Brilliant

STUDY CENTRE

Puliyannoor P.O., PALA

30 - 01 - 2013

KERALA CEE MEDICAL MODEL EXAMINATION

Ph - 04822 206416, 206516, 206459

www.brilliantpala.org

1.

B) E ext E cell

C) E cell 0

D) E ext E cell

E) None

B) Potentiometer

C) Galvanometer

D) Ammeter

E) None

For which of the following order of reaction t1/2 is directly proportional to initial concentration of reactant?
A) Zero order

4.

M1

The emf of a cell is measured by:

A) Voltmeter

3.

Paper I - (Physics + Chemistry)

VERSION

An electrochemical cell can behave like an electrolytic cell when

A) E ext E cell

2.

Batch: All Batches

B) First order

C) Second order

D) Third order

E) None

Choose the incorrect statement

A) Catalyst allows the rate of reaction by changing Ea
B) e Ea RT is fraction of molecules with energy equal or greater than Ea
C) Second t 12 of first order reaction is half of the first t 12
D) Both A and B
E) A, B and C

5.

The following chemical reaction is of zero order at high pressure 2NH 3 g N 2 g 3H 2 g choose the correct
option for the reaction
A) Rate of reaction is proportional to the conc. of NH3
B) Unit of rate constant is mol L-1S-1
C) Half life of the reaction is independent of conc. of NH3
D) Both A & B
E) A,B & C

6.

2
2
Consider the following statements regarding electrochemical cell Zn S Zn aq Cu aq Cu S

I. Electrons move from Zn to Cu

II. Concentration of Zn2+ will increase and that of Cu2+ will decrease when cell operates
III. When cell becomes dead, E 0cell 0
Choose the correct statement(s)
A) I, II and III
7.

C) I & II

D) II & III

E) I only

The amount of electricity required to obtain 10 mole of Al from molten AlCl3 is

A) 10F

8.

B) I & III

B) 60F

C) 20F

D) 30F

E) 1F

During rusting following redox reaction takesplace 2H 1 2 O 2 Fe H 2 O Fe 2 , E 0 1.67V . What is

G 0 of the reaction
A) -322.31 KJ

B) -161.155KJ

C) 322.31KJ

D) 161.155KJ

E) None

FT13 N/CEE/MOD/PCB/[M1]

9.

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Smelting is termed to the process in which

A) The ore is heated in the absence of air
B) Ore is cold
C) The ore is heated in the presence of air
D) Ore is melted
E) None

10. Which reaction is involved in extraction of Ag by cyanide process

A) AgBr +Na2S2O3 Na 3 Ag S2 O 3 2
B) AgCl NH 4 OH Ag NH3 2 Cl
C) Ag 2S NaCN Na Ag CN 2
D) Both B & C
E) None
11. Spelter is
A) Impure copper B) Impure zinc

C) ZnO

D) CuO

E) Impure Au

12. Bauxite is not purified by

A) Halls process

B) Serperk process

C) Baeyer process

D) Hoops method

E) None
13. Which one of the following chemical units is certainly to be found in an enzyme?

OH
O
A)

O
HO

H
B)

HO

O
O
O R

O
O

N
C)

D)

N
14. Glycolysis is

E) none

A) Conversion of glucose to haem

B) Oxidation of glucose to glutamate

C) Conversion of pyruvate to citrate

D) Oxidation of glucose to pyruvate

E) none

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15. Which of the following statement not true for step growth polymer/condensation polymer.
A) They are formed by a series of independent reactions.
B) There is no elimination of H2O/ NH3/HCL during condensation polymerization.
C) Monomers combine to give dimer, dimer combine to give tetramer and the process continue in a stepwise
manner.
D) Nylon 6 , Nylon 6,6, Dacron, Glyptal, Bakelite are step growth polymers.
E) Both B and D
16. Polymers in which the chains are held by vander waal force of attraction known as
A)Elastomers

