Model Test Paper

IIT JAM
Chemistry (CY)
Model Paper with Answer Key
Based on Exam Pattern
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Chemistry-CY (MQP)
Chemistry (CY)
Model Paper with Answer Key
Duration : 180 minutes
Maximum Marks : 100
Read the following instructions carefully.

1.
This test paper has a total of 60 questions carrying 100 marks. The entire question paper
is divided into Three Sections A, B and C. All sections are compulsory. Questions in
each section are of different types.
2.
Section A contains Multiple Choice Questions (MCQ). Each MCQ type question has
four choices out of which only one choice is the correct answer. This section has 30
Questions and carry a total of 50 marks. Q.1 Q.10 carry 1 mark each and Questions
Q.11 Q.30 carry 2 marks each.
3.
Section B contains Multiple Select Questions (MSQ). Each MSQ type question is
similar to MCQ but with a difference that there may be one or more than one choice(s)
that are correct out of the four given choices. The candidate gets full credit if he/she
selects all the correct choices only and no wrong choices. This section has 10 Questions
and carry 2 marks each with a total of 20 marks.
4.
Section C contains Numerical Answer Type Questions (NAT). For these NAT type
questions, the answer is a real number which needs to be entered using the virtual
numerical keypad on the monitor. No choices will be shown for these type of questions.
This section has 20 Questions and carry a total of 30 marks. Q.1 Q.10 carry 1 mark
each and Questions Q.11 Q.20 carry 2 marks each.
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Chemistry-CY (MQP)
SECTION-(A) MULTIPLE CHOICE QUESTIONS (MCQ)

1.
Which of the following are non-polar ?

(i)
SiF4
(ii)
Xef4
(iii)
SF4
(iv)
BF3
(v)
NF3
Select the correct answer using the codes below :
2.
3.
(A)
1, 2, 3 and 4
(B)
2, 3, and 5
(C)
3, 4, and 5
(D)
1, 2 and 4
The decreasing order of the first ionization energy of the following elements is
(A)
Xe > Be > As > Al
(B)
Xe > As > Al > Be
(C)
Xe > As > Be > Al
(D)
Xe > Be > Al > As
Which of these compounds are aromatic in character ?
(A)
CN
(B)
CN
(C)
(D)
All of these
(B)
3
H3 C
CH2
4.
R-alanine is represented by______

1 NH
2 COOH
(A)
H
3 CH
NH2
COOH
NH2
HOOC
CH3
4
H
2 COOH S
R
3
(C)
(D)
H3C
NH2
H
5.
Toluene when refluxed with bromine in the Presence of light gives mainly______
(A)
O-bromotoluene
(B)
M-bromotoluene
(C)
O and p-bromotoluene
(D)
Benzyl bromide
6.
Tertiary alcohol can be converted into primary amine by the use of______
(A)
NH3 / Al2O3 / B
(B)
HCN
(C)
RCN /H
(D)
CH3NH2 / P2O5
Chemistry-CY (MQP)
7.
8.

If a Particle has linear momentum p 2i j k , at position r 3i j k , then its angular
momentum is ________
(A)
(B)
2 i 5 j k
i 2k

(C)
(D)
5 i 2j
2i 5 j k
=
p T
(A)
U
(C)
S
(B)
(D)
S
V
9.
An electron is found in an orbital with one radial node and two angular nodes. Which orbital
electron is in ?
(A)
15
(B)
2p
(C)
3d
(D)
4d
10.
n-simple molecule of solute A associate in solution as nA

(A)n The degree of association is
x. what is the number of particles at equilibrium ?
(A)
1 + x + (x/n)
(B)
1 - x (x/n)
(C)
1 + (2x/n)
(D)
None of above
11.
The final product of the reaction is:
CHOH
3
h
Hu
coome
(A)
(B)
coome
coome
(C)
(D)
coome
12.
In the given reaction O

R C OH
reagent may be:
(A)
PCl5
(C)
ClCo CoCl
Dmf
O
reagent
R C Cl
(B)
SoCl2
(D)
All of these
Chemistry-CY (MQP)
13.
In the given reaction sequence

h
CHCl3
(A)
CH3 OH
(B)
(excess)
(B) is _______
O
(A)
Cl C Cl
(B)
Cl C O CH 3
(D)
CO2 + HCl
(C)
CH3O C O CH3
CHCOOCH5
CH
22COOC22H5
H
14.
+
[ x]
CHOH
2
[ x ] is :
CH2COOH
CH2COOH
(A)
(B)
(C)
15.
CH2
CH2 C
CH2 C
(D)
CH2 O
CH2 O
In the given reaction

