Useful

MOLE CONCEPT
FOUNDATION BUILDER (OBJECTIVE)

1.
(D)
2.
(D)
3.
(B)
4.
(A)
(Most stable isotope of carbon)
5.
(D)
6.
(C)
7.
(A)
Moles of gas =
5.6
0.25
22.4
Molecular weight of gas =
7.5
30
0.25
Hence NO.
8.
(A)
Molecular weight of C 60 H122 60 12 122 842.
842
Weight of a molecule =
1.39 10 21 g .
23
6.022 10
9.
(A)
1 mole contains Avogadro number of atoms.
10.
(A)
1.4
0.05.
28
Number of atoms = 0.05 2 6.02 1023 .
= 6.02 1022 .
Moles of N 2
11.
(D)
(A)
(B)
(C)
(D)
12.
22.4 10 3
NA 6.022 10 23
22400
22
6.022 10 23 3.011 10 23
44
11.2
6.022 10 23 3.011 10 23
22.4
0.1 6.022 10 23 6.022 10 22
(C)
Number of gms of H 2SO4 0.25 98 24.5
CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1
13.
(D)
0.5
2
Volume of H2 in l = 0.5 22.4 11.2l .
Moles of H 2
14.
(D)
19.7 1000
100
197
Atoms of Au = 100 6.022 10 23 6.022 10 25 .
Moles of Au =
15.
(A)
Mass of one molecule of CO 2
16.
44
7.3110 23
6.02 10 23
(C)
Number of moles of H 2
0.224
0.01
22.4
17.
(B)
18.
WH 3 3 9g
[B]
19.
In one H2O molecule: 10 proton, 8 neutrons, 10 electrons

36g
2mols
Hence in 36 ml, n H2O
18g / mol
Protons = 2N A 10 20 N A
[C]
20.
n atoms
WN 3 14 42g
w
. Hence it should be of same weight W
at.wt
[A]
21.
no. of moles =
[B]
22.
23.
24.
10 3 N A
10 3
NA
wt 103 mol.wt 103 M 0 g M 0 mg
1
16
A:12 g ; B 16 8g ; C : 10 g ; D
8g
2
2
[A]
A : 2.5 5N A 12.5 N A ; B :10N A ; C : 4 3N A 12N A ; D 1.8 8N A 14.4N A .
Hence [D]
52 amu
13
4 amu
[C]
25.
One ion contains: 7 + 24 + 1 = 32 e

total es 2 N A 32 64 NA
[B]
26.
n C 0.5 6 3
[D]
27.
28.
29.
30.
wt = 36 g
28
46
36
54
; B: ; C: ; D:
44
46
18
108
[C]
A:
180
10
18
no. of es 10 10 N A 100 N A
[D]
n H 2O
2.48
0.01
248
nH 2O 5 0.01 molecules 0.05 N A
[c]
n Na 2S2O3 .5H 2O
n Ag
90 10
1
1
atom N A 5 1022
100 108 12
12
[c]
31.
n H 2O
18 333
= 9. Hence [B]
54 (96 3) (18 18)
32.
n H 2O
0.018
103 . Hence, molecules = 103 NA
18
[C]
33.
n N 3
4.2
0.3 .
14
total = 0.3 8N A 2.4N A
[A]
34.
35.
3.42
0.12
342
atom = 0.12 N A [D]
n C 12 n C12H 22O11 12
8.4
0.1
84
Each contain (12 + 6 + 24) protons
n MgCO3
Hence, total 0.1 42NA 2.5 1024

[B]
36.
n total
4.4 2.24
0.2
44 22.4
molecules = 0.2N A
[B]
37.
[D]
38.
n gas
w
w
mol.wt. 3a
[B]
39.
40.
41.
42.
43.
558.5
10 moles
55.85
In 60 g carbon, n C 5
[A]
n Fe
twice = 10 moles
Say n Mg PO n ; then n O 8n
3
4 2
0.25
8n = 0.25 n
3.125 10 2
8
[B]
w
w
2 :
2 2 :1
nx : ny
10
20
Hence [B]
X
46 96 180 180 X 55.9
100
[C]
25.4 8 1 1
: : 2:5
127 16 5 2
Hence I 2O5 . [C]
n I : nO
44.
mol. Wt = 2 VD = 100
71
w chlorine
100 71g
100
w metal 29 g
[A]
45.
(D)
CaCO3
CaO CO2
1
Quantity of limes tones = wt. of one mole mole of CaCO3

= 100 kg
46.
(A)
Moles of H 2S 2
11.2
Moles of SO 2
0.5
22.4
SO 2 2H 2S 3S 2H 2O
moles 1
given
0.5
2
3 0.5
x
1.5
1
L.R.
47.
(C)
100
1.724
58
Moles 2H 3PO4 3Mg OH 2 Mg 3 PO 4 2 6H 2 O
Moles of Mg OH 2
Moles
2
2 1.724
Given
3
Weight of H 3 PO 4
48.
2 1.724
98 112.6g
3
n H2O n CH3OH 2 4
wt 4 18 72g
[D]
49.
WO 3.6769 2.0769 1.6g

with
2 mole X
5 mole'O '
1.6
with
' n ' moles
mole 'O '

16
0.2
n
0.04
5
[A]
50.
Ag2CO3
2Ag
2.7
WAg
2 108 2.11g
216 60
[A]
51.
n CO2 2 n C2 H5OH 2
WCO2 2 44 88g
Hence [D]
52.
53.
54.
KClO 3
KCl 3 O 2
2
48g
Hence % loss in wt =
100 39.18
122.5
[C]
2
2
2
n Fe n H 2O
Wiron 56 37.39
3
3
3
[A]
n CaCO3 n CaO
1.62
n CaCl2 0.0289
56
% of CaCl2
0.0289 111
100 32.11%
10
[B]
55.
(D)
3BaCl 2 2Na 3PO4 Ba 3 PO4 2 6NaCl

