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AIPMT - 2008
AIPMT - 2008
Q.2
Q.3
(2) zero
(3) 2 mv
(4) mv/ 2
Q.7
(1) E along KO
(3) 3 E along KO
Q.5
Q.6
(2) 3E along OK
(4) E along OK
Q.8
Q.9
Q.4
O
D
the
A
ZX
nucleus
proton
and
neutron
Q.10
Q.11
Distance
Q.1
C
A
B
t Time
(1) D
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
D
S
(2) A
(3) B
(4) C
CAREER POINT .
Q.12
Q.13
Q.14
AIPMT - 2008
Q.18
Q.19
Q.20
(3) I1 + I2
I 2 )2
(4) ( I1 +
(2) OR gate
(4) NAND gate
0.5
Q.15
Q.16
ML2
6
(2)
(3)
Q.17
ML
24
2 ML2
24
Q.21
Q.22
(4)
I 2 )2
0.5
ML
12
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
CAREER POINT .
AIPMT - 2008
Q.23
Q.24
Q.25
Q.26
1
00
0
0
(2)
0
0
(4)
00
Q.30
Q.31
Q.27
Q.28
Q.29
F3
F1
S
R
F2
(1)
(3) F3 F1 F2
(4)
(F3 F1 ) 2 + F22
Q.32
Q.33
Q.34
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
CAREER POINT .
Q.35
Q.36
Q.37
AIPMT - 2008
Q.41
Q.38
Q.39
Q.40
3
N
4
(3) 0.5 N
3N
(4) 1.5 N
(1) 1 watt
(3) 4 watt
(2) 5 watt
(4) 2 watt
Q.42
Q.43
Q.44
Q.45
30
60
(2)
(1)
2N
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
(3)
f1
f2
(4)
f2
f1
CAREER POINT .
Q.46
AIPMT - 2008
Q.47
Q.48
m2
in such a way that its axis makes an angle of 60
Q.52
Q.53
Q.54
Q.55
Q.49
2 :1
(3)
3 :
(2)
2
2 :
(4) 1 :
Q.50
Q.51
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
CAREER POINT .
Q.56
Q.57
Q.58
Q.59
Q.60
AIPMT - 2008
Q.63
(1) 1/m (h / )
(2)
( h / )
(3) 1/2m (h / )
(4)
(h / 2)
Q.64
Q.65
Q.66
Q.67
(1)
(iii) HC C
is in the order of (1) (i) > (iii) > (ii)
(3) (ii) > (i) > (iii)
Q.61
Q.62
(2)
CH2OH
(3)
(2) (i) > (ii) (iii)
(4) (iii) > (ii) > (i)
Q.68
NO2
(4)
Q.69
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CAREER POINT .
Q.70
AIPMT - 2008
(i) RC C
(ii)
Q.75
Q.76
(iii) R2C= C H
(iv) R3C C H 2
is in the order of :
(1) (iv) > (ii) > (iii) > (i)
(2) (i) > (iii) > (ii) > (iv)
(3) (i) > (ii) > (iii) > (iv)
(4) (ii) > (iii) > (iv) > (i)
Q.71
(2)
(3)
OH OH
CH
CH
OH
OH
C
CH3
(4)
CH
CH3
Q.72
Q.73
Q.74
CH
C
O
CH2C
(2)
(3)
CH2
CH3
CH3
N
CH3
CH3
(4)
CH3
N
Q.77
Q.78
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
CAREER POINT .
Q.79
Q.80
AIPMT - 2008
Q.85
Green chemistry means such reactions which (1) are related to the depletion of ozone layer
(2) study the reactions in plants
(3) produce colour during reactions
(4) reduce the use and production of hazardous
chemicals
Q.86
Q.81
Q.82
Q.83
Q.84
of diamond is 4
(2) The number of Bravais lattices in which a
crystal can be categorized is 14
(3) The fraction of the total volume occupied by
the atoms in a primitive cell is 0.48
(4) Molecular solids are generally volatile
Q.87
RBr+Cl DMF
RCl+Br
Which one of the following has the highest
relative rate ?
CH 3
|
(1) CH3 C CH 2 Br (2) CH3CH2Br
|
CH 3
Q.88
Q.89
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
(2) Boron
(3) Germanium
(4) Arsenic
CAREER POINT .
