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Training Program
Auxiliary Boiler 12 Ton/Hr , 12 Barg
By. PT Basuki Pratama Engineering
Items of Training
I.
II.
III.
IV.
V.
VI.
Preface
Utilizing Equipments
System Description
Operation Sequence
Maintenance
Boiler Operation Water Treatment
PREFACE
: 12 Ton/Hr , 12 Barg
: 12 Barg / 9 Barg
: 89 % (min)
: Diesel Oil
: 812 Kg/Hr
Capacity (max)
Driving Motor
Control
Regulation
: 812 Kg/Hr
: 26 KW
: Fully Automatic
: Fully Automatic
: 10,000 Kg/Hr
: 260 oC
: 8 Barg
: 12 Barg / 300 oC
: 18 Barg
: 12,000 Liter/Hr
: 132 M
: 11 KW
: 0.13 Barg
: 1 Barg
: 12,000 Ltr
: 12 M3/Hr
: Dia 1900 x 4200 S/S
: Dia 650 x 1400 S/S
: 25,000 Liter
: Dia 2500 x 5000 S/S
: Atmospheric
: Atmospheric
: Pulsatron LPD3S2-365
Max. Capacity
Working Pressure
Voltage
C/W Storage Tank
Tank Contents
Material
C/W Mixer
Type
Motor Rating
: 1.9 Ltr/Hr
: 17 Barg
: 230VAC 50 Hz / 0.5A 1 Phase
: 650 Liter
: Polyethylene
: MIX6/2 EMEC
: 110 W
: Pulsatron LPF4S2-365
Max. Capacity
Working Pressure
Voltage
C/W Storage Tank
Tank Contents
Material
C/W Mixer
Type
Motor Rating
: 3.2 Ltr/Hr
: 17 Barg
: 230VAC 50 Hz / 0.5A 1 Phase
: 650 Liter
: Polyethylene
: MIX6/2 EMEC
: 110 W
10QHH01BB101
DAILY FUEL TANK
10QHF01BB001
BLOW DOWN TANK
10QLB11AC001
SUPERHEATER
10QLB11BB901
CONDENSATE POT
10QUA03AC001,10QUA03AC002
10QUA03AC003
SAMPLE COOLER
10QHH01AV101
DIESEL OIL BURNER
10QHA01AC101
STEAM BOILER BHS-12000-LO
10QLA11AP101/102
FEED WATER PUMP
10QHN01BV101
CHIMNEY
10QLA11AC101&10QLA11BB101
FEED WATER TANK WITH DEAERATOR
10QLA11BB901
CONDENSATE POT
10QLF11AP201
FWT DOSING DEVICE
10QLF11AP101
BOILER DOSING DEVICE
10
11
Logic Diagram
Feed Water Tank
FIELD INPUTS
CONTROL SWITCHES
LOGIC
BY PASS LEVEL
INDICATOR
10QLA11CL01QN
LIS 144
L5
FIELD OUTPUT
DRY RUN
FEED PUMP
H10
AUDIBLE
ALARM
BS
NAND
DISTURBANCE
L4
NAND
HW ALARM
FW TANK
H11
L1
WATER HIGH
BS
DISTURBANCE
NAND
L2
AUDIBLE
ALARM
SOLENOID VALVE #1
ON
NAND
L13
S7
AND
1
AUTO
OR
SOLENOID VALVE 1
OPEN
10QLA11 AA002
FCV 159
S
R
MANUAL
SOLENOID VALVE 1
WILL CLOSE WHEN
LEVEL REACH L2
OFF
L3
L4
NAND
SOLENOID VALVE #2
NAND
ON
S8
L14
AND
2
AUTO
OR
MANUAL
S
R
SOLENOID VALVE 2
OPEN
10QLA11 AA007
FCV 161
SOLENOID VALVE 2
WILL CLOSE WHEN
LEVEL REACH L3
OFF
12
Instrument
L2
L3
System Description
Water inlet valve can operate manually and automatically with selector switch
water tank valve in control panel. Auto status, valve operate depend on level
switch. If water level :
Above L1; valve1 & valve2 close, alarm FWT high, digital input FWT on, and
disturbance indicator FWT high ON.