Moles
3
2
1
6
1 0.2
0.5
0.2
0.1
2
(L.R.)
56.
Ca OH 2 H 2SO 4
CaSO 4 2H 2O
0.5
0.2
LR
n CaSO4 n Ca OH 0.2
2
[A]
57.
A 2B
C 3D
5
8
LR
nB
n
4 ; n D 3 B 12
2
2
Hence [B]
nC
n : 4Al
58.
3C
2400
200
12
1350
50
27
Al4C3
L.R
given
4Al 144
w 1800g
given
50 W
[D]
59.
2A
2B
B
2C
3C
4D
60.
61.
2 2 4
n D nA
2 1 3
32
3
[D]
Mol.wt. 0.8 28 0.2 32 28.8
M
VD
14.4
2
[C]
Dcl2 wrt air
Dcl2
Dair
M cl2
M air
71
29
Hence [A]
62.
30.4
14 16x 14 x 2
100
M
46
oxide
1.44
MO 2
32
Say NO X . Then
Doxide wrt O2
[B]
63.
molality
n
w solvent
1000 urea : NH 2 C NH 2
||
18
60
1000 0.192
1500
1.052
18
[B]
64.
65.
66.
1
n
Molarity
1000 98 1000 0.01
V mL
1000
[D]
Al3 20 0.2 2 0.2M
40
[A]
1 mole KMnO4
5 moles FeSO4
V 0.01
50 0.01
V 10mL
[D]
67.
100
4
n H
0.001 2 2 10
1000
no. of H 2 104 N A 1.2 1020

[B]
68.
3 molal 3 mole NaOH in 1000g solvent

120 1000
vol
1009mL
d 1.11
n
3
Molarity
1000
2.97
V mL
1.009
[A]
69.
(B)
2.65 1000
0.1 M.
106 250
0.1 10
After dilution of 10 mL solution =
0.001M
1000
n NaCl
1
70.
X NaCl
0.0177
n NaCl n H 2O 1 1000
18
[A]
Molarity of NO 2 CO 3
GET EQUIPPED FOR JEE MAIN
1.
KClO3
KCl 3 O 2
2
3
2Al
O
Al 2O 3
2 2
nO
n Al2O3 2 1
3
2
[A]
2.
Consider 1 L solution
29
d 1000 H2SO4 3.6 98
100
d = 1.22 g/mL
[A]
N2
3.
n:
3H2
10
, n O2 3
2NH3
15
LR
10 5
n N2 5
n H2 0
10 moles
[A]
Fe2 SO 4 3 3BaCl2
3BaSO 4 2FeCl3
4.
n:
?
n BaCl2
3
n FeCl3
2
n BaCl2 2 3 0.75moles
2
[C]
5.
3CuSO4 2Al
Al2 SO4 3 3Cu
displaces
54g Al 192 g Cu
displaces
27g Al
96g
[C]
6.
CH4
2O2
CO2
5
8
54=1
4
n CO2 4 ; nCH 4 (remaining) = 1
2H2O
[A]
7.
X
C10H X nO 2
10CO 2 H 2O
2
X
Hence, n 10
4
X
with
1 mole C10 H X
10 moles
4
with
2.5 moles
32.5 moles
x 32.5 1
13
4
2.5
x 13 10 4 12
[C]
i.e. 10
8.
9.
10.
with
100g CaCO3
2mole HCl
with 25L
g
0.75 M HCl
1000
0.9375g
[D]
2.125
V L Molarity
143.5
2.125 1000
Molarity
0.59
143.5 25
[B]
with
2X
3 16g Oxygen
n AgCl n Cl n HCl
with
1g
0.16g Oxygen
3 16
X
150
0.16 2
[D]
11.
12.
3
2Al O2
Al2O3
2
1
n:
n
2
3
with
2 27g Al
mole O2
2
with
1

mole
2
2 27
18g
3
[D]
n BaSO4 nSO2 nS (POAC on S)
13.
8 1
32 4
[D]
n NaBr n1 , n KBr n 2 say

0.97
n AgBr n Br n1 n 2
0.00516
108 80
Also, n1 103 n 2 119 0.560
0.56 103 0.00516

0.00178
16
WKBr 119n 2 0.212 g
[B]
16g
31.2
A : nH 4
4 ; B : nH 4
1.64
16g
76
n2
14.
C : n H 22
34.2
36
2.2 ; D : n H 12
2.4
342
180
Hence [A]
15.
Total atoms
= 200 0.05 NA 1020 NA
0.05 NA 31022
[C]
16.
Mol. Wt of A 2 B3 150 96 246
For 5 mol, 246 5 g = 1.23 kg
[C]
17.
18.
19.
20.
21.
200
144
6.43 N A ; C
N A 3 9N A
342
48
D : 2.5 3N A 7.5N A .
Hence [A]
A :10N A ; B :11
[D] obvious
1
1
1
1
A : 3N A ; B :
26N A ; C : 8N A ; D : 2N A
44
114
30
26
Hence [A]
9.2
2 n 1 n 0.4
46
[C]
n CO2 n , say. Then n O 2n
22.
wt 0.4 30 12g
8
1
n
16
4
[D]
A : 0.2 14 g 2.8g ; B :
3 1023
6 1023
12 g 6g ; C : 32 g ; D : 7 g.
Hence [A]
23.
[D]
1 gram molecule: 44 g
1 molecule of CO 2 = 44 amu
24.
n H n 2 2n 4 10n
n C 2n 1 2n
n C : n H 1: 5
[A]
25.
Total charge = 1 N A 3e 3N A e coulomb

Hence [D]
69.98
Mol.wt 2112 mol.wt 360
100
[D]
26.
12g H 2O
8% H 2O
27.
45g silica
45g silica
43g others
43g others
100goriginal
' w 'grams
8 % of w = water
i.e. 92 % of w = silica others
92
Hence,
w 88g w 95.65
100
45
% of silica
100 47%
95.65
[D]
28.
M3N2 .
28 % nitrogen
28
3M 28 28 M 24
100
[C]
29.
0.014% mol.wt 2 at.wt of N

