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16-25, 2013
Available online at http://www.ijsrpub.com/ijsres
ISSN: 2322-4983; 2013 IJSRPUB
http://dx.doi.org/10.12983/ijsres-2013-p016-025
School of Civil Engineering, Engineering Campus, University Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
2
Department of Civil Engineering, College of Engineering, University of SalahaddinErbil, Iraq
*Corresponding Author: cehamidi@eng.usm.my
Received 25 December 2012; Accepted 19 January 2013
Abstract. Leachate is created while water penetrates through the waste in a landfill, carrying some forms of pollutants. The
aims of this study were the review on physical-chemical methods for landfill leachate treatment. The physical-chemical ways
for landfill leachate treatment like Chemical precipitation, Chemical Oxidation, CoagulationFlocculation, Membrane
filtration, Ion exchange, Adsorption and Electrochemical treatment are studied. Chemical precipitation is generally used as pretreatment in order to remove high strength of ammonium nitrogen; fenton oxidation is one of these advanced oxidation
processes with high efficiency and low capital costs; coagulationflocculation has been used for the removal of nonbiodegradable organic compounds and heavy metals from landfill leachate; nanofiltration (NF) is one of membrane filter and it
has found a place in the removal of recalcitrant organic compounds and heavy metals from landfill leachate; adsorption is the
most widely used technique for the removal of recalcitrant organic compounds from landfill leachate; the ion-exchange method
offers a number of benefits containing the ability to handle shock loadings and operate over a wider range of temperatures. The
landfill leachate properties, technical applicability and constraints, effluent discharge alternatives, cost-effectiveness,
regulatory requirements and environmental impact are important factors to selection of the most suitable treatment technique
for landfill leachate treatment.
Key word: Adsorption method, Chemical Oxidation, Ion exchange, Leachate, Membrane filtration,
1. INTRODUCTION
Which passes through the solid waste fill and
facilitates transfer of pollutants from solid phase to
liquid phase, landfill leachate is generated by the
penetrating water. Because of the inhomogeneous
nature of the waste and due to the different
compaction densities that will be encountered, water
will be able to percolate through and appear as
leachate at the base of the site (Cotman and Gotvajn,
2010). Landfill leachate could be a main foundation of
water contamination, if not treated and disposed
safely, because it could enter through soil and subsoil.
Therefore, before release, the treatment of hazardous
leachate components has been made a legitimate
obligation to prevent pollution of water resources and
to elude both acute and chronic toxicities (Aziz et al.,
2011a).
Landfill leachate includes organic and inorganic
contaminants in high rates. Leachate is created while
water penetrates through the waste in a landfill,
carrying some forms of pollutants like ammonianitrogen (NH3-N), chemical oxygen demand (COD),
biological oxygen demand (BOD5), colour, suspended
solids and heavy metals. It may become a potential
contamination source which threats soil, surface water
and groundwater, if they are not collected carefully
and not discharged safely. Therefore, landfill leachate
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Mojiri et al.
Trends in Physical-Chemical Methods for Landfill Leachate Treatment
4. CHEMICAL OXIDATION
Chemical oxidation processes were developed at
different sites in during the last years. A combination
of oxidation agents as ozone or hydrogen peroxide
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International Journal of Scientific Research in Environmental Sciences (IJSRES), 1(2), pp. 16-25, 2013
5.
COAGULATION-FLOCCULATION
FLOCCULATION-PRECIPITATION
6.1. Microfiltration
6. MEMBRANE FILTRATION
A membrane could be defined as a material that
creates a thin barrier capable of selectively resisting
the move of different constituents of a fluid and
therefore affecting separation of the constituents
(Visvanathan et al., 2000). Usually, a thin layer of
material with a high surface porosity and a narrow
domain of pore size affect the physical structure of the
membrane. Different membrane filtration techniques:
microfiltration, ultrafiltration, nanofiltration, and
reverse osmosis are used in landfill leachate treatment.
