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TEMPERATURE
THERMAL EQUILIBRIUM
Two bodies are in thermal equilibrium (i.e at the same temperature) when there is no net
transfer (exchange) of heat between them.
Zeroth Law of thermodynamics states that if bodies A and B are each separately in thermal
equilibrium with body C, then A and B are in thermal equilibrium with each other.
If body C is a thermometer and gives the same reading when in contact with bodies A and B
separately, then A and B are in thermal equilibrium with each other. So, temperature of a
body is that property which determines whether it is in thermal equilibrium with
another body.
TEMPERATURE SCALE
1 THE EMPIRICAL SCALE
A thermometric property is a physical property which either increases only with
increasing temperature or decreases only with increasing temperature.
The empirical temperature scale is a scale based on experimental results using a
thermometric property. It is established using a thermometric physical property X of a
substance and two fixed points. X can be volume or length of column of a liquid (liquid-inglass thermometer), resistance of a metal (resistance thermometer), e.m.f (thermocouple) and
pressure of a fixed mass of gas at constant volume (constant-volume gas thermometer)
The two fixed points are ice point and steam points which are fixed temperatures at standard
atmospheric pressure and are also easily reproducible. An example of the empirical scale is
the centigrade scale where X between the two fixed points is divided into 100 equal parts (or
degrees).
(a) Linear Scales:
Hence,
, where
Linear
variation
Xs
X
Xi
100
calibration graph
/C
C
Junction at room
temprature
mV
,
where = temperature
difference between the two
junctions.
The cold junction is known
as the reference junction and
is usually kept at 0 C. The
hot junction is known as the
hot junction or measuring
junction.
mV
copper
iron
copper
iron
cold
junction
hot
junction
Measuring junction
R/
e.m.f /V
/C
/C
Between 1 and 2 variation of e.m.f with temperature is not single value and so cannot be
used to measure temperatures.
Over a small temperature range, there is a rapid change in resistance and the variation is more
or less linear. This makes the thermistor a sensitive thermometer over this temperature range
and so can be used to detect small changes in temperature.
Limitations of the empirical (centigrade) scale
Different types of thermometer measuring the same temperature show different readings on
the centigrade scale. Reasons: (i) the thermometric property may not vary linearly with
temperature, (ii) different thermometric substances do not respond in the same way to
changes in temperature, except at the two fixed points or points of calibration. Also, it is not
obvious whether one particular thermometric property P is better than another.
2 THE IDEAL GAS TEMPERATURE (or ABSOLUTE THERMODYNAMIC) SCALE
An absolute (thermodynamic or ideal gas temperature) scale overcomes the limitations of the
empirical scale because it does not depend on the thermometric property of any substance.
It is defined by the Ideal Gas Equation pV=nRT.
3
The two fixed points on the thermodynamic scale are:
1. absolute zero (0 K): temperature at which particles have no k.e.
2. triple point of water (Ttr = 273.16 K) : temperature at which ice, pure water and water
vapour all coexist in equilibrium.
Ttr is fixed at 273.16 K to make temperature difference between ice point and steam point
exactly 100 K on the thermodynamic scale.
The unit of thermodynamic scale is the Kelvin (K). One Kelvin is defined as
of the
pV
or
So,
(pV)tr
An ideal gas is only theoretical. In practice real gases
behave closely to the ideal gases at very low pressures.
So for a real gas,
real gas
0
pV
Ttr
ideal gas
T/K
...........
...........
...........
/cmHg
/cmHg
/K
real gas
ideal gas
(or
of
Advantages
Disadvantages
Thermocouple
Self-powered
cheap, robust
Wide temperature range
short response time
Non-linear scale
Low voltage across junctions
Reference point required
Thermistor Thermometer
allows remote measurement
cheap, robust, short response time, very
sensitive ( 200C-1)
Poor accuracy, non-linear scale
Current source required
Self heating,
narrow temperature range
Thermometer
Range/C
Mercury-inglass
-39 to 357
(limited)
n.t.c Thermistor
-50 to 200
(limited)
Thermocouple
-250 to
1500
(wide)
Accuracy
Poor
Poor
Average
Sensitivity
Response
time
Scale
Average
Medium
Linear
High
Short
(small heat
capacity)
Nonlinear
Average
Short
(small heat
capacity)
Nonlinear
Uses
Measuring
temperature of
cooling or heating
water
Room temperature
measurement,
electronic
thermometers,
measuring varying
and remote
temperatures
Measuring
temperature that
varies rapidly at a
point or a remote
place