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Angular Capillaries
Ahmed Al-Futaisi, SPE, Sultan Qaboos U., and Tad W. Patzek, SPE, U.C. Berkeley/Lawrence Berkeley
Natl. Laboratory
Summary
In this paper, we extend to three fluid phases a prior finite-element
study of hydraulic conductance of two-phase creeping flow in
angular capillaries. Previously, we obtained analytic expressions
for the hydraulic conductance of water in corner filaments. Here,
we present the results of a large numerical study with a highresolution finite-element method that solves the three-phase creeping flow approximation of the Navier-Stokes equation. Using the
projection-pursuit regression approach, we provide simple analytic
expressions for the hydraulic conductance of an intermediate layer
of oil sandwiched between water in the corners of the capillary and
gas in the center. Our correlations are derived for the oil layers
bounded by the concave or convex interfaces that are rigid or allow
perfect slip. Therefore, our correlations are applicable to drainage,
spontaneous imbibition, and forced imbibition with maximum feasible hysteresis of each contact angle, oil/water (O/W), and gas/oil
(G/O). These correlations should be useful in pore-network calculations of three-phase relative permeabilities of spreading oils.
Finally, we compare our results with the existing correlations by
Zhou et al.18 and Hui and Blunt,19 who assumed thin-film flow
with an effective film thickness proportional to the ratio of the
flow area to the length of the no-flow boundary. On average, our
correlations are two to four times closer to the numerical results
than the corresponding correlations by Zhou et al. and Hui and
Blunt.
Introduction
Because direct measurement of flow of three immiscible fluids is
very difficult, the pore-scale models of three-fluid systems15 have
blossomed. One of the more important advancements in such models was the approximation of single-pore geometries as angular
capillaries with square or arbitrary triangular cross sections. Although real pores are not exactly square or triangular, this approximation allows one to capture the flow of water in the pore corners
and the flow of oil and gas in the pore center. As illustrated in Fig.
1a, when three fluids are moving in a single angular capillary, the
most wetting fluid (water or Fluid 1) resides in the corner and the
most nonwetting fluid (gas or Fluid 3) fills the center. The third
fluid (oil or Fluid 2) forms an intermediate layer sandwiched between the other two fluids. In some cases of large contact angles
and positive spreading coefficients, we may find more than one
sandwiched layer (Fig. 1b). These intermediate layers are a few
micrometers thick and have been observed in micromodel experiments.69 It is drainage through these oil layers that is responsible
for the high oil recoveries seen experimentally.1012 Although it
was initially thought that only spreading oils could form such
layers in angular pores, it has been theoretically predicted and
experimentally verified that nonspreading oil can also form intermediate layers in the crevices of the pore space.6,9,13 Therefore,
the formation of sandwiched layers is not only related to the positive spreading coefficient, but also depends on the curvatures
of the O/W and G/O interfaces, the corner geometry, and the
contact angles.3
252
Fig. 1Different configurations of (1) water, (2) oil, and (3) gas in a single triangular pore.
cos21 +
cos32 +
, b2 = r2
. . . . . . . . . . . . . . . . . . (2)
sin
sin
ij
2
Eij1 =
cosij +
sin
Eij2 =
cosij +
cosij
sin
A L =
2
E32
1
32
E32
2 E0
2
E32
1
b1
b2
b1
b2
sin cos if 21 + = 2
21
E21
2 E0
2
E21
1
. . . . (4)
otherwise.