OR
6.2. Ultrafiltration
Ultrafiltration is a selective process utilizing pressures
up to 10 bar. This technique is efficient to remove
suspended matters either by direct filtration or with
biological treatment to replace sedimentation unit. It is
strongly dependant on the kind of material
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Trends in Physical-Chemical Methods for Landfill Leachate Treatment
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International Journal of Scientific Research in Environmental Sciences (IJSRES), 1(2), pp. 16-25, 2013
9. ELECTROCHEMICAL TREATMENT
In recent years, electro-chemical ways were used for
treatment of organic materials having high toxicity
and low biological degradability. Electro-chemical
ways like electrocoagulation (EC), electro-oxidation
and electro-photo-oxidation were frequently applied
for treatment of wastewaters from textile, tannery and
oil industries. Treatment of landfill leachate via
electro-chemical ways is also another important
interest area. In most of the studies in this field,
especially the electro-oxidation method was examined
(Deng, 2007).
8. ADSORPTION
Adsorption is the most widely used technique for
the removal of recalcitrant organic compounds from
landfill leachate. Fundamentally, adsorption is a mass
transfer process by which a substance is transferred
from the liquid phase to the surface of a solid, and
becomes bound by physical and/or chemical
interactions (Kurniawan et al., 2006). The adsorption
of contaminants onto Activated Carbon in columns or
in powder form provides better reduction in COD
levels than the chemicals ways, whatever the initial
organic matter concentration (Table 3). The main
drawback is the need for frequent regeneration of
columns or an equivalently high consumption of
powdered activated carbon (PAC). Adsorption by
activated carbon has been used along with biological
treatment for effective treatment of landfill leachate.
Nonbiodegradable organics, inert COD and the color
may be reduced to acceptable levels for biologically
treated landfill leachate (Renou et al., 2008).
Adsorption technique is recognized as the efficient
and promising elementary approach in wastewater
treatment processes (Foo and Hameed, 2009). It is
used as a stage of integrated chemical-physicalbiological method for leachate treatment, or
simultaneously with a biological process. The most
commonly used adsorbent is granular activated carbon
or PAC (Mojiri, 2011).
The adsorption using granular activated carbon
(GAC) or powder activated carbon (PAC) has been
receiving a considerable attention newly for the
removal of organic and inorganic contaminants from
polluted wastewater because of its inherent physical
properties, large surface area, micro-porous structure,
high adsorption capacity and surface reactivity
(Kurniawan et al., 2006).
Rodriguez et al. (2004) studied PAC and different
resins efficiency in the reduction of nonbiodegradable organic matter from landfill leachate.
Activated carbon presented the highest adsorption
capacities with 85% COD decrease and a residual
COD of 200 mg L1 (Renou et al., 2008).
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Trends in Physical-Chemical Methods for Landfill Leachate Treatment
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International Journal of Scientific Research in Environmental Sciences (IJSRES), 1(2), pp. 16-25, 2013
Table 2: Removal of organic and inorganic compounds using NF or RO ( Kurniawan et al., 2006)
Location of Landfill
Type
of
Membrane
Species
NA (Not Available)
Kind
of
Process
NF
NTR-7250
Odayeri (Turkey)
Mustankorkea (Finland)
Spillepeng (Sweden)
NF
NF
NF
SW
Desal 5-DL
AFC-30
Chung
Nam
(South
Korea)
Yachiyo (Japan)
Pietramelina (Italy)
RO
RO
SW-4040
DT
RO
SW30-2521
Hedeskoga (Sweden)
Spillepeng (Sweden)
Wijster (Holland)
Ihlenberg (Germany)
RO
RO
RO
NF
RO
Lipowka (Poland)
Pressure
(bar)
NH3-N
Metal
BOD
BOD/COD
Cr(III)
Cu(II)
Pb(II)
NA
NA
Pb(II)
Zn(II)
Cd(II)
NA
Mn(II)
NA
NA
NA
NA
25
6-8
20
3000
920
2000
950
220
NA
NA
84
NA
NA
9-11
1500
97.4
1400
33.7
0.69
0.23
0.03
NA
NA
0.61
0.50
0.03
NA