Q.90
AIPMT - 2008
H3CCHCH=CH2+HBr
(X)
Q.96
CH3
Here (X) (predominantly) is :
(1) CH3CHCHCH3
Br
CH3
(2) CH3CHCHCH3
CH3 Br
Q.97
Q.98
Q.99
(3) CH3CHCH2CH2 Br
CH3
Br
(4) CH3CCH2CH3
CH3
Q.91
Q.92
[
]3
3+
(4) [Co(NH 3 )6 ]
(2) Co(C 2 O 4 )3
Q.100
Q.93
Q.94
Q.95
Q.101
l
3
2
a:
a:
a (2) la : 3a : 2a
2
2
2
(3)
l
l
l
3
l
a
a:
a:
a (4) a : 3a :
2
2
4
2
2 2
A
competitive
dehydrogenase is :
(1) -ketoglutarate
(3) malonate
Q.102
In the hydrocarbon,
6
5 4
2 1
3
CH3CH=CHCH2CCH
The state of hybridization of carbons 1, 3 and 5
are in the following sequence :
(1) sp,sp2, sp3
(2) sp3, sp2, sp
2
3
(4) sp, sp3, sp2
(3) sp , sp,sp
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inhibitor
of
succinic
(2) malate
(4) oxaloacetate
CAREER POINT .
Q.103
Q.104
Q.105
Q.106
Q.107
Q.108
AIPMT - 2008
Q.109
Q.110
Q.111
Q.112
Q.113
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
Method
(1) The pill
(2) Condom
(3) Vasectomy
(4) Copper-T
Mode of Action
(a) Prevents sperms
reaching cervix
(b) Prevents implantation
(c) Prevents ovaulation
(d) Semen contains no sperms
Answer codes :
(1) 1 = (c), 2 = (d), 3 = (a), 4 = (b)
(2) 1 = (b), 2 = (c), 3 = (a), 4 = (d)
(3) 1 = (c), 2 = (a), 3 = (d), 4 = (b)
(4) 1 = (d), 2 = (a), 3 = (b), 4 = (c)
10
CAREER POINT .
Q.114
Q.115
Q.116
Q.117
Q.118
AIPMT - 2008
Q.119
Q.120
Q.121
Q.122
Q.123
Q.124
Q.125
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
11
CAREER POINT .
Q.126
AIPMT - 2008
Q.131
Q.132
Q.133
Q.134
Q.135
Q.136
B
C
Q.127
Q.128
Thermococcus,
Methanococcus
and
Methanobacterium exemplify:
(1) bacteria whose DNA is relaxed or positively
supercoiled but which have a cytoskeleton as
well as mitochondria
(2) bacteria that contain a cytoskeleton and
ribosomes
(3) archaebacteria
that
contain
protein
homologous to eukaryotic core histones
(4) archaebacteria that lack any histones
resembling those found in eukaryotes but
whose DNA is negatively supercoiled.
Q.129
Q.130
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12
CAREER POINT .
Q.137
Q.138
Q.139
Q.140
Q.141
Q.142
Q.143
AIPMT - 2008
Q.144
Q.145
Q.146
Q.147
Q.148
Q.149
Q.150
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
13
CAREER POINT .
Q.151
Q.152
Q.153
Q.154
Q.155
AIPMT - 2008
Q.156 In the light of recent classification of living
organisms into three domains of life (bacteria,
archaea and eukarya), which one of the
following statements is true about archaea?
(1) Archaea completely differ from both
prokaryotes and eukaryotes
(2) Archaea completely differ from prokaryotes
(3) Archaea resemble eukarya in all respects
(4) Archaea have some novel features that are
absent in other prokaryotes and eukaryotes
Q.157
Q.158
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
1.1
0.8
0.8
9.0
- 10.3
8.2 1.1 11.2
8.4 2.2 4.1
7.3 11.3 2.1
CAREER POINT .
Q.160
Q.161
Q.162
Q.163
Q.164
AIPMT - 2008
Q.165
Q.166
Q.167
Q.168
Q.169
Q.170
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
15
CAREER POINT .
Q.171
AIPMT - 2008
Q.172
Q.173
Q.174
Q.175
Q.176
Q.177
Q.178
Q.179
Q.180
Bacillus
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
16
CAREER POINT .
