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Structure of Atom
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
.
Limitations:
1} Could not explain Gay Lussacs Law of volume combination.
2} It failed to explain why atoms of different elements differ in mass, size, and valence.
3} It dont tell why atoms combine to form molecule.
4} Dont speak about the binding forces which bind atoms to form a visible matter.
5} Does not account for the difference between allotropes, e.g. charcoal, graphite, diamond.
Drawbacks : With time, further studies by scientist showed some flaw in Daltons Theory.
1} Atom is not the ultimate, instead it is further made up of some subatomic particles. However,
saying an atom is the smallest particle that takes part in chemical reactions is true.
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
2} After the discovery of Isotopes, we knew that an element may have two or more atoms
having different masses.
3} Discovery of Isobars showed us that atoms of different elements can also resemble in mass.
With time a new theory, called Modern Atomic Theory got developed removing the limitations
and drawbacks of Daltons Theory.
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
Discovery of Electron
J.J. Thomson in 1897 recognized that the constituting particles of cathode rays (which were for
the first time observed by William Crookes in his Vacuum Tube Experiment, 1870s) are one of
the subatomic particles out of which atoms are made. Let us explain his modified Cathode Ray
Experiment which he used to analyze the cathode rays:
Experimental Setup: A genuine CRT is basically a glass tube as shown in daig. Equipped with
two metal plates connected with a high voltage battery. The plate connected with ve terminal is
called Cathode and with +ve terminal is called Anode. Some florescent/Phosphorescence
material( like ZnS) is coated on the inner glass of anode side. The tube is evacuated to 10 -2 to 106
atm and perfectly sealed.
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
For his experiments, Thomson modified the above CRT a little bit. The glass tube was as shown
below. A hole was made in Anode plate. He also made arrangements for applying electric and
magnetic fields on the ray. He evacuated below 10-6atm.
(3) Obs: Cathode rays can rotate and move the fan or wheel placed in there path.
Con: To rotate or move wheel cathode rays must have kinetic energy and for K.E. they must
have mass. Hence Cathode rays must be constituted of material particles (particles, because they
form distinct spots).
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
(4) Obs: In the presence of electric field the spots starts to form on that half of the screen which
was towards +ve plate i.e. cathode rays were getting attracted by +ve plate. In presence of
magnetic field also cathode rays showed behavior as if they possess ve charge.
Con: Cathode particles are vely charged.
(5) Obs: The mass to charge ratio of cathode particle was very less than the smallest charged
atom known (H+ or H-).
Con: They were the subatomic particles.
(6) Obs: The natures of cathode rays were independent of the materials used for electrode and
gas inside the tube.
Con: These were the fundamental particles which are the necessary constituent of the atoms
of all elements.
In 1894 G.J Stoney had proposed the atoms of electricity i.e. cathode particles should be called
electrons. Thus, electrons are the fundamental subatomic particles which have some definite
mass and carry a negative charge.
Q: Write down properties of cathode rays.
Ans: Cathode rays have following properties:
(1) Cathode rays travel in Straight lines and hence cast shadow of the object
placed in their path.
(2) They are consist of matter particles and hence possess kinetic energy.
Thats why they can move a wheel/fan placed on their path and produce
heat on striking.
(3) Cathode rays are constituted of vely charged particles and hence deflects
in electric and magnetic field.
(4) They cause fluorescence to the glass on which they fall.
(5) They can penetrate through thin metallic sheets.
(6) They ionize the gas through which they travel.
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
Anode rays
Goldstein in 1886 performed the same William Crookes Vacuum Tube Experiment with a little
modification and observed one more type of ray, which was coming out from anode and called
this anode ray.
Experimental Setups: A genuine CRT experiment was setup but instead of a simple metal plate
this time a perforated metal plate was used for cathode.
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
electric and magnetic field.
(5) The value of +ve charge on anode particles depends on nature of gas.
(6) The value of e/m ratio also, depends upon the nature of the gas taken in the discharge
tube.
Some hundred meters from the "Jardin des Plantes", where is working Becquerel, a young
polish woman, Marie Sklodowska has just get married with Pierre Curie, director of studies at
the Physics and Chemistry School of Paris. She works with him in his small laboratory .
