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LOVE TO SINK
MY TEETH INTO
THESE!
eyond our
traditional role
in supplying
corrosion inhibitors to
the paints and coatings
market, HALOX
is actively involved
in solving corrosion
problems for a variety
of other markets.
These include metal
pretreatments, metal
working fluids, adhesives,
inks, and much more.
Mx (PO4 )y
Hydrolysis
Corrosion Inhibitor
+
-
PAINT FILM
H2 O
Fe 2+
FePO4
Fe
Anode
Anodic passivation
Precipitate
M(OH)x
e-
Cathode
Cathodic precipitation
HALOX SZP-391
A strontium zinc
phosphosilicate inhibitor with
the broadest formulating
latitude.
HALOX SW-111
A strontium phosphosilicate
inhibitor for high solids,
solvent-borne, water-borne
epoxies and acrylics.
HALOX 430
A heavy metal-free calcium
phosphate inhibitor combining
cathodic passivation and
ion scavenging/exchange
mechanisms.
HALOX CW-291
A surface treated calcium
borosilicate inhibitor for
solvent-borne coatings.
HALOX 310
A low-cost corrosion inhibitive
pigment with hydrophobic
modification.
HALOX SZP-391 JM
A finely micronized strontium
zinc phosphosilicate inhibitor
with even broader formulating
latitude
HALOX CW-2230
A calcium borosilicate inhibitor
for alkyd and 2K polyurethane
systems.
HALOX 410
A zinc-free organically
modified pigment for
water-borne or solvent-borne
coatings.
HALOX 430 JM
A finely micronized heavy
metal-free calcium phosphate
inhibitor combining cathodic
passivation and ion scavenging/
exchange mechanisms.
I n o r g a n I c
SUBSTRATE
ProDUct LIst
haLoX sZP-391
THERE IS NO kNOCk-Off!
ZAM Plus
HALOX SZP-391
PPS-10
Wayncor 226
ZCP
HS Phenolic Alkyd
BHRS
Salt Spray
528 HRS.
Water Reducible
Epoxy Ester - CRS
Ext. Exposure
3.5 YRS.
DTM Water-borne
Acrylic - CRS
Prohesion
672 HRS.
Water-borne
Acrylic
Galvanized
Prohesion
840 HRS.
I n o r g a n I c
5
4
WATERBORNE
3
2
1
ACRYLIC
ALKYD
HYBRIDS
EPOX
EPOXY
POLYURETHANE
haLoX 430
COIL
WASH
PRIMER PVB
SOLVENTBORNE
ACIDIC
VINYL
ACRYLICS
Water-borne
Acrylic Primer
CRS
Water-borne
Acrylic DTM
Galvanized
Water-borne Epoxy
CRS
Solvent-borne
Coil Coating
Phosphate Steel
Hybrid Acrylic
Alkyd
CRS
WATERBORNE
3
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
PRE-COATED
METAL (COIL)
AIRCRAFT
PRIMERS
WASH
(ETCH)
PRIMER
ACIDIC RESINS
(VINYL
ACRYLICS)
SOLVENTBORNE
haLoX sZP-391 JM
3% HALOX
SZP-391 JM
3% HALOX
SZP-391
6% HALOX
SZP-391
6% HALOX
SZP-391 JM
BLANK
3% COMPETITOR A
3% HALOX 550
3% HALOX 550
3% HALOX SZP-391 JM
WATERBORNE
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
haLoX 430 JM
HYBRIDS
PRE-COATED
METAL
(COIL)
HIGH GLOSS
DTM
SOLVENTBORNE
WASH
(ETCH)
PRIMER
MICRONIZEd PROduCTS
D50 6m
Dgg 30m
CALCIuM
M PHOSPHATE + ION EXCHANGE
EXCHANGE
HALOX 430 JM is designed for long-term
corrosion protection and is suitable for clear
coat systems.
