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ABSTRACT Water splitting to form hydrogen and oxygen using solar energy in
the presence of semiconductor photocatalysts has long been studied as a potential
means of clean, large-scale fuel production. In general, overall water splitting can
be achieved when a photocatalyst is modified with a suitable cocatalyst. It is
therefore important to develop both photocatalysts and cocatalysts. In the past five
years, there has been significant progress in water splitting photocatalysis, especially in the development of cocatalysts and related physical and materials chemistry. This work describes the state of the art and future challenges in photocatalytic
water splitting, with a focus on the recent progress of our own research.
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Figure 1. Schematic energy diagrams of photocatalytic water splitting by one-step and two-step photoexcitation systems. C.B., conduction
band; V.B., valence band; Eg, band gap.
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Figure 3. Schematic illustration of H2 evolution on core/shellstructured nanoparticles (with a noble metal or metal oxide core
and a Cr2O3 shell) as a cocatalyst for photocatalytic overall water
splitting.
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treatment by oxidation or reduction. The latter two advantages are effective when the core is introduced by an in situ
photodeposition method. The elimination of activation procedures involving heat treatment is especially beneficial for
nonoxide photocatalysts, which tend to be less heat-resistant.
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Figure 4. (A) Scheme for the preparation of GaN:ZnO loaded with both Mn3O4 and core/shell-structured Rh/Cr2O3. (B) Photocatalytic
activity of GaN:ZnO modified with different cocatalysts under visible light ( > 420 nm). (C) Illustration of the reaction scheme for overall
water splitting on GaN:ZnO modified with Mn3O4 and core/shell-structured Rh/Cr2O3.
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REFERENCES
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AUTHOR INFORMATION
Corresponding Author:
*To whom correspondence should be addressed. Tel: 81-3-5841-1148.
Fax: 81-3-5841-8838. E-mail: domen@chemsys.t.u-tokyo.ac.jp.
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Biographies
Kazuhiko Maeda received his BSc. from Tokyo University of
Science (2003), MSc. from Tokyo Institute of Technology (2005),
and Ph.D. from The University of Tokyo (2007). From 2008 to 2009,
he was a postdoctoral fellow at The Pennsylvania State University
working with Professor Thomas E. Mallouk and is currently an
Assistant Professor at The University of Tokyo. His research interests are photocatalytic and photoelectrochemical water splitting
using semiconductor particles of (oxy)nitrides, inorganic metal
oxide nanosheets, and polymeric carbon nitride, combining nanotechnology and materials chemistry.
Kazunari Domen received his BSc. (1976), MSc. (1979), and
PhD. (1982) in chemistry from the University of Tokyo. He joined
the Tokyo Institute of Technology in 1982 as an Assistant Professor
and was subsequently promoted to Associate Professor in 1990 and
Professor in 1996. He moved to The University of Tokyo in 2004 and
is currently a full Professor. His current research interests include
heterogeneous catalysis and materials chemistry, with particular
focus on surface chemical reaction dynamics, photocatalysis, solid
acid catalysis, mesoporous materials, and fuel cell catalysts. Further
information on the Domen research group can be found at http://
www.domen.t.u-tokyo.ac.jp/.
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Maeda, K.; Teramura, K.; Lu, D.; Takata, T.; Saito, N.; Inoue, Y.;
Domen, K. Photocatalyst Releasing Hydrogen from Water.
Nature 2006, 440, 295.
Hata, H.; Kobayashi, Y.; Bojan, V.; Youngblood, W. J.; Mallouk,
T. E. Direct Deposition of Trivalent Rhodium Hydroxide
Nanoparticles onto a Semiconducting Layered Calcium Niobate for Photocatalytic Hydrogen Evolution. Nano Lett. 2008,
8, 794799.
Zong, X.; Yan, H.; Wu, G.; Ma, G.; Wen, F.; Wang, L.; Li, C.
Enhancement of Photocatalytic H2 Evolution on CdS by
Loading MoS2 as Cocatalyst under Visible Light Irradiation.