0.014
i.e.
M 2 14 28
100
2800
M
2 105
14 103
[D]
30.
(A)
Average atomic mass =
90 20 21x 22 10 x
100
20.11
x = 9%
31.
(B)
32.
(C)
6.023 10 23
1
6.023 10 23
3.01 10 22
Moles of HCl =
0.05
6.02 1023
3.01 10 22
HCl
0.05
6.02 10 23
Moles of Ca OH 2
Ca OH 2 2HCl CaCl 2 2H 2 O
1
0.05
1
0.05 1
0.025
2
L.R.
33.
(A)
1.595
0.01
1595
Weight of solvent = 100 1.595 = 98.505
98.505
Volumes of solvent
82 10 3 L
1.2 1000
0.01
Molarity
0.12M
82 103
(B)
28
(A)
atoms of O 2
6.022 10 23 ~ 3 10 23
32
3
(B)
atoms of Be 6.022 10 23 ~ 2 10 23
9
8
(C)
atoms of C 6.022 10 23 4 10 23
12
19
(D)
atoms of F2 6.022 10 23 1 10 23
19
(C)
X
Y
X
Y
20
80
:
1 : 2
XY2
10
200
Moles of CuSO 4
34.
35.
36.
(C)
Auogaduos hypothesis
37.
(A)
3 2.68
0.00335
24 100
Number of magnesium atoms = 0.00335 6.022 10 23
2.011021 atoms.
(A)
25 10 3
Moles of comphon
0.164 10 3
10 12 16 16
Number of atoms 0.164 103 6.022 10 23 .
9.9 1019
(D)
Moles of e 52 2 54 .
Moles of magnesium =
38.
39.
40.
(B)
Moles of Ag =
1
.
107
1
107 2
107 2 32
Mass of Ag 2S
1.1495
107 2
1.1495
Mass of ore required =
100 85.78g
1.34
Moles of Ag 2S required =
41.
(D)
Moles of Al = 27
27
2Al 2NaOH 2H 2 O 2NaAlO 2 3H 2

Moles
2
2
2
2
3
31
Given
1
excess
1.5
2
(L.R.)
Vol. of H 2 evolved = 1.5 22.4 33.6 L .
WINDOW TO JEE MAIN
1.
(A)
n solub le
Vso lub le Lt
Molarity
Vsolution is affected by Temperatuere.

2.
(C)
n Fe
560
10
56
No. of atoms = 10 NA
In 70 g of N
In 20 g of H
3.
(A)
5.
(B)
70
N A 5 NA
14
20
no. of atoms =
N A 20 N A
1
no. of atoms =
4.
(D)
6.02 10 20
NA
Molarity
0.01
0.1
6.
(C)
7.
(C)
V=1L
Wtotal 11.021000 1020g

nsoluble = 2.05
Wtotal
352.8
100 1216.55g
29
= 1020 123 = 897 g
molality
2.05
2.28
0.897
8.
(B)
9.
(B)
V = 1L
nsoluble = 3.6
wsoluble = 3.6 98 352.8
352.8
100 1216.55g
29
1216.55
density
1000
w total
= 1.22 g/ml
10.
(C)
14.
(A)
11.
(B)
12.
(C)
13.
(C)
weight
N A species
atomic weight
In 4 g of hydrogen
4
Number of atoms N A 2 4N A
2
[Here species = 2 because hydrogen is present as H2]
In 71 g of chlorine = 2NA
71
Number of atoms = N A 2 2N A
71
In 127 g of iodine,
127
Number of atoms =
N A 2 2N A
127
In 48 g of magnesium,
48
Number of atoms =
N A 1 2N A
24
[Here Mg is present as Mg so species = 1]
Thus, the number of atoms are largest in 4 g of hydrogen.
Number of atoms
15.
(b)
Heavy water is D2O
In it,
Number of p 1 2 8 10
Number of e 1 2 8 10
Number of n 0 1 2 8 10
(D have1 n0 because it is actually, 1H2)
16.
(d)
18 g H2O contains 2 g H
0.72 g H2O contains 0.08 g H.
44 g CO2 contains 12 g C
3.08 g CO2 contains 0.84 g C
C:H
0.84 0.08
:
0.07 : 0.08 7 :8
12
1
Empirical formula = C7H8
17.
(c)
3 M solution means 3 moles of solute (NaCl) are present in 1000 L of solution.
Mass of solution = volume of solution density
1000 1.252
= 1252 g
Mass of solute = No. of mole molar mass of NaCl
358.5g
= 175.5 g
Mass of solvent = (1252 175.5)g
= 1076.5 g
= 1.076 kg
Molality
moles of solute
mass of solvent in kg
3
2.79m
1.076
18.
(a)
M1V1 M 2V2
V1 V2
10 2 200 0.5
200 10
20 100
210
120
0.57 M
210
Final concentration, M
FOUNDATION BUILDER (SUBJECTIVE)

1.
2.
X
2X X
y given . For B :
Y
20
40 20
1.6
0.1moles 6 10 22 molecules
16
Each molecule has (6 + 4) = 10e s
n CH 4
total e s 6 1023
3.
n H 2O
18g
1mole
18g mol
1 molecule has (2 + 8) = 10 e s
1 mole contains 10N A electrons.
4.
O2 :10 e,8 protons,8 neutrons per ion.

in1mole:10N A e,8 N A protons,8N A neutrons
5.
Atomic mass = NA mass of oneatom
6 1023 6.64 1023 g 40 g

wt
1
wt of one atom 3.98 10 23

2.5 1022
6.
no. of atoms =
7.
removed 1021 44amu 7.35 102 g

CO2 ,remaining 200 73.5 126.5mg
n CO2
8.
126.5 103
0.002875
44
1mole N3 charge NA 3e 2.88 105 C
9.
3.2 103
2 10 4 moles
64
n S n Na 2S2O3 .5H 2O 2 2 5 103 10 2
n O nSO 2 2
n O : nS
10.
11.
104
102
0.01
n O 3 n NaNO3 2 n NO2
1
m 10m 2 0.03 0.333 0.363
6
1
n N n NaNO3 n NO 2 10 103
6
= 0.01 + 0.166
= 0.176
23
6 10
t s
6 1017 s
6
10
6 1017
t hr
1.67 1014
3600
1.67 1014
t yr
1.9 1010 years
24 365
12.
atomic wt = 6.644 1023 6 1023