CH3
H C OH
TsCl / pyridine
[x]
H C OH
CH3
[ x ] will be _______
CH3
CH3
H C OTs
H C O Ts
(B)
(A)
H C OH
H C OTs
CH3
CH3
CH3
HC
(C)
O
HC
(D)
No reaction
CH3
Chemistry-CY (MQP)
16.
In the given reaction

OH
COOH
HNO 3 / H2SO 4
[x]
[x] is :
17.
(A) 2-hydroxy-3-nitrobenzoic acid
(B) 2-hydroxy-2-nitrobenzoic acid
(C) 2-hydroxy-5-nitrobenzoic acid
(D) 2, 4, 6-trinitrophenol
When sulphanilic acid is treated with excess of bromine water, it gives _____
Br
SO 3H
(A)
(B)
Br
Br
Br
SO 3H
Br
NH2
SO 3H
Br
Br
(C)
(D)
Br
18.
NH2
Br
Br
NH2
Which of the following will be more reactive for E1 reaction?

Br
Br
C CH 2 CH 3
(A)
(B)
C6H5 CH CH3
Br
Br
(C)
(D)
CH2
CH2
CH C CH 3
CH CH CH3
CH3
19.
The shape of which one of the orbitals corresponds to the angular wave function in the figure
given above ?
(A)
dx2-y2
(B)
dxy
(C)
py
(D)
px
Chemistry-CY (MQP)
20.
21.
22.
23.
The ground stable energy of hydrogen atom is -13.6 ev what is the ground state energy of life?
(A)
3.4 ev
(B)
13.6 ev
(C)
40.8 ev
(D)
122.4 ev
Taking into account the isoelectronic Principle and VSEPR Theory, predict in which one of the
following pairs, both molecular species have Pyramidal geometry ?
(A)
BO33 and SO32
(B)
CO32 and NO3
(C)
SO23 and ClO3
(D)
SO3 and ClO3
XeF3+ belongs to which one of the following AXnEm nomenclature (A = Central, X = singly bonded
liquid and E = an unshared electron pair) ?
(A)
AX3E0
(B)
AX3E1
(C)
AX3E2
(D)
AX3E3
Consider the 0.1N aqueous solutions of the following electrolytes:

1.
NaOH
3.
CH3 COOH
2.
NH4OH
4.
HCl
The correct sequence of their increasing p is
24.
25.
26.
(A)
2, 1, 3, 4
(B)
3, 4, 2, 1
(C)
4, 3, 2, 1
(D)
4, 3, 1, 2
The molecule N (Sime3)3 has a

(A)
pyramidal shape and is a lewis base
(B)
pyramidal shape and lewis acid
(C)
T-shaped geometry and is a lewis and
(D)
Trigonal planar geometry and has no lewis base character
Haemoglobin a complex containing iron is a constituent of blood. The oxidation state of iron of
the complex is ________
(A)
zero
(B)
+1
(C)
+2
(D)
+3
Match list-I (The metallozymes) with list-II (The metal present in the enzyme) and select the
correct answer using the codes given below the lists:
List - I
List - II
A.
Carboxy peptidase
1.
Fe
B.
Cytochrome
2.
Cu
C.
Nitrogenose
3.
Zn
D.
Ascarbate oxidase
4.
Mo
Chemistry-CY (MQP)
Codes :
27.
28.
(A)
(B)
(C)
(D)
The isomerism that are possible in the w(III) complexes [Co(NH3)3 (NO2/3)] and [Co(NH3)3 NO2]Cl2
respectively, are _______
(A)
Coordination and position
(B)
Optical and linkage
(C)
Geometrical and linkage
(D)
None of these
For the reaction :

2Cl(g) Cl2 (g)
the thermodynamic properties
29.
(A)
G, H, and S are positive.
(B)
G, H, and S are negative.
(C)
G and H are negative and S is positive.
(D)
G is negative and H and S are positive.
For an enzyme catalysed reaction