Q.181
Q.182
AIPMT - 2008
Q.186
Q.187
Q.188
Q.189
Q.190
Q.191
(2) Stomach
Fats Lipase
Micelles
(3) Duodenum
sin
Triglycerides Tryp
Monoglycerides
amylase
Q.183
Q.184
Q.185
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
17
CAREER POINT .
Q.192
Q.193
Q.194
Q.195
AIPMT - 2008
Q.196
Q.197
Q.198
Q.199
Q.200
Ascaris is characterized by :
(1) presence of true coelom but absence of
metamerism
(2) presence of true coelom and metamerism
(metamerisation)
(3) absence of true coelom but presence of
metamerism
(4) presence of neither true coelom nor
metamerism
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
18
CAREER POINT .
AIPMT - 2008
1
1
21
4
41
2
61
4
81
4
101
3
121
3
141
4
161
3
181
2
2
1
22
1
42
1
62
4
82
1
102
4
122
2
142
3
162
4
182
4
3
1
23
3
43
3
63
3
83
3
103
4
123
3
143
2
163
1
183
1
4
1
24
1
44
2
64
3
84
2
104
3
124
1
144
4
164
4
184
1
5
3
25
4
45
2
65
2
85
4
105
4
125
2
145
1
165
3
185
2
6
3
26
4
46
2
66
3
86
3
106
3
126
2
146
2
166
2
186
3
7
4
27
2
47
3
67
1
87
2
107
4
127
4
147
2
167
1
187
2
8
2
28
3
48
3
68
2
88
4
108
3
128
3
148
2
168
3
188
4
9
3
29
1
49
4
69
2
89
2
109
2
129
3
149
2
169
3
189
3
10
2
30
3
50
3
70
3
90
4
110
1
130
4
150
4
170
3
190
4
11
4
31
4
51
1
71
3
91
3
111
3
131
4
151
3
171
2
191
4
12
3
32
4
52
1
72
1
92
1
112
1
132
4
152
2
172
4
192
3
13
3
33
3
53
4
73
1
93
2
113
3
133
3
153
2
173
3
193
3
14
1
34
1
54
3
74
1
94
2
114
1
134
2
154
4
174
2
194
1
15
4
35
1
55
1
75
4
95
4
115
3
135
2
155
1
175
1
195
4
16
4
36
2
56
1
76
2
96
4
116
4
136
1
156
4
176
3
196
4
17
4
37
2
57
4
77
4
97
2
117
4
137
3
157
2
177
2
197
1
18
2
38
3
58
3
78
3
98
1
118
1
138
4
158
1
178
1
198
4
19
1
39
1
59
3
79
2
99
1
119
2
139
3
159
1
179
1
199
3
20
2
40
3
60
2
80
4
100
3
120
3
140
4
160
2
180
1
200
3
2.
since = Li
L=
45
O cos 45
2
= = 1H
i 2
cos 45
sin 45
3.
Change in momentum = P
= Px i + Py j, since Px = 0
i.e.
magnetic
force
is
F = q B ,
= Py j = P y Piy ;
= 2m sin 45 = 2 m j P
= 2m
e sign shows the direction of change in
momentum in e y-direction.
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P = F .V = 0
As F r , V r , dr .
or dW = F . dr = 0
19
CAREER POINT .
4.
5.
h
10 3
=
6.
AIPMT - 2008
7.
10
dp d(m )
=
;
dt
dt
m = mass of system as conveyor belt with sand
drops at time t.
d
dm
+
Fext. = m
dt
dt
d
but constant, so,
=0
dt
dm
Fext =
= M
dt
OK and it is equal to E.
8.
R = R 0 A1 3
Am
So nuclear density =
9.
Mass defect
m = ZM p + (A Z )M n M (A, Z )
Binding energy= mC
BE = ZM p + (A Z )M n M(A, Z ) .C 2
M(A, Z) = ZM p + (A Z)M n
10.
m s = 2.73 10 21 m s
Fext. =
9.1 10 31 3 10 6
27.3 10 25
BE
C2
300
t
270
t = 9 sec
10 =
20
CAREER POINT .
11.
AIPMT - 2008
17.
14.