= 40 g/mol
40 1000g
n
1000 moles
40 g / mol
13.
nC
106 g
12g / mol
No. of atoms = n C 6 1023 5 1016

14.
15.
16.
r = 0.1 inch = 0.254 cm

85.6
Fe
ball
100
ball Vball density
4
3
0.254 7.75 0.532 g
3
85.6
Fe
0.532 g 0.455g
100
0.455
n Fe
and no. of atoms = 4.9 1021
56
0.086
starch = wt of 1 atom = 31 g
100
3100
starch
3.6 104
0.086
VNH 3 n NH 3 22.4 L
17.
18.
3.4
22.4 4.48L
17
PV
1 1
0.04464
RT 0.0821 273
n moleculs n O2 N A 2.69 1022
n O2
O3 O2
600mL
Vml 600 V mL
V
600 V 32 1g
48
22400
22400
V = 200 mL
19.
Element
% (with in 100 g)
40.2
Mn
26.8
33
no. of (in 100 g) atom

40.2
1.03
39
26.8
0.48
55
33
1.06
31
ratio
2
1
2
K 2Mn P2
20.
Say
nO n
n H 15n
70
And n C
15n 10.5n
100
C10.5H15O or C 21H30O 2 is empirical formula
1
Mol. Wt
314
0.00318
C21H30O2
Then
21.
weight
9.03 10 20
0.311g
weight
6.02 1023
mol.wt.
mol.wt 207.33g
131.3 19n 207.3 n 4
22.
23.
58.97
102 59.9 n C 5
100
13.81
H
102 14.08 n H 14
100
27.42
N
102 27.97 n N 2
100
C5H14 N 2
C
12
12
CO2 0.9482 0.2586
44
44
n C 0.02155
2
H H 2O 0.02154
18
n H 0.02154
n C : n H 1:1 CH
24.
12
cylinder
100
cylinder r 2 h density
Co
3.14 6.25 10 8.2 1610.7
Co
1
12
n Co
1610.7 3.28
58.9
58.9 100
no.of atoms 3.28 6 10 23
1.98 1024
25.
Mol. Wt = wt of 1 mole mix = 2VD = 76.6

(x mol. NO2 + (1 x) mol. N 2O4 ) = 76.6 g
x 46 1 x 92 76.6
15.4
n NO2 in 1 mole = 0.335
46
100
n mix in100 g
76.6
x
n NO 2 in 100 0.335 n mix
= 0.437
26.
molality
n
solvent
1000
Consider 1L of solvent
C2 H5OH
mol.wt 46
n=8
solvent 1.025 1000 8 46 657
molality
27.
8
1000 12.18
657
2NaHCO3
Na 2CO3 CO2 H2O
Na 2CO3
no effect
loses
2 84g NaHCO3
62g CO2 H 2O
loses
g
0.124
0.124
168 0.336 g
62
0.336 100
% of NaHCO3
16.8%
2
and Na 2CO3 100 16.8 83.2%
28.
C 74.27
74.27
6.1892
12
7.79
7.79
1
12.99
0.928
14
4.95
0.309
16
H 7.79
N 12.99
O
29.
4.95
6.1892
20
0.309
7.79
25
0.309
0.918
3
0.309
0.309
1
0.309
C20 H 25 N3O
20
of C atoms 100
49
40.816 %
2CH3CHO O 2 2CH 3COOH

20g
10g
:
20
10
0.45
0.31
n:
44
32
L.R
(A) n CH3COOH n CH3CHO 0.45
CH3COOH 27.27g.
10 20 44
0.852
32
2
n O2 32 2.727g
(B) n O2 left
O2
(C) % yeild
23.8
100 87.2%
27.3
30.
3 20 4 40 8 50
n CH n A

3.2
2 100 2 100 3 100
31.
n CH 4 n1 and n C2H 4 n 2 ,say
now, n1 16 n 2 28 5g
14.5
also, n CO2 n1 2n 2
0.33
44
n1 0.193 and n 2 0.068
CH 4 100 16n1 100
60%.
5
5
%C2 H 4 40%
%CH 4
32.
POAC on carbon
n C n K 2CO3 1 n K Zn
2
moles of product
2 Fe
CN 6 2
n K2CO 3
12
12
0.0166
33.
n Cu n Cu NO3 .3H 2 O (POAC on Cu )

2
10
product
63.5 124 54
63.5
38.03g
34.
AgNO3
NaCl
5.77
4.77
n
n
170
58.5
0.03394
0.08
L.R.
n AgCl n AgNO3 0.03394
AgCl
NaNO3
AgCl 0.03394 143.5 4.87g
35.
CaCO3
CaO CO 2
n1
n1
MgCO3
MgO CO2
n2
n1 100 n 2 84 1.84
n1 56 n 2 40 0.96
n1 0.01
n 2 0.01
%CaCO3
36.
0.01 100
100 54.35%
1.84
Cl2 2KOH KCl KClO

H 2 O
3KCl
O 2KCl KClO
1 1 3 n Cl2
n KClO4 n Cl2
1 3 4
4
1385
n Cl2 4
40
39 35.5 64
Cl 2 40 71 2840g
37.
POAC on Cl (eventually on completion)

n Cl2 2 n KCl 1 n KClO4
n Cl
142
2 2 4 0.5
71
4
3.5moles
1g KClO3 n 2 moles
n KCl
38.
n1 moles
KClO 4 KCl
KCl O 2
3
146.8
n O2 n 1
n1 0.00437
2
22400
n2
1g
n 0.00379
39 35.5 48 1
3
n 2 0.00284
4
1g O 2 0.79029g
n KClO4
resiude
0.00284 39 35.5 64
100
0.79
49.789%
%KClO 4
39.
CH 3 x AlCl y CH 4 yCl
Cl AgNO3 AgCl NO3
1. n CH4 x.n CH3
AlCly
0.222
0.643
x.
16
15x 27 35.5y
2. n AgCl n Cl y.n CH3
AlCl y
0.996
0.643
y.
108 35.5
15x 27 35.5y
x
1.99 2
y
0.643 2y
0.222
in1,
16
30y 27 35.5y
1 2
y 1 and x 2
40.
KClO3
KCl O2
2
6.125g
Zn 2HCl ZnCl 2 H 2
H 2 1 O2 H2 O
2
in (1),
3
n O2 n KClO3 0.075
2
in (3),
n H 2 2 n O 2 0.15
in (2),
n Zn n H 2 0.15
41.
42.
(1)
(2)
(3)
Zn 0.15 65.3 9.795g