B) Thermoplastics

C) Thermosetting plastics

D) Fibres

E)Resins

17. Food preservative used to inhibit growth of yeast and moulds is

A) Sodium sorbate B) Cyclamate

C) BHT

D) SO2

E)Tetrazine

18. Orlon is a polymer of

A) Styrene

B) Tetrafluroethene

C) Vinyl chloride

D) Acrylonitrile

E) None

19. A hypothetical reaction A 2 B2 2AB follows the mechanism as given

A 2 A A Fast ; A B2 AB B Slow ; A B AB Fast

The order of the overall reaction is
A) 1.5

B) 2.5

C) 3

D) 2

E) 0

20. 99% of first order reaction was completed in 32 min, when will 99.9% of the reaction complete?
A) 24 min

B) 8 min

C) 4 min

D) 48 min

E) 30 min

21. For a chemical reaction 2X Y Z , the rate of appearance of Z is 0.05 mole L1 hr1. The rate of
disappearance of X will be:
A) 0.05 mole L1 hr1
C) 0.1 mole L1 hr1

B) 0.06 mole L1 hr1

D) 0.25 mole L1 hr1

E) 0.01 mole L1 hr1

22. An ore of tin containing FeCrO4 is concentrated by :

A) Froth floatation process

B) Magnetic separation method

C) Electrostatic method

D) Gravity separation method

E) Reduction

23. Chemical leaching is useful in the concentration of :

A) Copper pyrites B) Bauxite

C) Galena

D) Cassiterite

E) None of these

24. The equivalent conductivity of monobasic acid at infinite dilution is 348 ohm-1 cm2 eq-1. If the resistivity of
the solution containing 15g acid (mol. wt. 49) in 1 litre is 18.5 ohm cm, what is the degree of dissociation of
acid?
A) 45.9%

B) 40.2%

C) 60.4%

D) 50.7%

E) 32.7%

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25. The ionic conductance of Ba2+ and Cl ions are respectively 127 and 76 1cm 2 at infinite dilution. The
equivalent conductance (in ohm-1 cm2) of BaCl2 at infinite dilution is :
A) 203

B) 279

C) 101.5

D) 139.5

E) 142.2

C) 4

D) 5

E) 6

26. Oxidation state of Cr in CrO5 is

A) 2

B) 3

27. Column I

Column II

(Compound)

(Oxidation state of sulphur)

a) Sulphurous acid (H2SO3)

p) + 5

b) Peroxy mono sulphuric acid (H2SO5)

q) + 3

c) Dithionic acid (H2S2O6)

r) + 6

d) Dithionous acid (H2S2O4)

s) + 4

A) a s; b r; c p; d q

B) a r; b q; c p; d s

C) a s; b r; c q; d p

D) a r; b q; c s; d p

E) None

28. The oxidation state of three bromine atoms in tribromoocta oxide (Br3O8) is :
A) +4, +4, +4

B) +6, +5, +6

C) +6, +4, +6

D) +3, +4, +3

E) +6, +6, +6

29. The compound which reacts fastest with Lucas reagent at room temperature is
A) butan-1-ol

B) butan-2-ol

C) 2-methyl propan-1-ol

D) 2-methyl propan-2-ol

E) Both A & B

30. The intermediate species involved in the acid catalysed dehydration of alcohol is :
A) free radicle

B) carbanion

C)carbene

D) zwitter ion

E) carbo cation

31. Identify Z in the series ,

C3H7OH
A)

B)

C)

D) CH3-C CH

E) none

CH Cl
Alk.KMnO
Zn dust
X
Y

Z, the product Z is:

32. Phenol
Anh.AlCl
3

A) Benzaldehyde

B) Benzoic acid

C) Benzene

D) Toluene

E) Benzylchloride

33. In the following sequence of reaction,

P I2
H2O
Mg
HCHO
CH3CH 2 OH
A
B
C
D
ether

The compound D is
A) butanal

B) n-butyl alcohol

C) n-propyl alcohol

D) propanal

E) butan-2-al

FT13 N/CEE/MOD/PCB/[M1]

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34. Predict the product?