Below L5; valve1 & valve2 open, alarm FWT low, FWP off, digital input FWT
low, disturbance indicator FWT ON.
L4
Pressure switch
L5
By-pass level
indicator
If pressure feed water tank below setting (set=0.1 bar), pressure switch signal
to digital input feed water tank pressure to low
Solenoid valve
Logic Diagram
Dosing System
FIELD INPUTS
CONTROL SWITCHES
LOGIC
FIELD OUTPUT
Solenoid Valve
Service Water Inlet
FCV 159
DOSING PUMP 2
AUTO/OFF/MANUAL
S2
DOSING PUMP 2
ON
FCV 161
L2
OR
AND
AUTO
OR
MANUAL
S
R
DOSING PUMP 2
START
10QLF11 AP201
HV 177
OFF
13
Dosing pump :
Supply hydrazine and amine from feed water tank
dosing to feed water tank
Mixer pump :
Mix hydrazine and amine in feed water tank dosing
System Description
Dosing device can operate manually and
automatically with selector switch dosing pump2 in
control panel. Auto status, dosing device operate
depend on solenoid valve1 water inlet feed water
tank.
Dosing pump
Mixer
14
Logic Diagram
Daily Fuel Tank
FIELD INPUTS
CONTROL SWITCHES
LOGIC
BY PASS LEVEL
INDICATOR
10QHH01
L1
L2
FIELD OUTPUT
OIL LEVEL
HIGH
OIL HIGH
L16
AND
OIL LEVEL
L3
LOW
L17
L4
INTERLOCK
TO BURNER
(OFF BURNER)
OIL LOW
S9
L15
AND
LCV 239
AUTO
OR
MANUAL
S
R
10QHH01
AA002
SOLENOID VALVE
OIL INLET
OFF
L1
L2
Instrument
L3
L4
L5
System Description
Fuel oil inlet valve can operate manually and automatically with selector switch oil
inlet valve in control panel. Auto status, valve operation depends on level switch. If
oil level :
Above L1; valve close, digital input fuel oil tank level high on, and indicator oil to
high on.
Below L4; valve open, indicator oil to low on, alarm oil tank to low, burner off
(manual ON)
Below L5; valve open, digital input fuel oil tank level to low on
By-pass level
indicator
Solenoid valve
15
Oil Measurement
Instrument
Oil totalizer :
Display water totalizer in control panel
Recorder :
Record oil flow in control panel.
Recorder
System Description
Flow meter signal to oil totalizer, oil flow rate, oil flow recorder, and
auxiliary analog output (4-20mA) fuel firing rate (terminal X3 74;75).
Flow rate
Totalizer
16
System Description
Temperature sensor signal to temperature display for saturated steam
temperature.
Sensor PT 100
Temperature Display
Logic Diagram
Blow out
FIELD INPUTS
CONTROL SWITCHES
LOGIC
FIELD OUTPUT
S12
SELECTOR
OPEN
OFF
10QLB11
AA903
SERVO MOTOR
CLOSE
BLOW OUT
10QLB11AA903
10QLB11
CF01
FT
137
FT 137 BUILT IN
PRESS. TRANSMITTER
FOR TEMP.
COMPENSATION
BLOW OUT
I
SET POINT=2 Bar
Press. After
Super Heater
START
PID CONTROL
Controller Burner
17
Instrument
Steam display
and controller
System Description
Flow meter signal to steam totalizer, steam display controller, and steam
flow recorder in control panel. Blow out valve can operate manually and
automatically with selector switch blow out in control panel. Auto status,
valve open (blow out steam) if pressure super heater not reach (set = 2
bar) and burner not OK.
Actuator valve
Valve
Logic Diagram
Super Heater
FIELD INPUTS
CONTROL SWITCHES
LOGIC
FIELD OUTPUT
P
TE
211
260C
I
D
SET POINT
10QLB11
CP01QB
PT
207
PRESSURE
FLOW
10QLB11
CF01
FT
137
10QLB11
AA008
SERVO MOTOR
SUPER HEATER FLAP
18
Super heater
Instrument
Actuator damper
super heater
Sensor PT 100
System Description
Temperature sensor signal to temperature super heater display in control panel
and auxiliary analog output (4-20mA) super heater steam temperature (terminal
X3 76;77).