P L = 2 1
b1
+ L 21 + L 32 , . . . . . . . . . . . . . . . . . . . . . . . . . (5)
b2
L 21 =
A L
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (8)
P 2
L
b1 E21
0
otherwise,
2
b2 E21
1
. . . . . . . . . . . . . . . . . . . (6)
Mathematical Formulation
Assuming steady-state, creeping isothermal flow of Newtonian,
incompressible, and constant viscosity fluids, the combined continuity and Navier-Stokes equations that describe the flow reduce
to an elliptic Poisson equation are as follows:
i
x1, x2 i, . . . . . . . . . . . . . . . . . . . . . . . . . . . . (10)
i
b1
2 sin if 21 + = 2
b2
b1
1
cos cos sin32
1 32 +
if 21 + = 2
b2 cos2
E1
E32
1
. . . . (9)
E21
b1
1 cos32 sin
min 1, 32
otherwise
b2
E1 cos21 sin
2v1 =
i = 1, 2, 3, j i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (3)
The layer dimensionless cross-sectional area, A L, is defined
as follows:
32
E32
2 E0
=
G
L
xj
b2
vi 2
b22 2
j = 1, 2, 3
j = 1, 2, 3. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (12)
i2v i = 1
1 =
1
3
, = 1, 3 = . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (13)
2 2
2
Numerical Approximation
We solve the boundary value problem (Eqs. 13 through 16) numerically using the finite-element method (FEM). The FEM solution was obtained using the MATLAB Partial Differential Equation (PDE) Toolbox (MathWorks, Natick, Massachusetts).21 The
Toolbox provides a powerful and flexible environment for the
study and solution of partial differential equations in two space
dimensions and time. We now present examples of mesh generation, solution visualization, and convergence.
Mesh Generation. Accuracy of the FEM solution depends on how
well the computational domain is discretized. A good numerical
solution requires a mesh that follows the shape of the duct walls
and the curvatures of the interfaces. The PDE toolbox has many
powerful built-in functions that enable the user to generate the
finite-element meshes with the required properties. In our simulations, we have used the built-in MATLAB function initmesh to
initiate the first discretization of the domain. Then, the initial mesh
is refined five more times using the function refinemesh. In each
refinement, each triangle in the mesh is divided into four new
triangles. Because of the layer symmetry with respect to the corner-angle bisector, the FEM analysis is performed on 12 of the
domain. Depending on the layer geometry, the maximum number
of elements generated for a layer (half-domain) in our simulations
was 109,824, whereas the minimum number of elements was
5,376. The average number of elements of all the cases considered
in this analysis was 20,446. In Fig. 4, we present examples of layer
meshes for two geometrical configurations. The number of elements shown in the plot is just for illustration; the meshes used in
the numerical analysis were much finer.
Dimensionless Velocity Profile. Once we have generated a mesh
and specified appropriate boundary conditions, we solve Eq. 13 in
order to calculate the profile of the dimensionless velocity in the
layer. In Fig. 5, we show the dimensionless velocity profiles in a
specific layer for the four boundary conditions: BC-1, BC-2, BC-3,
and BC-4. The layer dimensionless area, A L , the circumference,
, are 0.1901, 3.7913, and 0.0132,
P L , and the shape factor, G
L
respectively. Benefitting from the symmetry of the layer with respect to the corner-angle bisector, the FEM analysis is performed
using 16,896 elements on 12 of the layer; the second half mirrors
the first one. From Fig. 5, one can see that the interface boundary
conditions influence significantly the velocity profile and, therefore, the average velocity and hydraulic conductance of the layer.
The average dimensionless velocity in the layer, <v L>, is calculated as follows:
N
v A
k=1 k k
, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (18)
v L =
N
A k
k=1
where Nthe total number of elements in the layer, A kthe element k dimensionless area, and v kthe element k dimensionless
September 2003 SPE Journal
Fig. 4Layer mesh generation for two geometrical configurations: (a) =24, 21=0, 32=0, and b1/b2=0.25; and (b) =60, 21=80,
32=10, and b1/b2=0.3.
velocity calculated at the center of the element. The average dimensionless velocities in the layers shown in Fig. 5 are 0.0016,
0.0053, 0.0027, and 0.0163, respectively, with the boundary conditions BC-1, BC-2, BC-3, and BC-4.
The dimensionless hydraulic conductance, g L, of the layer is
N
g L = 2
v A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (19)
k k
k=1
b24
g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (20)
2 L
in Fig. 5 exhibit similar behavior; therefore, we restrict our description to a single boundary configuration, BC-2: The no-slip
O/W interface and the perfect slip G/O interface. The same conclusions can be applied to the other three boundary conditions.
