Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
DISSIMILAR
METALS
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MIL-STD-BBqB
CHG
NOTICE 3
NOT MEASUREMENT
SENSITIVE
MIL-STD-889B
NOTICE 3 (USAF)
17 May 1993
MILITARY STANDARD
DISSIMILAR METALS
TO ALL IIOLDERS OF MIL-STD-889B:
1. THE FOLLOWING PAGES OF MIL-STD-889B HAVE BEEN REVISED AND
SUPERSEDE THE PAGES LISTED:
DATEPAGENEW
SUPERSEDED
DATEPAGE
November
1979
21
May 17
1993
REPRINTED
WITHOUT
CHANGE
1976 7 July
3. Holders of MIL-STD-889B will verify that page changes and additionsindicated above have
been entered. This notice page will be retained as a check sheet. T h s issuance, together with
appended pages, isa separate publication. Each notice isto be retained by stocking points until
the military standard is completely revised or cancelled.
Custodians:
Air Force - 11
Preparing activity:
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Review activities:
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AMSC:
DISTRIBUTION STATEMENT A. Approved for public release; distributionis unlimited.
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r=
MIL-STD-889B N O T I C E I G D
m 7779933 0035273 8 m
MIL-STD-889B
NOTICE 1
21 November 1979
MILITARY
STANDARD
DISSIMILAR
TO
ALL
HOLDERS
OF
METALS
MIL-STD-889B:
NEW
7 July
1976
(REPRINT
WITHOUT
CHANGE.)
21 November 1979
21 November 1979
7 July
1976
(REPRINT
WITHOUT
CHANGE)
21 November 1979
21 November 1979
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5
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2.
7
7
7
7
7
7
2
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5
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July
July
July
July
July
July
1976
1976
1976
1976
1976
1976
.Custodians:
Army - MX
Navy - AS
Air Force- 11
Preparing activity:
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Review activities:
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Navy
EC, OS
Air Force - 13, 17, 99
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3.
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DEPARTMENT OF DEFENSE
MIL-STD-889B
7 July 1976
CONTENTS
Paragraph l.
1.1
1.1.1
2.
2.1
3.
4.
5.
5.1
5.2
TABLES
Appendix
A.
Recommendedtreatmentsinorder
effectiveness- - - - - B. What is involved in galvanic corrosion-
of protective
--------
iii
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10
17
MIL-STD-889A
2 2 September 1969
MILITARY STANDARD
DISSIMILAR
1.
METALS
SCOPE.
2.
mFERENCED DOCUMENTS.
SPECIFICATIONS
MILITARY
MIL-S-8802
FSC MFFP
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3.
DEFINITIONS.
3.1 Dissimilar metals. This standard terms metals dissimilar when two
or otherwise electrically connected to
metal specimens are in contact
each other in a conductive solution and generate
an electric current.
DETAILED REQUIREMENTS.
Minimizing dissimilar metal corrosion.
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flI-STD-&BqB
CHG N O T I C E 3
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5.1.2 Table II list metals in the order of their relative activity in sea water environment.
The list begins with the more active (anodic) metal and procedes down to the least active
(cathodic) metalof the galvanic series. A galvanic series appliesto a particular
is expected to be encountered
electrolyte solution; hence for each specific solution which
for actual use, a different order or series will ensue. Galvanic series relationships are
useful as a guide for selecting metalsto be joined, will help the selectionof metals
having minimal tendencyto interact galvanically, or will indicate the needor degree of
protection to be appliedto lessen the expected potential interactions. Generally, the
closer one metal is to another
in the series, the more compatible they will be,
i.e., the
galvanic effects will be minimal; conversely, the farther one
metal.is from another, the
greater will be the effect. In a galvanic couple, the metal higher in the series represents
the anode, andw
i
l
l corrode preferentially in the environment.
5.1.3 Metals widely separated in the galvanic series mustbe protected if they are to be
joined. Appropriate measures should be taken to avoid contact. This can be
a
accomplished by applymg to the cathodic membera sacrificial metal coating having
potential similar to or near thatof the anodic member;by sealing to insure that the faying
surfaces are water-tight;by painting or coating all surfaces to increase the resistance
of
electrical circuit.
5.1.4 A small anodic area relative to the cathodic area should be avoided. The same
metal or more noble (cathodic) metals should be utilized for small fasteners, and bolts.
