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t=
0
dx
r A V
Time (sec)
Volume of NaOH in
(mL)
Ca (mol/L)
rate of rxn
(mol/L.S)
0.0007
0.233
0.230
20
3.4
0.00066
0.194
0.194
30
3.6
0.00064
0.178
0.177
40
3.8
0.00062
0.163
0.163
50
0.0006
0.150
0.150
60
4.2
0.00058
0.138
0.138
70
4.4
0.00056
0.127
0.127
80
4.8
0.00052
0.108
0.108
90
4.8
0.00052
0.108
0.108
100
4.8
0.00052
0.108
0.108
Table 1
Table 1 shown the raw data of batch experiment , from this data note when
time increasing the volume of NaOH need to titrate increase or the
concentration of HCl will be decrease to reach steady state and become
constant after period of time .
r A=k C A C B (1 )
The relation between CA and CB is equal then
C A =
C B
so :
n= +
r A=k C A n .(2)
When taking logarithm for equation (2) and plotting ln(-Ra) versus ln(Ca) can
determine the order of reaction from the slop and k from intercept.
CA
r A=lnk +nln ) ..(3)
ln
2.5
2
1.5
ln(Ra) (mol/L.s)
1
0.5
0
1.4
1.5
1.6
1.7
1.8
1.9
ln (Ca) (mol/L)
2.1
2.2
2.3
From the figure 1 the rate of reaction is first order and the constant k will be
equal 0.8187sec-1
Conclusion:
1- Check that all material and equipment are cleanly and its have to
used .
2- Be careful when measuring any material to prevent any error in
calculation
References:
1- 8:15-8:30 Michigan university .
http://www.umich.edu/~elements/5e/asyLearn/bits/batch/index.htm
2- Khalil Halholi. chemical processing laboratory.Irbid.JUST.2011/2012
3- . Scott Fogler . Element of Chemical Reaction Engineering .Michigan
university 5thedition .
Time
(sec)
Volume of NaOH
in (mL)
0.0007
20
3.4
0.00066
30
3.6
0.00064
40
50
3.8
4
0.00062
0.0006
60
4.2
0.00058
70
4.4
0.00056
80
4.8
0.00052
90
4.8
0.00052
100
4.8
0.00052
Ca
rate of
(mol/L)
rxn
0.233333
333
0.23
0.194117
0.19361
647
765
0.177777
0.17744
778
444
0.163157
0.16290
895
789
0.15
0.1498
0.138095
0.13792
238
857
0.127272
0.12712
727
987
0.108333
0.10820
333
833
0.108333
0.10822
333
222
0.108333
0.10823
333
333
2.5
2
1.5
ln(Ra) (mol/L.s)
1
0.5
0
1.4
1.5
1.6
1.7
1.8
1.9
ln (Ca) (mol/L)
CA
t
dC A
dt= C r
Ao
Then
r A=
t=
C A C A 0
r A
2.1
2.2
2.3