Fig. 7 relates the logarithm of the dimensionless hydraulic
conductance to the corner half-angle , the O/W contact angle 21,
and the G/O contact angle 32 for a fixed ratio b1/b2. For small
corner half-angles, < 10, the variation of the hydraulic conductance with 21 and 32 is relatively minor. However, as the corner
half angle increases, < 10, the hydraulic conductance varies
considerably with 21 and 32. For a fixed , increasing 21 decreases the layer hydraulic conductance, whereas increasing 32
increases it. Also, both contact angles, 21 and 32, affect the
hydraulic conductance considerably. The effect of the ratio b1/b2
on the layer hydraulic conductance is shown in Fig. 8. One may
notice that increasing b1/b2 results in a large variation of the hydraulic conductance. A smaller variation is observed when b1/b2 is
less than 0.4.
As mentioned in the mathematical formulation of the problem,
we are not considering here the momentum transfer boundary condition that assumes continuity of velocity and shear stress along
the interfaces (Eq. 17). However, because this boundary condition
is somewhere between the no-slip and perfect-slip ones, it is
worthwhile to compare the hydraulic conductances obtained with
the latter two boundary conditions by fixing some parameters: We
set the boundary condition and the contact angle at the G/O interface to no-slip and 0, respectively. With the same layer geometry,
the problem is solved twice, first with the no-slip O/W interface
(BC-1), and second with the perfect-slip O/W interface (BC-3).
The dimensionless hydraulic conductances for the two cases are
plotted in Fig. 9. The type of BC has a strong influence on the
hydraulic conductance. For small values of b1/b2 (i.e., for the two
interfaces of the sandwiched layer far from each other), the values
of the two conductances are similar, and their ratio is close to 1.
However, as the corner half-angle increases, this ratio becomes
smaller, reflecting the clear difference between the two BCs. For
the extreme cases of large b1/b2 (the interfaces very close to each
other) and large , the conductance ratio can be less than 0.3. This
simple comparison illustrates the importance of considering the
third boundary condition (Eq. 17), because the real flow is perhaps
neither perfect-slip nor no-slip.
Figs. 7 through 9 demonstrate that the different combinations of
, 21, 32, and b1/b2, and the boundary conditions may result in a
Fig. 5Velocity distribution in a sandwiched layer (=60, 21=90, 32=10, and b1/b2=0.25) with different interface boundary
conditions: BC-1, BC-2, BC-3, and BC-4, respectively.
September 2003 SPE Journal
255
Fig. 6Convergence of the FEM solution for eight different layers with BC-2: No-slip O/W interface and perfect-slip G/O interface.
huge variation of the layer hydraulic conductance. They also foreshadow the diffculty of creating an easy-to-use relationship among
these parameters and the layer hydraulic conductance. As our
analysis shows, there is no straightforward relation between the
layer conductance and its geometrical features, such as area, perimeter, or shape factor. Therefore, a rigorous statistical procedure
is required to derive best correlations for the layer hydraulic
conductance.
Universal Curves for the Layer
Hydraulic Conductance
Here we attempt to derive the universal curves that approximate
the hydraulic conductance of the sandwiched layer. As shown
above, regular statistical procedures may not describe adequately
the nonlinear interactions among the dimensionless dependent
Fig. 7The logarithm of the dimensionless hydraulic conductance vs. corner half-angles and contact angles 21 and 32 for
b1/b2=0.8, and with BC-2.
256
Y = 0 +
f X + , . . . . . . . . . . . . . . . . . . . . . . . . . (21)
j j
j=1
Fig. 8The logarithm of the dimensionless hydraulic conductance vs. the b1/b2 and contact angles 21 and 32 for =15, and
with BC-2.
September 2003 SPE Journal
Fig. 9The ratio of the dimensionless hydraulic conductance of BC-1 to BC-3 for different layer geometries.