4.77
52
3840
NA
AFC99
NA
NA
NA
Cd(II)
Zn(II)
Cu(II)
Cr(III)
NA
NA
NA
SS
NA
40
30
40
36-60
NA
27.6
1254
925
335
1797
170000
1780
541
280
140
336
3350
743
pH
NH3-N
Metal
NA
NA
NA
NA
0.40
NA
NA
7.6
NA
89
66
NA
72
50
NA
450
5
0.30
0.05
NA
6
97
100
96
98
100
99
93
NA
NA
97
88
94
NA
100
0.50
1200
0.31
98
NA
0.02
NA
NA
0.25
NA
NA
125
NA
NA
54
510
331
0.10
NA
NA
0.03
0.03
0.28
7
6.5
6.5
7.7
6.4
7-8
95
98
98
99
96
97
82
98
98
100
58
NA
100
97
99
NA
NA
NA
98
NA
NA
Table 3: Treatment effectiveness of landfill leachate with the use of adsorption (Renou et al., 2008)
COD (mg.L-1)
879-940
640
108
800-2000
BOD/COD
0.03
0.06
0.04-0.07
pH
7.5
8
-
From
Landfill
Landfill
Landfill
Landfill
625
9500
1533-2580
10,750-18,420
0.3
0.03-0.04
0.55
7.9
7
7.5-9.4
7.7-8.2
7000
716-1765
7
7.58-7.60
Landfill
Landfill
Landfill
Landfill
Landfill leachate +
Municipal sewage
Synthetic wastewater
Pilot plant
Adsorbent
Granular activated carbon (columns)
Granular activated carbon (columns)
Powdered activated carbon
Activated carbon (concentration range
210 g L1)
Powdered activated carbon (2 g L1)
Peat
Powdered activated carbon (2 g L1)
CaCO3 (particle size range 24 mm)
Powdered
activated
carbon
(concentration range 0.13.5 g L1)
Powdered activated carbon (02 g L1)
Granular activated carbon and resins
Removal (%)
91 COD
96 TOC
55-77 color
69 COD
38 COD
90 COD
90 COD
85 non-biodegradable
COD (GAC)
59 non-biodegradable
COD (resin)
Acknowledgement
The authors would like to acknowledge the University
Sains Malaysia (USM) for provision of research grant
to conduct this work, and their supports.
REFERENCES
Ahn WY, Kang MS, Yim SK, Choi KH (2002).
Advanced landfill leachate treatment using an
integrated membrane process. Desalination,
149: 109114.
Amokrane A, Comel C, Veron J (1997). Landfill
leachates
pretreatment
by
coagulationflocculation. Water Resource, 31 (11): 27752782.
Aziz SQ, Aziz HA, Yusoff MS (2011). Optimum
Process Parameters for the Treatment of Landfill
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Trends in Physical-Chemical Methods for Landfill Leachate Treatment
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International Journal of Scientific Research in Environmental Sciences (IJSRES), 1(2), pp. 16-25, 2013
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Mojiri et al.
Trends in Physical-Chemical Methods for Landfill Leachate Treatment
Amin Mojiri is a PhD candidate in environmental engineering, School of Civil Engineering, Universiti
Sains Malaysia (USM), Pulau Pinang. He is fellowship holder and research assistant at the School of Civil
Engineering (USM). He is a member of Young Researchers Club, Islamic Azad University, Iran. He is
editor and reviewer of some international journals. His area of specialization is waste management, waste
recycling, wastewater treatment, wastewater recycling, and soil pollutions.
Dr Aziz is a Professor in environmental engineering at the School of Civil Engineering, Universiti Sains
Malaysia. Dr. Aziz received his Ph.D in civil engineering (environmental engineering) from University of
Strathclyde, Scotland in 1992. He has published over 200 refereed articles in professional
journals/proceedings and currently sits as the Editorial Board Member for 8 International journals. Dr
Aziz's research has focused on alleviating problems associated with water pollution issues from industrial
wastewater discharge and solid waste management via landfilling, especially on leachate pollution. He
also interests in biodegradation and bioremediation of oil spills.
Dr. Shuokr Qarani Aziz is a lecturer in the Civil Engineering Department, College of Engineering,
University of Salahaddin-Erbil, Iraq. He received B.Sc. degree in Civil Engineering and M.Sc. in Sanitary
Engineering from University of Salahaddin-Erbil, Iraq; Ph.D. in Environmental Engineering from
Universiti Sains Malaysia (USM), Malaysia. He is editor and reviewer of some international journals. His
area of specialization is Water Supply Engineering, Wastewater Engineering, Solid Waste Management,
and Noise Pollution.
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