FIITJEE JEE Advanced Test Solutions

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AITS-FT-I-(Paper-2)-PCM(Sol)-JEE(Advanced)/16
JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(PAPER-2)
ALL INDIA TEST SERIES
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Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
A, B
A, B
A, B
9.
B, C
B, D
A, C
10.
C, D
B, C
B, D
11.
A, D
A, B, C
A, B
12.
13.
14.
15.
16.
1.
(A) p,q, (B) p,q,

(C) p,q,s, (D) r,s
(A) p,r,s, (B)p,r,s,t,

(C) q, r, (D) p, r, s
(A) r, (B) t,
(C) q, (D) r
4
(A)p,s, (B) q,r,t,

(C) p,s, (D) q,r,t
3
2.
1.
(A) p, q, r, s
(B) p, r, s
(C) t (D) p, s
(A) q, (B) p,
(C) r, s, (D) r
8
2.
3.
4.
5.
6.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Physics
PART I
SECTION A
charge in flux
R
resis tance
B
0 2I
1
A n
R
4 r
R
IAn
0
2rR
1.
2.
Relative acceleration of rod with respect to wedge is parallel to the inclined plane.
3.
4.
v vD
fapp
f0
v fs
Simply use the above relation
for B to C part
A
h1
v = gT
B
liquid
h2
C
u = gT
a
v v 0 g
v0
T
2
0
O gt
0
v0 a
T
g
2
0
20 0
20
3
0
5.
Calculate the initial and final distance of object from the concave mirror.
6.
To avoid t toppling
F
N
fx
mg
net 0
F a mg
a
0
2
mg
2
Now apply Newtons laws of motion.
F
7.
As we know
L0 = L1 + L2
L1 = due to rotational motion
L2 = due to linear motion.
8.
If temperature of a body is constant that means amount of hear energy received and amount of
hear energy emitted are equal.
9.
If direction of field is along the x-axis then its magnitude will be 20 V/cm other wise greatest then
hat.
10.
Apply conservation of linear momentum

2
KE
2 mass
11.
Calculate the time constant
R
a
b
Battery is replaced by a wire

L
L
Rab R
12 13. Now apply newtons law of motion for the particle B.
T
B
60
m r
mg
mg
14 16. Initially current will pass through the resistance only.

I
R1 = 4 k
C1
E
R2
7 k
C2
Power in R2 = 7 (I2) = 2.8 W

2
Power in R1 = 4 I = 4 (4) = 1.6
-6
2.8
7 103
Charge in C1 = 3 10 8 10
= 240 C.
SECTION B
1.
In such type of situation, we have to use these basic facts.

(a) charge will flow between the two body if there is potential difference between the two.
(b) during this process energy will lose due to sparking.
2.
At equilibrium Fnet will be zero and at the extreme point, particle will be in state of rest.
SECTION C
1.
in this situation block B will not move at all.

N
fk
2a1
T 2 = 2T 1
T2
mag
Now apply newtons laws of motion.
T1
a1
mg
mg
2.
a sin30o
v 02
R
v = 8 m/sec
30
a sin30o
a = 2 m/sec
Where R is radius of curvature.
3.
apply newtons laws of motion for the body A and body B

N
M
A
Mgsin
Mgcos
T Mg
m
B
4.
length of rod is R 2
Hollow sphere
2v
O
v
P
Velocity of point P
2v R v
KE of rod = rotational KE t translatory KE
5.
simply use this concept

After earthing a conductor its potential will become zero.
If conductor are connected together both will be at the same potential.
6.
from P T diagram, write the P T equation.

By using PV = nRT
Find P in terms of volume
w Pdv .
Chemistry
PART II
SECTION A
1.
C
Reimer Tiemanns reaction
2.
B
+
The cell reaction is: H2(g) + I2(s)