0 = 7.5325
1 = 1.6435
z = 0.1367ln + 0.4339lnG
L
+ 0.7444lnA L 0.174032 0.4568
b1
b2
0 = 7.9998
z = 0.0797ln + 0.5540lnG
L
0 = 7.2153
z = 0.3227ln + 0.5948lnG
L
b1
b2
1 = 1.8026
1 = 1.7558
z = 0.4405ln + 0.14981lnG
L
1 = 1.7474
0 = 6.4543
g L g LFE
g LFE
100. . . . . . . . . . . . . . . . . . . . . . . (27)
where g LFEthe hydraulic conductance calculated by the finiteelement model. The mean absolute relative errors of these approximations are 9.5, 9.8, 13.9, and 18.0% for BC-1, BC-2, BC-3,
and BC-4, respectively. The actual conductance is calculated with
Eq. 20.
The most widely used expressions for the hydraulic conductance of the sandwiched layers were derived by Zhou et al.18
257
= Ac2321 sin2
2cos32 1 cot1 3R2o3
32
2
tan,
2
sin
A c =
cos32 +
A w =
A3o321 sin2tan
A w
A
. . . . . (32)
= 12sin21 322cos32 12
1 =
b1
sin
b2 cos21 +
A o = A c A w. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (33)
, . . . . (30)
b1 cos32 +
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (31)
b2 cos21 +
R o =
258
+ 32 +
whereas the dark-color points belong to the Hui and Blunt approximation (Eq. 32) for nonzero O/W contact angles. The mean absolute relative errors of these approximations are 22.2, 24.1, 28.0,
and 64.9% for BC-1, BC-2, BC-3, and BC-4, respectively. Thus,
the projection-pursuit regression method gives results better than
the expressions proposed by Zhou et al. and Hui and Blunt.
Discussion
The hydraulic conductance of an intermediate layer of oil (see Fig.
1), sandwiched between the corner water and the central water or
gas, has a rather complex dependance on the combination of the
boundary conditions at both interfaces, the contact angles, 21 and
32, and the layer thickness at the wall, b2b1, that in turn depends
on the respective capillary pressures, the corner half-angle, , and
the contact angles. When a combination of the corner half-angle
and the contact angles causes the layer surfaces to be either concave or flat and concave (see Fig. 2), the layer hydraulic conductance is relatively high. When the inner surface of the layer becomes convex, 21 + > /2, the layer conductance rapidly decreases. The diminishing layer thickness at the wall, b2b1 0,
which corresponds to b2/b1 1, causes the layer conductance to
decrease exponentially, especially when both contact angles go to
zero and the corner half-angle increases (see Fig. 7), or when the
inner contact angle 12 goes to 180 (see Fig. 8). The components
of the independent variable z in Eq. 22 and their scaling followed
those in Ref. 15. In particular, the inverse of the layer thickness at
the wall b1/b2 enters z with the negative sign: The thinner the layer,
the more negative the logarithm of the hydraulic conductance.
The oil hydraulic conductance at low oil saturations is a complex function of the system geometry and rock wettability. Its
Conclusions
A numerical approach has been developed to obtain the hydraulic
conductance of an intermediate fluid layer sandwiched between
two other fluids. This approach has led to the simple and accurate correlations of the layer hydraulic conductance with the various layer geometry descriptors, and with four different boundary conditions:
1. Expressions for calculating the layer perimeter, area, shape
factor, and stability have been derived from the corner half-angle
, the interface contact angles 21 and 32, and the meniscus-apex
distances b1 and b2.
2. A standard finite-element method has been used to solve
numerically Poissons equation for creeping, isothermal flow in an
intermediate fluid layer formed in a corner of a polygonal capillary. Each flow domain was discretized with a mesh that followed
the shape of the capillary walls and the curvatures of the interfaces.
3. The layer hydraulic conductance has been calculated for four
sets of boundary conditions: BC-1 (no-slip water/oil interface and
no-slip oil/gas interface), BC-2 (no-slip water/oil interface and
perfect-slip oil/gas interface), BC-3 (perfect-slip water/oil interface and no-slip oil/gas interface), and BC-4 (perfect-slip water/oil
interface and perfect-slip oil/gas interface).
4. Simple comparison between the hydraulic conductance values for perfect-slip and no-slip boundary conditions indicates that
it might be essential to consider the momentum transfer boundary
condition that assumes continuity of velocity and shear stress
along the interfaces.
259
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