Material Safety Data Sheet

According to Regulation (EC) No. 1907/2006

Release: 2.0 (EU)
Date / Revised: Aug. 1, 2011
Date of Print: Aug. 1, 2011

Product Name: THANOX 168

MSDS Number: 1012EU

1. IDENTIFICATION OF THE SUBSTANCE/PRODUCT AND COMPANY/ENTERPRISE

Trade Name
Use
Producer/Supplier

THANOX 168
Stabilizer
Rianlon Chemical Co., Ltd.
No.6 Huangshan Road, TEDA Hangu Modern Industrial Park,
Tianjin 300480 China
Tel.: +86-22-83718817
Fax: +86-22-83718815

2. HAZARDS IDENTIFICATION
Classification of the substance
or mixture
Classification
(1272/2008/EC)
Classification
(67/548/EEC, 1999/45/EC)
Label elements
Labeling
(1272/2008/EC)
Other hazards

Not a hazardous substance or mixture

In accordance with EC directives or respective national laws, the product does
not need to be classified nor labeled.
Hazard statements: Not a hazardous substance or mixture
In case of occurrence of dust, risk of dust explosion.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical identification
CAS Number
EC-Number

Tris(2,4-di-tert-butylphenyl)phosphite
31570-04-4
250-709-6

4. FIRST AID MEASURES

Skin contact
Eye contact
Inhalation

Ingestion

MSDS of THANOX 168(EU)

Wash off with soap and plenty of water. Do not use organic solvents.
Rinse immediately with plenty of water for at least 15 minutes. In case of eye
irritation, seek medical attention.
Move to fresh air. In case of irritation of respiratory system or mucous
membranes, seek medical attention. In case of indisposition, seek medical
attention. In case of prolonged exposure, seek medical attention.
Immediately give plenty (> 500 ml) of water (if possible charcoal slurry). In case
of spontaneous vomiting be sure that vomitus can freely drain due to danger of

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Material Safety Data Sheet

According to Regulation (EC) No. 1907/2006

Release: 2.0 (EU)
Date / Revised: Aug. 1, 2011
Date of Print: Aug. 1, 2011

Product Name: THANOX 168

MSDS Number: 1012EU

suffocation. Give water repeatedly. Artificial induction of vomiting should be

restricted to first aid staff. Give nothing by mouth in cases of unconsciousness or
convulsion. Seek medical advice.
5. FIRE-FIGHTING MEASURES
Measures Suitable extinguishing
media
Extinguishing media which must
not be used for safety reasons
Exposure hazards

Special protective equipment for

firefighters
Combustion products

Water spray, Carbon dioxide (CO2), Foam, Dry powder

High volume water jet
Contaminated water from fire hoses or sprinklers, etc., must be prevented from
draining into watercourses, sewers, or the ground water. Sufficient measures must
be taken to retain water used for extinguishing. Contaminated water and soil must
be disposed of in conformity with local regulations.
Wear full protective clothing. Wear self-contained breathing apparatus.
Oxides of carbon; Oxides of phosphorus; Toxic gases/vapors.

6.ACCIDENTAL RELEASE MEASURES

Personal precautions
Environmental precautions
Methods for cleaning up

Do not breathe vapors/dust. Remove all sources of ignition. Avoid contact with
skin, eyes and clothing.
Do not flush into surface water, sanitary sewer or ground water system.
Use mechanical handling equipment. Collect the spilled product into suitable
containers, which must be tightly sealed and properly labelled. Avoid dust
formation.

7. HANDLING AND STORAGE

Handle and open container with care. Avoid dust formation and ignition sources.
Ensure good local exhaust ventilation. Do not eat, drink or smoke at the
workplace.
Keep away from food and drink. Store in the original container securely closed.
Storage
Caution, keep this product well sealed. Keep in cool, dry place. Close containers immediately after use.
Danger! Explosion risk. Risk of explosion if an air-dust mixture forms. Avoid creating dusty conditions. Empty only
into earthed containers. If container is larger than 2000 liter in volume, or when flammable solvents are present inert
container or use a system otherwise designed to prevent or contain an explosion --seek expert advice.
Handling

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

MSDS of THANOX 168(EU)

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Material Safety Data Sheet

According to Regulation (EC) No. 1907/2006

Release: 2.0 (EU)
Date / Revised: Aug. 1, 2011
Date of Print: Aug. 1, 2011

Product Name: THANOX 168

MSDS Number: 1012EU

Protection Exposure limit(s)

Technical measures/Precautions
Respiratory protection
Hand protection
Eye protection
Skin and body protection

8h TWA: 10.0 mg/m3. Exposure limit for inhalable dust.

