Cbse Sample Papers For Class 12 Sa2 Chemistry Solved 2016 Set 10 Solutions

CBSE Sample Papers for Class 12 SA2
Chemistry Solved 2016 Set 10

Answers
Section A
1.Convert 10 alcohol to 2 alcohol.
Ans.
CH CH 0H
3
2
Ethyl alcohol
Cu) CH~HO CH3MgBr>

573 K Acetaldehyde Dry ether
p<:! aloohol)
J ..
OMQBr.
II.CHY
r
l
.
......CH-CHa
I
Addition product
H -/HzO
0. H
I
. . . . ) OH3= CH- CH3
-Mgl(OH)Br
Isopropyl alcohol
(2~ alcohol~
2.Write a test to differentiate between pentan-2-one and pentan-3-one.

Ans.
For iodoform test, the compound must have either a

CH 3 - C = 0 group orGH 3 - CH 2 - OH group.
R'
Pentan-2-one gives posltiv@ iodoform test whereas

pentan-3-one does not.
o
II
CH 3 CH 2 CH 2 - C- CH 3 + 3NaOI
~ CH aCH 2 CH 2 COONa
Sodium butanoate
+ CH 13
Iodoform
o
II
CH 3 CH2 - C CH 2 CH 3 + NaOI~ No ppt.

(yeHow)
(1)
3.How do you explain the presence of all the six carbon atoms in glucose
in a straight chain?
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Ans.
Glucose reacts wUh hydrogen iodide to form n-hexane. It

proves that all the six C-atomiS in glucos.e lie, in a straight
chain.
OHC-(CHOH)4 - CH {jH
HI/H@at
Heductiol1
D-gilicose
CH3-CH2,- CH2-CH2 - CH2 - CHa

n.flexane
(1)
4.Why does white ZnO(s) becomes yellow on heating?

Ans.
OIn heating , ZnO loses oxygen according to the fo llowing

reactfon,
ZnD
. .(S),
. - ,
.. ) zn2+ +21 0.2 + 2e
Heating .
Zn 2+ ions and electrons move to. interstitial sites and

F-centres are ,created whichl impart yellow coliour to ZnO
{s).
(1)
S.Iodine is more soluble in KI than in water.

Ans.
Section B
6.Account for the following:
(i) Alkaline medium inhibits the rusting of iron.
(ii) Why is alternating current used for measuring resistance of an
electrolytic solution?
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Ans.
(I) Ac.id rain ,incr,sas,es the rat,e of rusting,
CO 2,+ HP -----7>H 2G0 3

Fe
+ 2H+
---)0
,. ~
H + HCO"3
Fe2+ + H2
Rust
If m,edium Is alkaline! H (acid rain)

hence rustingl is inhibite,d .
IS
neutralised
H+ + OH- ~ HiJ
(1)
(ii) AC (Alternating Current) prevents electrolysis of

el,ectrolyte hence, concentration remains oonstant. (1)
7.What are the IUPAC names and give the structure of the insecticide
DDT and BHC ? Why is their use banned in India and in other countries?
Ans.
The IUPAC name of
(il DDT is 2, 2-bis (4-chlorophenyl)-1 ,
1, 1-trichloroethane.
CCI3
-0- -0-
CI
/;
CH
/;
CI
(ii) BHC is benzene hexachloride.
(1/2)
CI
C~CI
C I Y CI
CI
(1/2)
\-,-,
Us'e of DDT and SHe are banned in various countries due
to thefollowiing reasons (any two) :
(i) These are non-biodeQlradable.
(ii) When washed wlith rain water, th,ese chemicals reach

t;h,e water sources and harm the aquatic life due to their
toxic nature,
(iii) These pesticides are not metabolised They enter in

the food c.hain and get accumu lated in the human
body,
U)
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8.What will be the osmotic pressure of 0.1 M monobasic acid, its pH is
at 2SOC?
Ans.
HA~H++A-
[H+] :: Ca
1'0 .2
0,1 xu
10- 2
0.= - -
0,1
= 10-1
=0,1
.., Total number of particles in solution = 11+ a
= 1+ 0.1
;: 1.1
(1)
Now, 1t =CRT(1 + a)
= 0,1 ><0.0821 x298x1 .1

= 2.69 atm
(1)
9.Give two requirements for vapour phase refining.