(A): B,
(B): A,
7
7
(C): n C n B .
2
2
C O 2 CO, CO 2
n1
n2
POAC on C
12
n C n1 n 2 1
12
POAC on O : n O n1 2n 2
20
1.25
16
n 2 1.25 1 0.25
and n1 0.75
n CO : n CO2 n1 : n 2 3 :1
43.
2NaOH H 2SO 4 Na 2SO4 2H 2O

n NaOH
15 1 1
4
n H 2SO 4
7.5 10
2
1000 10 2
H2SO4
strength
1000
VH2SO4 mL
6.125g / L
44.
Molarity
n
10 103
1000
103 0.1M
V mL
100
in gram / L 0.1 39 16 1 5.6g / L
45.
100
4
n SO2 n H 2SO4
0.001M 10
4
1000
no. of ion n SO2 n A 6 1019
4
46.
n CuSO 4 .5H 2 O n Cu 2 0.5 0.01 5 10 3
weight n mol.wt 5 103 249.5

1.2475g
47.
M1V1 M 2 V2 M 3V3
50 0.5 75 0.25
M final M 3
50 75
0.35Molar
48.
Molality
49.
n I2
1000
solvent
3 30
1000 0.4molal
250
n I2 n C6 H 6
0.2
Say, we have 1 mole mix.

Then, n I2 0.2 and n C6H 6 0.8
molality
50.
n I2
C6 H6
1000
0.2
1000 3.205m.
0.8 78
Consider 1L solution.
t solution 1000 1.06 10609.
10
solution 106g
100
n KCl
Molailty
1000
Vsolution (mL)
106 74.5 1000
1.4228M
1000
KCl
51.
30%NH3 . 70%water.
70
i.e.
solution water 105g
100
100
i.e. solution
150 150g
70
150
Vsolution
166.67mL
density 0.9
52.
Consider 1L of solution,
solution 1.025 1000 1025g
n ethanol M V 8 1 8moles
ethanol 8 46 368
n
molality ethanol 1000
solvent
8
1000
1025 368
12.176molal
53.
2SO 2 O 2 2SO3
nSO 2 nSO3 nSO3 5

54.
55.
56.
4FeS2 11O2 2Fe2O3 8SO2

600
800
5
23
120
32
1
So moles of Fe2O3 2.5
2
146
n NH3 n HCl
4
36.5
Wt NH3 4 17 68g
2H 2 O 2 2H 2O
6
29
3
0.90625
2
32
LR
wt H 2O formed 0.90625 2 18 32.625 g

wt H 2 left 3 0.90625 2 2 2.l325g
57.
245
w
3
2
95
58.5
58.
w 226 g
AgCl AgBr
n1
n2
n1 n 2 108 60.94
%Ag
100 n1 143.5 n 2 188 100

n
1 0.31955
n2
n1
35.5 100
n
n1 35.5
%Cl
100 2
n1 143.5 n 2 188
n1
143.5 188
n2
4.856%
%Br 100 60.94 4.856 34.2%
59.
CO2 H2O unbalanced

COOH2
H SO
2
POAC n C n CO2 1 n COOH 2
10
2
2
90
9
2
V CO2 22.4L 4.977L
9
60.
acid is H3A. salt is Ag3A
1moleAg3A 3mole Ag
n Ag 0.37 108
n Ag3 A
0.00114
3
3
0.607
0.00114
mol.wt of Ag3 A
mol. wt 108 3 A 531
A 207
wt of H3A 210
GET EQUIPPED FOR JEE ADVANCE
ONE OPTION CORRECT
1.
N2
3H 2
say, wt :14x
3x
14x x
3x
to
28 2
2
x
3x
tt
y
3y
2
2
NH 3 was 40% by mol.
2NH 3
2y
40 x
3x
3y 2y
y
100 2
2
2x
x
5y 2x 2y y
3.5
7
y
i.e. 2y
X N2
x y
1
x 2 y 2
2x 2y 2 x y 1
1.75 1 0.75
2 2.5
5
0.15
(A)
2.
n(A) n(B)
M A n(A) 1.4g and M B n(B) 0.8
M
0.8
B
0.57.
M A 1.4
(C)
3.
with
3.2g metal
0.4g oxygen
64g metal g oxygen
64
0.4 8g
3.2
128g metal with 16g O
i.e. M 2O
(B)
4.
with
4M
96g O. sin ce X 4 O 6
with
5.72g
4.28g O
5.72 6 16
MX
32
4 4.28
(A)
5.
224
0.01
mol.wt 22400
wt
1
mol.wt
100
n 0.01
n
3 at.wt. 100 at.wt 33.3g

33.3
mass of one atom
5.53 1023 g
6.02 10 23
(C)
6.
7.
PV
2 0.35
3.123 102
mol.wt RT 0.0821 273
1
i.e.
3.123 102
2 At.wt
at.wt 16
wt of one atom
.
NA
NA
(C)
n
I 2 Cl2 ICl, ICl3

n1
n2
POAC on I
n(I)
25.4
n1 n 2
127
POAC on Cl
14.2
n(Cl)
n1 3n 2
35.5
n1 : n 2 1:1
(A)
8.
FeSO 4 : n1 SO 42 n1 and Fe 2 n1
Fe 2 SO 4 3 : n 2 SO 42 3n 2 and Fe 3 2n 2
n1 3n 2 given
n1
3
n2
Fe 2
n
n n
1 1 2 3: 2
3
Fe
2n 2
2
(D)
9.
0.36M : V1 say and 0.15M : V2say

