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Aug. 7, 2014
US. Cl.
CPC .................................. .. COIB 17/765 (2013.01)
USPC
14/343,092
(86)
PCT/EP2012/069099
PCT N0.:
371 (0X1),
(2), (4) Date:
(30)
Mar. 6, 2014
Publication Classi?cation
(51)
Int. Cl.
C013 17/765
(57)
ABSTRACT
?rst oxidized process gas, (0) reacting SO3 With water, (d)
condensing H2804, (e) Withdrawing a ?rst desulphurized
process gas and a ?rst stream of sulphuric acid, (i) from the
desulphurized process gas Withdrawing a recycle stream of
desulphurized process gas, Wherein the recycle stream is
added to said stream of feed gas or said ?rst oxidized process
(2006.01)
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Fig. 2
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Fig. 3
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Fig. 4
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Aug. 7, 2014
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[0001]
phur source such as HZS, sulphur and spent acid, and ?ue
gases from combustion plants. More speci?cally it relates to
a process with reduced equipment requirements involving
recycle of the desulphurised process gas.
[0002] Sulphuric acid can be produced from gases contain
ing sulphur oxides. One such process is based on the oxida
tion of SO2 to SO3 in the presence of water vapour, followed
by condensation to HZSO4, and is sold under the trade name
WSA (the Wet gas Sulphuric Acid) by the company Haldor
TopsoeA/ S of Denmark. The source of sulphur may either be
an off-gas with high sulphur content, or more typically, a gas
produced by combustion of a sulphur rich source, such as
elemental sulphur or hydrogen sul?de.
[0003]
[0004]
respectively.
[0009]
lytic reactor.
[0011] Sections of the present application relates to a pro
cess having two desulphurisation steps. In this respect, the
terms upstream or ?rst desulphurisation process or desulphu
risation unit shall be understood as related to one desulphu
[0006]
tioned as such.
[0013]
between S02 and S03 towards SO2 such that less sulphuric
acid is formed.
cess gas
[0018]
sulphuric acid.
[0019]
Aug. 7, 2014
US 2014/0219910Al
recycle stream, and upstream the mixing point, with the asso
ciated bene?t of removing $02 from a ?ue gas as sulphuric
ary sulphur removal process steps taken from the group con
acid droplets,
[0029] (n) removal of sulphuric acid mist by electrostatic
precipitation, and removal of precipitated sulphuric acid
[0030] (o) removal of sulphur oxides by absorption in a
scrubber, wherein said scrubber contains an alkaline solution
and/or an oxidative solution with the associated bene?t of
plant.
[0039]
[0031]
[0041]
Aug. 7, 2014
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[0052]
[0055]
Example 1
[0049]
Combustion
(not shown)
Cooling
(4)
(8)
(12, 36)
Reheating
(18)
(24, 18)
(30, 38)
(34)
[0057]
Example 2
[0058] The process unit is designed as a Double Conversion
Double Condensation unit according to an embodiment of the
Cooling
Mixing process gas with recycle gas
(not shown)
(4)
(6, 22, 40)
Aug. 7, 2014
US 2014/0219910 A1
-continued
Reheating
(8)
(12, 36)
(18)
(22, 42)
(24, 18)
(30, 38)
(34)
Example 3
Cornbustion
(not shown)
Cooling
(4)
(44)
(46)
conversion,
no
Example 2 recirculation
recirculation recirculation & scrubber Unit
5731
85 600
Air
88400
recycle
88400
S02 converter
5731
68600
5731
71000
(20%)
(17%)
71400
74400
(19%)
(16%)
88600
92100
(0%)
(+4%)
Nrn3/h
Nrn3/h
Nrn3/h
Nrn3/h
Recycle
17100
17700
Nrn3/h
Process
74400
57400
59400
Nrn3/h
(23%)
(20%)
gas after
recycle
Clean Gas
Power production
droplets,
Single
Exalnple 1
PG inlet
Exalnple 3
PG before
Feed Flow
Combustion
73500
13.3
56500
61700
(23%)
( 17%)
13.6
(+2.5%)
13.7
Nrn3/h
MW
(+3.0%)
Sulphur in
50
50
50
clean gas
as S02
S02 rernoval
kg/h
99.83
99.83
99.83 %
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