Ans.
(i) The meta'il should forms a volatile compound with

availlable reagent
(1)
(i i) The
volati'e
compound
should
be
decomposable so that the recovery is Hasy.
easily
Above two conditions are required for vapour phase

refining . Ni is r'efined by this method .
(I)
10.
Calculate the order of the reaction from the following data

2NH3 ~ N2 + 3H2 (reaction)
Or
What are Pseudo first order reactions? Give one example of such reactions,
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Ans.
We know,
11
= 1 + !?g(t 112 )1 -Iog(( 1(2 )2

log P2 - log P1
= 1+ log 3,5.2 -
(1)
log 1.82
log 100 -l og 50
(1 /2)
= 1 95 ~ 2
(1/2)
Alt'e rnate method

t 1/2
For
QC
(a)1- n
=:> 3,52 oc (50) 1-n
For II ~ 1.82
... (i)
oc (100) 1- n
, ' . (ii)
(1)
From (i} and (ii),
-{~~ = C~~ Y-Il

By ta king log on both sjdes
109(,\ 31..52)
= (1 - n)IOQi(2)
82
2
(1/2)
0,286 = (1 ~ n)(-O,30 )
0 , 286
= (1- n)
0.3
0,95;;;; 1- n
n=1
0,95 = t 95
(1 /2)
Hence, the reaction IS of second order.
Or
The reaction wh ich is b imoleculia r but has order one, is

called Pseudo first order reaction . When one reactant
uSlsd in a very la rge excess then that concentration wou ld
hard ly change at all,
For example, acidic hydro!ysls Of e::.~vr.

H"
CH~OOC ~5+ H~ " ' ''CHsCOOH+ C~sOH
(2)
SectionC
11.(i) Write the structure of pyrophosphoric acid, dithionic acid and
Marshall's acid.
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(ii) PCl s reacts with finely divided silver on heating and a white silver salt
is obtained, which dissolves on adding excess aqueous NH3 Write the

reactions involved to explain what happens?
Ans.
(i) Structure of pyrophosphoric acid (H 4PP7) is given
bellow.
II
I
HO-P-
O-
OH
II
I
P-
OH
OH
(1 /2)
Structure of Marshall's acid, (H28iJa) (+ 6)
o
sII
0:71 "
a
sII'
0 - 0 / I ~O
OH
OH
(112)
Structure of dithion Ie acid (iH!zSP6 J( + 6)
o 0
III II
~I-I=O
OH OH
(lf2)
Oi) PCI5 + 2Ag ~ 2 Agel ;. PCI3

White ppt.
AgCI+ 2NH3(aq) --+ [Ag(NH 3 btCl(Soluble compllex)
(11/2)
l2.Vapour pressure of pure water at 298 K is 23.8 mmHg. 50 g of urea

(NH 2 CONH 2 ) is dissolved in 850 g of water. Calculate the vapour
pressure of water for this solution and its relative lowering.
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Ans.
Step I Calculation of vapour pressure of water for this
solution.
Accord ing to the Raou lt's law
P'A - Ps
P'A
== nB
nA
WB
Me Wa MA
=. - =- x WA Me WA
MA
(Pure water)
PA
== 23.8 mm
= 50 9 , WA(water) = 850 9
1
M8(Urea) = 60 9 mol- .
WS(Urea)
M A(Water)
= 18
mol-
On , placing the values in Eq 0)

1
p eA -. Ps _ (50 g) x (18 9 mol- )
pOA
(60 9 mol- I) x (SSO g)
;;;; 23.8 - Ps ;;;; 0.01762

