )l 5 6 e

@ ? t 2 s O 142c

6. The conbuslion ol 12.0 mg ol a nonocsboxylic a.id, which cortains only carbon,

hydrcem md oxyed, g.v 17.6mg oI COzmd 7.20 mg ofH:O.
(A) wnich is the conpNilioml fomnla of thh conpoud?

O cHro

@ cHo:

@ cH:o1 @ crHro, O crH6o:

(B) Del@in the nolecnld wigni oflnis conpomd.

o30

@60

@45

@46

@74

?. Answcr inc followi.g qusiios abouta synlheiicpolynd.

(A) Cnoosethe coftd conbimtion ofnononeB iflhe polymerhs amidebonds.
O elnykn mdpropylchc
O propylhernd vinyl chbnde
@ hdmelhylenedianine andadipic acid @ viryl alcohol md ethylene
O trepnt fic acidefld etnybne slycol

{B) wlicn of the following polymes is nade or repestilg uniis linked by anide bonds?

O PE

@ tET

O Nylon6.6

@ Pvc

O PvA