SA 15 16 XII XII Chemistry Unit-1 Section-B

Success Achiever (Solutions)
Physical Chemistry
87
Section - B : Linked Comprehension Type

C1. 1. Answer (2)
Equivalent of NaOH = Eq. of HCl
x
1
x4g
40 10
where x = pure wt.
2. Answer (4)
Apply, N1V1 = N2V2
2
1
1
V 22
10
2
V = 10 litre
3. Answer (2)
Equivalent of metal carbonate = Equivalent of metal oxide.
C2. 1. Answer (2)
5
KH(IO3 )2 ICI
Change in oxidation state = 2(5 1)
=8
Equivalent weight of KH(IO3)2 =
M
8
2. Answer (3)
Given equivalent weight of bivalent metal = 32.7
Molecular weight of bivalent metal = 32.7 2
Molecular weight of its chloride = 2 32.7 + 2 35.5
= 136.4
3. Answer (3)
Equivalent weight of NH3 as a base =
molecular weight
17
1
C3. 1. Answer (4)

(1) 16 g of O2 0.5 moles of O2 0.5 22.4 L = 11.2 L
(2) 3 moles of SO2 3 22.4 L 67.2 L
(3) 5.4 L of NO2
(4) 24.092
1023
molecules of CO2 =
24.092 10
6.023 10
23
23
= 4 moles of CO2
= 4 22.4 L of CO2,
= 89.6 L of CO2
Thus 24.092 1023 molecules of CO2 occupies highest volume.
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Physical Chemistry
2. Answer (3)
Number of es present in one molecule of water = 2 + 8 = 10
Mass of es present in one molecule of water = 10 9.1 1031 kg
= 9.1 1030 kg
Mass of es present in one mole of water = 6.023 1023 9.1 1030 kg
= 5.48 106 kg
3. Answer (2)
Number of atoms present in 1 molecule of SO2 = 3
(1) Number of atoms present in 1 mole of NO2 = 3 6.023 1023 atoms of NO2
(2) Number of atoms present in
NO2 = 3 atoms
1
6.023 10 23
moles of NO2 = Number of atoms in 1 molecule of
(3) Number of atoms present in 6.023 1023 molecules of NO2 = 3 6.23 1023 atoms
(4) Number of atoms in 46 g of NO2 = Number of atoms in 1 mole of NO2
= 3 6.023 1023 atoms
Hence (2) is the right answer.
C4. 1. Answer (2)
En =
kz 2
n2
Using above equation
kz 2
E E1 = 0 2
1
= 2.179 1018J 4
= 8.716 1018J
In moles = 8.176 1018 6.023 1023
= 5249 kJ mole1
First ionisation energy is lower than second ionisation energy.
2. Answer (3)
Potential energy = 2 Total energy
= 2 8.716 1018 J
= 1.743 1017 J
3. Answer (3)
IE = En
2.179 10 18 4 2
= 3.4864 1017 J
=
12
C5. 1. Answer (4)

Kinetic energy increases with increase in frequency of incident photon.
Number of photons increases with increase in intensity of light.
2. Answer (3)
On increasing intensity of incident photon, number of photoelectrons increases and hence current also
increases.
Physical Chemistry
89
3. Answer (1)
E=
1J =
n hc
n 6.6 10 34 3 10 8
4 10 7
n = 2.0 1018
C6. 1. Answer (2)
Radial node = 6 0 1 = 5
2. Answer (1)
Fact
3. Answer (1)
C7. 1. Answer (3)
Full filled electronic configuration have higher ionisation energy because of extra stability due to symmetry
and exchange energy.
2. Answer (3)
Due to high atomic number and same size, element of 5d series have high ionisation energy.
3. Answer (3)
Nitrogen have high ionisation energy than oxygen because of high stability.
C8. 1. Answer (1)
2. Answer (4)
3. Answer (2)
C9. 1. Answer (1)
HSO4 has minimum charge per atom.

2. Answer (1)
It is weaker acid than H2SO4 and HClO4
3. Answer (3)
It contains no -bond or vacant d-orbital.
C10. 1. Answer (4)
Bond order of O2 2 : 5
2. Answer (1)
N2 (Bond order) 2.5

N2 (Bond order) 2.5
3. Answer (3)
C11. 1. Answer (4)
Both have bond order equal to 3.
2. Answer (3)
O
||
O Cl
||
O
O , bond order =
7
= 1.75
4
3. Answer (3)
High bond order, more bond energy.
90
Physical Chemistry
C12. 1. Answer (3)