Damper operate regulation if flow steam reach 960 kg/h and pressure > 7.7 bar.
If temperature 280C digital input super heater temp. high on.
If temperature 300C disturbance indicator super heater temp. to high on
Pressure Transmitter :
Pressure Transmitter are used to measure pressures in liquids
and gases. The pressure is converted into an electrical signal
Pressure Transmitter
System Description
Valve saturated steam out operate with selector switch main
steam valve in control panel ( open-close valve ).
if pressure reach 8 bar in pressure display control panel operator
can operate this switch.
Valve
Actuator steam out
19
Logic Diagram
Blow Down Tank
FIELD INPUTS
CONTROL SWITCHES
LOGIC
FIELD OUTPUT
TEMPERATURE CONTROL
10QHF01
TIC231
10QHF01
CT01
TE
232
ON
TEMPERATURE HIGH
OFF
SET POINT= 50 C
SET POINT
BLOWDOWN TANK
ON
S3
BLOWDOWN TANK
AUTO/OFF/MANUAL
L3
AND
AUTO
OR
MANUAL
10QHG01
AA002
SOLENOID VALVE
COOLING WATER IN
OPEN
OFF
20
System Description
Service water inlet valve can operate manually and automatically
with selector switch blow down tank valve in control panel. Auto status, valve
operation depends on setting temperature (set = 50C). If temperature over
setting valve open and conversely.
if temperature increase (>60C), digital input blow down tank discharge
temperature high on.
Sensor PT 100
Solenoid valve
21
Instrument
System Description
Controller turn actuates the rapid action blow down valve by
means of compressed air and closes it again at end of the
pulse (blow down) duration. The blow down intervals can be
adjusted.
Schematic layout
Sightglass
Logic Diagram
Surface Blow Down
FIELD INPUTS
CONTROL SWITCHES
10QHA01
CT01QP
CE
124
ELECTRODE
CONDUCTANCE
SWITCH
DESALTING ON/OFF
LOGIC
FIELD OUTPUT
DESALTING
REGULATOR AND
CONDUCTIVITY
LIMITER
LKER 1
OPERATION
10QHA01
BT001
10QHA01
AA005
SERVO MOTOR
DESALTING VALVE
22
Instrument
Conductivity
electrode
System Description
Surface blow down can operate manually and automatically with
selector switch blow down valve in control panel.
Automatic system work depends on value setting. If condensate
boiler over setting value, valve open and operate conversely
Logic Diagram
Boiler Water Level Control
FIELD INPUTS
CONTROL SWITCHES
LOGIC
FIELD OUTPUT
HIGH WATER
LEVEL
10QHA01
CL05QN
L7
LEHH
103
HIGH WATER
ELECTRODE
10QHA01
CL04QN
AUDIBLE
ALARM
BS
LOW WATER
LEVEL
L6
10QHA01
LELL
104
ELECTRODE
10QHA01
CL07QN
LT
106
CONTINUOUS WATER
LEVEL PROBE
10QHA01
AA026
MOTORIZED VAVE
SERVO MOTOR
10QHA01
CL08QN
10QHA01
AA026
AND
AND
ZS
SWITCH OFF DELAY
MIN. POSITION SWITCH
SERVO DRIVE
EXTRA LOW
WATER LEVEL
10QHA01
CL06QN
LELL
105
ELECTRODE
L8
WATER LEVEL
CONTROL
NRS 1-7b
AUDIBLE
ALARM
BS
BOILER
10QHA01
23
boiler level :
Indicator level boiler in control panel
Control valve
Sensor
Controller
LT 106
NRR 22e
Valve
LCV 184
Actuator valve
Indicator lamp
Valve
Level boiler
24
If pressure boiler over pressure switch regulation setting (9.5 bar); burner interlock
(auto operate), pressure high indicator panel on, display fault in panel, and digital
input steam pressure high on.