AdvANTAGES: The jet-milled feature offers
significant advantages for thin film applications (<10
microns). Its easy to disperse and provides cleaner
grinds for improved corrosion inhibition efficiency.
It is a moderate solubility corrosion inhibitor
and hexavalent chromate replacement option for
galvanized, Galvalume and aluminum alloys.
MECHANISM:: Cathodic passivation and ion
exchange/scavenging
3 COATS
PARTICLE REDUCTION
Dgg 5m
JET-PULVERIZATION
50 MICRONS
75 MICRONS
50 MICRONS
2 COATS
S U B S T R A T E
2k S/B POLYuRETHANE
SALT
ALT SPRAY 336 HRS.
CRS - 50 MICRONS
BLANK
D50 2m
< 25 MICRONS
1 COAT
5% HALOX 430 JM
7% ZINC
CHROMATE
5% HALOX 430 JM
1.5% HALOX 550
WATERBORNE
3
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
PRE-COATED
METAL (COIL)
AIRCRAFT
PRIMERS
WASH
(ETCH)
PRIMER
ACIDIC RESINS
(VINYL
ACRYLICS)
SOLVENTBORNE
I n o r g a n I c
haLoX sW-111
2k
k HIGH SOLIdS POLYAMIdE
E CuREd EPOXY
SALT
ALT SPRAY 1,008 HRS. CRS - 44% PvC 1.4 MILS./35 MICRONS dfT
STRONTIuM PHOSPHOSILICATE
BLANK
8% Modified Zinc
Aluminum Phosphate
6% Zinc Aluminum
Polyphosphate
6% HALOX
SZP-391
8% HALOX
SW-111
WATERBORNE
I n o r g a n I c
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
haLoX cW-291
WASH
(ETCH)
PRIMER
SOLVENTBORNE
ACIDIC RESINS
(VINYL
ACRYLICS)
MEdIuM OIL
IL ALkYd - SALT
ALT SPRAY 708 HRS. CRS
CALCIuM BOROSILICATE
HALOX CW-291 is a calcium borosilicatebased corrosion inhibitor designed for long-term
corrosion protection where heavy metals are of
concern. CW-291 can match the performance of
toxic corrosion inhibitors such as zinc chromate.
AdvANTAGES: It is the highest solubility
corrosion inhibitor used to optimize early corrosion
resistance via anodic passivation. HALOX CW-291
can be used in synergy with zinc phosphate-based
inhibitors.
MECHANISM: Anodic passivation and
saponification (insoluble salt formation with acid
binders)
BLANK
HALOX CW-291
HALOX SZP-391
HALOX SZP-391 :
HALOX CW-291
2:1
WATERBORNE
3
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
WASH
(ETCH)
PRIMER
ACIDIC RESINS
(VINYL
ACRYLICS)
SOLVENTBORNE
haLoX cW-2230
CALCIuM BOROSILICATE
HALOX CW-2230 is a calcium borosilicate-based
corrosion inhibitor engineered for long-term
corrosion protection where heavy metals are a
concern. CW-2230 has low moisture content (0.5%)
which makes it highly compatible and efficient for
systems cross-linked with isocyanates. It can be
efficiently formulated into medium and long oil
alkyds, epoxy esters and modified alkyd systems.
AdvANTAGES:: HALOX CW-2230 offers
the highest solubility corrosion inhibitor used
to optimize early corrosion resistance via anodic
passivation.