Eighteen months later, she presents her PhD thesis about the U-rays (radioactivity) of Henri
Becquerel. She shows that, like uranium, the thorium is radioactive. And, in July of 1898, with
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
the help of Pierre, she succeeds in isolating a new material, a million time more radioactive than
uranium, that she calls "polonium". Then, from penchblende ore (many tons!), Pierre and Marie
extract by hand some milligrams of an other new material, 2.5 millions times more radioactive
than uranium: the radium. For this discovery, Pierre and Marie Curie receive the physics Nobel
prize in 1903. Some years later, Marie Curie, alone since the death of Pierre in 1906, isolates
metallic radium with an electrolytic procedure and receives the Nobel price of Chemistry, in
1911. One kilogram of radium during 1600 years gives more than 60 billions of Joules,
equivalent to the electricity consumption of a Paris inhabitant in one year! Where does this
considerable amount of energy come from, like from a magic source?...
In 1899, Rutherford found that there were two types of radiations (U-rays) coming out from
radioactive elements, one was less penetrating and other was high penetrating. He named them
and -rays. In 1900, Paul Villard discovered a new type of radiation coming out from
radioactive elements which has very much greater penetrating power. In 1903 Rutherford named
it -rays.
With time it was recognized that -particles are nothing else but doubly ionized Helium atom or
you can say the Helium Nucleus. Thus -particle carries 2 unit +ve charge and 4u mass. particle was recognized to be a similar particle with e- i.e. it carry 1 unit negative charge and
mass equal to that of an e-. -rays where the very high energy EM radiation (photons).
Thus there were three types of rays:
Ray
Resemble
2+
Mass
Charge
2e
-ve plate
1e
+ve plate
No charge
dont bends
He
4u
e-
1
1800
EM radiation
Bends towards
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
accept the existence of a center point in atom which must be very massive and highly positively
charged which he called Nucleus. Observations of this experiment led him to formulate a new
atomic model called s Atomic Model.
Experimental setup: A thin gold foil of thickness 0.0004 mm (a few hundreds of atoms thick)
was bombarded with -rays using a radioactive element as its source, kept inside a lead block. A
slit is placed in the path of -ray to obtain a narrow beam. The gold foil was surrounded by a
ZnS screen. The whole experimental setup was placed in an evacuated chamber to prevent
scattering by the air molecules.
Expectations of Rutherford: Rutherford had a strong belief on his mentor J.J. Thompsons
Plum Pudding Model of atom. So he thought that if an alpha particle will collide with an atom, it
will just fly straight through (as if some rockets were shooted on our solar system from some
were outside the galaxy, assuming planets only in our solar system and representing e-). It would
be affected only by the atoms electric fields, and Thomsons at. model predicted that the
electric fields in an atom are just too weak to affect alpha particles. Hence even if there will be
deviations, deviations will be very small.
Observations:
i.
Most of the rays (approx. 99%) passed with very small deviations.
ii.
Less than 1% rays showed larger deflections.
iii.
A very small fraction of rays also showed deflections by angle greater than 90 .
iv.
1 out of 8000 rays returned by 180 deflection.
Conclusions:
i.
First observation is in well accordance with Thomsons at. model acc. to which there
is nothing inside an atom that can deflect -ray with appreciable amount whose mass
is 4u and has very high velocities ( 5% of speed of light).
ii.
Last three observations cant be explained by Thomsons at. model and are against of
it.
iii.
Last three observations shows that there must exist some centre point in atom which
should be very massive and highly positively charged. Because the greater of
deflections of -particles seen can be caused from a highly positive charge massive
centre only.
Hence Rutherford discarded the Plum Pudding at. model of Thomson and proposed a new
atomic model in 1911, called Rutherford Atomic Model.
Postulates of Rutherford atomic model:
i.
An atom is composed of two parts, nucleus and extra nuclear portion. The nucleus is
at the centre of atom.
ii.
The nucleus contains almost of the mass of atom and that much positive charge which
is equal to the total negative charge caused by e-s in a neutral atom.
iii.