If pressure boiler over pressure switch limiter setting (10 bar); burner interlock
(manual operate), pressure high indicator panel on, digital input steam pressure to
high on
Pressure switch
Pressure limiter
Logic Diagram
Operation Burner
FIELD INPUTS
CONTROL SWITCHES
LOGIC
AUTOMATIC
BURNER
CONTROLLER
LAL 2.25
BURNER START/
FAILURE RESET
10QHA01
CP03QN
PSHL
110
FIELD OUTPUT
BURNER
ON
L21
10QHH01
DPOO1
* MANUAL RESET ON
PRESSURE SWITCH
AND
DISTURBANCES
PRESSURE BOILER
NOT HIGH
10QHH01
AV101
WATER LEVEL
EXTRA LOW
BLOWER MOTOR
AND
S13
COMPOUND REGULATOR
SERVO MOTOR
START PID
BURNER CONTROL
CONTROLLER
AUTO
DECREASE
S
10QHH01
AV101
STEADY
INCREASE
OFF
10QHH01
AV101
10QHH01
CR001
FLAME SENSOR
IGNITION TRANSFORMER
FLAME INTENSITY
25
Logic Diagram
Control Damper Burner
FIELD INPUTS
CONTROL SWITCHES
LOGIC
FIELD OUTPUT
PT
207
PRESSURE
TRANSMITTER
D
SET POINT= 8.5 Bar
SET POINT
10QHA01
AV101
COMPOUND REGULATOR
SERVO MOTOR
COMPOUND
REGULATOR
POSITION
Burner controller
START CONTROLLER
START
PID CONTROL
CONTROLLER IN MANUAL MODE
OPEN/STOP/CLOSED
Burner Controller
System Description
Burner off if one of this condition happens : Boiler pressure too high,
boiler extra low, and oil low level and must start again.
Burner
26
FIELDINPUTS
CONTROL SWITCHES
L OGI C
FWP1
DOSINGPUMP1
AUTO/OFF/MANUAL
S1
LAMPINDICATORS(LCP)
DOSINGPUMP1
ON
FWP2
L1
OR
AND
AUTO
OR
MANUAL
FIELDOUTPUT
S
R
DOSINGPUMP1
START
10QLF11 AP101
HV177
OFF
27
Dosing pump :
Supply phosphate from boiler dosing to feed water
tank
Mixer pump :
Mix phosphate in boiler dosing
Dosing pump
System Description
Dosing device can operate manually and
automatically with selector switch dosing pump2 in
control panel. Auto status, dosing device operation
depends on solenoid valve1 water inlet feed water
tank.
Mixer
Logic Diagram
Feed Water Pump Operation
FIELD INPUTS
CONTROL SWITCHES
LOGIC
FIELD OUTPUT
F.W PUMP 1
OPERATION
S5
SELECTOR FEED WATER
AUTO/OFF/MANUAL
L9
F.W. PUMP 1
AND
AND
AND
OR
OR
F.W. PUMP 1
10QLA11 AP101
AND
AUTO
MANUAL
OFF
S6
SELECTOR FEED WATER
PUMP1/OFF/ PUMP2
OR
F.W PUMP 2
OPERATION
PUMP 1
L10
F.W. PUMP 2
PUMP 2
OR
AND
OR
OFF
4
F.W. PUMP 2
10QLA11 AP102
DEAERATOR
LEVEL NOT LOW
BOILER
LEVEL NOT HIGH
AND
AND
AND
AND
PUMP 1 TRIP
PUMP 2 TRIP
28
Instrument
Pressure Indicator
System Description
Temperature sensor signal to temperature display for flue gas
temperature.
Sensor PT 100
Temperature Display
29
Water totalizer :
Display water totalizer in control panel
Recorder :
Record water flow in control panel.
Recorder
System Description
Flow meter signal to water totalizer, water flow rate, and water flow
recorder.
Totalizer
Flow rate
30
Control Panel
31
Disturbance indicator
1. Emergency switch
2. High water level
3. Burner Disturbance
4. Extra low level
5. Over load F.W.P 1
6. Over load F.W.P 2
7. Over load burner
8. Steam pressure high
9. S.H steam temperature to high
10. Feed water tank low
11. Feed water tank high
V. Maintenance
32
Prior to start up of the installation and when each shift commences, the operating personnel (boilerman) must convince themselves of
the installations proper operating condition.