2H (aq) + 2I (aq)
2
Ecell = E
o
cell
H I
0.0591
log
2
PH2
H 0.1
0.0591
0.7714 = 0.535
log
2
1
pH = 3
3.
C
Mosleys equation is :
a z b
= az ab
Given that, ab = 1, a = tan45o = 1
51 1 50 2500 Hz
4.
A
H2O
S 2Cl2
SCl4
OH
HO
S
OH
HO
Hybridisation of S in H2SO3 =
5.
OH
1
6 2 0 4 sp3 3 1
2
B
H
H
6.
H2O
HO S O
up
down
A
10 3
1000 0.01 M
50 50
0.1 50
[Cl-] initial just after mixing
0.05 M
50 50
I.P = [Ag+] [Cl-] = 5 104
I.P K sp
[Ag+]initial just after mixing =
Ag aq
Cl aq AgCl s
0.01M
0.05
initial conc.
0.04 M
conc. after precipitation
K sp Ag Cl
1010 Ag 0.04
Ag 2.5 109 M
7.
A
OCH 3
OCH 3
OCH 3
OCH 3
H+
O2/Pt
Ph - CH = CH2
H+
Ph
O
O
OH
H3C
Ph
+
H3C
1. -H +
-H 2O
OCH 3
H3C
Ph
O
H2 O
OCH 3
+O H
+
OH2
Ph
O
2. H
CH3
Ph
CH3
Ph
CH3
rearrangement
Ph
OCH 3
CH3
OCH 3
OH
+
HO
C
Ph
CH3
-H +
C
Ph
CH3
C
CH3
Ph
(Y)
CH3
(X)
8.
A, B
All reducing sugars are muatrotating. Although (IV) is an hydroxy ketone and hence
reducing but it cant mutarotate as it not a carbohydrate, cant form ring. In (II) the glycosidic
linkage is in between two anomeric carbons and hence ring opening cant occur, thus non
reducing as well as non mutarotating.
9.
B, D
In B and D compound after mixing undergoes H bonding and hence boiling point will be raised
and hence vapour pressure lowered.
10.
B, C
Fact
11.
A, B, C
Re dhot Fe tube
CH3 C CH
Al2O 3 /Cr2 O3 /
n C6H14
4H2
Cl
t - Buo-
CHCl3
12.
NH4NO3
N2 O H2 O
(B )
(C)
N2 O P4 P4 O10 N2
(D)
13.
C
P4 O10 HClO 4
Cl2 O7 H3PO4
P4 O10 6H2O 4H3PO 4
14.
D
If k1, k2 and k3 be the rate constants of the reaction along path I, II and III respectively, then
overall rate constant of consumption of A will be k1 + k2 + k3. So,
86.625 min
0.693
k1 k 2 k 3
or k1 k 2 k 3
0.693
8 10 3 min1
86.625
0.693
4 103 min1
173.25
0.693
k2
2 103 min1
346.5
k 3 8 103 4 2 103 2 103 min1
k1
% distribution of C
15.
2k 2
2 2 103
100
40
k1 2k 2 k 3
10 10 3
A
d A
dt
k1 k 2 k 3 A
8 103 0.25 2 103 mol L1 min1
dC dD
dt
dt
dt
k1 A 2k 2 A k 3 A
dB
k1 2k 2 k 3 A 10 103 0.25 2.5 103 mol L1 min1 .
16.
Ea overall
k 1E a1
k1 k 2 k 3
k 2Ea2
k1 k 2 k 3
k 3E a3
k1 k 2 k 3
0.5 40 0.25 60 0.25 80

55 kJ / mol
SECTION B
1.
(A p, r, s) (B p, r, s, t) (C q, r) (D p, r, s)
3
O 2 2HF
2
P4 3OH 3H2 O
PH3 3H2PO 2
3XeF4 6H2 O
XeO3 2Xe
B2H6 6H2O
2H3BO3 6H2
B OH3 2H2 O
B OH 4 H3 O
3Br2 3Na2 CO 3
5NaBr NaBrO3 3CO2
2.
(A p, s) (B q, r, t) (C p, s) (D q, r, t)
Fact
SECTION C
1.
3
92
2.
U238 o n1
92 U239
Np239
Pu239
93
94
2
1
3.5
8
Effective no. of atoms of Y = 4 1 = 3
Effective no. of atoms Z = 8 4 = 4
34
Therefore, required answer =
2
7
2
Effective no. of atoms of X = 4 4
3.
6
H3C
CH2
HC
CHO
OH-
CH3
CH2
CH2 CH3
OH-
CH
CH3
CH3
H2C CH3
H3C
CH2
HO
H2C CH3
C
CH CH CHO
H3C
CH2
HO
H2C CH3
H3C
H3C
CH3
OH-
CH2 CH3
C2H5
H3C
C
HO
HC
CH3
CH3
H3C
CH2
CH2
CH2
CH2
H3C
CH2 HC
CH2
CH2
CH3
OH
OHH
CH
CH3
H3C
CH3
CH2 HC
CH
CH
OH CH3
CHO
CH3
OH
OH-
CH3
4.
OH-
H3C
CH2 CH3
H3C
10
H3C
CH3
CH2
CH
CHO
CH3 CH3
2
U nC v T
5.6
C v 10
22.4
50
Cv
5 cal
10
Cp Cv R Cp 7 cal
12.5
CP 7
1.4
CV 5
The gas is thus diatomic
5.
6
No. of eq. of NaOH that can be produced theoretically for 100% current efficiency = no of
equivalents of NaCl decomposed = no of eq. of Cu deposited
wt. of Cu
31.75
1
Eq. wt. of Cu 63.5 / 2
No. of eq. of NaOH produced experimentally =
% yield
6.
meq. of NaOH
1000
N V 1 60
0.06
1000 1000
0.06
100 6%
1
4
Hoffmanns mustard oil reaction is a test of 1o amine.
SH
R NH2 S C S
S
NHR
HgCl2
RNCS
(Alkyl isothiocyanote)
smells like mustard oil
+ HgS + 2HCl
11
Mathematics
PART III
SECTION A
1.
f x
x dx
0
n
x dx
0
f x n 1
2.
y y 3 y
n n 1
2
n2 n
2
y dx 3 ydx
x A 1y 2 A 2 y A 3
3.
d AC
d
bcosec .cot asec tan
a sec
bcosec
b
B
x
2
AC
b a3 b3
b
1
3
a a3 b3
1
a3
3
2 2
2
a3 b3
4.
Let , , , be the four roots

