Prof.

Anand Yadavs Chemistry Private Tuitions

Chap: Soln and Colligative
1.

The number of moles of NaCl in 1000 ml of 3 molal solution is

a) One
b) Two
c) Three
d) none

2.

The molal freezing point constant for water is 1.86oC/M. The freezing point of 0.1M NaCl
solution is expected to be
a) -0.372oC
b) -0.732oC
c) 0.186oC
d) -0.186oC

3.

The vant Hoff factor of Ca(NO3)2 is

a) 1
b) 2

c) 3

d)5

4.

Which of the following pairs of solutions can be expected to be isotonic at the same
temperature?
a) 0.1M Ca (NO3)2 and 0.1M Na2SO4
b) 0.1M urea and 0.2M MgCl2
c) 0.1M urea and 0.1M NaCl
d) 0.1M NaCl and 0.1M Na2SO4

5.

If 20g of NaOH is dissolved in 1 dm3 of water, molality of the solution will be

a) 0.5
b) 1
c) 0.001
d) 0.005

6.

At the boiling point of the solution at 1 atm pressure, if the partial vapour pressure of the
solute is 60 mm, then that of solvent is
a) 60 mm
b) 700 mm
c) 820 mm
d) unpredictable

7.

Which one of the following statements is true for a solution?

a) Normality is always equal to molarity
b) Normality is always less than molarity
c) Molarity is always less than normality
d) Molarity is either equal to or less than normality

8.

The freezing point of the liquid is the temperature at which the vapour pressure becomes
a) less than that of its own solid
b) more than that of its own solid
c) equal to of its own solid
d) equal to that of ice

9.

Osmosis is the flow, through semipermeable membrane of

a) solvent molecules from pure solvent to solution
b) solvent molecules from solution of lower conc. to that of higher concentration.
c) solute molecules from a solution of higher conc. to that of lower concentration.
d) both a & b

10. Solution A contains 5.85g of NaCl in 500 cm3 of water & solution B is 0.2 M glucose in water.
Temperature being same, which one of the following is true?
a) Both the solution are isotonic
b) A is hypertonic w.r.t. B
c) B is hypertonic w.r.t. A
d) A is hypertonic w.r.t. B

11. The vapour pressure of the solvent is 80 mm. on adding a non volatile solute its drops to 60
mm. The mole fraction of the solute in the solution is
a) 0.25
b) 0.75
c) 0.6
d) 0.8
12. A 5 % solution of glucose is isotonic with a 1 % solution of solute A. The molecular weight of
A is
a) 900
b) 180
c) 36
d) 90
13. Which of the following happens, in case of solution, when the mole fraction of a solute in the
solution decreases?
a) V.P. increases
b) F.pt. increases
c) O.P. increases
d) both a&b
14. Which one of the following solution has highest normality?
a)1 M HCl
b) 0.5 M H2SO4
c) 0.4 M H3PO4

d) 0.55 M H2SO4

15. The three solutions containing 10 g of glucose and 10 g of sucrose in equal volumes have
osmotic pressures of P1, P2 and P3 respectively. Which one of the following is correct in these
cases
a) P2 > P1 >P3
b) P2 > P3 > P1
c) P1> P2 >P3
d) P3 > P1 > P2
16. The boiling points of liquid A,B,C and D are 800C, 650C, 1840C and 2120C respectively. The
order of the V.P. at room temperature is
a) D >C >A >B
b) B >A >C >D
c) A >B >C >D
d) D >C >B >A
17. Vapour pressure of the pure solvent is defined as the ratio of the lowering pressure in a
solution to the
a) mole fraction of the solute
b) mole fraction of the solvent
c) molality of the solution
d) molarity of the solution
18. the increase in boiling point of a solution of 10g of solute mol. wt. 100) in 100g water is Tb, \
the molal elevation constant of water is
a) 10
b) 10 Tb
c) Tb
d) Tb/10
19. 1000g of a 4% salt solution contains
a) 4g salt
b) 4 moles of salt

c) 40g solvent

d) 40g salt

20. Which of the following exhibit the maximum freezing point lowering?
a) 0.1 mol kg-1 KCl
b) 0.1 mol kg-1 MgCl2
c) 0.1 mol kg-1 (COOH)2
d) 0.1 mol kg-1 C12H22O11
21. Abnormal osmotic pressure is result of
a) very low temperature
b) polar solvent

c) low solubility d) association

22. 6.023 1020 molecules of a non electrolyte are present in 10 cm3 of a solution. Molarity of the
solution is
a) 0.1M
b) 0.001 M
c) 0.05 M
d) 0.00005 M

23. Osmotic pressure of a sugar solution at 298 K is 2.5 atm. Concentration of the solution in g/ lit
is
a) 351.07
b) 3.51
c) 35.1
d) 70
24. The sum of mole fractions of the components of a binary solution is always equal to
a) 100%
b) unity
c) 0.1
d) less than one
25. Amalgam is an example of _______ type of the solution?
a) Na in kerosene
b) Na in mercury
c) Na in water

d) Na in alcohol

26. The relative lowering of V.P. of a solution of 6g. of urea in 108 g of water would be equal to
a) 0.164
b) 0.18
c) 0.33
d) 0.0164
27. In a solution if the lowering of V.P. is 1/20th of the vapour pressure of pure solvent. The mole
fraction of the solute
a) 0.95
b) 0.05
c) 0.5
d) 0.9
28. The freezing point of a solution containing 0.1 mole of glucose in 250g of water would be
[Kf = 1.88o]
a) -0.752 oC
b) -0.188 oC
c) 0.752 oC
d) 0.188 oC
29. If 1 is the osmotic pressure of a solution containing 6g of acetic acid per dm3 & 2 is that of a
solution containing 5.85g of NaCl dm-3 at the same temperature, then
a) 1 < 2
b) 1 > 2
c) 1 = 2
d) 2 1 = 2
30. At 27oC the solution of sucrose has osmotic pressure of 2.46 atoms hence the strength of the
solution is
a) 1M
b) 10 M
c) 0.1M
d) 2 M