BF3
?
ROH CH 2 N 2

A) R COOCH 3 N 2

B) R O CH 3 N 2

C) R CH 3

D) R CO CH 3

E) None

35. Oxidation number of nitrogen is given correctly for

Compound

Oxidation No.

A) Co NH3 5 Cl Cl2 O

B) NH2OH

-1

C) (N2H5)2SO4

+2

D) Mg3N2

-3

E) Both b & d
36. The equivalent weight of MnSO4 is half its molecular weight when it is converted to
A) Mn2O3

C) MnO4

B) MnO2

D) MnO24

E) None

37. A sample of HCl is placed in an electric field of 2.5104 N/C. The dipole moment of HCl is 3.41030 Cm.
Find the maximum torque that can act on a molecule
A) 7.61026Nm

B) 4.31026 Nm C) 6.51026Nm

D) 8.51026Nm

E) 5.61026Nm

38. An electron is projected with a velocity Vo at an angle in the presence of an electric field E as shown in
figure

Find minimum value of d so that electron doesnt hit the plate

A) d

mV02
2eE

B)

mV02 cos 2
2eE

C)

mV02 sin 2
2eE

D)

mV02 tan 2
2eE

E)

mV02
2e

39. Two charges Q1 and Q2 are distance d apart two dielectrics of thickness t1 and t2 and dielectric constant
K1 and K2 are introduced as shown. Find the force between the charges

Q1Q 2
A) 4 d t t k t k t 2
1 2 1 1 2 2
o
Q1Q 2
C) 4 d k t k t
o
1 1
2 2
E) None of these

B) Zero
Q1Q 2

D) 4 k t k t d t t 2
o
1 1
2 2
1
2

FT13 N/CEE/MOD/PCB/[M1]

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40. A child stands inside a large charged metal sphere will her hair stand on end?
A) Yes

B) No

C) Incomplete information

D) No guess about her hair style

41. Two thin wire rings each having a radius R are placed at distance d apart with their axes coinciding. The
charges on the two rings are +Q and Q. The potential difference between the rings are
QR
A) 4 d 2
0

C)

Q
4 0

B)

R 2 d2
R

Q
2 0

R 2 d2
R
QR
E) 3 d
0

D) Zero

42. A parallel plate capacitor with plate area 100cm2 and seperation between the plate 5mm is connected
across a 24V battery. The force of attraction between the plates is of the order of
A) 106 N

B) 108N

C) 104N

D) 107N

E) 105N

43. Mark the correct option

A) Gausss law is valid only for symmetrical charge distributions
B) Gausss law is valid only for charges placed in vaccum
C) The electric field calculated by Gausss law is the field due to charges inside the Gaussian surface
D) The flux of electric field through a closed surface due to all the charges is equal to the flux due to the
charges enclosed by the surface .
E) both A & D
44. Find the drift velocity in Cu wire if it has 1A current through 2mm2 cross section. Free electron density is
8.51022 cm3
A) 0.36mms1

B) 0.36cms1

C) 0.036mms1

D) 0.036cms1

E) 0.026mms1

45. Two non-ideal batteries are connected in parallel then

1) The equivalent emf is less than either of the two emfs
2) The equivalent internal resistance is less than either the two internal resistances
A) both 1 and 2 are correct

B) only 1 is correct

C) only 2 is correct

D) both 1 and 2 are wrong

E) None

A) 8A, 9 , 54V, 36V

B) 8A, 9 , 36V, 54V

C) 9A, 8 , 36V, 54V

D) 4A, 3 , 12V, 54V

E) 2A,3,36V,12V

46. In the fig. below find I,R, 1 and 2

FT13 N/CEE/MOD/PCB/[M1]

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47. An electric bulb is rated 220V 100 watt. The power consumed by it when operated on 110V will be
A) 50 watt