Then 4 and 1
AM = GM

1
x 4 4x3 ax 2 5x 1 x 1
a 6, b 4
5.
Let APB =
PA 2 PB 2 AB2
cos
2PA.PB
12
PA 2 PB 2 AB 2 2PA.PB cos 2PA.PB as cos 1

2
PA PB AB 2
Thus the max value of |PA PB| is AB

This is possible only when P lies on AB but P lies on AB
P is the point of intersection of x + y = 2 and 2x + 3y + 1 = 0.
6.
r
6!
P
q
2 x 3x 2
P!q!r!
P q r 6 & q 2r 5
coeff 5052
7.
tan3 tan2 tan2 tan

sin 3 2
sin 2
cos 3 cos 2 cos 2 cos

sin 2 sin sin2 0
sin 0 or sin2 0
n
is not for possible as n is odd tan is not define.
2
Hence n, n z is the only solution.
n, n z or 2 n
8.
AB c, BC a, AC b
In OBD
A
z O
E
y
A x
B
OD
OB
x
cos A
R
x R cos A
cos A
a
a
b
c
cos A
2R
2 sin A
sin A sinB sinC
a
a
x cot A tan A
2
2x
Similarly
b
tanB
2y
x
c
2z
Also tan A tanB tanC tanA .tanB.tanC (when A+ B + C = )
And tanC
13
9.
a
b
c
abc
2x 2y 2z 8xyz
a b c abc

x y z 4xyz
4
tan x cot x
(A) 0 x
also ln sin x 0
ln sin x
tan x
ln sin x
cot x

(B) in 0,
2
cosecx 1
4ln cos ecx 5ln cosec x

(C) in 0, , cos x 0,1
2
lncos x 0
also
1

2
10
1 1
2 3
ln cosx
1

3
ln cos x
= 5m 3n
7(5m 3n)2 + 5m2 3n2 = 0
6m2 7mn + 2n2 = 0
2
n
m n or m
3
2
If m = 2/3n
from (1)
= 1/3 n
If m = n/2
..
= -n/2
cos
1 1 2 1 3 2
12 22 33
11.
14 6
12 22
2
2

a b c d a 2 a.b 4 2d. a b c
Let d a b c

Then d.a d.b d.c cos
cos
Also 2 2 2 1 3cos2 or cos

2
3
a b c d 4 2.
3
7
12
a,b,c are mutually r
1
3
42 3
12.
end point of latus rectum P(1, 2) & Q(1, -2)

PAQ is isosceles right angled
14
slope of PA is 1
In equation y 2 = - (x 1)
x+y3=0
similarly equation of line QB
xy3=0
2
solving x + y 3 = 0 with parabola y = 4x
2
3 x 4x
x 1,9
co-ordinate of B & C are (9, -6) & (9, 6) respectively
Area of trapezium
1
12 4 x8
2
64 sq units
13.
let the circumcenter of trapezium be T(n, 0)