MECHANISM:: Anodic passivation and
saponification (insoluble salt formation with acid
binders)
BLANK
5% Competitor B
5% Competitor A
3% HALOX CW-2230
1% HALOX 430 JM
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
WASH
(ETCH)
PRIMER
SOLVENTBORNE
ACIDIC RESINS
(VINYL
ACRYLICS)
Water-borne Acrylic
CRS - Salt Spray
750 HRS.
Water-borne
Low VOC Acrylic
CRS Salt Spray
550 HRS.
WATERBORNE
3
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
COIL
WASH
PRIMER PVB
PHENOLIC, EPOXY
ACIDIC
VINYL
ACRYLICS
SOLVENTBORNE
I n o r g a n I c
WATERBORNE
haLoX 310
ORGANICALLY
RGANICALLY MO
MOdI
d fIE
f dM
MINERAL
INERAL PIGMENT
PIGMENT
HALOX 310 is a low-cost corrosion inhibitor
recommended for light industrial maintenance
coatings. It provides better corrosion protection
than comparable low-cost commodity zinc-free
inhibitors. This product contains less than 2.5%
zinc compounds falling below the hazardous labeling
threshold for Europe.
AdvANTAGES:: HALOX 310 can be used in
multiple resin systems (solvent-borne and waterborne). It provides superior corrosion protection
over competitive low-cost alkaline earth metals.
MECHANISM:: Precipitation, anodic passivation
and hydrophobicity
BLANK
6% Dicalcium Phosphate
6% HALOX 310
8% Zinc Phosphate
5
4
I n o r g a n I c
3
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
haLoX 410
HYBRIDS
PRE-COATED
METAL
(COIL)
HIGH GLOSS
DTM
SOLVENTBORNE
WASH
(ETCH)
PRIMER
ORGANICALLY
RGANICALLY MO
MOdI
d fIE
f dM
MINERAL
INERAL PIGMENT
PIGMENT
HALOX 410 is a low-cost, heavy metal-free
corrosion inhibitor recommended for light
industrial maintenance coatings.
AdvANTAGES:: HALOX 410 can be used in
multiple resin systems (solvent-borne and waterborne). It provides superior corrosion protection
over competitive low-cost alkaline earth metals,
and does not require hazardous labeling.
MECHANISM:: Precipitation, anodic passivation
and hydrophobicity
BLANK
7% Calcium Phosphate
7% HALOX 410
7% Zinc Phosphate
WATERBORNE
3
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
PRE-COATED
METAL
(COIL)
HIGH GLOSS
DTM
WASH
(ETCH)
PRIMER
SOLVENTBORNE
o r g a n i c
ProDUct List
HALOX 515
A liquid (27% active) flash
rust and long-term corrosion
inhibitor.
HALOX 570
A powder (100% active) flash
rust and long-term corrosion
inhibitor.
HALOX 630/630 HF
A liquid (70% active) adhesion
promoter and corrosion inhibitor.
HALOX 650
A powder (100% active) adhesion
promoter and corrosion inhibitor.
haLoX 515
AMINO CARbOXyLATE
LATE CHEMISTRy
HEMISTR
HALOX 515 is a liquid organic corrosion inhibitor
for high gloss (direct to metal) coating systems.
AdvANTAGES:: Its a liquid, flash rust and
corrosion inhibitor for water-borne coatings.
bENEFIT: An effective weld seam corrosion
preventative that does not affect the coatings gloss.
It is post-addable and environmentally-friendly! It
is nitrite-free, phosphate-free, heavy metal-free
and does not require hazardous labeling. It provides
synergy with anti-corrosive pigments (HALOX
SZP-391, HALOX 430, etc.) to maximize corrosion
resistance.
