NEET Model Papers Free Practice Set 2 Chemistry

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1. 1. Question
Occasional deaths due to liquor consumption among poor people are due to

Presence of ethyl alcohol

Old stock of alcohol

Methyl alcohol present

Pressure of excess

gas

Incorrect

Methyl alcohol is poisonous in nature. Even a small dose causes blindness whereas high
dose causes death. So it is unfit for drinking purposes.
2. 2. Question
In Reimer Tiemann reaction, the electrophile involved in the reaction is

Incorrect

3. 3. Question
Which of the following compounds is most susceptible to nucleophilic attack to the carbonyl
group?

Incorrect

Electron withdrawing group increases the possibility of nucleophilic attack due to dispersal
of ve charge near carbonyl group.
4. 4. Question
Which of the following products is formed when propanal reacts with NaOH?

Incorrect

5. 5. Question
The correct order of stability of hydrides is

Incorrect

The stability of hydrides decrease in the group from Mg to Ba in group II.

6. 6. Question
p-cresol reacts with chloroform in presence of KOH(aq) to form a compound (X). X reacts
with hydrogen cyanide followed by hydrolysis to form (Y). What is the structure of Y?

Incorrect

7. 7. Question
An organic compound of molecular formula C 9H12O, on reaction with I2 and KOH gives an
yellow precipitate. The most likely structure of the compound will be

Incorrect

The compound gives +ve test with I 2 & KOH means Iodoform test. Therefore the molecule
must contain COCH3 group. So the structure d on oxidation can form COCH 3 with 3
hydrogen atom. Hence it undergoes Iodoform test.

8. 8. Question
Which of the following acids has the smallest dissociation constant?

Incorrect

Br shows lowest I effect.

So it is least acidic.
9. 9. Question
The correct order of reactivity in electrophilic substitution reaction of following compounds is

III > II > I > IV

IV > III > I > II

I > IV > III > II

II > III > IV > I

Incorrect

+I and hyperconjugation effect increases the electron density in o and p position. Thus
electrophilic substitution increases.
NO2 shows I and R effect.
Br shows I and +R effect.
10.

10. Question

Which of the following statement is not correct?

Alizarin is a natural dye.

Congo red is a synthetic dye.

Malachite green is a triphenyl methane dye.

Methyl orange is a basic dye.

Incorrect

Acid dyes are sodium salts of azo dyes containing sulphonic acid and carboxylic acid groups
such as congo red, methyl orange, methyl red etc.
11.

11. Question

Match the following:

List I
(A) Bakelite
(B) Aspirin
(C) Chlorophyll
(D) Haemoglobin

List II
(I) Magnesium.
(II) Formaldehyde
(III) Oxygen carrier
(IV) Salicylic acid

Incorrect

Self Explanatory.
12.

12. Question

The relative Lewis acid character of boron halides follows the order of

Incorrect

The order can be explained on the basis of the tendency of the halogen atom to back donate
its electrons to the boron atom and makes its less electron deficient.
13.

13. Question

The composition of common glass is

Incorrect

Ordinary glass is a mixture of sodium silicate and calcium silicate.

14.

14. Question

Silver salt of acetic acid on refluxing with C 2H5Cl gives

Methyl acetate

Ethyl ethanoate

Ethyl propionate

Methyl methanoate

Incorrect

15.

15. Question

Hydrolysis of benzonitrile in presence of mineral acid produces

Aminobenzene

Benzoic acid

Nitrobenzene

Methyl benzoate

Incorrect

16.

16. Question

Which of the following is most polar among the halogen compounds?

FF

Cl Cl

Cl F

Br F

Incorrect

(d) The electronegative difference between the atoms is more. So more polar.
Br F
difference = 1.2
2.8 4.0

In

(a)
(b)
(c)

17.

F F
4.0 4.0
Cl Cl
3.0 3.0
Cl F
3.0 4.0

difference = 0
difference = 0
difference = 1.0

17. Question

The reaction is carried out in a vessel containing 2 moles of acetic acid, 2 moles of ethyl
alcohol and 2 moles of water at 80C to attain the equilibrium. It was found that about 48%
of the acid is esterified. What will be the equilibrium constant of the reaction?

0.051

0.51

0.67

0.15

Incorrect

18.

18. Question

Which of the following statement is wrong?

The plot of log K vs 1/T is a straight line.

