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1. INTRODUCTION
Fiber Reinforced concrete (FRC) may be defined as a composite materials made with
Portland cement, aggregate and incorporating discrete discontinuous fibres. Plain
concrete possesses a very low tensile strength, limited ductility and Plain concrete
possesses a very low tensile strength, limited ductility and little resistance to cracking.
Internal micro cracks are inherently present in the concrete and its poor tensile
strength is due to the propagation of such micro cracks, eventually leading to brittle
fracture of the concrete. It has been recognized that the addition of small, closely
spaced and uniformly dispersed fibers to the concrete would act as crack arrester and
would substantially improve its Compressive and flexural strength properties. This
type of concrete is known as fiber reinforced concrete.
Civil structures made of steel reinforced concrete normally suffer from corrosion
normally suffer corrosion of the steel by the salt, which results in the failure of those
structures. Constant maintenance and repairing is needed to enhance the life cycle of
those civil structures. There are many ways to minimize the failure of the concrete
structures made of steel reinforce concrete. The custom approach is to adhesively
bond fibers polymer composites onto the structure. This also helps to increase the
toughness and tensile strength and improve the racking and deformation
characteristics of the resultant composite. But this method adds another layer, which
is prone to degradation. These fibers polymer composites have been shown to suffer
from degradation when exposed to marine environment due to surface blistering. As
a results, the adhesive bond strength is reduced, which results in the de-lamination of
the composite. Another approach is to replace the bars in the steel with fibers to
produce a fiber reinforced concrete and this is termed as FRC. Basically this method
of reinforcing the concrete substantially alters the properties of the non-reinforced
cement-based matrix which is brittle in nature. Possessed little tensile strength
compared to the inherent compressive strength.
The principal reason for incorporating fiber into a cement matrix is to increase the
toughness and tensile strength, and improve the cracking deformation characteristics
of the resultant composite. In order for fibers reinforced concrete (FRC) to be a
viable construction material, it must be able to compete economically with existing
reinforcing systems.
MATERIALS USED
The different materials used in this investigation are:
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Phospogypsum
Steel Fiber
Cement
The cement used in all mixtures was commercially available 53 grade Ordinary
Portland Cement (OPC).
Coarse aggregates
The coarse aggregate having 20mm normal size well-graded aggregate according to
IS-383 is used in this study. The coarse aggregate procured from quarry was sieved
through 20mm, 16mm, 12.5mm, 10mm and 4.75mm sieves. The material retained on
12.5mm, 10mm and 4.75mm sieves was filled in bags and stacked separately and used
in the production of Self Compacting Concrete.
Fine aggregates
The fine aggregate that falls in zone-I was obtained from a nearby river course. The
sand obtained was sieved through all the sieves (i.e.4.75mm, 2.36mm, 1.18mm, 600,
300, 150). Sand retained on each sieve was filled in different bags and stacked
separately for use. To obtain zone-I sand correctly, sand retained on each sieve is
mixed in appropriate proportion.
Phosphogypsum
Generally, a ton of phosphoric acid production generates about 4.5 to 5 tonnes of
phospho-gypsum. Major phosphogypsum producing fertilizer units are Coromandal
Fertilizer Ltd, Visakhapatnam in Andhra Pradesh; Gujarat State Fertilizers and
Chemicals Ltd, Vadodara in Gujarat; FACT Udyogmandal, Ernakulam in Kerala,
RCF, Chembur, Mumbai in Maharashtra; Paradeep Phosphates Ltd in Orissa, SPIC
Tuticorin and Coromandal Fertilizers Ltd, Thiruvalur in Tamil Nadu.
Phosphogypsum is a by-product in the wet process for manufacture of phosphoric
acid (ammonium phosphate fertilizer) by the action of sulphuric acid on the rock
phosphate. It is produced by various processes such as dehydrate, hemihydrate or
anhydrite processes. In India the majority of phosphogypsum is produced by the
dehydrate process due to its simplicity in operation and lower maintenance as
compared to other processes. The other sources of phosphogypsum are by-products of
hydrofluoric acid and boric acid industries.
