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The content of this SDS is also valid in Spanish Mexican language to cover all Central, South America (except Brazil) and the Caribbean countries.
Section 1. Identification
GHS product identifier
Other means of
identification
Product type
Identified uses
For controlled demolition, reinforced concrete cutting, rock breaking, quarrying, stone dimension, mining, excavating...
Manufacturer
Distributor/Canada
Emergency telephone
number (with hours of
operation)
: +1-575-874-9188
(24/7)
Signal word
Hazard statements
: Warning
: H319 - Causes serious eye irritation.
H315 - Causes skin irritation.
H335 - May cause respiratory irritation.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
www.kmkregservices.com www.askdrluc.com www.ghssmart.com
1/11
: Mixture
: Expanding Cement.
CAS number
Calcium dihydroxide
Aluminium oxide
60 - 100
1-5
1305-62-0
1344-28-1
2/11
Skin contact
Ingestion
: Remove person to fresh air and keep comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get
medical attention. If necessary, call a poison center or physician. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Continue to rinse for at least 20 minutes. Get medical attention.
: Wash out mouth with water. Move exposed person to fresh air. If material has been
swallowed and the exposed person is conscious, give small quantities of water to drink.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Never give
anything by mouth to an unconscious person. Get medical attention if symptoms occur.
3/11
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. See also Section 8 for additional information on hygiene
measures.
4/11
: Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Exposure limits
Calcium hydroxide
Diiron trioxide
Aluminum oxide
Canada
Occupational exposure limits
TWA (8 hours)
Ceiling
Ingredient
List name
ppm
mg/m Other
ppm
ppm
mg/m Other
Calcium dihydroxide
US ACGIH 4/2014
AB 4/2009
BC 7/2013
ON 1/2013
QC 1/2014
ON 1/2013
QC 12/2012
US ACGIH 4/2014
AB 4/2009
BC 7/2013
5
5
5
5
5
0.1
0.1
5
5
5
5
3
10
5
5
1
10
1
1
10
Silica, vitreous
Diiron trioxide
Diiron trioxide, Fe
Diiron trioxide
Diiron trioxide, Fe
Aluminium oxide
Aluminium oxide, Al
Aluminium oxide
Aluminium oxide, Al
ON 1/2013
QC 1/2014
US ACGIH 4/2014
AB 4/2009
BC 7/2013
ON 1/2013
QC 1/2014
mg/m Other
10
-
Notations
[3]
[a]
[b]
[a]
[c]
[d]
[e]
[b]
[f]
[a]
[g]
[a]
[c]
[a]
[f]
[3]Skin sensitization
Form: [a]Respirable fraction [b]Respirable dust [c]Respirable [d]Dust [e]Fume [f]Total dust [g]Dust and fumes
5/11
Exposure limits
Calcium hydroxide
Silica, vitreous
Diiron trioxide
Aluminum oxide
Appropriate engineering
controls
Environmental exposure
controls
: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation.
:
:
:
:
:
:
:
:
Solid. [Powder.]
Gray.
Odorless.
Not available.
Not available.
1000C (1832F)
Not available.
Not available.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
www.kmkregservices.com www.askdrluc.com www.ghssmart.com
6/11
: Not available.
: Not available.
: Not available.
:
:
:
:
:
Not available.
:
:
:
:
:
Not available.
Not available.
Not available.
Not available.
0 % (w/w)
Not available.
3.2
Very slightly soluble in the following materials: cold water.
Not available.
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: No specific data.
Incompatible materials
: Reactive or incompatible with the following materials: oxidizing materials, acids and
moisture.
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Result
Species
Calcium dihydroxide
LD50 Oral
Rat
Dose
7340 mg/kg
Exposure
-
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
Calcium dihydroxide
Rabbit
10 mg
Sensitization
There is no data available.
Carcinogenicity
Classification
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
www.kmkregservices.com www.askdrluc.com www.ghssmart.com
7/11
OSHA IARC
NTP
ACGIH EPA
NIOSH
Silica, vitreous
Diiron trioxide
Aluminium oxide
A4
A4
3
3
-
Category
Route of
exposure
Target organs
Calcium dihydroxide
Aluminium oxide
Category 3
Category 3
Not applicable.
Not applicable.
:
:
:
:
8/11
:
:
:
:
Result
Species
Exposure
Calcium dihydroxide
Aluminium oxide
96 hours
4 days
TDG / NOM-003-SCT
IMDG
IATA
UN number
Not regulated.
Not regulated.
Not regulated.
Not regulated.
UN proper
shipping name
9/11
Packing group
Environmental
hazards
No.
No.
No.
No.
Additional
information
: Not available.
: United States inventory (TSCA 8b): All components are listed or exempted.
: Not listed
: Not listed
: Not listed
: Not listed
: Not listed
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ
: Not applicable.
SARA 311/312
Classification
: Immediate (acute) health hazard
Composition/information on ingredients
Name
Fire
Sudden
hazard release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Calcium dihydroxide
Aluminium oxide
60 - 100
1-5
No.
No.
No.
No.
Yes.
Yes.
No.
No.
No.
No.
SARA 313
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
www.kmkregservices.com www.askdrluc.com www.ghssmart.com
10/11
CAS number
Form R - Reporting
requirements
Aluminium oxide
1344-28-1
1-5
Supplier notification
Aluminium oxide
1344-28-1
1-5
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts
: The following components are listed: Calcium dihydroxide; Silica, vitreous; Diiron
trioxide; Aluminium oxide
New York
: None of the components are listed.
New Jersey
: The following components are listed: Calcium dihydroxide; Silica, vitreous; Diiron
trioxide; Aluminium oxide
Pennsylvania
: The following components are listed: Calcium dihydroxide; Diiron trioxide; Aluminium
oxide
California Prop. 65
No products were found.
Canada
Canadian lists
Canadian NPRI
CEPA Toxic substances
Canada inventory
International lists
National inventory
Australia
China
Europe
Japan
Malaysia
New Zealand
Philippines
Republic of Korea
Taiwan
:
:
:
:
:
:
:
:
:
:
:
:
:
04/15/2015
03/15/2013
5
KMK Regulatory Services Inc.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
11/11