M V M 2 V2
M final 0.24 1 1
V1 V2
36V1 0.15V2
0.24
V1 V2
V
0.36 1 0.15
V2
or
0.24
V1
1
V2
V
V
0.36 1 0.15 0.24 1
V2
V2
V 0.09 3
1
V2 0.12 4
(D)
10.
0.24
At mass N A mass of an atom
6 1023 3.98 1023 24g

(C)
11.
Fe 2 Fe CN 6
Fe 3 56 7
C 6 12 3
(C)
12.
obvious (D)
13.
obvious (B)
14.
1gatom 1mole of atom 14g.
(A)
15.
Na 2CO3 2HCl 2NaCl H 2O CO 2

n HCl 2 n Na 2CO3 VHCl M HCl
V3 2
1.431
V 9mL.
106
(B)
16.
17.
They must have same mol. wt.

(C)
V2micron sphere
V
20 Asphere
4 2 10 6 3
3
109
3
9
4 2 10
3
(A)
18.
19.
KClO3
KCl O2
2
n o2 0.1 2
n KClO3
3
3
30
2
2
2
122.5
% purity 30
100 81.66%
10
(B)
V ml m 1 0.65
6.5 10 4 moles
1000
1000
BaCl 2 .2H 2 O 137 71 36 6.5 10 4 0.1586g
n
BaCl2 137 71 6.5 10 4 0.1352g

(A)
20.
1.36 V 200 2.4

1.24
500
V 102.941mL
(B)
11.5
100
M C6 H5CH3 9.31g
71
21.
22.
CuSO 4 .5H 2O n1 , MgSO 4 .7H 2 O n 2

total t 5g and anhydrous 3g
249.5n1 246n 2 5
M C6H5COOK
and 159.5n1 120n 2 3

on solving, n1 0.0149 and n 2 0.0052
CuSO 4 .7H2 O. 3.729g
%by t
3.72
100 74.4%
5
(C)
23.
C 7 H 6 O 3 C 4 H 6 O 3 C9 H 8 O 4 C 2 H 4 O 2
: 2g
4g
0.01449
n : 0.0144 0.039
L.R
theoretical yield 0.01449 M C9H 8O 4

2.69
%yeild 80.76%
(A)
24.
25.
26.
2XI3 3Cl 2 2XCl3 3I2

0.5
0.236
n XI3 n XCl3
M 381 M 106.5
M 138.88 139
(B)
2
2
no.of molecules 500cm 0.21nm
n
V Molarity
NA
6 1023
n
i.e.V
2.395 10 5 L.
4.24 256
(B)
in 10 mL CuCl2 n1 , and CuBr2 n 2

n AgBr 2n 2 and n AgCl 2n1
2n 1 143.5 2n 2 188 0.9065g
and 2n 1 2n 2 188 1.005g

then n1 0.00115 and cuBr2 0.35g
25% and 58%
(A)
27.
n XH 4 2n and n X2 H6 n, say
n x n XH4 n X2H6 2 4n
5
4n and 2n X 4 n. 2X 6 5.628
X
5
5
i.e.
X 4 2X 6 5.628
2X
4X
5 10 5 7.5
or,
5.628
2 X 2 X
17.5
or X
27.86 28
0.628
(A)
i.e.
28.
M AgNO3
0.0125 39 80
0.0105M
1mL
42.5
n AgNO3
1000
0.00446
n NaBr 2n Na 2SO 4
0.0105
n AgNO3
n1
n2
n1 2n 2 0.00446
also, n1 103 n 2 142 2 5 t of 1

29.
th
portion
Let acid be HA
Salt: BaA 2 .2H2O
BaA2 H 2SO4
BaSO4 2HA
4.29
21.64
0.477
137 2A 36 1000
A 121
HA 122
30.
total moles =n (say)

0.15 n moles of CH 3COOH
0.15n 60 0.85 n 18 30
30
n
1.234
9 15.3
n NaOH n CH3COOH 0.15 n 0.18519
VNaOH 18.5 L B
31.
C2 H 6 3.5O2
n1 moles
2CO2 3 H 2O
C2 H 4 3O2
2CO2 2 H 2O
n2 moles
PV
1 40
1.218
RT 0.0821 400
130
also 3.5 n1 3n2 nO2
4.06
32
n1 0.817
n1 n2
n2 0.401
%C2 H 4 33% and C2 H6 67% A
32.
Al
K
S
O
no. of atom
0.3889
0.388
0.775
3.1
%
10.5
15.1
24.8
49.6
ratio
1
1
2
8
33.
Vmolecule
100 A 300 A
4
1.299 1024
mol. Wt N A Vmol desnity
6 1023 1.299 1024 1.2 103 kg m3

939 kg (B)
More than one correct
1.
3 moles in 1L 1250 g
wNa2S2O3 3 46 64 48 474
474
100 37.92%
1250
3
3
(B) x
0.065
1250 474 46.11
3
18
n
1000
(C) molality of Na
wsolvent
3 2
1000 7.73
1250 474
(A) % by weight
2.
mol. wt = wt of 22.4 L=28.896 g

mol.wt
VD
14.48
2
(A) and (B)
3.
[A] : 32 g
[ B]
1
64 32 g
2
[ D] : 32 g
Ca NO3 2 Na2C2O4
CaC2O4 2 NaNO3
4.
millimoles :
6
3
3
LR
[A],[C],[D]
5.
1.12
0.02
56
0.02 100 2 g
CaO n CaCO3
wCaCO3
wCaCl2 0.02 111 2.22 g

wNaCl 2.22 g
[ A, C]
6.
nNaCl 100 m moles ; n HCl 300 m moles
nCaCl2 200 m moles 200 Ca 2 , 400 Cl
cation 600 3
anions 800 4
Cl 800 2 M
400
A , C
7.
Obvious A,B,D nH 4
8.
3 mole NH 3
wH 3 14 42 g
WN 3 14 42 g
molecule 3 N a 18 1023
atoms 4 3 N A 72 1023
[ A], [B]. [C],[D]
9.
Obvious : [A], [B]
10.
[B],[C]: obvious others depend on volume
14.
Hence [C], [D]