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Current worldwide production of phosphoric acid yields over 100 million tons of
phosphogypsum per year. While most of the rest of the world looked at
phosphogypsum as a valuable raw material and developed process to utilize it in
chemical manufacture and building products, India blessed with abundant low-cost
natural gypsum piled the phosphogypsum up rather than bear the additional expense
of utilizing it as a raw material. It should be noted that during most of this time period
the primary reason phosphogypsum was not used for construction products in India
was because it contained small quantities of silica, fluorine and phosphate (P205) as
impurities and fuel was required to dry it before it could be processed for some
applications as a substitute for natural gypsum, which is a material of higher purity.
However, these impurities impair the strength development of calcined products. It
has only been in recent years that the question of radioactivity has been raised and this
question now influences every decision relative to potential use in building products
in this country.
Some attempts have been made to utilize phosphogypsum as base and fill
materials (in the form of cement-stabilized phosphogypsum mix) in the construction
of highways, runways, etc. In other attempts, phosphogypsum was recycled for
manufacture of fibrous gypsum boards, blocks, gypsum plaster, composite mortars
using Portland cement, masonry cement, and super-sulphate cement.
Steel Fibers
Fibers reinforced concrete may be defined as composite materials made with Portland
cement, aggregate and incorporating discrete discontinuous fibers.
When the fiber reinforcement is in the form of short discrete fibers, they act
effectively as rigid inclusions in the concrete matrix. Physically, they have thus the
same order of magnitude as aggregate inclusions, steel fibers reinforcement cannot be
therefore regarded as a direct replacement of longitudinal reinforcement in reinforced
and prestressed structural members. However, because of the inherent material
properties of fibers concrete, the presence of fibers in the body of the concrete or the
provision of a tensile skin of fibers concrete can be expected to improve the resistance
of conventionally reinforced structural members to cracking, deflection and other
serviceability conditions.
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:
:
:
:
:
:
Water
The potable water, which is free from concentration of acids and organic substances
was used for mixing the concrete.
METHODOLOGY
An experimental study is conducted on fiber reinforced cement concrete by
replacing 10%, 20%, 30% of cement by Phosphogypsum and total volume of concrete
by 0.75% of fiber reinforcement for different elevated temperatures. Absolute volume
method is carried out with various percentages of Phosphogypsum replacing cement
has been made use in the present investigation. The test consisted of carrying out
compressive strength test on cubes, split tensile strength test on cylinders and to study
the strength variation of concrete with addition of fiber reinforcement and
phosphogypsum partially.
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1.
2.
3.
4.
Property
Specific gravity
Normal Consistency
Initial Setting Time
Final Setting Time
Experimental Values
3.15
33.75%
75min
245min
Property
Specific gravity
Bulk density
Water Absorption
Fineness modulus
Grading
coarse aggregate
2.67
1239 Kg/m3
0.5%
7.36
fine aggregate
2.61
1574 Kg/m3
3.14
Zone-I
Table 3 Abstract of workability values of fresh of Steel fiber reinforced & phosphogypsum
concrete mixes
Sl. No
% of Phosphogypsum
% of
Steel
fiber
Slump
value
Compaction
factor value
Vee - Bee
degree
(seconds)
1
2
3
4
0%
10%
20%
30%
0.75
0.75
0.75
0.75
24.6
26.0
27.4
29.1
0.85
0.84
0.82
0.74
4.8
7.3
9.0
12.5
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Designation
of Mix
Temperatur
e in 0 C
Duration of
Exposure in
hrs
Compressive
strength (Mpa)
% Variation over
reference mix
Increase
0% of PG
RoomTemp
100
200
300
10% of PG
200
300
20% of PG
200
300
30% of PG
32.11
1.87
32.98
4.63
30.02
4.76
29.47
6.50
27.88
11.55
25.55
18.94
24.53
22.18
22.64
28.17
19.82
37.12
34.21
8.53
34.60
7.74
1.13
35.09
6.40
2.57
33.87
12.82
1.00
33.62
14.07
1.74
32.47
16.47
5.08
31.69
24.04
7.36
30.54
24.48
10.74
29.28
29.34
14.41
28.34
42.97
17.17
Room Temp
100
31.52
4
Room Temp
100
21.78
30.90
22.47
30.01
3.18
23.31
29.32
7.02
21.74
27.59
0.20
21.67
26.47
0.51
20.91
25.00
3.99
20.57
19.49
5.56
20.01
18.43
8.13
19.67
13.13
9.70
18.58
6.26
14.70
16.61
47.30
16.87
47.45
1.59
17.14
48.04
3.18
16.41
45.33
1.19
15.95
45.88
3.97
15.41
44.72
7.22
15.10
40.89
9.07
14.67
40.18
11.66
14.11
37.66
15.03
13.61
31.35
18.08
Room Temp
100
200
300
Decrease
% Varitation of
corresponding mix at
room temperature
Increase
Decrease
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Sl.No
1.
