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FIITJEE

JEE(Main), 2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST IV
(Main)

ALL INDIA TEST SERIES

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14

S. No.
1.

PHYSICS

CHEMISTRY
A

MATHEMATICS

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.

24.

25.

26.

27.

28.

29.

30.

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14

Physics

PART I
SECTION A

1.

Zero after decimal point is also significant.

2.

a2 v12 t 2 v 2 t 2

a
B

v 2 v12

3.

600 T = ma
600 360
2
amin
4 m/s
60

4.

mgt 0

7.

mu = m(v/2) + mv
v = (2/3)u
u 2u

e 3 3
u
e = 1/3

8.

9.

v0
2gt 0

Friction force on upper block is f = ma


So work done = ma s

2 R 2
GM
R2

GM
R32

v1t

mv 0
mv 0
2

5.

vt

GM
R12

4 2
T2
42R32
T 2R12

dv
m 6rv
dt
0.5

dv
1
6
dt
v
18

2
t
n
t = 3n4 sec
0.5 3

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3
AITS-FT-IV-PCM (Sol)-JEE (Main)/14

mg qE
qE
where geff =
g
geff
m
m

12.

T 2

13.

Maximum will be corresponding to source position A


and minimum to source friction B.
3
2cos1
2
5
So, time interval =

18.

B
C

VP Vpindued VPq V0
Vpinduced

P
O
R

kq kq

r
r1

r1
O
r

20.

21.

16
CV 2
(i)
25
6
qi CV
.(ii)
5
11
qf CV
(iii)
5
1
16

Uf
CV 2 CV 2
2
2 5

Charge flown from battery = CV


Work done = CV2
Heat produced H = U + W
1 6

1
1
16

CV 2 CV 2
CV 2 CV 2 CV 2
2
2
25
2 5

vi

As A and B will be at same potential so


charge flown equal to Q.

B
Q

A
r
R

2 0I0

22.

B B 2A BB2

23.


Using e B d v

2a 2

0I0
2 a
P

So, e = BvR
R2

45
v

O
/2

24.

B(x)dx 0

/ 2

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4
AITS-FT-IV-PCM (Sol)-JEE (Main)/14

25.

1
q2
1
LI20
2 (C1 C2 ) 2

q L C1 C2 I0
q1

27.
29.

q
C1 C1I0
C1 C2

C1 C2

Icoherent
4I
2
Iincoherent 2I

Using Einstein equation


E = W + eV
o

12400 ev A
4

= 4.6 eV + eV

0.2 10 A
V = 1.6 Volts

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14

Chemistry

PART II
SECTION A

1.

For Li2 , rLi2

2.

0.529
9 4
1
0.529
r3 r2
9 4
3

For H, rH r3 r2

rH
3

rLi2
1

2Cu2S 3O2
2Cu2 O 2SO2
Cu2O FeS FeO Cu2 S
2FeS 3O2 2FeO 2SO2
FeO SiO2 FeSiO3 Slag

4.

This is a 3o and resonance stabilized carbocation.

5.

Cumulated diene is least stable, evolve max heat in the hydrogenation reaction.

11.

Number of revolution made by an electron per sec

2
v
2Ze

n
2rn
n2h2
nh 2

2
4mZe

42mZ 2 e4 42me4 Z 2


n3h3
h3 n3

Z2
1
6.66 1015 6.66 1015
n3
8
= 8.3 1014

13.

Vapour pressure depends on temperature not on size of container.

14.

There is no intermolecular forces of attraction in ideal gases.

16.

3A B
2C
d B 1 d C
1 dA

K A B
3 dt
dt
2 dt
dA

3K A B K A B
dt
i.e. K 3K
d C
2
So that
2K A B = K A B
dt
3
r

17.

KP PCO2 , which will depends temperature of the system only.

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14

18.

Water will be neutral as [H ] = [OH ]

20.

Zinc is more electropositive than silver therefore, it displaces less electropositive silver.

21.

Carnalite is a double salt KCl.MgCl2.6H2O which give test of K+, Mg+2 and Cl.

22.

2Cu2 2CN 2Cu CN2


3KCN
Cu CN CuCN
K 3 Cu CN 4

23.

Mass number change only by -particles and atomic number reduces by 2 unit by each -particle
and increase by 1 unit by -particle.

27.

CH 2OH

CH 2OH
OH

H
OH

OH

OH
OH

OH

H
H

Galactose unit

OH

Glucose unit

The 1st step is electrophilic addition i.e. rate determining step, more stable will be the intermediate
better will be the rate of reactions.

28.
29.

CH2OH
CH2 C

OEt

,dry HCl

CH2OH

O
CH2

OEt

O
LAH / THF

CH2

CH2 OH
H2 O

CH2

CH2 OH EtOH

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14

Mathematics

PART III
SECTION A

1.

HHH , RR , I,I, P,P , AYU =

12

2.

C7

7!
1 198 7!
2!2!

a b a b a b 2 |a + b| = |a b|
a
a
1 1
b
b
a

is perpendicular bisector of (1, 0) and (1, 0)


b
a

is purely imaginary
b

3.

dV t
K T t
dt
2

V t

K T t
C
2

At t = 0, V = I C I

KT2
2

Scrap value V(T) V(t = T) = C = I

4.