B.
The function of the water level limiters must be checked daily and at the start of each shift, unless they are self monitoring,i.e. specialdesign, devices. External devices must be blown out
Temperature and pressure limiters need not be checked daily. The intervals for these units depend on their nature-refer to weekly
checks and servicing.
The time intervals for checking safety valves must be agreed by the operator and technical expert considering the service life of the
sealing faces, daily checking is not recommended.
Blowing out
Water level indicators and external feed water controllers and limiters must be blown out, attention being paid to the necessary
operating sequence for shut-off and blown out valves.
Checks of all fire systems
f.1. Keep the fire chamber free from residues and coke sediment
f.2. Smoke-free combustion
f.3. Correct oil temperature when using heavy fuel oil
f.4. Suitable oil pressure
Checks to be carried out when using heavy fuel oil
g.1. Gas pressure
Water analysis
Refer to the operating log book and the water directives
Note
Pay attention to the operating instructions issued by the supplier of the water treatment plant. Devices or checking the feed water
generally do not suffice for checking the boiler water. Please enquire in cases of doubt.
Boiler blow down
Check sealing points and lock them and, if necessary, retighten them and renew the packings
Important note
If controllers are rendered inactive by malfunction, the installation must be observed continuously if its operation is continued. If safety
devices should fail, please inform our Customer Service and, if necessary, shut down the installation and inform the installer for the
installation of BASUKI representative in your area, or directly to us (refer to our contact address & phone/fax numbers)
C.
D.
E.
F.
G.
H.
I.
J.
K.
33
Semi-annual Checks
Controllers and safety devices must be serviced and
checked by a technically competent person after every
period of 6 months. We recommend our customer
service for this purpose.
34
35
36
37
Source of corrosion :
Dissolved gas: oxygen,
carbon dioxide, and ammonia.
Oxygen is the most aggressive.
Cause pitting corrosion
38
Reaction :
Waterside Deposition
Boiler deposits result from hardness salts, metallic oxides, silica and a number
of other feed water contaminants that can enter the system.
Minimizing the adverse impact of these contaminants is the role of the boiler
water treatment program.
Even the best controlled systems occasionally have upsets that cause
excessive amounts of contamination to pass into the boiler. Some examples
would be:
39
Mechanism of Deposition
Reaction:
10Ca2+ + 6PO43- + 2OH- 3Ca3(PO4)2Ca(OH)2 Calcium hydroxyapatite
3Mg2- + 2SiO32- + 2OH- + H2O 2MgSiO3Mg(OH)2H2O Serpentine
Formula
Acmite
Na2OFe2O34SiO2
Analcite
Na2OAl2O34SiO22H2O
Anhydrite
CaSO4
Aragonite
CaCO3
Brucite
Mg(OH)2
Calcite
CaCO3
Cancrin
4Na2OCaO4Al2O32CO29SiO23H2O
Hematite
Fe2O3
Hydroxyapatite
Ca10(OH)2(PO4)6
Magnetite
Fe3O4
Noselite
4Na2O3Al2O36SiO2SO4
Pectolite
Na2O4CaO6SiO2H2O
Alpha-Quartz
SiO2
Serpentine
3MgO2SiO22H2O
Thenardite
Na2SO4
Wallastonite
CaSiO3
Xonotlite
5CaO5SiO2H2O
40
Embrittlement
Caustic embrittlement or
intercrystalline cracking
Catastrophic results
Causes:
1. Leakage of boiler water
2. Concentrated caustic soda occurs from the concentrated boiler
water.
3. There is high metal stress in the area of caustic concentration and
leakage.
External Treatment
Applied to water prepared for use as boiler feed water, refers to the
chemical and mechanical treatment of the water source.
Internal Treatment
41
Minimize hardness
Ex : Calcium and Magnesium, migratory iron, migratory copper, colloidal
silica, consistent with boiler design and operation parameters.