23.8
= 0.4194
Ps = 23.3806
23.8- Ps
'" 23.38mm Ha
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Step II Calculation of relative lowering of vapou r
pressure.
Relative lowering of vapour pressure
PA -P
P'A
s
;;;;;: ---=--'-----=-
(23.8 - 23.38) mm
(23.8 mm)
=.;.......--~"'"'-----
= 0.0176
Or
Alternative met hod
Relative loweri ng of vapour pressure
50 QI
;;;; nB ;;;;;:
nA
"'" 50
60
60g mol850 g
18g mol- 1
x ~ "'" 0.0176
850
(3)
An element occurs in bcc structure. It has a cell edge length of 250

pm. Calculate the molar mass, if its density is 8.0 g cm- 3 Also, calculate
the radius of an atom of this element.
13.
Ans.
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Given, cell edge length . a = 250 p m
Density
:=
=250 x 10 - 10 cm
8 Qi em -3
For bee unit cel l, Z =2
Molar mass, M = ?
ZM
Density, d "'" ---:
..3~.a N A
B"",
2 xM
(250 x10- 10 )3(6.022
x 102J)
(1/2)
(250 x10- 10)3('6.022' x1023)

M=
:.: 8
2
;;;; 9.409:.:
"'- 37.64g mo l -
(1/2)
1
(1)
For bee unit cell ,
4r =-J3a
J3.a
( = --
(1/2)
1.732 x250
;;;;;;
4
"",108.25pm
14.
(1/2)
(i) Calculate the number of Coulombs required to deposit 40.5 9 of AI when the electrode reaction
is AI 3 + + 3e- ----t AI .
(ii) How many grams of silver could be plated out of a shield by electrolysis of a solution
containing Ag+ ions for a period of 4h at a current strength of 8.5 A?
Ans.
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(i) The charge Q on n moles of electrons is given by
Q ;;;;nF
Thus, charge on 3 moles of electrons
Q "" 3mol
x 96500 C mol-
,." 289500C
iMolar mass of All ~ .27 9 mol- 1
:. 1:0 deposii t 27 9 of AI, the electric charge requ ired
;;;; 289500 C
.'. To deposit 40.5 9 of AI. the electric charge required
= (289500 C) x (40.5 .)
(27 g)
; ; ; 4.342 x 105C
{P/2)
=Ixt
(4 x 60 x 60seconds) = 122400 C
(ii) Quantity of charge (0 ) passed
= (8. 5, amp) x
The electrode reaction is
Ag + +
e-
) Ag
1mol
96500 C
l mol
107.8 g
96500 C charge produces sHver = 107.8 g

12.2'400 C charge produces silver
;; (107. B g) x (122400 C)
(96500 C)
= 136. 73g
15. A solution containing 0.319 g of CrC13 -6H2 0 was passed through a

cation exchange resin and acid coming out of the cation exchange resin
required 28.5 mL of 0.125 M NaOH. Determine the correct formula of the
complex [molecular weight of the complex =266.5gmor1].
Ans.
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cr -
HCI - INaOH
From the number of moles of NaOH , number of moles of

CI- are determined. Hence, complex is known .
Let the number of CI- ions .outside the' coordination sphere

or number of chloride ions which can be ionised be n. When
the solution of the comp~ex ~s passed through cation
exchanger, nCI- i ons will combine wah H+ (of the cation
exchanger) to form HCl.
Moles of NiaOH = MV
1000
nCI- + nH+ - - ? nHCI
Thus , 1 mole of the complex wm form n moles of He!'

1 mole of complex == n mole of Hel == n mole of NaOH
0319 g
Mole of the complex ;;;;;
,.
" , 1 = 0 ,0012 mol
266.5 9 molMole of NaOH used = ,28.5 x 0 .125 = 0.0036 mol
1000
;;;;; 0.0012 mole of complex

E O.0036 mole of NaOH
"'" 0,0036 mole of Hel
1 mole of complex;:
0.0036
0.0012
= 3 moles of Hel
n ::: 3
Thus, all the CI- ions are outside coordinati on sphere.