Designation
of Mix
0% of PG
Temperat
ure in 0 C
Room
Temp
100
200
300
10% of PG
Room
Temp
100
200
300
20% of PG
Room
Temp
100
200
300
30% of PG
Room
Temp
100
200
300
Duration
of
Exposure
in hrs
Split tensile
Streng th
(Mpa)
% Variation over
reference mix
Increase
Decrease
% Varitation of
corresponding mix
at room
temperature
Increase Decrease
3.83
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
4
6
8
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4.13
4.54
3.07
2.94
2.85
2.56
2.32
2.10
1.63
7.83
18.54
19.84
23.24
25.59
33.16
39.43
45.17
57.44
5.21
36.07
5.69
5.95
3.82
3.75
3.71
3.64
3.35
3.27
3.08
37.78
31.15
24.48
27.54
30.31
42.26
44.59
55.74
88.89
9.20
14.25
26.67
28.05
28.74
30.11
35.63
37.24
40.92
3.08
19.61
3.31
3.56
2.76
2.70
2.66
2.37
2.22
2.01
1.57
19.94
21.63
10.25
8.32
6.68
7.34
4.47
4.16
3.72
2.37
38.07
2.55
2.66
2.34
2.29
2.18
2.04
1.94
1.83
1.46
38.21
41.42
23.91
22.17
23.50
20.45
16.35
12.72
10.33
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7.39
15.56
10.51
12.45
13.62
22.96
28.02
34.63
49.03
7.58
12.12
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1.52
3.54
8.08
14.14
18.18
22.73
38.38
40.00
35.00
30.00
25.00
20.00
15.00
10.00
5.00
0.00
0%
10%
20%
30%
6.00
5.00
4.00
3.00
2.00
1.00
0.00
0%
10%
20%
30%
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COMPRESSIVE STRENGTH(Mpa)
PG+FR(1000C)
40
35
30
25
20
4 Hrs
15
6 Hrs
10
8 Hrs
5
0
0%
10%
20%
30%
COMPRESSIVE STRENGTH(Mpa)
PG+FR(2000C)
40
35
30
25
20
4 Hrs
15
6 Hrs
10
8 Hrs
5
0
0%
10%
20%
30%
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PG+FR(3000C)
35
30
25
COMPRESSIVE
STRENGTH(Mpa)
20
4 Hrs
15
6 Hrs
10
8 Hrs
0
0%
10%
20%
30%
PG+FR(1000C)
7
6
5
4
4 Hrs
6 Hrs
8 Hrs
1
0
0%
10%
20%
30%
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PG+FR(2000C)
4
3.5
3
2.5
2
4 Hrs
1.5
6 Hrs
8 Hrs
0.5
0
0%
10%
20%
30%
PG+FR(3000C)
4
3.5
3
2.5
2
4 Hrs
1.5
6 Hrs
8 Hrs
0.5
0
0%
10%
20%
30%
From Fig 4 to Fig 10 it is observed that both compressive strength and split tensile
strength increased at 10 % replacement of cement by phosphogypsum even at
different elevated temperatures and duration of exposure.
It is also observed that there is decrease in compressive strength and split tensile
strength for replacing cement by phospogypsum greater than 10%, however up to
20% replacement of cement by phosphogypsum has same strength as that of
conventional concrete.
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4. CONCLUSIONS
Based on experimental investigation conducted and the analysis of test results, the
following has been concluded.
From the study it is observed that up to 10% phosphogypsum & steel fiber
reinforcement is the optimum dosage which can be mixed as partial replacement to
cement for giving maximum possible increase of compressive strength and split
tensile strength.
It was also observed that for 10% phosphogypsum both the compressive strength and
split tensile strength was is high at 1000 C for exposure duration of 4 and 6 hrs.
The normal transporting, placing and finishing methods used for plain concrete can
also used for SFRPGC.
REFERENCES
[1]
[2]
[3]
[4]
[5]
[6]
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