The larger is the relative anode area, the lower the galvanic current density on
the anode,
the lesser the attack.The galvanic corrosion effectmay be considered as inverse to the
anode-cathode area ratio.
3
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MIL-STD-887B
CHG N O T I C E 3
7
-I
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MIL-STD-889B
2 1 November 1 9 7 9
TABLE II. Galvanic series of selected metals in Seawater. " -
Active (Anodic)
Magnesium (Mg)
Mg Alloy 'AZ-31B
Alloy
MG
HK-31A
Zinc (hot-dip, die cast
or plated)
Beryllium (hot pressed)
Aluminum (Al) 7072 cl. on 7075
Al alloy 2014-T3
Al alloy 1160-Hl4
Al alloy 7079-T6
Cadmium (plated)
Uranium
Al alloy 218 (die cast)
Al alloy 5052-0
Al alloy 5052-H12
Al alloy 5456-0, H353
Al alloy 5052-H32
Al alloy 1100-0
Al alloy 3003-H25
A l . alloy 6061-T6
cast)
Al a.lloy A360 (die
Al alloy 7075-T6
Al alloy 1160-Hl4
Al alloy 6061-0
Indium
Al alloy 2014-0
Al alloy 2024-T4
Al alloy 5052-Hl6
Tin (plated)
Stainless steel 430 (active)
Lead
Steel 1010
Iron, cast
Stainless steel410 (active)
Copper (plated, castor wrought)
Supersedes page5 of 7 July 1976
5
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MIL-STD-889B
21 November 1979
MIL-STD-889B
7 J u l y 1976
a c i d o r a l k a l i n e materials ( n e u t r a l pH), and f r e e o f c a r b o n o r
metallic
particles,notsubjecttobiodeteriorationor
w i l l notsupportfungal
water, t h e n t h e s e may b e c o n s i d e r e d
growth,anddonotabsorborwick
n o n - m e t a l l i c ss u i t a b l ef o rj o i n i n g
t o metals. Many materials c l a s s e d
n o n - m e t a l l i c will i n i t i a t e c o r r o s i o n of metals t o whichthey are j o i n e d ,
e.g.,cellulosicreinforcedplastics,carbonor
metal l o a d e d r e s i n
materials, asbestos-cementcomposites.
5.1.7
Where magnesium i s o n eo ft h e
metals i n v o l v e d i n t h e d i s s i m i l a r
metal c o m b i n a t i o n o r w h e r e s t a i n l e s s
s t e e l i s used i n c o n t a c t w i t h
i t s e l f , i t i s r e q u i r e d t h a t the edges of t h e j o i n t b e a d e q u a t e l y s e a l e d
t o p r e v e n t excess g a l v a n i c o r crevice a t t a c k . Where i t is n o tr e q u i r e d
t h a t t h e material b e e l e c t r i c a l l y c o n t a c t e d , t h e n
a n o n - m e t a l l i ci n s u l a t i n g g a s k e t i n g material may be used.
5.1.8 I ft h ee n v i r o n m e n tt ow h i c ht h ec o u p l e
i s t ob ee x p o s e d
is highly
a g g r e s s i v e , i t i s a d v i s a b l e t o employ maximum p r o t e c t i v e m e a s u r e s , o t h e r wise some compromise i n the p r o t e c t i v e s y s t e m c o u l d b e a l l o w e d . I n a n y
e v e n t , n:aximum p r o t e c t i v e s y s t e m s a l w a y s s h o u l d b e e m p l o y e d
when magnesium i s one of t h e metals i n v o l v e d , w h e t h e r o r n o t t h e c o m b i n a t i o n
is t o serve i n a n e l e c t r i c a l conducting system:.
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5 . 2P r e c a u t i o n sa n dm e t h o d sf o rj o i n i n g .
Where i t becomes n e c e s s a r y
thatrelativelyincompatible
metals m u s tb ea s s e m b l e d ,t h ef o l l o w i n g
are p r o v i d e d f o r a l l e v i a t i o n o f g a l v a n i c
precautionsandjoiningmethods
corrosion.
I GD W 7 7 7 7 7 I I 0 0 3 5 3 0 0 5 W !
f l I L - S T D - B B 7 BN O T I C E
~~~
MIL-STD-889B
7 July 1976
c.
6.
APPENDICES.