J. Am. Chem. Soc. 2008, 130, 71767177.
Jang, J. S.; Ham, D. J.; Lakshminarasimhan, N.; Choi, W.; Lee,
J. S. Role of Platinum-Like Tungsten Carbide as Cocatalyst of
CdS Photocatalyst for Hydrogen Production under Visible
Light Irradiation. Appl. Catal. A: Gen. 2008, 346, 149154.
Maeda, K.; Teramura, K.; Lu, D.; Saito, N.; Inoue, Y.; Domen,
K. Noble-Metal/Cr2O3 Core/Shell Nanoparticles as a Cocatalyst for Photocatalytic Overall Water Splitting. Angew. Chem.,
Int. Ed. 2006, 45, 78067809.
Maeda, K.; Teramura, K.; Lu, D.; Saito, N.; Inoue, Y.; Domen,
K. Roles of Rh/Cr2O3 (Core/Shell) Nanoparticles Photodeposited on Visible-Light-Responsive (Ga1-xZnx)(N1-xOx) Solid
Solutions in Photocatalytic Overall Water Splitting. J. Phys.
Chem. C 2007, 111, 75547560.
Maeda, K.; Sakamoto, N.; Ikeda, T.; Ohtsuka, H.; Xiong, A.;
Lu, D.; Kanehara, M.; Teranishi, T.; Domen, K. Preparation of
Core/Shell-Structured Nanoparticles (with a Noble-Metal or
Metal-Oxide Core and a Chromia Shell) and their Application
in Visible-Light Water Splitting. Chem.;Eur. J. 2010, 16,
77507759.
Sakamoto, N.; Ohtsuka, H.; Ikeda, T.; Maeda, K.; Lu, D.;
Kanehara, M.; Teramura, K.; Teranishi, T.; Domen, K. Highly
Dispersed Noble-Metal/Chromia (Core/Shell) Nanoparticles
as Efficient Hydrogen Evolution Promoters for Photocatalytic
Overall Water Splitting under Visible Light. Nanoscale 2009,
1, 106109.
Yoshida, M.; Takanabe, K.; Maeda, K.; Ishikawa, A.; Kubota, J.;
Sakata, Y.; Ikezawa, Y.; Domen, K. Role and Function of
Noble-Metal/Cr-Layer Core/Shell Structure Cocatalysts for
Photocatalytic Overall Water Splitting Studied by Model
Electrodes. J. Phys. Chem. C 2009, 113, 1015110157.
Hisatomi, T.; Maeda, K.; Takanabe, K.; Kubota, J.; Domen, K.
Aspects of Water Splitting Mechanism on (Ga1-xZnx)(N1-xOx) Photocatalyst Modified with Rh2-yCryO3 Cocatalyst. J. Phys. Chem. C 2009, 113, 2145821466.
Maeda, K.; et al. Photocatalytic Overall Water Splitting
Promoted by Two Different Cocatalysts for Hydrogen and
Oxygen Evolution under Visible Light. Angew. Chem., Int. Ed.
2010, 49, 40964099.
Yoshida, M.; Yamakata, A.; Takanabe, K.; Kubota, J.; Osawa,
M.; Domen, K. ATR-SEIRAS Investigation of the Fermi Level of
Pt Cocatalyst on a GaN Photocatalyst for Hydrogen Evolution
under Irradiation. J. Am. Chem. Soc. 2009, 131, 1321813219.
James, B. D.; Baum, G. N.; Perez, J.; Baum, K. N. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production; U.S. Department of Energy, Final Report, December
2009.
Yuliati, L.; Yang, J. H.; Wang, X.; Maeda, K.; Takata, T.;
Antonietti, M.; Domen, K. Highly-Active Tantalum (V) Nitride
Nanoparticles Prepared from a Mesoporous Carbon Nitride
Template for Photocatalytic Hydrogen Evolution under Visible Light Irradiation. J. Mater. Chem. 2010, 20, 42954298.
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