Objectives :
To remove oxygen, carbon dioxide and other non-condensable gases
from feed water
To heat the incoming makeup water and return condensate to an optimum
temperature
Minimizing solubility of the undesirable gases
Providing the highest temperature water for injection to the boiler, from
ambient temperature to 103 C to prevent boiler from thermal shock
42
Remedy
1. Insufficient venting-increase vent rate by opening the manually operated air vent valve.
2. Check steam pressure reducing valve. Check valve for free operation, and see that
control line is connected to the connection provided in the deaerator.
3. Check water and, if possible, steam flow rates vs. design. Trays or scrubber and inlet
valves are designed for specific flow ranges.
1. Improper spray from spray nozzle. Check nozzle for sediment or deposit on seat or
broken spring.
2. Excessive free air due to leaking stuffing boxes on pumps upstream of deaerator that
have negative suction head. Repair stuffing box or seal with deaerated water.
1. Trays collapsed-possibly from interrupted steam supply or sudden supply of cold water
causing a vacuum.
Excessive consumption of
oxygen scavenger
2. Condensate may be too hot. Water entering the deaerating heater must usually be
cooled if the temperature is within 20 F of saturation temperature of the steam.
Check the design specification to determine what inlet water temperature was originally
intended.
1. Improper operation of inlet control valve. Adjust as necessary.
2. Check faulty operation of steam pressure reducing valve.
3. Check relief valves on the deaerator and in the main steam supply system for proper
operation.
1. Check for improper operation of steam pressure reducing valve.
43
9
10
11
12
14
approximate pH
365 36.5
3.6
0.36
ppm HCl
40
4
0.4
400
4 000
40 000
200 000
ppm NaOH
Mineral Carryover
Definition:
Carryover is generally considered to be any
contaminant that leaves a boiler steam drum with
the steam.
Causes:
Mechanical Factor: Priming (sudden pressure
while load rises)
Chemical Factor: Foaming (by alkalinity, organic
and synthetics contaminant), Selective vaporous
carryover
Effects:
1.
Deposition in regulators and valving
2.
Deposition in superheaters
3.
Deposition in control valves and turbines
4.
Process contamination
44
Caustic Corrosion
Characteristics :
Localized corrosion
45
Hydrazine
Magnetite build up
N2H4 + 6Fe2O3 4Fe3O4 + N2 + H2O
REAKSI HYDRAZINE
Oxygen scavenging,
N2H4 + O2 N2 + 2 H2O
Stochiometric reaction,
dosage of 35 % solution 8.6 ppm/1 ppm residual
oxygen
Poisonous,
LD50 rating class 5 toxin 82 mg/kg
46
Neutralizing Amines
Function:
To neutralize the carbon dioxide and then provide small
additional amounts to buffer the pH to 8.5 or 9.5.
WATER SPECIMENT
47
3. Boiler Water
Spec. Conductivity:
Silica
:
pH
:
Phosphate
:
4. Steam
Spec. Conductivity: < 5.0 us/cm at 25 deg.C
Silica
: < 0.02 ppm SiO2
pH
: 8.5 ~ 9.5
Iron
: <0.02 ppm Fe
% Blow down :
Concentration of dissolved solids in Feed water =
Concentration of dissolved solids in blowdown
Quantity of blow down/Feed water
% Make up :
Concentration of dissolved solids in Feed water =
Concentration of dissolved solids in Make-up water
Quantity of makeup/ Feed water
48
CR = 1/%blowdown x 100 =
Concentration dissolved solids of blowdown
Concentration dissolved solids of Feed water
Feed water = Make up + Condensate
Feed water = Boiler Capacity + Blow down
Boiler Water
Spec. conductivity : > 150 uscm
Silica:
: > 2 ppm SiO2
pH:
: > 10.5
Method
1. Wet conservation binds the oxygen of the water held in the boiler.
oxygen binding agents are: Hydrazine & Sodium sulphite
2.
Dry conservation ensures that no moisture remains in the boiler effectively preventing
corrosion of the steel
49
N2H4
N2H4.H2O 24%
g/m3
g/m3
20 - 30
50 100
100- 350
150 - 450
140-210
350 700
700 - 2000
1000 - 3000
50
Na2SO3 92%
g /m3
200-300
450 900
900 - 3000
1500 - 5000
51
Purpose
Testing for excess of oxygen binding agent in the case if wet conservation
i.