6.1 Appendix A.
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PROJECT NUMBER:
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MFFP-0113
MIL-STD-889B
7 July 1976
APPENDIX A
RECOMMENDED
TREATMENTS
IN
ORDER
OF
PROTECTIVE
EFFECTIVENESS
10. GENERAL
10.1 Scope. This appendix lists protective systems for each metal or
alloy with optimum treatments listed first, and others in descending
order of preference.
10.2 Application. Each listing is presented as a guide only each
application must be reviewed considering service conditions, design
requirements and maintenance costs,
20, REFERENCE DOCUMENTS
SPECIFICATIONS
FEDERAL
QQ-P-416
TT-C-490
MILITARY
And-
Aluminum
Alloys
MIL-C-8514
Pretreatment,
Compound,
Coating
Netal
Resin-acid {Asg)
'
MIL-A-8625
Anodic
Coatings,
Aluminum
And
For
Aluminum
Alloys
MIL-C-8837
Deposited)
(Vacuum
Coating,
Cadmium
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MIL-"3171
Magnesium
Alloy,
Anodic
Treatment
of
MIL-C-5541
Chemical
Conversion
Aluminum
Coatings
On
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-I-
11
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+ paint
+ paint
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plating.
b. Netallic coating, e.g., sacrificialZn or Cd, with supplemental
surface treatment, or non-sacrificial, e.g., Cu or Ni, without paint
coating system, for direct metallic contact or for achieving least potential difference between joined metals. For metals of strengths greater
than 220 ksi, metallic coating, if required, to be applied by non-electrolytic methods; zinc or cadmium prohibited.
d.
system.
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. chromium
a. Apply metallic coating as may be required to minimize electrical potential difference between the metalsbe to
joined and apply
to diminish ibn contamination
paint or resin coating system, primarily
from metals of this group onto more anodic metals to which they might
be joined, thereby diminishing potential damage to the more anodic metal.
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15
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s e r v i c e i s e l e c t r i c a l ,o ra p p l yc o n f o
b . May be used b a r e i n e l e c t r
s e r v i c ec, o n d i t i o n ps e r m i t t i n gS. e a l
16
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APPENDIX B
GENERAL
10.1 S c o p e T
. h i sa p p e n d i xe x p l a i n st h ep r i n c i p a lf a c t o r st h a t
a r ei n v o l v e di nt h e
phenomenon o f g a l v a n i c c o r r o s i o n .
10.2 Application.Thisappendix
contractually binding.
20.
i s t u t o r i a lo n l y
and i s n o t
REFERENCED
DOCUMENTS
Not A p p l i c a b l e .
30.
GENERAL REQUIREMENTS
30.1 F a c t o r si n f l u e n c i n gg a l v a n i cc o r r o s i o n S
. e v e r a lf a c t o r s
i n f l u e n c et h ek i n e t i c s
of g a l v a n i cc o r r o s i o n .
Among t h e s ea r e
thepolarizationbehaviorofthemetalsundertheprevailing
c o n d i t i o n s ;t h e areas of t h e a n o d ea n dc a t h o d e ;t h ee l e c t r i c a l
r e s i s t a n c e and c u r r e n t ; t h e t y p e
and c o n c e n t r a t i o n of t h e
e l e c t r o l y t e ; t h e pH of t h e e l e c t r o l y t e medium; t h ed e g r e eo f
a e r a t i o no rm o t i o n
of t h e e l e c t r o l y t e medium. B a s i cf a c t o r s
a r et h ee l e c t r i c a lp o t e n t i a l s
of t h e e l e c t r o d e s , c u r r e n t ,
and
r e s i s t a n c e s ,e x p r e s s e d by
where E, i s t h e p o t e n t i a l of t h ec a t h o d e (as p o l a r i z e d ) ; Ea t h e
Re t h e r e s i s t a n c e of t h e
p o t e n t i a l of t h ea n o d e( a sp o l a r i z e d ) ;
e l e c t r o l y t es o l u t i o np a t hi nt h eg a l v a n i cc i r c u i t( i n t e r n a l
c i r c u t t ) ; and R, the r e s i s t a n c e o f t h e e l e c t r o d e s ( e x t e r n a l
circuit).
17
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can
MIL-STD-889B
7 J u l y 1976
solutionpathin-thegalvaniccircuit(internalcircuit);and
r e s i s t a n c eo ft h ee l e c t r o d e s( e x t e r n a lc i r c u i t ) .
