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This article is about the material. For the song by Amer- 1 Terminology
ican industrial metal band Fear Factory, see Genexus (album).
While the term insulator implies low electrical conducNot to be confused with Dielectric constant or Dialectic. tion, dielectric typically means materials with a high
A dielectric material (dielectric for short) is an electri- polarizability. The latter is expressed by a number called
the relative permittivity (also known in older texts as dielectric constant). The term insulator is generally used to
indicate electrical obstruction while the term dielectric is
-+ -+
used to indicate the energy storing capacity of the mate-+ -+
rial (by means of polarization). A common example of
-+ -+
a dielectric is the electrically insulating material between
-+ -+
the metallic plates of a capacitor. The polarization of the
-+ -+
dielectric by the applied electric eld increases the capac-+ -+
-+ -+
itors surface charge for the given electric eld strength.[1]
-+ -+
dielectric
The term "dielectric" was coined by William Whewell
-+ -+
-+ -+
(from "dia-electric) in response to a request from
-+ -+
Michael Faraday.[3][4] A perfect dielectric is a material
-+ -+
with zero electrical conductivity (cf. perfect conduc-+ -+
tor),[5] thus exhibiting only a displacement current; there-+ -+
fore it stores and returns electrical energy as if it were an
-+ -+
-+ -+
ideal capacitor.
-+ -+
-+ -+
-+ -+
Charge
+Q
-Q
Electric
field E
Plate
area A
2 Electric susceptibility
Plate separation d
DIELECTRIC POLARIZATION
e = 0.
The electric displacement D is related to the polarization
density P by
E
d
D = 0 E + P = 0 (1 + e )E = r 0 E.
2.1
+q
M -q
P() = 0 e ()E().
Note the simple frequency dependence of the susceptibility, or equivalently the permittivity. The shape of the
susceptibility with respect to frequency characterizes the
dispersion properties of the material.
Moreover, the fact that the polarization can only depend
on the electric eld at previous times (i.e., e(t) = 0 for
t < 0, a consequence of causality, imposes Kramers
Kronig constraints on the real and imaginary parts of the
susceptibility e().
3
3.1
Dielectric polarization
Basic atomic model
In the classical approach to the dielectric model, a material is made up of atoms. Each atom consists of a cloud
of negative charge (electrons) bound to and surrounding
a positive point charge at its center. In the presence of an
electric eld the charge cloud is distorted, as shown in the
top right of the gure.
M = F(E)
When both the type of electric eld and the type of material have been dened, one then chooses the simplest
function F that correctly predicts the phenomena of inThis can be reduced to a simple dipole using the terest. Examples of phenomena that can be so modeled
superposition principle. A dipole is characterized by its include:
3
Refractive index
Group velocity dispersion
Birefringence
Self-focusing
Harmonic generation
3.2
Dipolar polarization
Dipolar polarization is a polarization that is either inherent to polar molecules (orientation polarization), or
can be induced in any molecule in which the asymmetric distortion of the nuclei is possible (distortion polarization). Orientation polarization results from a permanent dipole, e.g., that arising from the 104.45 angle between the asymmetric bonds between oxygen and hydrogen atoms in the water molecule, which retains polarization in the absence of an external electric eld. The assembly of these dipoles forms a macroscopic polarization.
4 Dielectric dispersion
In physics, dielectric dispersion is the dependence of the
permittivity of a dielectric material on the frequency of
an applied electric eld. Because there is a lag between
changes in polarization and changes in the electric eld,
the permittivity of the dielectric is a complicated function
of frequency of the electric eld. Dielectric dispersion is
very important for the applications of dielectric materials
and for the analysis of polarization systems.
3.3
Ionic polarization
TUNABILITY
5.1
Debye relaxation
Paraelectricity has been explored as a possible refrigeration mechanism; polarizing a paraelectric by applying an electric eld under adiabatic process conditions
raises the temperature, while removing the eld lowers
() = +
,
the temperature.[8] A heat pump that operates by polariz1 + i
ing the paraelectric, allowing it to return to ambient temwhere is the permittivity at the high frequency limit, perature (by dissipating the extra heat), bringing it into
= s where s is the static, low frequency per- contact with the object to be cooled, and nally depolarmittivity, and is the characteristic relaxation time of the izing it, would result in refrigeration.
medium.
This relaxation model was introduced by and named after
the physicist Peter Debye (1913).[6]
5.2
7 Tunability
Tunable dielectrics are insulators whose ability to store
electrical charge changes when a voltage is applied.[9][10]
ColeCole equation
8.2
Dielectric resonator
3 have a paraelectricferroelectric transition just below From this, it can easily be seen that a larger leads to
ambient temperature, providing high tunability. Such greater charge stored and thus greater capacitance.
lms suer signicant losses arising from defects.
Dielectric materials used for capacitors are also chosen
such that they are resistant to ionization. This allows the
capacitor to operate at higher voltages before the insu8 Applications
lating dielectric ionizes and begins to allow undesirable
current.
8.1
Capacitors
Charge
+Q
Electric
field E
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-+
-Q
dielectric
Plate
area A
Plate separation d
Solid dielectrics are perhaps the most commonly used diCharge separation in a parallel-plate capacitor causes an internal electrics in electrical engineering, and many solids are
electric eld. A dielectric (orange) reduces the eld and increases very good insulators. Some examples include porcelain,
glass, and most plastics. Air, nitrogen and sulfur hexthe capacitance.
auoride are the three most commonly used gaseous disolid dielectric material with high permittivity as the in- electrics.
tervening medium between the stored positive and negative charges. This material is often referred to in technical
Industrial coatings such as parylene provide a dieleccontexts as the capacitor dielectric.[13]
tric barrier between the substrate and its environment.