V=
(I
=( I
+ I2
I min
I2
A+B
= 5 1014 Hz
34
I max =
)
)
) +(
I I ) + (I
2
I1 + I 2
= I1 + I 2 + 2
1 2
I1 I 2
+ I 2 2 I1 I 2
= 2(I1 + I 2 )
19.
20.
6.6 10
I max + I min
A+B
3.2 10 19
I = I1 + I 2 + 2 I1 I 2 cos
18.
15.
2 1.6 10 19 = 66 10 34
13.
12.
l=
4 3
r
3
4 7
= amp
3 3
i
34
7 12
5
and 3 =
= i4
i 4 12 7
3 7
4
V
r
100 = 3 100
V
r
i 3 = i1 + I 2 = 1 +
16.
3
P
L/2
L/2
0.5
0.5
1
N
21
CAREER POINT .
i3
AIPMT - 2008
When sign of coefficient of t and x are opposite
dx
= V > 0 i.e., wave is propagating
it means
dt
in the direction of growing x.
12/7
M
N
i4
1/4
23.
Q
Q
and E =
;
4 0 r
4 0 r 2
Given V = Q 1011 = Q 40r
1
r=
4 0 1011
V
i.e.,
E=
r
QV
E=
= Q 1011 40 1011
r
= 40Q 1022 volt m1
V=
16
i4 =
amp = 3.2 amp
5
VNM = P.D. across N and M = i4 1
= 3.2 1 = 3.2 volt
Second approach.
VPM = 1 A 4 = 4 volt
VPN
1
and VPN + VNM = 4 V
=
VNM
4
1
.VNM + VNM = 4
4
16
VNM =
V = 3.2 V
5
24.
0C Scale
100C
C = 39C
F.P.
W Scale
239W
39W
=
100
200
C
or W =
200 + 39
100
39
=
200 + 39 = 78 + 39 = 117
100
So, temperature on new scale is 117W
corresponding to 39C.
22.
1
0 0
(0)
25.
Path difference x = x1 x2 = 15 10 = 5 m
= T = 300 0.05 = 15 m
2
2
2
=
. x =
5=
15
3
26.
Maximum acceleration a = 2 A
a1
2 A
(100) 2
1
= 12 =
= 2
2
a2
2 A
(1000)
10
27.
Lattice parameter
4r
a=
2
W
0C
C =
medium having
permeability (0).
21.
B.P.
Since
and
2a
2 3.6
=
4
4
= 0.9 1.41 = 1.27
r=
28.
= 1 Hz
1
= = 0.2 m
5
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100
t
100
15 10 60 90
=
= 8.1 kW
100
22
CAREER POINT .
29.
AIPMT - 2008
(E . d)2
2 d
32.
11l
l
=
10 10
10A
and therefore, A =
11
11l
P
2
10 = l (11) = 1.21 R
So R =
2
A
10A
(10)
11
Now resistance becomes 1.21 times of initial
and specific resistance is the intrinsic property
so remains same.
1
0AE2d
2
Energy stored in capacitor + Energy loss in the
process of charging = Energy given by cell.
A 0 2
=
V
d
= 2 Energy stored in capacitor
Since energy stored in capacitor = Energy loss
in the process of storing the charge in capacitor.
30.
33.
34.
35.
36.
Voltage gain =
11
u = 1.5 10 m
u = = 10 cm = 0.1 m
h
= i
u
h0
0.1
11
1.5 10
hi =
31.
hi
1.39 10 9
1.39 10 8
1.5 10
11
= 9.2 104 m
F3
Fhorizontal = (F3 F1)
Fvertical = F2
9
= 0.09, voltage gain = 10
100
AV
10 =
9
.AV
1+
100
10
= 100
AV =
0.1
37.
where
F = (F3 F1 ) 2 + F22
and
F3
Resultant of
F2
AV
,
1 + .A V
where =
F1
l
A
Now, l = l +
R=
is F
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R = 4450
23
CAREER POINT .
38.
AIPMT - 2008
m11 = m22
gun
42.
shell
4 1 =
200
2
1000
2
= 20
1
...(1)
1
= e4t
e
1
1
m1 12 + m2 22 = 1.05 103
2
2
1 2
2
2 1 +
2 = 1.05 103
...(2)
10
By equation (1) and (2)
2 = 100 m/s
39.