Hydrazine measurement
Hydrazine forms in an acid solution with p-dimethylaminobenzaldehyde, depending on
concentration, a yellow to red colored quinoid compound for color comparison
Reagents
Sulphuric 2% p-dimethylaminobenzaldehyde solution Colour comparison ampoules
(Both available from Farbenfabriken Bayer AG, Leverkusen, Germany, or their agents)
Procedure
1. The water sample to be tested for hydrazine content must first be cooled to < 40C
(sampling is best carried out with a cooling agreement). The boiler water may first have to
be filtered.
2. 5 ml of this water sample is filled up to the first calibration mark into the empty ampoule, 5
ml hydrazine reagent is filled in to reach the second calibration mark, and then shaken
twice. The test liquid will turn yellow. Now the reference ampoule or color comparison
sheet nearest to this color shade is determined. The value shown on this ampoule or the
sheet indicates the hydrazine (N2H4) content in kg/l of the water sample.
3. If the test liquid shows yellow color shades which are not covered by the comparison
scale, the N2H4 content is situated above 1 mg/l. These values, too, can be determined
more accurately by first diluting 1 ml of the water to be tested with 99 ml cold tap water,
mixing 5 ml of this diluted water with 5 ml reagent and comparing against the color scale.
The value found must then depending on the dilution used be multiplied by 100.
4. The reagent must always be stored in a dark and cool place. Storage life approximately 1
year (see use-by date printed on the label). The effectiveness of the reagent solution can
be verified at any time by mixing 5 ml tap water with 5 ml reagent, after which there must
be, no coloration exceeding the zero value of the color scale.
52
Reagents
Phosphoric acid D.1.14 (25%)
0.01 standard iodine solution (Store in a cool place in a brown bottle)
Starch solution, approx. 1%
Instruments
300 ml Erlenmeyer flask
10 ml graduated pipette
20 ml burette, 0.1 ml graduation
Procedure
1. 100 ml of the sample, cooled to room temperature and filtered clear is filled into a 300
ml Erlenmeyer flask and acidified with 3 ml phosphoric acid (reagent a)
2. After that, add approx. 0.5 to 1 ml of the starch solution (reagent c)
3. Using a burette, 0.01 standard iodine solutions (reagent b) is now added until the
sample turns blue.
4. 1 ml 0.01 standard iodine solution corresponds when using 100 ml sample solution to
approx. 6.3 mg/l sodium sulphite (Na2SO3)
Quick test
Small test sticks can be used for a quick determination of the sulphite content (e.g.
Sulphite Test made by Fa.Merck)
53
Purpose
Alkaline boiling is carried out to removal of oils, fat and silica in newly installed
boilers, and drying the heat insulating material of boilers.
Applicable Item
Auxiliary Boiler BHS-12000-LO
: 1 unit
: 1 unit
: 4 pair
: 4 pair
: 1 unit
Consumable Material
Sodium hydroxide
Sodium Phosphate
Sodium Sulfite
100 kg
200 kg
60 kg
Application
1.
Fill the demineralized water to the Feed Water Tank approximate of volume (6 m3)
Fill the phosphate dosing tank with 500 liter Demineralized Water.
Transfer the mixing solution to Feed Water Tank by Hand Transfer pump. Measured
the pH of the solution in the feed water tank. The pH of the feed water tank < 11.5
but higher than 10.5
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Turn on The feed water pump to transfer the solution to the boiler
Now the solution in the boiler will be approximate of volume of the Boiler.
While maintain the temperature or pressure, prepare the solution as per point
6.
After the boiler temperature is about 70 C than slowly drained the solution
up to solution level of the boiler while take the solution sample for
analyzing than feeding the new solution to the boiler. The concentration of
the cleaning agents while draining & feeding must not fall below of the
initial level.
7.
After the boiler water have been drained approximate the volume of the
boiler, or the Feed Water Tank have transfer the solution approximate 12 m3,
than closed the drained valve, repeat the point j to full fill the boiler with the
solution again.
8.
9.
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THE END
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