B) 75 watt

C) 40 watt

D) 25 watt

E) 35 watt

48. Two resistors when connected in parallel have an equivalent resistance of 2 and when in series, of 9 .
the value of the two resistors are
A) 2 and 9

B) 3 and 6

C) 4 and 5

D) 2 and 7

E) 1 and 3

49. A long copper tube of inner radius R carries a current I. The magnetic field B inside the tube is
A)

0I
2R

B)

0I
2R

C) Zero

D)

0I
4R

E)

0I
R

50. Two infinity long conducting wires carry current as shown in the figure. If the wire carrying current along x
direction produces a magnetic field B at point (2a, a, 0), then the resultant magnetic field at point P is

A) 2.0Bk

B) 1.5Bk

C) Zero

D) 1.5Bk

E) 2.5Bk

51. The deflection in a moving coil galvanometer is reduced to half when shunted with a 40 resistance. The
resistance of the galvanometer is
A) 80

B) 40

C) 15

D) 20

E) 10

52. A proton, a deuteron and an -particle having the same K.E. are moving in circular orbits in the given
magnetic field B. If R p , R d and R denote the radii of orbits of the particles respectively then
A) R p R d R

B) R R p R d

C) R R d R P

D) R R d R P

E) None of these

53. Helium nucleus travelling along a curved path in the magnetic field has velocity V. The velocity of protons
moving in the same magnetic field along the same curved path will be
A) V

B)

V
2

C) 2V

D) 4V

E) 3V

54. A current of 50mA flows in a rectangular coil of effective area 75103m2. If the coil is in equilibrium in a
field of 40G, then the torque is
A) 150Nm

B) 1.5105Nm

C) 1.5107Nm

D) 1.5103Nm

E)2.5106Nm

55. A 10 cm long magnet has pole strength 12Am. The magnetic field at a distance 20cm from it is
A) 2.4105T

B) 3.4105T

C) 3.8105T

D) 3.0105T

E) 2.8105T

FT13 N/CEE/MOD/PCB/[M1]

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56. Horizontal component of earths field is 3105T and of dip is 53. Find magnetic field of earth at that place
(tan 53 = 4/3)
A) 4105T

B) 3105T

C) 5105T

D) 1105T

E) 2105T

57. A magnetic needle free to rotate in a fixed vertical plane stays at an angle 60 with the horizontal. If the dip
at that place is 37, find the angle of the fixed vertical plane with the meridian (tan 37=3/4)
1
A) cos

3
5

1
B) cos

3
1
C) cos 4

1
3

1 2
D) cos
3

E) cos 1 3

58. The area of I-H curve and area of B-H curve are related as
A) Area of I-H curve < area of B-H curve
B) Area of I-H curve > area of B-H curve
C) Area of I-H curve = area of B-H curve
D) Area of I-H curve area of B-H curve
E) None of these
59. A powerful magnet attracts
A) All materials
B) Only ferromagnetic materials and their ores
C) Some materials and repels some other materials
D) Only iron and its ores but does not repel any material
E) None of these
60. The electric field strength at a distance r from the centre of a charged sphere of radius R is E. If r > R, how
much work will be done in bring a test charge q0 from infinity to that point:
A) q0 RE

B) (1/2) q0 RE

C) q0 rE

D) (1/2) rE

E) zero

Brilliant
STUDY CENTRE

Puliyannoor P.O., PALA

30 - 01 - 2013

KERALA CEE MEDICAL MODEL EXAMINATION

Ph - 04822 206416, 206516, 206459

www.brilliantpala.org

Answer Key with Hints

1.

2.

3.

4.

5.

6.

When all stop functioning E cell 0

7.

Al3 3e Al
3F 1mole
30F 10 mole

8.

G 0 nFE 0

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

t1
2

Batch: All Batches

1
n 1
a 0 ; For n = 0 ;

VERSION

M1

t 1 a0
2

2 1.67 96500
KJ 322.31KJ
1000

N C
Peptide bonds are present in enzyme
|| .

