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Enthalpy changes
DCP and CE
Aim: determining the enthalpy change for the single displacement reaction
between zinc and copper sulphate.
Zn(s) +CuSO 4 (aq) Cu(s )+ ZnSO 4
Material required:
1.
2.
3.
4.
Beaker
Thermometer
Zinc
Copper sulphate
DCP:
Important calculations:
1. Mass of Zinc:
a. Moles:
1.2 0.01 g
1.2
=0.018
65
Temperature ( 0.1)
Trial 1
25.5
25.2
25.1
25.2
25.2
Trial 2
25.2
25.2
25.1
25.1
25.2
Trial 3
25.4
25.3
25.2
25.2
25.2
27.9
28.3
28.6
28.8
28.9
27.6
27.9
28.4
28.6
28.9
27.8
27.9
28.3
28.7
29.0
300
330
360
390
420
450
480
510
540
570
600
29.2
29.3
29.4
29.1
29.0
28.8
28.7
28.6
28.4
28.1
27.9
29.1
29.3
29.3
29.2
29.2
29.1
28.9
28.7
28.6
28.4
28.2
29.3
29.5
29.6
29.4
29.2
28.9
28.8
28.7
28.5
28.4
28.3
30
60
90
120
150
180
210
Temperature
( 0.1)
mean
25.5
25.2
25.4
25.4
25.2
25.2
25.2
25.3
25.1
25.1
25.1
25.2
25.2
25.1
25.2
25.2
25.2
25.2
25.2
25.2
Zinc added
27.9
27.6
27.8
27.8
28.3
27.9
28.0
27.9
28.6
28.4
Precision
Standar
Rang
d
e
deviatio
n
Accuracy
error
Error
%
0.3
0.15
0.039
0.1
0.06
0.040
0.1
0.06
0.1
0.06
0.040
0.00
0.040
0.3
0.15
0.036
0.4
0.23
0.036
0.3
0.15
0.035
0.1
0.040
240
270
300
330
360
390
420
450
480
510
540
570
600
28.4
28.3
28.8
28.6
28.7
28.9
28.9
29.0
29.2
29.1
29.3
29.3
29.3
29.5
29.4
29.3
29.6
29.1
29.2
29.4
29.0
29.2
29.2
28.8
29.1
28.9
28.7
28.9
28.8
28.6
28.7
28.7
28.4
28.6
28.5
28.1
28.4
28.4
27.9
28.2
28.3
28.7
0.2
0.10
0.035
28.9
0.1
0.06
0.035
29.2
0.2
0.10
0.034
29.4
0.2
0.12
0.034
29.4
0.3
0.15
0.034
29.2
0.3
0.15
0.034
29.1
0.2
0.12
0.034
28.9
0.3
0.15
0.035
28.8
0.2
0.10
0.035
28.7
0.1
0.06
0.035
28.5
0.2
0.10
0.035
28.3
0.3
0.17
0.035
28.1
0.4
0.21
0.036
Graphical Representation:
I used the best fit line and extrapolation to estimate the change in temperature
after adding zinc in a situation where no heat is lost. The gradient shows the rate, at
which the temperature decreases.
5.34
To calculate the enthalpy change, I have used the following formula:
Enthalpy change=( mass of water specific heat capacity temperature change )
mass of water =volume of copper sulphate solution
Temperaturechange=5.34
50 5.34 4.2=1121.4 J
1121 . 4
1
=112140 Jmo l
0.010
112.14 kJmol
CE
Conclusion:
1
Evaluation:
Possible errors and their improvements:
1.
Thermometer was looked at from different angles and therefore readings may
have been unreliable the error of parallax. This weakness could have
introduced systematic error to the temperature measurements.
Make sure that your eyes are perpendicular to the scale while taking readings
2. Some heat was lost to the surroundings and therefore measured temperature
values would not be accurate. This probably contributed the most to the
experimental error and therefore would be the biggest weakness of this
experiment.
3. Measurement of 50 ml of copper sulphate had some uncertainty because of
meniscus measurement uncertainty.