14
Mol. Wt
22.4 28
11.2
Match the following

1.
2.
13 12
100 38.33%
407
6
(II) wt % of H
100 1.47%
407
(III) wt of H: wt of Cl 6 : 6 35.5
(IV) mo. of C: O =13:2
(I) wt % of C
(a)
wSO2
Wo2
(P)
(A)
(C)
(E)
2s
(b) d 10 5 2 g cc sp. gr 2 s
(c) M 2VD 32 Q
(d) molecular
3.
132
3
44
at anons = 9(R)
20
(a) Al 3
0.04 M
400
H 40 0.084
500
Total =0.12 M
Cl 60 40 0.2 M
500
(P), (S)
20
(b) K
0.2M
100
Cl 20 0.2M
100
(S)
12
(c) K
0.12 M
100
[ P], [Q]
SO42 6 0.06 M
100
(d) wH 2 SO4 200
24.5
49 n H 2 SO4 1 2
100
H 1 1000 5 M
200
SO42 1 2 1000 2.5M
200
[R]
4.
(A) VSO2 11.2 L
wSO2 32 g
1
2 NA
2
(B) n H 2 1 2 VH 2 11.2 L
total atoms
wH2 1 g , , total atoms N A P

(C) no. of atoms 0.5 3 N A 1.5 N A
[P], [Q], [R]
(D) 1moleO2 V 22.4 L
Atoms 12 1023
wt 32 g
[S]
COMPREHENSION TYPE
Passage 1
1.
wt of 1 atom 1amu 1.66 1024 g. (C)
2.
n S n H 2SO4 100 wt 3200g. (A)
3.
3.4
M s 2 32 M 1882.3 (B)
100
4.
C O 2 n C n C n O2 1
VO2
20
Vair 22.4C Vair 112L (B)
100
Passage 2
1.
Consider 1 L.
n KOH 6.9 KOH 6.9 56 386.4

30
solu 386.4 solu 1288g
100
d 1.2889g / mL. (A)
134
PV
0.2 2
M H2SO4 2 n NH3
1000
RT 0.0821 303
M H 2SO 4 0.06 (C)
2.
1600 0.205
0.2 V 40mL (A)
1600 V
3.
n H 2S
n H2SO4
5 34
5
1
5
34
V 0.2 5 V 25L (A)
4.
n H2SO4
Passage 3
18g
3 1023 g (D)
23
6 10
1.
m H2O
2.
Avogadros law. (A)
3.
obvious Mass is 16amu. (C)
4.
obvious (A)
Passage 4
1.
AgNO3 NaCl AgCl NaNO3

5.77
4.77
n:
n AgCl 0.0339
170
58.5
wt 4.88g
0.0339
0.081
L.R (A)
2.
H 2SO4 0.12 98 11.7g (A)
INTEGER
1.
0.5 mole N3 .N 3 has 10e .

5moles.
2.
CO2
132
3
44
nC 3
3.
MCl X : say. mol.wt M 106.5
n Cl n MClX X
n Cl n Ag
0.22x
M 106.5x
0.51
3 103
170
6.4
112s (Dulong petites law)
0.57
0.22 x
3 103 x 3
112 106.5x
M
8 2800
4
100 56
4.
n Fe
5.
x 5 20 2
2.6 5x 40 2.6x 52
x 20
6.
n 1
Cn H 2n 2 n
O 2 nCO 2 n 1 H 2O
2
n 1
n
2 7 4n 3n 2 7n or n 2
n
4
1440
2
mol.wt 60 12
7.
8.
5
solu 0.3g solu 6g
100
9.
10.
0.25
89600 Fe n 56 n 4
100
CO2 C6 H10O5
1g algae
2g algae
1g strach
1g strach
POAC on carbon
n CO2 1 n (C6H10O5 )n 6n
1
1
6n
162n
27
1 27
time
8
4.7 10 3
EXPERTISE ATTAINERS
1.
POAC on Co
n Co3O4 3 n Co 1
n Co
0.2125 3
Co n Co 59 0.156 g
177 64
n PPt 1 n Co
ppt n ppt mol.wt 1.52g
2.
90
0.5g Fe Fe2O3 n1
100
10
0.5g Fe
Fe3O 4 n 2
100
0.45
n1 2
n1 0.04
56
0.05
n2 3
n 2 0.0003
56
wt of mix= 160 n1 232 n 2 0.71g
(a)
(b) 0.5g Fe
Fe 2O 3 n
0.5
n 4.46 103
56
Fe2 O3 0.7142 g
n2
3.
(i) n AgNO3 n AgCl n NaCl n HCl

n1
n2
2.567
n1 n 2 0.0179
143.5
(ii) NaCl is not affected
1.341
n
Cl n AgCl n 2
143.5
n 2 0.009345
n1 0.0856
Now, n1 58.5 n 2 M 1gram

0.5
M
53.5
0.009345
4.
y
z
C x H y Clz O2
xCO 2 H 2O Cl2
2
2
0.22
0.195
n
(1)
x CO2
44
12x y 35.5Z
y n
0.22
0.0804
..(2)
H 2O
18
12x y 35.5 z 2
768 37.24
0.12
PV 760 1000
0.0012
n
RT
0.0821 382
12x y 35.5z
Solving, x 2; y 4 and z 2
C2H4Cl2
5.
..(3)
Consider 1 mole mix t 55.4
N 2 , NO 2 , N 2O4
n1
n2
n3
n1 n 2 n3 1
Now, after heating,
NO2 n 2 2n3
N O
2
2NO2
no. of moles = n1 n 2 2n 3 1 n 3
New Average mol. Wt 39.57