2 tan1 x tan1 x

tan1 x

KT 2
2

3 2
0
8

x = 1
5.

t2 2

lim

1 1
1 1
t 2 2 1 2 2 1
t t
t t

Now ||x 1| 6| = k has four distinct solutions if k (0, 6)


Number of integral values of k is 5
t

xx
2

6.

f x

7.

CaseI: when

p2
2 p 6 and f(2) = 8
2

P=2
CaseII: when

p2
2 p>6
2

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14
2

p 2 4 3p 2
D
8
8
4a
4

P = 82 5
p 8 2 5 and p 8 2 5 (rejected)
Sum of values of p is 2 8 2 5 10 2 5 10 20
m + n = 30
2

8.

We have (x y) + (y 3) = 0
x=y=3

9.

We have f(x) > f(2) x < 2


lim f x f 2 1
x 2
2

a 9a 9 1
a2 9a 10 0
a 1 or a 10
But a is positive. Hence a 10. That is a [10, [
Note that when a = 10
3 x, x 2
f x
2x 3, x 2
So that f is continuous at 2, f(2) does not exist and f(x) 0 x R. Therefore, x = 2 is a critical
point and f(x) changes sign from negative to positive at x = 2
10.

We have a b

1
a

1
and b a
1
1
a
b
a
b
1
ab
1
b
b
1
1
a b (ab 1)(a b) = 0
a
b
ab = 1 a b
1
a b
a2 b2 = 1
ab

a b

11.

Probability that calculator of brand r is selected and is defective


6

kr

7r k
7r r 2 8k

21 21 r 1
3

.. (1)

Let Er denote the event that calculator of brand r is selected P(Er) = kr


Since Er(r = 1, 2, .., 6) are mutually exclusive and exhaustive events we must have
6

P Er 1

r 1

kr 1 k 21
r 1

required probability =

8k
8 p

3
63 q

(p + q) = 71

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9
AITS-FT-IV-PCM (Sol)-JEE (Main)/14

12.

P(r) = (2r + 1)
n 1

n 1

P r

r 1

2r 1 n

r 1

1
n2 1
lim 3
2 n an bn2 c
a = 0, b = 2
So, (a + b) = 2

13.

14.

Let tan x = and tan y = then a tan + b sec = c and a tan + b sec = c
Obviously a tan + b sec = c has roots tan and tan
2
2
2
2
2
(a b ) tan 2 ac tan + c b = 0
2ac
c 2 b2
tan tan 2
and
tan

tan

a b2
a2 b2
xy
2ac
So

1 xy a2 b2

lim e2

x o

x x 2

1
1
e2 ln5

2x x 2 tan x 2
2
x

e2 5 1 ex 1
e2
lim
e2 ln 5 ln5
2sin x 1 cos x 2
x o
2
x

x
x x2

=1
2

15.

1 3tan2 1 cot1 1 3 tan2 1 1


1

=
1

2
3
cot
3
cot
3
tan3
cot 3
3 tan 1
3 tan1 tan 1

16.

1 sin2x 1/ x
e2
x 0
1

17.

lim

f(x) = x + 3x 2
x 3 3x 2
f x dx

2x c
3
2

18.

f(x) = (x 1) (x 2) (x 3) (x 4)
f 1 f 2 f ' 3 0
4
3
2
4
3
f ' x x 1 x 2 x 3 1 x 1 x 2 2 x 3 x 4
4
2
2
3
3
2
x 1 3 x 2 x 3 x 4 4 x 1 x 2 x 3 x 4
3
f(4) = 3(6 )

19.

a + ar = 12
ar2 + ar3 = 48
r2 = 4 r = 2, r 1, 2

.. (1)
.. (2)

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14

20.

3k 2 5k 3 6k 4
P
,
,

k 1
k 1
k 1
3
3k 2 13
Hence

k
k 1
5
2

1 2a a2 1 p p2

21.

22.

1
1 2b b2 1 q q2 = 2 21 22 = 812 = 8 4 16
2
1 2c c 2 1 r r 2

(a + b)x + (2b 2a)y + (3b 3a) = 0


a
a + b = 0
b
3
y
2
2

23.

24.

25.

x y 1
xy3

2
2

1
10
5/2
2
2
Here a = 10 and b = 5/2 and centre is (1, 2)
Locus of feet of perpendicular lie on auxiliary circle of ellipse
Equation of circle is (x 1)2 + (y 2)2 = 10

4; 0 x 2

2 x

2
f x
0; x 3n

2
x 2

2
Range of function = {0, 2, 4}

tan
2
2

bc a

1 cos

1 cos

1 b c

1 a
bc

abc

a b c a b c 1

26.

34 = 81

27.

We have, cos2 x (c 1)cos x + 2c 6 0 x R


(cos x 2)(cos x (c 3)) 0
cos x c 3
c31c4

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AITS-FT-IV-PCM (Sol)-JEE (Main)/14

28.

px2 + qx + r = 0
2
rx + qx + p = 0 (on subtract)
x = 1
So common root is 1
pq+r=0

29.

[{x}] = 0
1

f x 3 x7 7
1

1 7 7

x
7
7

f f x 3 3 x

1
f(f(x)) = x f (x) = f(x)
f 1(50) = f(50) and f(f(100)) = 100
1
f (50) f(50) + f(f(100)) = 100

30.

Put a = 2R sin A, b = 2R sin B


2R sin B (sin2 A + cos2 A) = 2a
2R sin B = 2a
b
2
a

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