40.
e1 = e4t t =
43.
e = E0 sin t
i = I0 sin (t )
Pav. = Erms . Irms . cos
E
I
= 0 . 0 . cos = E0I0 cos
2
2
44.
1N
30 30
30 30
60
60
2N
41.
45.
P = P1 + P2 =
46.
3 2 = i (5 + 1)
i = 1A
Power dissipated in 5
P = i2 R
= (1)2 5 = 5 watt
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
11.2 1.6 10
19
6.63 10 34 3 10 8
x = a sin t +
6
dx
=
= a cos t +
6
dt
max = a
= a cos t +
2
6
=
t =
t +
6
3
6
T
T
=
=
t=
6 6 2
12
P=
4
1
hc
11.2 1.6 10 19
= 1.1 107 m
Hence the wavelength of ultraviolet region.
4N
1N
1
4
x1 = N0 e5t
x2 = N0 et
x1
= e5t + t
x2
1
1
+
1 2
1 + 2
1 . 2
PV = nRT or
1
PV
RT
=
M
M0
or
1
RT
=
P
T
M0
T
1 2
/
= 2
P1 P2
T1
or
2
283
x
=
383
P2
or
383
x
=
283
2 / P2
24
CAREER POINT .
47.
mg N =
AIPMT - 2008
mv 2
r
52.
53.
2AB2(g)
mg
When N = 0, for weightlessness
mv 2
= mg
r
2 = rg = 20 10 = 200
= 14.14
48.
49.
A = r2 = 0.04
= BA cos
1
= 0.04 cos 60 = 0.02 Wb
Kp =
Kp =
initially
at eq.
[ PAB ] 2 [PB2 ]
[PAB2 ] 2
2x
2 + x P 2 + x P
2(1 x )
2 + x P
4x 3
P
Kp = 2 + x 2
4(1 x )
E
. r l2
R+r
4x 3 P 1
(As 1 x ~ 1 and 2 + x ~ 2)
2
4
x = (8Kp/4P)1/3 = (2Kp/P)1/3
Kp =
54.
55.
Fe(OH)3(s)
l
r+R
= 1
R
l2
r = 1 1 . R
l2
110 100
10 = 1
=
100
51.
0
x
MK 12 = MR2
K1 = R
MR 2
MK 22 =
2
R
K2 =
2
E l1 and E
0
2x
K2
1
2
=
=
R
K1
2
50.
2AB(g) + B2(g)
2
2(1 x)
3+
[ Fe ] [OH ]
[Fe(OH) 3 ]
K = [Fe3+] [OH]3
(as activity of solid is taken unity)
Concentration of OH ion in the reaction is
decreased by 1/4 times then equilibrium
concentration of Fe3+ will be increased by
64 times in order to keep the value of K
constant.
K=
56.
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(Volume)
25
CAREER POINT .
57.
pH = log10 [H+]
[H+] = 10pH
[H+] of solution 1 = 103
[H+] of solution 2 = 104
[H+] of solution 3 = 105
Total concentration of [H+]
The volume taken in each case is 1 L
= 103 (1 + 1 101 + 1 102
1
1 1
= 103 +
+
1
10
100
3 111
3
= 10
= 1.11 10
100
61.
62.
63.
64.
Given compound,
CH3CH CHCH2CHBrCH3
may also be written as follows :
CH3
H
H
|
C C
H
CH2C*CH3
|
Br
Both geometrical isomerism (cis-trans form)
and optical isomerism is possible in this
compound.
Number of optical isomer = 2n = 21 = 2
(Here n = number of asymmetric carbon)
Therefore, total number of stereoisomers
=2+2=4
65.
66.
66.
1.11 10 3
= 3.7 104 M
3
58.
AIPMT - 2008
59.
60.
CH > CH2
sp
sp2
26
CAREER POINT .
72.
68.
Bond order
69.
AIPMT - 2008
PbO
1.5
2.5
3.0
x mole
6.5
224
0.5
2x moles
x mole
3. 2
mole
36.5
mole
= 18 cm3 or mL
So volume occupied by one molecule of water
18
=
= 2.988 1023
6.023 10 23
= 3.0 1023 cm3
RC CH2
| (sp )
R
R
|
RC CH3 2
| (sp )
R
The electronegativity of hybrid orbitals,
depends on their 's' character. It follows given
order,
RC
73.