The slope of the line in Arrhenius equation of log K ~ 1/T is equal to

Plot of rate of reaction vs time will be a straight line.

The plot of rate of reaction vs temperature for normal reaction will be a straight

line.
Incorrect

The rate of reaction with time will be a curve.

19.

19. Question

Which of the following statement regarding the reaction

order is 2, molecularity 2

order 2, molecularity 3/2

order 3/2, molecularity 3

Incorrect

The rate of reaction

is correct?

Order = 1 + = 3/2, molecularity = 2.

20.

20. Question

The heat of combustion of propane is 2219 kJ/mole. Calculate how much heat is evolved in
the burning of 20.5 g of propane.

+ 1033.85 kJ

1033.85 kJ

103.38 kJ

1133.85 kJ

Incorrect

The equation is C3H8 + 5O2 3CO2 + 4H2O, H = 2219 kJ

1 mole of propane = 12 3 + 8 = 44
44 gm liberates 2219 kJ of heat
1 gm liberates (2219/44) kJ
20.5 gm liberates (2219/44) 20.5 = 1033.85 KJ
21.

21. Question

The enthalpy of formation of nitrous oxide is 20 kcal mol -1. Calculate the resonance energy
of nitrous oxide. Given bond enthalpies of N N, N = N, O = O and N = O bonds are 225
kcal, 99.5 kcal, 118.5 kcal and 144.5 kcal respectively.

39.25

29.25

20.25

99.25

Incorrect

22.

22. Question

What is the effective atomic number of Fe in [Fe(CO)5]?

36

34

32

30

Incorrect

Effective atomic number = Atomic no oxidation state + 2 co-ordination number

= 26 0 + 2 5
= 26 + 10 = 36.
23.

23. Question

A complex compound of Cr4+ with molecular formula CrBrx yH2O gives a total of 4 ions when
dissolved in water. How many Br ions satisfy the secondary valency in this complex?

zero

one

two

three

Incorrect

[CrBr(H2O)5]Br3, Cr4+ means 4 negative ions= 4 Br

Co-ordination no of Cr = 6. So inside square bracket 6 ligands must be present.
4 ions = 3 Br and one [CrBr(H2O)5)]3+. Inside square bracket, only one Br ion is present.
24.

24. Question

Which of the following metals will not react with CuSO 4 solutions?

Ni

Fe

Al

Ag

Incorrect

Silver is less electropositive than Cu. So it does not displace Cu metal from the its salt
solutions.
Ag + CuSO4 no. displacement reaction
25.

25. Question

Which of the following is diamagnetic in nature?

Incorrect

The last configuration of Cu is 4s1 3d10

In Cu+ 4s0 3d10. It contains zero unpaired electron. So it is diamagnetic in nature or zero
magnetic moment.
26.

26. Question

In which of the following

Incorrect

27.

27. Question

The change in oxidation number of Mn when MnO4 and MnO42, Mn2+, Mn2O3, MnO2 is

1, 5, 4,3

6, 2, 3, 4

2, 3, 4, 6

5, 4, 3, 1

Incorrect

28.

28. Question

Among the nitrogen family elements, the pentavalency becomes less stable as compared to
trivalency due to

High affinity value

Low electro negativity value

Inert pair effect

Stable electronic configuration

Incorrect

Atomic size increases along the group. Due to bigger size, from top to bottom, the inertness
of inner orbital takes place. The effect is called inert pair effect.
The outer electronic configuration
Then only p electrons are involved in bond formation. Hence the +3 oxidation state is more
pronounced.
29.

29. Question

The acidic strength of oxides of nitrogen increases in the order of

Incorrect

The acidic strength increases with the increase in oxidation state such as N 2O < NO <
N2O3 < N2O4 < N2O5.
30.

30. Question

Calculate the pressure exerted by 32g of methane in a 500 ml container at 27 if it obeys

Vander waals equation. Vander Waals constants are a = 2.253 atm L 2 mol1 and b = 0.0428
L mol1.

53.724 atm

65.402 atm

95.225 atm

82.672 atm

Incorrect

Here n = 32/16 = 2 mole

Vander Waals equation

31.

31. Question

Consider the following statements:

Roasting is carried out to
(i) convert sulphide and carbonate ore into its oxide
(ii) melt the ore
(iii) to remove volatile impurities
(iv) reduce into metal by coke
Which of the above statements is correct from the following?

i, ii, iii

ii, iii, iv

i, iii

ii, iv

Incorrect

Self Explanatory.
32.