Momentum before collision = mvx
Momentum after collision = mvx
Change in momentum due to one collision = mvx (mvx) = 2mvx
To strike again face Q, distance travelled = 2L
Time taken to strike face Q again =
2L
second .
vx
Number of collisions per second on face Q =
Change in momentum due to
vx
2l
vx
v
mv x 2
collision per sec on face Q along x axis = 2mv x x
.
2l
2l
l
2. Answer (1)
Change in momentum per sec due to collision of one molecule on opposite faces along x axis =
2mv x 2
l
3. Answer (3)
PV =
1
2
mnv rms
3
2 .
P v rms
C13. 1. Answer (3)

Tc
Pc
8a
27Rb
a
27b
Vc = 3b
Pc Vc 3
z = RT 8 .
c
2. Answer (4)
Both gases have polar bonds hence force of attraction high.
3. Answer (1)
At high temperature and low pressure gases behave like ideal gas.
C14. 1. Answer (3)

3O2 (g)
2O3 (g)
20 ml
at equil. (20 x)
0
+
2x
= 17
3
x = 9 ml
O2(g) remained = 20 9 = 11 ml which will be absorbed by alkaline pyrogallol.
Physical Chemistry
91
2. Answer (4)
O3 formed =
2
9 6 ml
3
which will be absorbed by turpentine oil.

3. Answer (1)
Both the components are absorbed one by one.
C15. 1. Answer (4)
For isochoric process
V = 0
U = q + P V
V = 0
When
U = q + 0
U = qV
Hence option (4) is correct.
2. Answer (4)
P1V1 = P2 V2 is not valid for isothermal expansion. It is valid for adiabatic expansion.
3. Answer (3)
When
CP
= 1.33
CV
Gas is Triatomic.
C16. 1. Answer (1)
At equilibrium G = 0, therefore Ecell = also be zero.
2. Answer (4)
Go = RT lnK
G0 = Ho TSo
RT ln K = Ho TSo
RT ln K = TSo Ho
ln K =
TS o Ho
Go
=
RT
RT
3. Answer (1)
At equilibrium,
G = 0
G = H TS
H TS = 0
T=
H
30 10 3
=
= 428.57
S
70
(1) is correct answer.

92
Physical Chemistry
C17. 1. Answer ( 2 )
Group-17 elements exist as di-atomic molecules.
2. Answer (3)
For X2(g), degree of freedom = 5
Cp
5R
7R
R
2
2
3. Answer (3)
Cp
Cv
7R 2
7
2 5R 5
C18. 1. Answer (3)

In (3) NH3 is donor and Cu+2 ion is acceptor. Hence NH3 is a base and Cu+2 ion is Lewis acid. Cu+2 is
not Bronsted acid because it cannot donate proton.
2. Answer (4)
BF3, AlCl3 and FeCl3 are electron deficient compounds and as such are Lewis acid, PH3 is a Lewis base.
3. Answer (3)
Fact.
C19. 1. Answer (3)
Final solution is an acidic buffer.
2. Answer (1)
pH = pK a log
[Salt]
[Acid]
= 5 log 2 + log 2
=5
3. Answer (3)
C20. 1. Answer (2)
OH will react with H3O+ favouring the equilibrium towards right.
2. Answer (1)
Addition of acid will shift equilibrium to left.
3. Answer (2)
Higher electronegativity will favour more acidic strength.
C21. 1. Answer (1)
1
2 =
4.24
=
2
2 =
0 .1
0.01
10 = 3.24
4.24
= 1.33
3.24
2 = 1.33%
Physical Chemistry
93
2. Answer (1)
pH = log10 [H3O+] = log C
= log K a C
= log
2 10 4 5 10 3
= log
10 10 7 = log 10 6 = 3
3. Answer (1)
1
=
2
1
=
2
K a1
K a2
2 10 4
K a2
K a2 = 8 104
C22. 1. Answer (1)
Oxidising power of halogen decreases from F2 to I2.
2. Answer (4)
Since reduction potential Zn2+ is more than Al3+ therefore Zn2+ has strong tendency to get reduced.
3. Answer (2)
Oxidation potential of A is higher than B therefore A has strong tendency to get oxidised.
C23. 1. Answer (2)
Let oxidation state of S = x
x + 2 10 = 0
x = +8
Here, +8 is greater than +6 which is maximum possible oxidation state for S, thus the molecule must
have peroxide linkage.
2. Answer (3)
23 V
: 1s 2 , 2s 2 , 2 p6 , 3s 2 , 3 p 6 , 4s 2 , 3d 3
Valence
electrons
Maximum possible oxidation state = +5