H2 + Cl2 2HCl
Hreaction = (BE)reactant (BE)product
= [(BE)HH + (BE)ClCl] [2(BE)HCl]
= 434 + 242 (431) 2
= 186 kJ
As Hreaction = 186 kJ
So enthalpy of formation of HCl
186 kJ
=
2
= 93 kJ mol1
74.
75.
70.
Cl
(sp)
electronegativity increases
71.
OH
OH
|
|
H3CCCHCPh
|
||
O
NH2 NaNO
NCl
HCl
76.
(B)
(A)
H2O
H3CC
|
O
||
CHCPh
N(CH3)2 Cold
CH3
CH3
27
CAREER POINT .
77.
PCl5(g)
AIPMT - 2008
PCl3(g) + Cl2(g)
Kp2 =
H = E + nRT
Here, n = Change in number of moles of
product and reactant
As n = +ve, so H = +ve
S = Sproduct Sreactant
S = +ve
78.
Uncertainty in momentum
(m) = 1 1018 g cm s1
Uncertainty in velocity
() =
79.
1 10 18
= 1.1 109 cm s1
28
9 10
K p1
Kp2
81.
HI(g)
1/2H2(g) + 1/2I2(g)
1/ 2
K=
[H 2 ]
[I 2 ]1/ 2
=8
[ HI]
H2(g) + I2(g)
K =
[HI]
= (1/8)2
[H 2 ][ I 2 ]
84.
85.
86.
Y+Z
...(1)
X
A
2B
...(2)
Y+Z
X
Initially 1
0 0
At eq.
1
Total no. of moles at equilibrium
= 1 + 2 = 1 +
A
2B
Initially, when t = 0 1
0
2
At eq.
1
Total no. of moles at equilibrium
= 1 + 2 = 1 +
Kp1 =
PY PZ
PX
[( / 1 + )P1 ][ / 1 + ) P1 ]
[1 / 1 + ] P1
z 4 / 3r 3
d3
Here a = edge length, r = radius of cation and
anion
Efficiency of packing in simple cubic or
primitive cell = /6 = 0.52
i.e., 52% of unit cell is occupied by atoms and
48% is empty.
K = 1/64
82.
P1
4P2
83.
2HI(g)
P1 36
= 36 : 1
=
P2
1
80.
(PB ) 2 [(2 / 1 + ) P2 ]2
=
PA
[1 / 1 + ] P2
87.
88.
89.
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
130
115
(Bond angles)
CAREER POINT .
90.
AIPMT - 2008
93.
94.
95.
3-methyl but-1-ene
Mechanism :
CH3
|
CH3CCH
|
H
CH2 + H+
CH3
| +
CH3CCHCH3
|
H
2 carbocation
(less stable)
sp
CH3
|+
CH3CCH2CH3
96.
3 carbocation
(more stable)
sp
sp
sp
CH
sp
5 moles of oxalate.
So number of moles of MnO 4 required to
oxidize 1 mole of oxalate = 2/5 = 0.4.
%
composition
Mole
ratio
Simple
ratio
38.71
38.71/12
3.22/3.22
= 3.22
=1
9.67/1
9.67/3.22
= 9.67
=3
51.62/16
3.22/3.22
= 3.22
=1
9.67
97.
k1 = 1016 e2000/T
k2 = 1015 e1000/T
The temperature at which k1 = k2 will be
1016 e2000/T = 1015 e1000/T
e 2000 / T
e 1000 / T
1015
1016
e1000/T = 101
loge e1000/T = loge 101
2.303 log10 e1000/T = 2.303 log10 101
1000
log10 e = 1
T
On solving, we get
92.
(major product)
2-bromo-2-methylbutane
51.62
CH3
|
CH3CCH2CH3
|
Br
CHCH2C
[ C 2 O 24 2e + 2CO2 ...(ii)] 5
+ Br
sp
1,2-hydride shift
91.
CH3CH
T = 1000/2.303 K
98.
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CAREER POINT .
99.
AIPMT - 2008
100.
CAREER POINT: CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-3040000
r +/r =
30