55.4
39.57
1 n3
n 3 0.4
Now, n1 28 n 2 46 n 3 92 55.4
28n1 46n 2 18.6
(1)
also n1 n 2 n3 1
n1 n 2 0.6
.(2)
Solving (1) and (2),

n1 0.5 ,and n 2 0.1
5 :1: 4
n
6.
IO 3 n HSO3 n
3 5.8
0.8788
HSO 3
1
3
23 127 48
w NaHSO3 9.139 g
n
I in 1st n IO3
5.8
198
IO3 n I n
IO3 0.00586
1
5
M NaIO3 5.8 198
n
IO3
0.2L 200 mL
M IO
n
7.
AgNO3 KI KNO3 AgI

2KI KIO3 6HCl 3ICl 3KCl 3H 2O
M KI VKI n KIO3
M 20
KI
2
1
2
M KI 0.3M
30
1
10
KI, excess n KIO3 n
KI, excess 10 m mole

2
1
Original KI 50 0.3 15m mole
n
Now,
KI used 5 m mole
n AgNO3 n KI used 5mmole w (AgNO 3 ) 0.85 g

purity 85%
8.
Let % of boron will at. Wt. 10.0 = x

Let % of boron will at. Wt. 11.01 = (100 x)
x 10.01 100 x100.01
10.81
100
x = 20%
9.
Let NaCl = w gms

kCl = (118 w) gms
POAC on Cl
w
0.118 w 0.2451
M Nacl
M kCl
M Agcl
w 0.118
w
0.2451
58.5 74.5 74.5 143.5

w = 0.0338 gm
Nacl = 0.0338 gm
kcl = 0.0842 gm
n nacl 5.777 104
n kcl 1.1310 3
POAC on Na; moles of Na 2O 2

= moles of NaCl 1
5.777 104
;
n Na 2O
1.1310 3
n k 2O
5.777104
Weight of Na 2O
62 0.01gm
2
1.1310 3
Weight of k 2o
94 0.1062
2
% Na2O = 3.58%.
% k2o = 10.62 %
10.
CxHy
y
C x H y x y x o 2 xCO 2 H 2 O
2
POAC on carbon
5 x vol.of CO 2 1
Now 1 vol. of CO2 = 10 mL (that obtained by kOH)
x=2
Vol. of O2 reactionary = 15 ml
Vol. of O2 reacted = 15 ml
1 ml of CxHy react with (2 + y/x) ml O2
5 ml of CxHy react with (2 + y/x) = ml 15 (given)
y= 4
formula = C2H4
11.
(a)
CO2 C 2CO
POAC on carbon
Let
CO = x l
CO2 = (1 x) l
x 1 2 1 x 1.6 1
2 x = 1.6 = 1
x = 0.4 l & (1 x)0.6 L
(b)
The molecular formula = M3N2
2 14
100 28
% Nitrogen =
3x 14 2
Where x = atomic wt of metal

100 28
24
x
3
12.
monobro min ation

C 2 H5
pat1 85%yeildC4 H10 55gm
90% yield
POAC on carbon
x
90 85
55
2
4 1

100 100 412 101
212 61
x = 74.37 gms
74.37
V
22.4L 55.53L
30
WINDOW TO JEE ADVANCED

INTEGER TYPE
2.
(4)
Boltzmann constant, k
R
or R k N A
NA
1.380 10 23 6.023 10 23
= 8.31174 J K1 8.312
Hence, no. of significant figures is 4

3.
(8)
Mass of 1 L solvent = 0.4g mL1 103 mL
= 400 g = 0.4 kg
Mole of solute
3.2
So molality (m)
Mass of solvent (kg) 0.4
=8m

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MOLE CONCEPT

FOUNDATION BUILDER (OBJECTIVE)

Molecular weight of gas =

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1

In one H2O molecule: 10 proton, 8 neutrons, 10 electrons

wt 103 mol.wt 103 M 0 g M 0 mg

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 2

One ion contains: 7 + 24 + 1 = 32 e

total = 0.3 8N A 2.4N A

Hence, total 0.1 42NA 2.5 1024

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3

Quantity of limes tones = wt. of one mole mole of CaCO3

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4

WO 3.6769 2.0769 1.6g

mole 'O '

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 5

3BaCl 2 2Na 3PO4 Ba 3 PO4 2 6NaCl

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 6

Al3 20 0.2 2 0.2M

no. of H 2 104 N A 1.2 1020

3 molal 3 mole NaOH in 1000g solvent

GET EQUIPPED FOR JEE MAIN

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 8

n NaBr n1 , n KBr n 2 say

0.56 103 0.00516

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 9

= 200 0.05 NA 1020 NA

Mol. Wt of A 2 B3 150 96 246

For 5 mol, 246 5 g = 1.23 kg

n CO2 n , say. Then n O 2n

Total charge = 1 N A 3e 3N A e coulomb

0.014% mol.wt 2 at.wt of N

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 12

2Al 2NaOH 2H 2 O 2NaAlO 2 3H 2

Vsolution is affected by Temperatuere.

Wtotal 11.021000 1020g

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 13

Empirical formula = C7H8

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 14

FOUNDATION BUILDER (SUBJECTIVE)

O2 :10 e,8 protons,8 neutrons per ion.

Atomic mass = NA mass of oneatom

6 1023 6.64 1023 g 40 g

wt of one atom 3.98 10 23

removed 1021 44amu 7.35 102 g

1mole N3 charge NA 3e 2.88 105 C

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 15

atomic wt = 6.644 1023 6 1023

No. of atoms = n C 6 1023 5 1016

r = 0.1 inch = 0.254 cm

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 16

no. of (in 100 g) atom

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 17

3.14 6.25 10 8.2 1610.7

no.of atoms 3.28 6 10 23

Mol. Wt = wt of 1 mole mix = 2VD = 76.6

n NO 2 in 100 0.335 n mix

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 18

2CH3CHO O 2 2CH 3COOH

n CH 4 n1 and n C2H 4 n 2 ,say

CH 4 100 16n1 100

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 19

n Cu n Cu NO3 .3H 2 O (POAC on Cu )