3. Answer (2)
As bonding pattern changes. No effect on oxidation state of central atom.
C24. 1. Answer (4)
ZnO becomes yellow due to presence of extra Zn2+ ion in interstitial sites.
2. Answer (4)
In Frenkel defects similar charges come closer this results in increase of dielectric constant of crystals.
94
Physical Chemistry
3. Answer (3)
AgBr has both Schottky and Frenkel defects.
C25. 1. Answer (3)
In ccp packing the % of vacant space is 26%.
2. Answer (1)
In hcp the C.N. of atom is 12.
3. Answer (1)
Void fraction =
238
0.48
500
Packing fraction = 0.52

Therefore nature of packing is simple cubic.
C26. 1. Answer (1)
d=
8 12
NA 3.6 108
3.42 g/cc
2. Answer (3)
1
NA
Total unit cell = 12
6.27 1021
8
3. Answer (3)
C27. 1. Answer (4)
w1
M1 w 2
1000
w1 mass of solute
w 2 mass of solvent
Initial amount of benzene = 0.9 78 = 70.2 g

xA
P
P
xA
760 670
0.12
760
A Napthalene (solute )
B Benzene (solvent )
(i)
xB = 0.88
0.12 1000
1.75
0.88 78
Mass of solvent (benzene) remaining in the solution =
w2 =
no. of moles of solute

1000
molality
0.1
1000 57.1 g
1.75
Amount of benzene solidified

= amount of benzene taken amount of benzene remaining
= 70.2 57.1 = 13.1 g.
Physical Chemistry
95
2. Answer (3)
Follow the solution of 1st part of eq. (i)
3. Answer (2)
Molality (m) =
0.2 1000
0.8
78
250
78
m=
Tf = Kfm
Tf = K f
250
78
(i)
For Kf
Kf =
Kf =
RTf 2
1000 Hf
M0
8.314 (278.5)
1000 10.67 10
78
Kf = 4.714
From equation (i)
Tf = 4.714
250
= 15.10 ~ 15.
78
C28. 1. Answer (4)

meq of the acid in 250 ml =
meq in 25 ml =
7.35
1000 in 250 ml
E
[E equivalent weight]
735
E
meq of acid = meq of base (NaOH)

735
= 1 15 (N V)
E
E = 49.
2. Answer (2)
M.m = 2 equivalent mass.
3. Answer (2)
meq of the acid =
NV =
7.35
1000
49
7350
49
7350
49 250
N = 0.6 N.
N=
96
Physical Chemistry
C29. 1. Answer (2)

2. Answer (3)
3. Answer (1)
100 98 molesof urea
98
180 / 18
2
molesof urea
98
10
moles of urea =
wt of urea =
120
98
20
120
60
98
98
C30. 1. Answer (1)

At pH = 0, E Ho / H = 0
2
2. Answer (2)
T
1
Use E H / H = 0.0591 pH log PH2

2
298
2
3. Answer (1)
Due to negative reduction potential of Zn.
C31. 1. Answer (1)
Due to same electrodes, Eo = 0.
2. Answer (2)
E=
C
0.0591
log 1
2
C2
E > 0, C2 > C1
3. Answer (4)
Because Eo = 0.
C32. 1. Answer (2)
2
ECu/Cu2 ECu/Cu2
Cu
0.059
log
2
Cu

OX ECu/Cu2 ECu2 /Cu 0.34

Now, ECu/Cu2 0.34
= 0.34
0.059
log0.1
2
0.059
2
= 0.3105 V
Physical Chemistry
97
2. Answer (2)
According to Nernst equation,
Ecell Ecell
Cu2
0.0591
log
2
Zn2
Zn2
0.0591
Ecell Ecell
log
2
Cu2
y = C + ( m)x
3. Answer (1)
Cu2 2e Cu
(i) G10 2 F x
Cu e Cu
Cu Cu e

E = y volt
(ii)
G02 Fy
By adding reaction (i) and (ii)

Cu2 Cu 2Cu
G03 2 G02 G10

2Fy2Fx
2F(y x)
For this reaction to become spontaneous G03 0 so 2F (y x) < 0, y < x
C33. 1. Answer (1)
Rate =
d [IO 3 ]
1 d [I ]
1 d [I2 ]
dt
5 dt
3 dt
2. Answer (2)
d [N2 ]
1 d [H2 ]
1 d [NH3 ]
dt
3 dt
2 dt
d [N2 ]
1 mole litre 1 sec 1
dt
d [NH3 ]
2 mole / litre sec
dt
appearance of NH3 is 34 gm litre1 sec1