In extra nuclear portion, e-s exists which revolves around the nucleus in circular paths.
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
iv.
Volume of the nucleus is extremely small in comparison with the volume of the whole
atom. Radius of atom is of the order 10-10m (angstrom) while the radius of nucleus is
of the order 10-15m (fermi).
We can also obtain the spectrum of EM radiations emitted by a source in invisible region, by
using a photographic plate (digital spectrometer these days) in place of screen. The instrument
(prism is the simplest one) used to separate and analyze the constituting frequencies of an EM
radiation beam is called Spectroscope.
Continuous spectrum of EM radiation emitted by a black body
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
Continuous Spectrum: When a white light is
passed through a prism it splits into light of
different frequencies, and in case of white light we
have all the frequencies of a certain region (visible
region in this case) causing the bands of different
color to merge with each other. Such a spectrum
which contains all the frequencies of certain region
is called Continuous spectrum.
The first set of lines in emission spectrum of hydrogen were seen by Balmer in 18__, in visible
region. This is called Balmer series. By using a photographic plate instead of a simple screen,
Lyman in ____ observed a set of frequencies emitted by hydrogen in UV region. This is called
Lyman series. With advancement of spectroscopes different scientist observed three more set of
frequencies lying in infrared regions.
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
Rydberg In 1890 gave a simple equation for calculation of wavelength (and hence frequency)
whose solutions were exactly those frequencies, which are emitted in a Hydrogen spectrum.
This is called Rydberg Formula and is given as
1
RH
1
n12
Where RH is a constant, called Rydberg constant and has a value 109677 cm-1 or 10967700 m-1.
Line spectrum of elements are called the
Finger Prints of the elements, because all
the elements have unique set of
frequencies in there line spectrum.
Hydrogen and Helium atoms are there in
sun; this fact was also discovered by
seeing line spectrum of sunlight.
Planck had introduced his constant in 1900 in a formula explaining the light radiation emitted
from heated bodies. According to classical theory, light energy by a heated body should be
produced at all frequencies and in comparable amount. This is not only contrary to the
observations, but also implies the absurd result that the total energy radiated by a heated body
should be infinite (since there are infinite frequencies possible). Planck postulated that
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Physics by : Shubham Chourasia Chemistry by: Kailash Sir Math by: Tarun Sir
Discovery of Proton
In 1919, Rutherford became the first person to deliberately transmute one element into another.
In this experiment, he had discovered some peculiar radiations when alphas were projected into
air. When he did this experiment with pure nitrogen, he observed there some oxygen atoms too
after the experiment. He used alpha radiation to convert Nitrogen atoms into atoms of Oxygen
acc. to the nuclear reaction (known today):
14
+ 2He4 8O17 + p+
7N
The proton was not known then. So, in this experiment, Rutherford identified the unknown
radiation (p+-ray) as the Hydrogen nuclei, by seeing their similarity to the radiation emitted
during his earlier experiment when he had bombarded Hydrogen gas with -particles to knock
out hydrogen nuclei from hydrogen atoms.
This experiment showed Rutherford that hydrogen nuclei were a part of nitrogen nuclei (and by
inference, probably other nuclei as well). Such a construction had been suspected for many years
on the basis of atomic weights which were whole numbers of that of hydrogen (Prouts
hypothesis). Rutherford decided that a hydrogen nucleus was possibly a fundamental building
block of all nuclei, and also possibly a new fundamental particle as well, since nothing was
known from the nucleus that was lighter. Thus Rutherford postulated the hydrogen nucleus to be
a new fundamental particle in 1920, and called them protons.
Discovery of neutrons
In 1921, Rutherford theorized about the existence of neutrons, which could somehow
compensate for the repelling effect of the positive charges of protons by causing an attracting
nuclear force and thus keep the nuclei from flying apart by the repulsion between protons.
Rutherfords theory of neutrons was proved in 1932 by his associate James Chadwick, who
recognized neutrons immediately when they were produced by other scientists and later himself,
in bombarding beryllium with alpha particles. In 1935, Chadwick was awarded the noble prize
in physics for this discovery.
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