RECOMMENdEd:
d: Water-borne acrylic DTM,
acrylic primers, polyurethane, water dispersible
alkyds, water reducible alkyds
haLoX 570
o r g a n i c
BLANK
3% HALOX 510
3% HALOX 515
vINyL
L MOdIFIEd EpOXy ESTER HybRId
SALT
ALT SpRAy 350 HRS. CRS 2.0 MILS. (50 MICRONS)
BLANK
1% HALOX 570
2% HALOX 570
2% HALOX 570
WEIGHT
De-ionized Water
28% Ammonium Hydroxide
62.8
7.2
HALOX 570
30.0
TOTAL
100.0
Stir slowly, adjust to pH 8-9
haLoX 630
ALkyLAMMONIuM
M SALT SOLuTION
(cut in Xylene)
haLoX 630 hF
BLANK
4% HALOX 630
BLANK
4% HALOX 630
ALkyLAMMONIuM
M SALT SOLuTION
haLoX 650
BLANK
4% HALOX 630
4% HALOX 630 HF
ORGANIC dIACId
BLANK
Commercial System
(Zinc Chromate)
4% HALOX 650
+ Ion Exchange
1% HALOX 650
o r g a n i c
(cut in PM Acetate)
H Y B R I D
PRoDUCt LIst
HALOX 550
A liquid sol-gel organic-inorganic hybrid
suitable for replacing hexavalent chromium
based corrosion inhibitors used in protective
coatings and surface treatments. It
forms a clear network and a non-porous,
hydrophobic, dense barrier at the metal
surface.
HALOX 750
An inorganic-organic powder corrosion
inhibitor used in light duty industrial
coatings.
INORGANIC
INHIBITOR
ORGANIC
INHIBITOR
HYBRID
CORROSION
INHIBITOR
HALoX 515
HALOX550: How
it works
HALOX 550 SYNERGY with Inorganic Pigments
RO
H2 O
OR
Si
OR
RO
OH
Si
M
O
+ ROH
O
IN
M
O
M
O
IN
M
O
OR
RO
RO
Si
OH + OH OH OH OH
Si
O
SUBSTRATE
OR
RO
ROH
SUBSTRATE
3. GELATION (CROSS-LINKING)
POLYMER
RO
Si RO
Si
Si
Si
O
Si
Si
O
+ H2 O + ROH
SUBSTRATE
HALoX 550
inOrgAniC-OrgAniC sOL-geL
HALOX 550 is a liquid organic-inorganic sol-gel
corrosion inhibitor designed for corrosion protection
in thin film coatings: water-borne and solvent-borne
finishes, gloss DTM, conventional primers, acrylic
clear coats, fast drying lacquers, wash primers, antifingerprint and conversion coatings.
AdvAntA
nt ges: It provides excellent corrosion
ntA
resistance in thin film applications. It reduces white
rust on galvanized steel and black rust on Galvalume
substrates. Furthermore, it reduces the oxidation of
silver, steel and aluminum alloys.
benefits: Does not affect gloss. It is postaddable and environmentally-friendly! It provides
synergy with anti-corrosive pigments (SZP-391,
HALOX 430, Zinc phosphate) to maximize
corrosion resistance.
reCOmmended:
mmended: It can be used in water-borne
and solvent-borne paints. Its also recommended as
an aqueous rust preventative (RP), which can be topcoated to improve adhesion and corrosion resistance.
meCHA
e
eCHA
nism: Hydrophobic film formation,
adhesion promoter, synergist
5% Competitor A
5% HALOX 550
10% Competitor A
BLANK
1.3% Modified
Zinc Phosphate
BLANK
7% Zinc Chromate
3% HALOX SZP-391
3% HALOX SZP-391
3% HALOX 550
H Y B R I D
SUBSTRATE
HALoX 750
Hybrid
HALOX 750 is an inorganic-organic hybrid for
industrial light duty coatings.
feAture:
ture: HALOX 750 is a hybrid corrosion
inhibitor combining organic and inorganic inhibitor
synergies.
AdvAntA
nt ges: Value-added: Improved humidity
ntA
resistance, wet adhesion, pigment dispersion
and stability, and lower oil absorption, barrier
properties, and anodic passivation.
benefits:
enefits: It is a cost-effective alternative to
modified zinc phosphate. It can potentially replace
strontium chromate in light duty applications.