The most obvious advantage to using such a dielectric
material is that it prevents the conducting plates, on which
the charges are stored, from coming into direct electrical
contact. More signicantly, however, a high permittivity
allows a greater stored charge at a given voltage. This can
be seen by treating the case of a linear dielectric with permittivity and thickness d between two conducting plates
with uniform charge density . In this case the charge
density is given by
V
d
c=
=
V
d
11
may retain excess internal charge or frozen in polarization. Electrets have a semipermanent electric
eld, and are the electrostatic equivalent to magnets. Electrets have numerous practical applications
in the home and industry.
Some dielectrics can generate a potential dierence
when subjected to mechanical stress, or (equivalently) change physical shape if an external voltage is
applied across the material. This property is called
piezoelectricity. Piezoelectric materials are another
class of very useful dielectrics.
Some ionic crystals and polymer dielectrics exhibit a
spontaneous dipole moment, which can be reversed
by an externally applied electric eld. This behavior is called the ferroelectric eect. These materials are analogous to the way ferromagnetic materials
behave within an externally applied magnetic eld.
Ferroelectric materials often have very high dielectric constants, making them quite useful for capacitors.
10
See also
REFERENCES
11 References
[1] Quote from Encyclopdia Britannica: "Dielectric, insulating material or a very poor conductor of electric current.
When dielectrics are placed in an electric eld, practically
no current ows in them because, unlike metals, they have
no loosely bound, or free, electrons that may drift through
the material.
Dielectrics (physics)". Britannica. 2009. p. 1.
Retrieved 2009-08-12.
[2] Arthur R. von Hippel, in his seminal work, Dielectric Materials and Applications, stated: "Dielectrics... are not a
narrow class of so-called insulators, but the broad expanse
of nonmetals considered from the standpoint of their interaction with electric, magnetic, or electromagnetic elds.
Thus we are concerned with gases as well as with liquids
and solids, and with the storage of electric and magnetic
energy as well as its dissipation. (Technology Press of
MIT and John Wiley, NY, 1954).
[3] J. Daintith (1994). Biographical Encyclopedia of Scientists. CRC Press. p. 943. ISBN 0-7503-0287-9.
[4] James, Frank A.J.L., editor. The Correspondence of
Michael Faraday, Volume 3, 18411848, Letter 1798,
William Whewell to Faraday, p. 442.. The Institution
of Electrical Engineers, London, United Kingdom, 1996.
ISBN 0-86341-250-5
[5] Microwave Engineering - R. S. Rao (Prof.). Retrieved
2013-11-08.
[6] P. Debye (1913), Ver. Deut. Phys. Gesell. 15, 777;
reprinted 1954 in collected papers of Peter J.W. Debye
Interscience, New York
[7] Chiang, Y. et al.: Physical Ceramics, John Wiley & Sons
1997, New York
[8] Kuhn, U.; Lty, F. (1965). Paraelectric heating and cooling with OH--dipoles in alkali halides. Solid State Communications 3 (2): 31. Bibcode:1965SSCom...3...31K.
doi:10.1016/0038-1098(65)90060-8.
[9] Self-correcting crystal may lead to the next generation of advanced communications. KurzweilAI.
doi:10.1038/nature12582. Retrieved 2013-11-08.
[10] Lee, C. H.; Orlo, N. D.; Birol, T.; Zhu, Y.; Goian,
V.; Rocas, E.; Haislmaier, R.; Vlahos, E.; Mundy,
J. A.; Kourkoutis, L. F.; Nie, Y.; Biegalski, M. D.;
Zhang, J.; Bernhagen, M.; Benedek, N. A.; Kim, Y.;
Brock, J. D.; Uecker, R.; Xi, X. X.; Gopalan, V.;
Nuzhnyy, D.; Kamba, S.; Muller, D. A.; Takeuchi,
I.; Booth, J. C.; Fennie, C. J.; Schlom, D. G.
(2013). Exploiting dimensionality and defect mitigation to create tunable microwave dielectrics. Nature
502 (7472): 532536. Bibcode:2013Natur.502..532L.
doi:10.1038/nature12582. PMID 24132232.
[11] Electrically tunable dielectric materials and strategies to improve their performances.
Progress
in Materials Science 55: 840893.
2010-11-30.
doi:10.1016/j.pmatsci.2010.04.004. Retrieved 2013-1108.
[12] Giere, A.; Zheng, Y.; Maune, H.; Sazegar, M.; Paul, F.;
Zhou, X.; Binder, J. R.; Muller, S.; Jakoby, R. (2008).
Tunable dielectrics for microwave applications. 2008
17th IEEE International Symposium on the Applications of
Ferroelectrics. p. 1. doi:10.1109/ISAF.2008.4693753.
ISBN 978-1-4244-2744-4.
[13] Mussig & Hans-Joachim, Semiconductor capacitor with
praseodymium oxide as dielectric, U.S. Patent 7,113,388
published 2003-11-06, issued 2004-10-18, assigned to
IHP GmbH- Innovations for High Performance Microelectronics/Institute Fur Innovative Mikroelektronik
12
Further reading
13
External links
14
14
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