Hence, complex is [Cr (H~)6]CI 3'
(3)
16. (i) What happens when gelatin is mixed with gold sol?
(ii) How do emulsifying agents stabilise the emulsion?
(iii) Why does bleeding stop by rubbing moist alum?
Ans.
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(i) Gold sol is a Ilyophobic sol. When gelatin ils mixed with
gold sol, the sol is stabilised ,
(l}
(ii) The emulsifying agent forms an interfac ial layer
between susp'ended particles and the dispersion
med!lum thereby stabi lising the emulsion.
(I)
:iii) Moist alum coagulates the blood, and so formed

blood clot stops bleeding.
(1)
17.(i) Give the name and structure of the initial material used in the
industrial preparation of phenol.

(ii) Write complete reaction for the bromination of phenol in aqueous
and non-aqueous medium.

(iii) Explain, why Lewis acid is not required in bromination of phenol.
Ans.
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(i} Cumene (Isopropyl benzene)
(
CH(CH3b
(1)
(ii) Bromination of phenol lin non-aqueous medium
OH
OBr
OH
OH
Br2 in CSz
273 K
o-bromophenol
Phenol
Sr
(minor)
p-brornoph enol
(major)
Bromination of phenol in aqueous medium
.6.
OH
OH
B)-yp"
. 'I. Sr
"
Phenol
3Br2
Bromine
water
Br
:2,4, 6~tribro mophenol
(1)
(iii) In bromination of phenol , the polarisation of Br2

molecule takes p lace even in the absence of Lewis
acid. lit is due to the high:ly activating effect of - OH
group attached to the benzene r'ing . Thus , lewis acid
is not required in brominatlon of phenol .
(1)
18. In what respect do prontosil and salvarsan resemble? Is there any

resemblance between azo dye and prontosil? Explain.
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18. Prontosil and salvarsan resemble in structure as prontosil
has - N=Nli nkag! which is similar to
-As = .As - linkage present in salvarsan. ALo dye also
has - N=N- linkage that resembles prontosil.
Structures of the three compounds are as foillows :
,OH
H2NX), AS
~AS
HO
0\:
'
INIH2
Salvarsan
(3)
19. Write the names and structures of monomers of

(i) natural rubber. (ii) terylene.
(iii) teflon.
Or
Are polyesters and polyacrylates same? Justify your answer.
Ans.
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Tile names and structures of monomers are as:
Monomers (structure)
S.No. Polmers
(I)
Natural rubber
Isoprene
CH 3
1
OH 2 = C CH = CH 2 (1)
Oi)
Tefylene
Ethylene glycol and
HOCHt:HPH
Terephthalic aoid
HooeD-' eaOH
_ ._ - - -_._._.._ - - ---_.
(iii)
__._._- _._._---
,-
__
__.(1)
--
--- -_. ._-_._.
Teflon or
Tetrafluoroethane
polytetrafluoroethe CF2 = CF2
(I)
ne
Or
Pollyesters and polyacrylates are different types of
polymers and differ in th e fo ll ow~l1g characteristics,

(i) Polyacrylates are homopolymers whi le, the polyesters
are co-polymers in natur,e.
(1)
(ii) The mode of synthesis of polyacrylates is adldHion
polymerisation wh ile, those of poll yesters is
condensation polymerisation .
(l)
occurs across C= C bond in

polyacrylates, whereas in polyesters" it is through ester
(iIi) Polymerisation
linkage"
20.
(1)
(i) Identify A and B in the following reaction.
o
~Cl
KeN I A
Hz/Pd )
(ii) Why is -NH2 group of aniline acetylated before carrying out nitration?
Ans.
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(i)
o
CI
eN
KeN )
2-(2-chloroothyl)
2-(2-cyanoethyl)
r::yc lohexanone
cydohexanone
(A)
(8)
(1 + 1)
(ii) - NH2 group of anil ine acety~ated (CHaCO) before
carrying out nitration because to p rated the nitrogen
atom during the nltration of converting the amine to an
am1de . After nitration , the amide protecting g'roup may
be removed Iby Ilyd rolysis.
2-(3-.aminopropyi) cyclohexanone
Note Aniline is .highly aotivated towards electrophilio
aromatic substitution. It is alsO' a base once protected,

the anilium ion is formed which is strongdeaclivator, its
basicity mak,es direct nitration impossible _
(1)
21.
(i) What are the essential and non-essential amino acids? Give two
examples of each type.