E1
E2
ES
E+S
E+P
E 1
Where the symbol have their usual meaning, using the steady state approximation for [ES]. The
overall rate equation workout to be
30.
(A)
k 2 [E0 ][S]
km [S]
(B)
k 1 k 2
k1
(C)
k1[E][S]
km [S]
(D)
k 2 [E][S]
km(k 1 k1 ) [S]
The standard oxidation potential of copper and silver electrodes are-
and
cu
cu
E = 0.84V
Ag
Ag
E = 0.79V
Respectively, an electrochemical cell containing a copper electrode dipping in a 0.1m CuSO4

solution and a silver electrode dipping in a 0.1m AgNO3 solution is formed using a salt bridge
when current is drawn from the cell.
(A)
Cu will be deposited and Ag will pass into solution as ions.
(B)
Both Cu and Ag will be deposited from their respective ionic states respectively.
(C)
Both Cu and Ag will pass into solution as ions.
(D)
Cu will pass into solution as ions and Ag will be deposited.
Chemistry-CY (MQP)
SECTION-(B) MULTIPLE SELECT QUESTIONS (MSQ)

1.
Which of the following are aromatic ?

(A)
(B)
(C)
(D)
2.
Which of the following compounds has (L) configuration ?

CH3
CHO
(A)
(B)
H C OH
H C NH 2
COOH
CH2OH
COOH
CHO
H C OH
HO C H
H C OH
(C)
(D)
H C OH
HO C H
CH2OH
CH2OH
O
OCH3
OH
3.
O
OH
II
III
IV
Which among these can exist tautomerism ?
4.
5.
(A)
(B)
II
(C)
III
(D)
IV
Lysione is not used as :

(A)
Disinfectant
(B)
Germ killer
(C)
Treating eye disease
(D)
Anti-cancer drug
Which of the following is correct about G ?

(A)
G = H TS
(B)
At equilibrium G = 0
(C)
At equilibrium G = RT logk
(D)
G = G + RT logk
Chemistry-CY (MQP)
6.
The angular momentum of electron can have the value (s) ___
(A)
(C)
7.
8.
9.
10.
h
2
2h
5h
22
(B)
(D)
The correct starting material and product of different disintegration series are______
(A)
232Th, 208pb
(B)
235U, 206pb
(C)
238U, 207pb
(D)
237Np, 209Bi
In which of the following set, both the species are isoelectronic and and isostructural?
(A)
CO32, NO3
(B)
SO42, ClO3
(C)
SO42, PO43
(D)
ClO3, CO32
Which of the following statement is/are correct

(A)
In CCl4, only dispersive forces exist
(B)
In CHCl3 molecule, both dipole forces as well as dispersive forces exist.
(C)
In H2O molecule, both hydrogen bonds as well as dispersive forces are present.
(D)
In cyanogen, the number of sigma and pi-bonds are 3 and 4 respectively
In which of these compounds does the carbon atom (underlined) nor use Sp3 hybridization for
bond formation.
(A)
CH 3 COOH
(B)
OC (NH2)2
(C)
(CH3)3 COH
(D)
C2H5 CHO
SECTION-(C) NUMERICAL ANSWER TYPE QUESTIONS (NAT)
1.
1
How many d-electrons in Cu+ (At. No. = 29) can have the spin quantum number ?
2
2.
One gram of
3.
The non-compressive volume of a gas is ____ times than the actual volume of gas molecules.
4.
Density of lithium atom is 0.53 g/cm3. The edge length of Li is 3.5 A. Find out the number of
lithium atoms is a unit cell. (N0= 6.022 x1023/mol& M= 6.94)
5.
Calculate the enthalpy of the following reaction :
226
Rq has an activity of nearly 1 Ci. The half life of
226
Ra is ____ years.
CH3 CH3(g)
H2C = CH2(g) + H2(g)
The bond energies of C-H, C-C, C=C and H-H are 99, 83, 147 and 104 kcal respectively.
Chemistry-CY (MQP)
6.
For a reaction A+B

C+D. If the concentration of A is doubled without altering the concentration
of B, the rate gets doubled, if the concentration of B is increased by nine times without altering
the concentration of A, the rate gets tripled. The order of reaction is _____
7.
For the hopothetical reactions, the equilibrium constant (k) values are given below:
A
B, K1 = 2 ;
C, K2 = 4 ;
D, K3 = 3 ;
The equilibrium constant (k) for the reaction A
D is _____
8.
What current strength in ampere will be required to liberate 10g of chlorine from sodium chloride
solution in one hour?
9.
How many stereoisomers exist with the following basic connectivity?