3. Answer (3)
Rate of disappearance of A =
Rate of appearance of A =
d[A]
k 1[ A ]
dt
d [B]
d[A]
k 2 [B]
dt
dt
Net rate of disappearance of A =
d[A]
k 1[ A ] k 2 [B]
dt
98
Physical Chemistry
C34. 1. Answer (1)

Rate = k[A]a [B]b
0.3 104 = k[0.01]a [0.01]b
(i)
1.2 104 = k[0.02]a [0.02]b
(ii)
2.7 104 = k[0.02]a [0.03]b
(iii)
from equation (ii) and (iii)

12 2
27 3
b=2
from equation (i) and (iii)
a
1 1 1
9 2 3
a=0
Rate = k[A]0 [B]2
0.3 104 = k[0.01]2
k = 0.3
2. Answer (1)
t=
x
for zero order reaction
k
x = a0 for completion of reaction

t=
a0
k
3. Answer (2)
A (g) B (g) C (g)

Initial pressure
P
0
0
At time t
P P
P
P
After long time
According to given conditions 2P = P0

P=
P0
2
P P + P + P = Pt
P 0
P = Pt P = Pt
P0
2
P 2.303
2.303

log
log
k=
0
t
P
P
P0
Pt
2
2
2.303
P0
log
t
2(P 0 Pt )
Physical Chemistry
99
C35 1. Answer (4)

2. Answer (3)
3. Answer (2)
In OA portion
1
x
p n [where n 1]
m
Straight line and is maximum adsorption

from A to B
1
x
p n where n > 1 but <
m
Moderate adsorption
In BC portion of the graph
x
pn [where n ]
m
Minimum adsorption
C35a. Answer (4)
(AIEEE 2012)
C36. 1. Answer (2)

Both are oppositely charged sols therefore can neutralise each other.
2. Answer (2)
... For 10 mL gold sol, 0.15 mg gum arabic is required.
For 50 mL gold sol, 0.75 mg are required amount of gum arabic in gram = 0.75 103.
3. Answer (3)
H
SnO 2
Sn+4
SnO2
[SnO2] Sn+4
C37. 1. Answer (4)

Let the activation energy of catalysed and uncatalysed reaction, be Ea and Ea then from the question
kuncatalysed reaction = kcatalysed
= Ae
Ea
RT
Ae
Ea
RT2
reaction
E a Ea
T1
T2
Ea
E 20
a
3Ea 4Ea 80
400
300
= Ea(f) = 80 J
2. Answer (4)
Threshold energy of the catalysed reaction
= Normal energy of the reactant + Ea
= 50 J + 60 J = 110 J
3. Answer (4)
H = Eaf(1) Ea(2)
20 = Eaf Ea(2)
Ea(2) = Ea(f) + 20 J = 100 J

SA 15 16 XII XII Chemistry Unit-1 Section-B

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Success Achiever (Solutions)

Section - B : Linked Comprehension Type

C3. 1. Answer (4)

Success Achiever (Solutions)

moles of NO2 = Number of atoms in 1 molecule of

C5. 1. Answer (4)

Success Achiever (Solutions)

HSO4 has minimum charge per atom.

N2 (Bond order) 2.5

Success Achiever (Solutions)

C12. 1. Answer (3)

Number of collisions per second on face Q =

Change in momentum due to

C13. 1. Answer (3)

Success Achiever (Solutions)

which will be absorbed by turpentine oil.

(1) is correct answer.

Success Achiever (Solutions)

C18. 1. Answer (3)

Success Achiever (Solutions)

Maximum possible oxidation state = +5

Success Achiever (Solutions)

Packing fraction = 0.52

Initial amount of benzene = 0.9 78 = 70.2 g

Mass of solvent (benzene) remaining in the solution =

no. of moles of solute

Amount of benzene solidified

Success Achiever (Solutions)

C28. 1. Answer (4)

meq of acid = meq of base (NaOH)

Success Achiever (Solutions)

C29. 1. Answer (2)

C30. 1. Answer (1)

Use E H / H = 0.0591 pH log PH2

OX ECu/Cu2 ECu2 /Cu 0.34

Success Achiever (Solutions)

By adding reaction (i) and (ii)

G03 2 G02 G10

appearance of NH3 is 34 gm litre1 sec1

Net rate of disappearance of A =

Success Achiever (Solutions)

C34. 1. Answer (1)

1.2 104 = k[0.02]a [0.02]b

2.7 104 = k[0.02]a [0.03]b

from equation (ii) and (iii)

x = a0 for completion of reaction

A (g) B (g) C (g)

According to given conditions 2P = P0

Success Achiever (Solutions)

C35 1. Answer (4)

Straight line and is maximum adsorption

C36. 1. Answer (2)

C37. 1. Answer (4)

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