Technical measures/Precautions
Effective dust mask.
Protective gloves
Suitable goggles or face protection
Working clothes , Closed footwear

9. PHYSICAL AND CHEMICAL PROPERTIE

Form
Color
Odor
Melting/freezing temperature
Boiling point/range
Relative density 20 C

pH value:(1%, 20-25 )

powder
white
odorless
183 - 187 C
not applicable
1.03 g/cm3
6

Flash point
Flammability
Ignition Temperature
Oxidizing properties
Self-ignition temperature

> 150 C
Not tested
not tested
not tested

Water solubility 20 C
Vapor pressure 20 C
Partition coefficient; Log Pow 20

< 0.005 mg/l

1.3E-8 Pa
>6

DIN 51584
BAM

380
EEC A 6
calculated

- 25 C

pH-value 1 % suspension in water 20

-25 C

Kinematic viscosity
Explosive properties
Evaporation rate
Vapor density

not tested
not tested
not tested
not tested

10. STABILITY AND REACTIVITY

Decomposition temperature
Conditions to avoid
Materials to avoid
Hazardous decomposition
products

MSDS of THANOX 168(EU)

> 350 C
Static discharges.
Strong acids, strong bases and strong oxidising agents.
No hazardous decomposition products known.

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Material Safety Data Sheet

According to Regulation (EC) No. 1907/2006

Release: 2.0 (EU)
Date / Revised: Aug. 1, 2011
Date of Print: Aug. 1, 2011

Product Name: THANOX 168

MSDS Number: 1012EU
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity:
rat/LD50:
Acute dermal toxicity:
rat/LD50:
Acute inhalation toxicity:
Not tested
Skin irritation/corrosion:
rabbit
Eye irritation/corrosion:
rabbit
Skin Sensitization:
guinea pig

> 6000 mg/kg

> 2000 mg/kg

OECD Guideline 402

non-irritant
non-irritant
Non-sensitizing.

12. ECOLOGICAL INFORMATION

Toxicity to fish:
Fish general (Pisces)/96 h/LC50:
> 100 mg/l
OECD 203/EC C.1
No effects at the highest tested concentration. The tested concentration is well above its water solubility
Toxicity to aquatic invertebrates:
Daphnia magna/24 h/EC50:
=510 mg/l
OECD 202
Toxicity to aquatic plants:
Scenedesmus sp./72 h/EC50:
> 75.2 mg/l
Guideline 92/69/EEC, C.3
No effects at the highest tested concentration. The tested concentration is well above its water solubility
Toxicity to microorganisms:
activated sludge/3 h/IC50:
> 100 mg/l
OECD 209
Biodegradation:
Not readily biodegradable.
OECD 301B
Bioaccumulation:
BCF
< 17
Additional remarks environmental fate and pathway:
Do not discharge product uncontrolled into the environment.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused
products
Contaminated packaging

MSDS of THANOX 168(EU)

Residual chemical should be disposed by incineration or by other modes of

disposal in compliance with local legislation.
Contaminated packaging material should be treated equivalent to residual

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Material Safety Data Sheet

According to Regulation (EC) No. 1907/2006

Release: 2.0 (EU)
Date / Revised: Aug. 1, 2011
Date of Print: Aug. 1, 2011

Product Name: THANOX 168

MSDS Number: 1012EU

chemical. Clean packaging material should be subjected to waste management

schemes (recovery recycling, reuse) according to local legislation.
14. TRANSPORT INFORMATION
Flash point
ADR/RID
IMO
ICAO

> 150 C
Class: Free
Class: Free
Class: Free

15. REGULATORY INFORMATION

Classification of the substance
or mixture
Classification
(1272/2008/EC)
Classification
(67/548/EEC, 1999/45/EC)
Label elements
Labeling
(1272/2008/EC)
Other hazards

Not a hazardous substance or mixture

In accordance with EC directives or respective national laws, the product does
not need to be classified nor labeled.
Hazard statements: Not a hazardous substance or mixture
In case of occurrence of dust, risk of dust explosion.

16. OTHER INFORMATION

THANOX is a registered trademark.
SVHC
All the ingredients in this product do not contain SVHCs. (Updated on 20/06/2011)
RoHS
The product meets the requirements of the guideline 2002/95/EC (RoHS) and its amendments.
Important
This information only concerns the above mentioned product and not be valid if used with other product(s) or any process.
The information is to our best present knowledge correct and complete and is given in good faith but without warranty. It
remains the users own responsibility to make sure that the information is appropriate and complete.

MSDS of THANOX 168(EU)

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