Br CH2 CH (CH3). CH2 CH3
10.
Use the following data to answer the question below:
H2
H = 28.6 kcal/mol
Ni
excess H2
(Ni)
H = 116.2 kcal/mol
(Anthracene)
The resonance energy of anthracene is _____
11.
What value of n in Huckel's rule applies to the aromatic compound shown above?
12.
When methyl glucopyranoside reacts with periodic acid, how many moles of the oxidising agent
are consumed per mole of sugar ?
13.
How many isomeric aldehydes are possible with formula C5H10O ?
14.
The ionic radius of the fluoride ion is ____ using only the following interionic distance and the
radius of the iodide ion 2.19A.
15.
RbI = 3.67Ao
KCl = 3.14Ao
RbBr = 3.44Ao
NaCl = 2.79Ao
KBr = 3.29Ao
NaF = 2.31Ao
How many nearest, neighbours are there in an atom or ions for an octahedral hole of a closed
packed structure ?
10
Chemistry-CY (MQP)
16.
In hydrogen atom, energy of first excited state is -3.4ev, then the K.E. of same orbital of hydrogen
atom is ____ev.
17.
The molecular MLx is planar with 7 pairs of electrons around M in the valence shell, the value
of x is ______.
18.
In the electronic structure of H2SO4, the total number of unshared electrons is ____.
19.
The dissociation constant of a substituted benzoic acid at 25C is 1.0 104. The pH of a 0.01
M solution of its sodium salt is _______.
20.
How many moles of AgCl would be obtained, when 100ml of 0.1m CO(NH3)5Cl3 is treated with
excess of AgNO3 ?
ANSWER KEY
SECTION-(A) MULTIPLE CHOICE QUESTIONS (MCQ)
1
A
11
C
21
C
2
C
12
D
22
C
3
D
13
C
23
C
4
A
14
C
24
D
5
D
15
C
25
C
6
C
16
D
26
D
7
B
17
B
27
C
8
A
18
A
28
B
9
D
19
B
29
A
10
B
20
D
30
D
9
A,B,C,D
10
A,B,D
SECTION-(B) MULTIPLE SELECT QUESTIONS (MSQ)

1
B,D
2
B,C
3
A,B,C
4
B,C,D
5
A,D
6
A,B,C
7
A,D
8
A,C
SECTION-(C) NUMERICAL ANSWER TYPE QUESTIONS (NAT)

1
5
11
4
2
1582
12
2
3
4
13
4
4
2
14
1.33
5
-30
15
6
6
1.5
16
3.4
7
24
17
5
8
7.55
18
16
9
2
19
8
10
84
20
0.02
11

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Maximum Marks : 100

Read the following instructions carefully.

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SECTION-(A) MULTIPLE CHOICE QUESTIONS (MCQ)

Which of the following are non-polar ?

Select the correct answer using the codes below :

Xe > Be > As > Al

Xe > As > Al > Be

Xe > As > Be > Al

Xe > Be > Al > As

Which of these compounds are aromatic in character ?

R-alanine is represented by______

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n-simple molecule of solute A associate in solution as nA

The final product of the reaction is:

In the given reaction O

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In the given reaction sequence

In the given reaction

In the given reaction

(A) 2-hydroxy-3-nitrobenzoic acid

(B) 2-hydroxy-2-nitrobenzoic acid

(C) 2-hydroxy-5-nitrobenzoic acid

Which of the following will be more reactive for E1 reaction?

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BO33 and SO32

CO32 and NO3

SO23 and ClO3

SO3 and ClO3

Consider the 0.1N aqueous solutions of the following electrolytes:

The correct sequence of their increasing p is

The molecule N (Sime3)3 has a

pyramidal shape and is a lewis base

pyramidal shape and lewis acid

T-shaped geometry and is a lewis and

Trigonal planar geometry and has no lewis base character

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Coordination and position

Optical and linkage

Geometrical and linkage

For the reaction :

the thermodynamic properties

G, H, and S are positive.

G, H, and S are negative.

G and H are negative and S is positive.

G is negative and H and S are positive.

For an enzyme catalysed reaction

The standard oxidation potential of copper and silver electrodes are-

Respectively, an electrochemical cell containing a copper electrode dipping in a 0.1m CuSO4

Cu will be deposited and Ag will pass into solution as ions.

Both Cu and Ag will pass into solution as ions.

Cu will pass into solution as ions and Ag will be deposited.

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SECTION-(B) MULTIPLE SELECT QUESTIONS (MSQ)

Which of the following are aromatic ?

Which of the following compounds has (L) configuration ?

Which among these can exist tautomerism ?

Lysione is not used as :

Treating eye disease

Which of the following is correct about G ?

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Which of the following statement is/are correct