32. Question

Which of the following is a correct statement about the extraction of magnesium?

Fused salt is electrolysed

Aqueous salt solution is electrolysed

Carbon reduction process

Self reduction process

Incorrect

Fused salt such as MgCl2 is electrolysed for the extraction of magnesium metal.
Mg++ + 2e Mg (cathode)
33.

33. Question

The electronegativity of the following elements follows the order

F > Cl > O > Br

F > O > Br > Cl

F > O > Cl > Br

O < F > Br < Cl

Incorrect

The electronegativity decreases from top to bottom in halogen family. But O is the 2nd most
electronegative element in periodic table. So the order is
F > O > Cl > Br
4.0 3.5 3.0 2.8
34.

34. Question

Which of the following is a strong bond?

Incorrect

The bond dissociation energies of F 2, Cl2, Br2 & I2 are nearly 159 kJ, 242 kJ, 193 kJ and 151
kJ respectively. So Cl2 forms a strong bond where Br2 & I2 follows the general order.
However due to inter electronic repulsions in small atom of F, the value is less.
35.

35. Question

From the reaction given below, name the product.

Chloropropane

2Chloropropane

2, 2Dichloropropane

Reaction is not possible.

Incorrect

The reaction follows markownikoffs rule as HCl does not follow peroxide effect in presence
of peroxide.

36.

36. Question

The brilliant orange red glow in the discharge tube for the advertisement mainly contains

Ne

Na

Ar

Incorrect

Self Explanatory

37.

37. Question

Which of the following elements will not react with fluorine atom?

Ne

Xe

Kr

Incorrect

Out of these elements, Ne shows highest ionization energy. It does not contain d orbital for
the excitation of electron from stable configuration to half filled orbital.
38.

38. Question

The IUPAC name of

4, 5 Diethyl 7 methylnon 4en 1 ol

4, 5, 7-Triethylnon 4en 1ol

4, 5 Diethyl 7 methyldec 5en 1 ol

None of these

is

Incorrect

39.

39. Question

The IUPAC name of the above compound is

2 Bromobicyclo[2. 2. 0] hept 4ene

7 Bromobicyclo[2. 2. 0] hept 2ene

7 Bromobicyclo[2. 2. 1] hept 2ene

None of the above

Incorrect

40.

40. Question

Which of the following is the main cause of depletion of ozone layer?

Incorrect

Chlorofluorocarbon is the main cause of depletion of ozone layer in atmosphere.

41.

41. Question

Which of the following is the strongest acid?

O-methyl benzoic acid

Acetic acid

Butanoic acid

Nitrobenzoic acid

Incorrect

Acidic character increases with the presence of electron withdrawing group. Here -NO 2 is a
withdrawing group. Hence nitrobenzoic acid is the most acidic compound.
42.

42. Question

Reaction of ethylamine in chloroform and alkali produces

Ethyl cyanide

Ethyl carbylamine

Ethyl alcohol

Ethyl cyanide and potassium carbonate

Incorrect

43.

43. Question

When SO2 is passed through acidified K2Cr2O7 solution, the solution

turns red

decolourises

turns green

Incorrect

The orange color of the solution turns green due to formation of chromium sulphate.
K2Cr2O7 + H2SO4 + 3SO2 K2SO4 + Cr2(SO4)3 + H2O
green
44.

44. Question

Air contains 21% of oxygen by volume. How much volume of air will be required for
complete combustion of 200 cc of acetylene?

2.381ltr

2.280 ltr

2.481ltr

1.291 ltr

Incorrect

2C2H2 + 5O2 4CO2 + 2H2O

(g)
(g)
They combine in the ratio of 2 : 5
2 vol. of C2H2 required 5 vol. of O2
2 vol. of C2H2 = 200 cc
1 vol. of C2H2 = 100 cc
5 vol. of O2 = 500 cc
Volume of air =
= 2380.95 cc = 2.381 ltr
45.

45. Question

The best combination of reagent for carrying out the conversion

RCH2CH2OH RCH2CH2COOH is

Incorrect

(i)
(ii)
(iii)

3R CH2CH2OH + PBr3 3RCH2CH2Br + H3PO3