reCOmmended:
mmended: Water-borne and solventborne paints: acrylic, alkyd, epoxy, epoxy esters
and hybrid coatings
5% Zinc Phosphate
H Y B R I D
5% HALOX 750
5% Modified Zinc
Phosphate
7% HALOX 750
7% Zinc Aluminum
Molybdenum
Orthophosphate
reCOmmendAtiOn (5 = strOngLy
L reCOmmended)
Ly
5
4
WATERBORNE
3
2
1
ACRYLIC
ALKYD
POLYURETHANE
EPOX
EPOXY
HYBRIDS
WASH
(ETCH)
PRIMER
ACIDIC
VINYL
ACRYLICS
SOLVENTBORNE
WAter-bOrne rust
ust Prevent
PreventAtive
HALOX 900 is a water-based, nitrite-free rust
preventative or temporary corrosion inhibitor
designed to offer corrosion protection to bare metal
surfaces prior to use, for example during storage,
metal processing, manufacturing, shipping and supply
intervals. HALOX 900 provides protection for
both ferrous and non-ferrous (aluminum & copper)
substrates.
feAtures:
tures: HALOX 900 is highly penetrative.
Its enhanced wetting ability allows it to form a
uniform quick-drying protective film which offers
indoor rust protection ranging from a few days to
months depending on the dilution level and exposure
conditions (see table below).
AdvAntAges:
ges: HALOX 900 pretreatments
allow customers to improve the performance of their
existing coatings without having to reformulate.
The performance required can be easily tailored
by controlling the dilution amount of the product in
water. The product does not have to be removed prior
to coating.
benefit: Saves time, resources, and money!
reCOmmended:
mmended: Short-term rust preventative
and pretreatment for steel, copper and aluminum,
water blasting rinses
BLANK (Tap
Water)
Competitor A
(Nitrite-free)
Competitor B
(Nitrite-free)
Without
Pretreatment
With
Pretreatment
HALOX 900 in
tap Water
t
HALOX 900
(Nitrite-free)
Competitor C
(Nitrite)
Without
Pretreatment
With
Pretreatment
dilutions by volume
indoor storage
s
Outdoor storage
s
1-2%
< 1 Week
Few Days
5-10%
Weeks 3 Months
1-2 Weeks
10-15%
6-9 Months
3-6 Months
> 20%
9-12 months
> 6 Months
S P E C I A L T Y
HALoX 900
PRoDUCt LIst
f L A S H
R u S T
fLAsH-X 150
fLAsH-X 350d
FLAsH-X 150
BLANK
FLAsH-X 330
2% Flash-X 330
R u S T
FLAsH-X 350D
BLANK
f L A S H
OrgAniC di-ACid
Cid COrrOsiOn
C
inHibitO
ibit r
ibitO
Flash-X 350D is a 97-100% active organic
corrosion inhibitor providing effective control of
in-can corrosion, temporary corrosion protection and
flash rust. This product is designed as an efficient
and effective replacement for nitrite-based
inhibitors, which are often reported as toxic.
benefit:
enefit: Its very effective at low loading levels
and improves coating adhesion.
reCOmmended:
mmended: Inks, fountain solutions
(FOGRA test), acrylic latex paint, water treatment
Distilled Water
30% fLA
f sH-X 350d solution
s
Weight
De-ionized Water
57.3
15.0
FLASH-X 350D
27.7
TOTAL
100.0
Stir slowly, adjust to pH 8-9
tHE PoWER oF
sYnERGY
S Y n E R g Y
BLANK
5% HALOX 430
(Inorganic Inhibitor)
2% HALOX 515
(Organic Inhibitor)
5% HALOX 430
1% HALOX 515
inOrgAniC inHibitO
ibit r
ibitO
PassivatiOn
OrgAniC inHibitO
ibit r
ibitO
Decrease P
Decrease ermeability
PassivatiOn
aDhesiOn PrOmOti
O On
Oti
imPrOveD wetting
POre P
re lugging
re P
5% HALOX 430
1% HALOX 515
EUROPE
NORTH
AMERICA
ASIA
AFRICA
SOUTH
AMERICA
AUSTRALIA
ANTARCTICA