(ii) What causes the disease sickel cell anaemia?
Ans.
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(i) Essentialaminoacidis Am ino acids which cannot
be synthesised in the body and must be taken in diet
are ca lled essential amino acids.
For example, valine, leuclne , phenyl alan ine, etc. (11/2)
Non~essential
be
amino, acids Amino acids which can

synthesised in the body are known as
non-essential amino acids.

For example, glycine, alanine, glutamic acid, etc . (11/2)
(ii) Sickel cell anaemia is a ,d isorder caused due to
abnormal molecular structure of haemoglobin . In this
disease, there is substitution of valline amino acid in
place of glutamic acid at 6th position in p-globulin
chain of haemoglobin.
22.
(i) Arrange the isomers of C 6 H 4 Cl 2 (aromatic) in the increasing order of melting point and
boiling point.
L ei A
U Y
ortho
Cl
para
Cl
~
~Cl
me ta
(ti) .Explain, why alkyl halides are generally not prepared in the laboratory by free radical
halogenation of alkanes?
Ans.
(i) Melting point

symmetry)
meta < ortho < para (due to
BoiUng point meta < para < ortho

(1)
(Ii) A'lkyl halides are not prepared in the laboratory by free
rad ical halogenation . This is due to the following
reasons :
(1)
(a)
a ,g ives
a mixture of isomeri:c monohalogenated

products having boi~ing points so close that they
cannot be easily separated in the laboratory. (1/2)
(b) Due to polyhal:ogenation, mixture becomes more
complex and hence, more difficult to separatE(Ji2)

SectionD
23. Oxygen atom transfer from N 02 to CO produces NO and Co 2
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NO, (g) + CO(g)-----
NO (g) + CO 2 (g)
This reaction can also be utilised to remove poisonous gases like N 02,
CO, etc., from the atmosphere.
The rate equation for this reaction at temperature less than 500 K is Rate
=k [N0 2 ]2.
Based on the above information, answer the following questions.
Can this reaction occur in one bimolecular step?

If the concentration of N 02 is doubled, what will be the rate of the
reaction?
Addition of catalyst increases the rate of the reaction. Why?
What values do you get from the above passage?
Ans.
,(i) If the reaction is bimolecular, it must involves collision

of one N0 2 molecule with one CO molecu le.
N0 2 + CO ----> NO
CO 2
The rate equation would be

Rate = k [N0 2 ][CO]
This does not agree with experiment, so the
mechan ism must involve more than a singlle step :
Step 12 N0 2 Slow
~N0 ' 3+
N0 ,
Rate =" k [N0 2
Step II N0 3 + CO
Fast
) N0 2 + CO 2
f
(1)
(ii) On doubling the concentration of N0 2 1 the new rate
becomles R'= k[2N0 2]2

~ 4k[N0 2 ]2
= 4R
i.R the rate becomes four times.

(1 )
(iii) Cata.lyst lower the activation energy. hence rate of the
reaction is increased.
(1)
(iv) Concern about the environment, poUution, human
health and control of N0 2 and CO pollution .
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(1)

SectionE
24. An alkene A (molecular formula CSHlO) on ozonolysis gives a mixture
of two compounds Band C. Compound B gives positive Fehling's test and

also forms iodoform on treatment with 12 and NaOH. Compound C does
not give Fehling's test but forms iodoform. Identify the compounds A, B
and C. Write the reaction for ozonolysis and formation of iodoform from
B andC.
Or
When liquid A is treated with a freshly prepared ammoniacal silver
nitrate solution, it gives bright silver mirror. The liquid forms a white
crystalline solid on treatment with sodium hydrogen sulphite. Liquid B
also forms a white crystalline solid with sodium hydrogen sulphite but it
does not give test with ammoniacal silver nitrate. Which of the two
liquids is aldehyde? Write the chemical equations of these reactions also.
Ans.
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Ozonolysils
, C 5 H 1O
B+C
(A)
B ~~)
Iodoform
Fehling's test
test
C ----+~
Iodoform
Note give Fehling.ls test
test
Since, Band G both give iodoform test, they must contain

