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UNIT
Answer (1)
H occupy the vacant space between metal atom in metallic lattice.
2.
Answer (1)
Para form have lower internal energy than ortho form.
3.
Answer (3)
In para hydrogen Nuclear spin of both hydrogen is opposite to each other, while in orthohydrogen both have
same spin.
4.
Answer (1)
D2O is slowly electrolysed as compare to water.
5.
Answer (1)
H2 has a lower activation energy.
6.
Answer (2)
The lack of reactivity is due to kinetics rather than thermodynamics.
7.
Answer (1)
Water being less conducting, consume a large amount of electricity during its electrolysis.
7a.
8.
Answer (2)
(AIEEE 2012)
Answer (3)
About 92% of the universe is made up of hydrogen.
9.
Answer (2)
PbS + 2Ca(OH)2
PbSO4 + 2CaH2
168
Inorganic Chemistry
1
p
1
e + energy
-particle
23. Answer (1)
24. Answer (4)
The fire produced cannot be extinguished by CO2 as it gets reduced by the hot metal hydride, so only sand
is useful as it is a solid.
25. Answer (1)
The stability of the hydrides decreases as the size of the cation atom increases
26. Answer (3)
27. Answer (2)
28. Answer (3)
29. Answer (1)
30. Answer (1)
31. Answer (3)
2NaOH + H2O2
Na2O2 + 2H2O
Inorganic Chemistry
169
volume strength
5.6
170
Inorganic Chemistry
Electrolysis
Na+ + Cl
At cathode
Na e Na
At anode
2Cl Cl2 2e
58. Answer (1)
On fusion ions are separated from each other.
59. Answer (2)
Bicarbonate ion of KHCO3 exists in dimeric state due to hydrogen bonding.
60. Answer (2)
61. Answer (3)
62. Answer (1)
63. Answer (3)
64. Answer (2)
65. Answer (4)
66. Answer (3)
67. Answer (2)
68. Answer (4)
69. Answer (1)
70. Answer (3)
71. Answer (2)
Ionic mobility Li+ Na+ < K+ < Rb+ < Cs+
M.P NaF > NaCl > NaBr > NaI
Covalent character NaF < NaCl < NaBr < NaI
72. Answer (3)
Na H2O NaOH
1
H2 ; H = ve
2
Inorganic Chemistry
171
BaC2 + N2
Ba(CN)2
BeC2 + N2 BeCN2
85. Answer (4)
HCl
Heat
Na
4H3BO3
B2O3
B + Na2O
Na2 [B4O5(OH)4] 8H2O
So compound C is Boron.
86. Answer (1)
When H3BO3 is treated with H2O2, monoperoxoboric acid is formed.
87. Answer (4)
This is peculiar property of Ga, Ge and Bi, these expand when converts from liquid to solid.
88. Answer (3)
Because of poor screening of 4f orbital Tl have high ionisation energy than Indium.
89. Answer (4)
90. Answer (4)
91. Answer (2)
92. Answer (1)
2BN 3H2 O B2 O3 2NH3
93. Answer (3)
At room temperature B reacts with fluorine and oxygen only but at very high temperature it reacts with almost
all metals and non-metals.
94. Answer (1)
Icosahedron is a regular polyhedron having 20 faces.
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172
Inorganic Chemistry
HBO2
> 200C
B2O3
Ca(OH)2(s) + C2H2(g)
Inorganic Chemistry
173
(SnCl6)2.
Sn(OH)4
excess
(AIEEE 2011)
Stability of hydrides from NH3 to BiH3 decreases due to decreasing bond strength.
117. Answer (2)
AsCl3 + 3H2O H3AsO3 + HCl
118. Answer (4)
White P is highly reactive with air, so it should be stored in cold water.
119. Answer (3)
All chalcogen except tellurium are polymorphic.
120. Answer (4)
O3 is unstable, diamagnetic and dark blue gas.
121. Answer (4)
NO is neutral oxide, BeO and Al2O3 is amphoteric.
122. Answer (2)
O
S
O
O
S
O
S
O
174
Inorganic Chemistry
[JEE (Main)-2014]
HClO4
ClO4 H
HClO3
ClO3 H
HClO2
ClO2 H
HOCl
ClO H
(i)
Cl
(ClO4 )
Cl
Cl
O
(ClO3)
Cl
O
Cl
O
Cl
O
O
Cl
(iii)
(ii)
Cl
Cl
(ClO )
Inorganic Chemistry
175
XeOF2 + 2HF.
XeOF4 + H2O
139a. Answer (4)
(AIEEE 2009)
2FeO + 2SO2
2FeS + 3O2
FeSiO3
FeO + SiO2
( slag)
176
Inorganic Chemistry
[JEE (Main)-2015]
2Fe + 3CO2
Fe2O3 + 3CO
159. Answer (1)
German silver contains approximately Cu56%, Zn24%, Ni20%.
160. Answer (4)
ZnS is zinc blende, whereas HgS is called Cinnabar.
161. Answer (1)
Nitrate are soluble in water.
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Inorganic Chemistry
177
(AIEEE 2012)
178
Inorganic Chemistry
[JEE (Main)-2015]
18
100 75
24
Inorganic Chemistry
179
(AIEEE 2011)
[Cu(CN)4]3
Cu+ + 4 CN
209. Answer (4)
Most common oxidation state of gold is +3.
210. Answer (4)
All these compound have metal-metal bonding.
211. Answer (3)
Hg have highest 1st ionisation energy, ionisation energy of Hg is about 1007 kJ/mole.
212. Answer (3)
Higher oxidation state of metal means acidic oxide.
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180
Inorganic Chemistry
Lu(OH)3
Ce(OH)3
Basic strength increase
FeCl3.6H2O Fe2O3
Fe(OH)3 + SO2 + HCl.
FeCl3.6H2O + SOCl2
[JEE (Main)-2015]
a
d
Pt
Pt
Pt
b
d
Inorganic Chemistry
181
Fe 5C5H5 2
233. Answer (4)
Mn2Cl10 does not contain Mn-Mn bond.
234. Answer (4)
Fact
235. Answer (2)
In KFe[Fe(CN)6] both d-d transition and charge transfer is observed.
236. Answer (2)
SO2 gives green coloration with acidified K2Cr2O7.
237. Answer (1)
In Fe+2 no unpaired e is present so the total spin is zero.
238. Answer (1)
-amido bis [pentaamminecobalt(I) nitrate].
238a. Answer (1)
(AIEEE 2012)
(AIEEE 2009)
182
Inorganic Chemistry
(AIEEE 2009)
en
en
NH3
en
en
Co
NH3
Co
NH3
NH3
[JEE (Main)-2013]
[Co(NH3)3Cl3) has two geometrical isomers, namely fac. and mer. Both of them have a plane of symmetry.
So, they are not expected to show optical isomerism.
Cl
Cl
NH3
Co
NH3
Cl
NH3
Cl
NH3
Co
Cl
NH3
fac.
mer.
NH3
Cl
n (n 2) B.M.
Inorganic Chemistry
183
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