O
It is a common pathway for both the aerobic & anaerobic respiration in which 1 glucose molecule is
converted to 2 molecules of pyruvate.

From slow step, rate = k[B2][A]

From Ist equation,keq = [A2] / [A2] or [A] =
Hence rate = k B2 k eq1/ 2 A 2

1/ 2

Hence order = 1.5

k eq A2

k B2 A 2

1/ 2

FT13 N/CEE/MOD/PCB/[M1]

20.

t99%

2.303
a
2.303
2.303 2 4.606
4.606
log 0
log100

k
1
k
k
k
k
32
a0
100

t 99.9%

21.

22.

23.

24.

Brilliant STUDY CENTRE

2.303
a0
2.303
6.909
96
log

log103
32
48 min
1
k
k
4.606
2
a0
1000

Rate =

d X
1 d X d Z

.05 ,
2 0.05 0.1
2 dt
dt
dt

Resistivity =

1
;
K

or K =

1
K 1000 1 49 1000
ohm1cm1 ; V

15.8
n
18.5 15

1 49 1000

v
Now, 18.5 15 348 0.507

25.

26.

27.

om (BaCl 2 ) oBa 2 2 ocl = 127 + 2 76 = 279 1cm 2 mol 1

O
28.

29.

+6
Br

+4
Br

Br

+6
O

Since carbocations are formed as intermediate, more stable the carbocation, higher will be the
reactivity of the parent compound
CH3

CH3
+

CH3 - C - OH

CH3

30.

31.

CH3
-

CH5 - C

Br

CH3

C3H7OH

CH3

H3C-C CH

H3C-CH=CH2

COOH

CH3

OH

32.

CH5 - C - Br

CH 3 Cl Anh.AlCl3

F.C.alkylation

Zn dust

ZnO

Alk.KMnO 4

(X)

(Y)

(Z)
Benzoic acid

FT13 N/CEE/MOD/PCB/[M1]

33.

Brilliant STUDY CENTRE

P I2
Mg.ether
CH 3CH 2 OH
CH 3CH 2 I
CH 3CH 2 MgI
A
B

H2O
HCHO

CH3CH2CH2OMgI
CH3CH2CH2OH Mg OH I

34.

35.

36.

37.

max = pE ;

38.

ay

= 3.410302.5104 = 8.51026Nm

eE
, u y V0 sin ;
m

2
2
or V0 sin

39.

40.

41.

V1

Q
4 0

2eE
d;
m

for the particle to fail to hit the plate 2 a y d u y 2

d

mV02 sin 2
2eE

1
Q
V2

and
4 0
R 2 d2
R
A0 V

d

2A0
2

42.

43.

44.

45.

46.

CV
Q

2A0
2A0

Vd

1

; V V1 V2
R 2 d2
R

A 0 V 2
2d 2

i
neA

2R 1 2 0 ......(1) ; 4 3 3I 1 ..........(2)

5 6 3I 2 ...........(3) ; 2R 3 5 6 ....(4)
solving eq (1) , (2), (3) and (4) we get R= 9 , I = 8A, 1 36V , 2 54V
47.

48.

Rp

R 1R 2
2 ;
R1 R 2

R1R 2 18 ;

R s R1 R 2 9

R1 9 R1 18

R 12 9R 1 18 0 ; R1 3 or 6

49.

50.

B1

0 2I
2 2

k 0
k Bk
4 a
4
a

B2 Bk ; B B1 B2 2.0Bk

FT13 N/CEE/MOD/PCB/[M1]

51.

52.

53.

m
q
mv
Bqr
B 2pr
,v
;for He, v
Bq
m
4pm

1
for profon, v

54.

Bpr
;
m

v1
2 v1 2 v
v

B
B

2 0 Md

4 d 2 l 2

55.

56.

57.

tan 1

Bv
tan

BH cos cos

cos

tan tan 37 3 / 4
3

tan 1 tan 60
4
3

58.

59.

60.

B H
5 10
cos

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