Then PT = PB
n 1
n 9
36
or n = 7
radius 40 2 10
14. 16 z 2 1
Case I when 1 1
We get 2 < 1
z i 1 2
or x = - y2 = 1 x2
or x2 + y2 = 1
case II > 1
2 1 0
z 2 1
or x 2 1, y 0
Roots are 2 1,0 , 2 1,0
One root lies inside the unit circle and other will lies outside the unit circle
Case III where is very large then
z 2 1
2
z 2 1
1
2
1
2
SECTION B
1.
total number of function = 3 = 729

(a) total number of onto function = 3 C116 3 C2 26 3 C3 36
3 192 729
540
15
(b) since f(ai) bi

It means that a1, a2, a3 cannot be assigned images b1, b2, b3
Number of function = 2333 = 216
(c) number of invertible function = 0
as function is not one one
(d) total many one function = 729 0
= 729
2.
(a) sin1 sin 3 10

3 10
(b) cos cos 4 10
1
4 10
1
(c) tan1 x tan1 if x 0
x 2
if x 0
2
n n 1
n n 1
(d) sin1
tan
1 n n 1
n n 1
n n 1
n n 1
sin1
tan
1 n n 1
n 1
n 1
n n 1
tan1 n
SECTION C
1.
let each friend has n sons.

3 tickets can be distributed among 2n sons in 2n C3 ways.
The number of ways distributing 3 tickets such that two tickets go to the sons of one and one
tickets goes to sons of the other.
n C2 n C1 n C1 n C2 2 n C1 n C2
probability that two tickets go to the sons of one and one tickets goes the sons of the other
2 n C1 n C2
2n
C3
6n2 n 1
2n 2n 1 2n 2
3n
2 2n 1
But from question

6
3n
7 2 2n 1
n 4
Hence total number of boys = 8.
2.
the equation of the tangents to the circle x + y = a at P and the hyperbola x y = a at Q are
x my a 1 m2
or x my a 1 m2 respectively
Where y = mx is intersecting line through (2, 0)
Let (h, k) be the point of intersection of these two lines
16
h mk a 1 m 2 are h mk a 1 m2
2
h mK a2 1 m2 and h mK a2 1 m2
2mhK h
m2 K 2 a2 2mhK h2 a2 0
m2
a2
a2 0
Elimination m from these two equation and we get

a 4 4y 4 x 2 a6
3.
A BC
Since ei 1, eiB C ei A eiA

e
i A B
ei2A
e
i A B
i A C
ei2B
i A C
i B C
i B C
ei2C
1 1
1 1 1
1 1 1
4
4 4
x 1
t
x2
4.
put
5.
OP HP
x2 y2 3 x
3
or y 2 6 x
2
Area of region =
9 y2
0 6 dy
= 3 sq unit
1
6.
1 2 3... n n
f x lim
n n n .... n
1
1
2
n
log f x lim log log ... log
n n
n
n
n
n
1
r
lim log
n
n
r 1 n
1
log x dx 1
0
f x e1
1
e
Hence e2f(x) = e2
1
e
e
e2 f x e 2

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FIITJEE

ALL INDIA TEST SERIES

(A) p,q, (B) p,q,

(A) p,r,s, (B)p,r,s,t,

(A)p,s, (B) q,r,t,

Apply conservation of linear momentum

Calculate the time constant

Battery is replaced by a wire

14 16. Initially current will pass through the resistance only.

Power in R2 = 7 (I2) = 2.8 W

In such type of situation, we have to use these basic facts.

in this situation block B will not move at all.

apply newtons laws of motion for the body A and body B

simply use this concept

from P T diagram, write the P T equation.

The cell reaction is: H2(g) + I2(s)

[Ag+]initial just after mixing =

conc. after precipitation

k1 2k 2 k 3 A 10 103 0.25 2.5 103 mol L1 min1 .

0.5 40 0.25 60 0.25 80

Effective no. of atoms of X = 4 4

The gas is thus diatomic

No. of eq. of NaOH produced experimentally =

bcosec .cot asec tan

Let , , , be the four roots

PA 2 PB 2 AB 2 2PA.PB cos 2PA.PB as cos 1

Thus the max value of |PA PB| is AB

tan3 tan2 tan2 tan

cos 3 cos 2 cos 2 cos

Also 2 2 2 1 3cos2 or cos

a,b,c are mutually r

end point of latus rectum P(1, 2) & Q(1, -2)

let the circumcenter of trapezium be T(n, 0)

Roots are 2 1,0 , 2 1,0

total number of function = 3 = 729

(b) since f(ai) bi

(a) sin1 sin 3 10

let each friend has n sons.

But from question

Elimination m from these two equation and we get

Since ei 1, eiB C ei A eiA

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