COCH 3 g roup and G does not give Fehling's test,
therefore C is a keto compound ,
.. Possible s ructure of A is
CH-:,-CH = C- CH3
~
CH 3
wh ich on ozonolysis gives an aldehyde and ketone.
A = CH 3 -CH = C-CH3
(2-methyilbut-2-ene)
(1)
CH 3
B=
H~
(Ethanal or aoeta~dehyde)
- CHO
(1)
(Propanone or acetone)
(1)
CH3 -CH = C- CH 3
(i) 0 3
'
~
(ii)lJ!/ HP
CH3
2-methylbut -2-ene
(CsH,o)
(A)
H3C-CHO+ 0 = C- CH3
EthanaJ
(B)
CH 3
Propanone
(C)
H? - CHO
(8)
3NaOl
NaOH/ 12
Heal
HCOONa + CHI3
+ 2NaOH
Iodofo rm
(yeHow ppt.)
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H3COOCH 3 + 3NaOI
(C)
NaOHH 2
Heat
CH 3COONa +
CHI3 +
Iodoform
(yellow ppL)
2NaOH
(1)
Or
Since, the liquid A reduces ammon iacal srlvm nitrate
(Tollen 's re agent} . compound A is an aldehyde,
(1)
H"
/C = O 2 [A9(NH3hIN03 + 2NH 4 0H
Aldehyde
To II en's reagent
(A)
---} 2N H4N0 3 + ReaOH + 2AgJ.. +
Hp
(l)
Silver mirror
"/C = O + NaHS03~ "/C"

/OS02
Aldehydes
o
etones
(A) or (8)
4NH3
ONa
Sod ium
hydwgen
sulptlite
Proton
transfer,
Bisulphite addition
compound (wh!te solrd)
(2)
CompoundA is an a~dehyde and compound B is keton(.l)

25. A violet compound of manganese A decomposes on heating to
liberate oxygen and compounds B and C of manganese are formed.

Compound C reacts with KOH in the presence of potassium nitrate to
give compound
On heating compound C with cone. H 2 S0 4 and N aCI, chlorine gas is
liberated and a compound D of manganese along with other products is
formed. Identify compounds A to D and also explain the reactions
involved.
Or
Transition metals can act as catalysts because these can change

their oxidation state. How does Fe(III) catalyse the reaction
between iodide and persulphate ions?
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Mention any three processes where transition metals act as

catalysts.
Ans.
Since , compound C on treating with Gone. Hp0 4 and

NaCl, '9ives CI2 gas, so ~t is manganese dioxide (MnO 2 ) . It
is obtained along with MnO~- when KMn04(violen is
heated, Thus t
A ~ IKMn04. B == K~n04 1 C ;;;; Mn0 21 D == MnCI2
(21/2)
The reactions involved are
2KMn04 ~ K;iV1n0 4 + Mn02 + 0 2

(A)
(8)
(C}
2MnOz + 4~OH
(C)
Mn02
(C}
+ 02 ----; 2K 2 MIl0 4 + ,2H 20

(B}
+ 4NaCI + 4H 2S0 4 ~
MnCI 2
(0)
+ 4NaHS0 4 +
2HiJ
+ CI 2
(21/.z)
Of
Reaction :between iodide and persulphate ion is
21- + S20ij-
Fe(HI
12 - 2S0~-
(1)
Ro:l:e of Fe (III) ions

,2Fe 3-+ ,
+ 21- ---*
2Fe2+ + Sp~-
2Fe 2r r 12
--t
2Fe3+ + 2S0~-
(1)
Oi) Trans it ion metals act as catalysts in the following

reactions :
(a) Vanadium (\I) oxide in contact process for

oxidation ofS0 2 t080 3 (1)
(b) Finelry divfded ir on in Haber's

conversion of N2 and H2 to NH 3 .
process
(c) Mn02 in preparation of oxygen ]rom KCI0
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In
(1)
3,
(1)

26. Assign reasons for the following.
Describe the favourable conditions for the manufacturing of (a)

ammonia by Haber's process, and (b) sulphuric acid by contact
process.
Draw the structures of the following.
PCIs(g) (b) Ss(g) (c) C1F3 (g)
Or
Assign reasons for the following.
Sulphur in vapour phase is paramagnetic.

Ammonia (NH 3 ) has greater affinity for protons than phosphine
(PH3 )
The negative value of electron gain enthalpy of fluorine is less than
that of chlorine.
BiCl3 is less covalent than PC1 3 Explain.
In noble gases, only xenon is known to form well established
chemical compounds.
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(b) Manufacture of sulphuric acid by contact
process
Equation is given be! ow.
2802 (g) +
02(g) ~
2S0 3 (g)
M-I; = - 196.6kJ mol- 1

The reaction is exothermic, reve rsib,le and the
forward reaction leads to a decrease in vollume.
Favourable conditions for maximum yield of 8 3 -
High pressure = 2 atm (2 bar)

Optimum temperature = 720 K
Catalyst = ViJ 5
(1)
(Ii) Structures
CI
(a}
".~. CI
.. ,.... s;:;.
""~~'-"'~~- '
CI <':............... ......
1.?!
_- 1' ~~~
.~
-~
CI --~ CI
PCI 5
(Trigol1all bipyramidal)
{l}
{b)
S6
(Cwwn-shapecl or
puckered rrng structure)
(c)
e lF3 (Distorted T-shape)
(1)
Or
Learncbse.in

(i) Sullphur in vapour state exists as 8 2 molecules. These
S2 mo~ecules have two unpaired ellectrons in
anti-bond ing n* - orbitals. Hence, sulphur vapour is
paramagnetic.
( 1)
(ii) Atomic size of N is less than that 'Of P Both NH3 and
PH 3 have affinity for protons and behave as Lewis
bases due to the presenoe of lone pair of e~ect rons on
the central atom. Due to smallier atomic size of N, the
availalbinty of Ilone pai r of electrons on N is more than
on P.
Hence, ammonia is more basic than phosphine. In
other words, ammonia has gr,eater affinlty for protons
than phosphine.
(1)
(iii) Atomic size of F is Iless than that of CI. Thus, the

lil nterelectronic repullsions in relative~y compact
2p~s.ubshell of F is more and the incoming electron [8
Il ess firmly held Ibythe nucleus . Thus, lesser amount of
energy is released when an electron enters in a
F-atom, i.e. negative value of electron gain enthalpy of
F is less.
On the other hand, CI-atom having larger atomic sli' ze
can easiliy accommodate an extra electron in relatively
Il arger 3p-subshell and thus, the negativ,e value of
electron gain enthalpy of CI is more.
(1)
(iv) BiCI 3 is less covalent than PCI 3 because the size of8i3+
,jlS much larger than p3+ (according: to Fajan's rule).,(l)
(v) Out of all noble gases, only xenon is known to form
well estabilised chemical compounds because,
(a) its ionisation enthalipy is not very high . lit lis much
lesser than He" Ne, Ar, Kr, etc.
(b) it is not unstable Ilike radioactive radon.
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(I)

Cbse Sample Papers For Class 12 Sa2 Chemistry Solved 2016 Set 10 Solutions

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Cbse Sample Papers For Class 12 Sa2 Chemistry Solved 2016 Set 10 Solutions

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CBSE Sample Papers for Class 12 SA2

Chemistry Solved 2016 Set 10

Cu) CH~HO CH3MgBr>

. . . . ) OH3= CH- CH3

2.Write a test to differentiate between pentan-2-one and pentan-3-one.

For iodoform test, the compound must have either a

Pentan-2-one gives posltiv@ iodoform test whereas

CH 3 CH2 - C CH 2 CH 3 + NaOI~ No ppt.