R,
the
30.2 Corrosiveenvironment.In
a l i q u i d medium o re l e c t r o l y t es o l u t i o n ,
a specifictemperatureof
of a g i v e n c o n c e n t r a t i o n o f t h e e l e c t r o l y t e , a n d
t h e medium, each metal h a s a s p e c i f i c e l e c t r i c a l p o t e n t i a l , i . e . , a b i l i t y
t o u n d e r g o d i s s o l u t i o n - t o f o r m metal i o n s w i t h t h e release o f e l e c t r o n s .
I n a verycorrosivesolution,havinghighconductivityandproducing
readily soluble corrosion products
of t h e metal, c o r r o s i o n will c o n t i n u e .
more probably w i l l
I n a l i m i t e d volume of solution, where conditions
d e v e l o p t o hamper c o r r o s i o n , e . g . , i n c r e a s e o f c o n c e n t r a t i o n o f
metal
i o n s ,t h ec o r r o s i o n
may d i m i n i s hw i t h time. On t h eo t h e rh a n d ,t h e
same metal as t h e a n o d e o f
a g a l v a n i c c o u p l e , w i l l t e n d t o e x h i b i t acceleratedcorrosion,whichcanberelatedto
a flowofcurrentinthe
c i r c u i t ,i ft h ec a t h o d e
i s u n a f f e c t e d by p o l a r i z a t i o n .I ft h ee l e c t r o d e s
polarizeprogressively,galvaniccurrentflowandcorrosion
w i l l subside
r a t e o fc o r r o s i o n w i l l d e c r e a s e
and may a c t u a l l ys t o p .G e n e r a l l y ,t h e
withhigherconcentrationsoftheelectrolyte,orwithlowertemperature.
G a l v a n i c e f f e c t s may change because of d i f f e r e n t pH c o n d i t i o n s w i t h i n
a ne l e c t r o l y t e .
A metal which i s t h e a n o d e i n
a neutraloracidicsolui s made b a s i c .
t i o n may become t h e c a t h o d e i f t h e s o l u t i o n
Oxygen d i s s o l v e d i n t h e e l e c t r o l y t e c a n d e p o l a r i z e t h e c a t h o d e
by
oxidizingabsorbedhydrogen.In
some cases, oxygen'may b en e c e s s a r yt o
rate of its
promoteoxidationoftheanode.Availableoxygenandthe
diffusion therefore can increase galvanic attack.
Ionswhich are g e n e r a t e d a t t h e e l e c t r o d e as c o r r o s i o n p r o c e e d s
c e n t r a t e a t o rn e a rt h ee l e c t r o d es u r f a c e s( p o l a r i z a t i o n )a n d
impede
cases, i n s t a t i c s o l u t i o n s ,t h ec o r c u r r e n tf l o w .F o re a c ho ft h e s e
r o s i o n a c t i o n i s diffusion-dependentand
is underdiffusion-control.
Agitation of the solution
w i l l i n c r e a s e t h e r e a c t i o n rate.
con-
3 0 . 3 C o n d u c t i v i t yo ft h eg a l v a n i cc i r c u i t . 'C o r r o s i o no f
a s i n g l e metal i n
anelectrolyteinvolvestheflow
of c u r r e n t f r o m l o c a l a n o d i c t o l o c a l
cath o d i c areas on t h e metal s u r f a c e .T h i s
is termed"local
c e l l corrosion"
and i s t h es i t u a t i o no fn o r m a lc o r r o s i o n ,R e l a t i v e l y
small d i f f e r e n c e s
i n p o t e n t i a l s of l o c a l c e l l s are t h e r e s u l t o f c o m p o s i t i o n a l d i s s i r p i l a r i - .
t i e s on t h e metal s u r f a c e b e c a u s e o f d i f f e r e n t
metal p h a s e s o r c r y s t a l
o r i e n t a t i o n ,c r y s t a li m p e r f e c t i o n ss e g r e g a t i o n s ,g r a i nb o u n d a r i e s ,a n d
o t h e rc o n d i t i o n s .
Themoreinhomogeneous
t h es u r f a c e ,t h e
moresuscept i b l e i t i s t og e n e r a la t t a c k .D i s s o l u t i o no ft h ea n o d e
relates t o t h e
galvaniccurrentaccordingtoFaraday's
law,
18
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MIL-STD-889B
7 J u l y1 9 7 6
shouldbespecifiedandmaintained
as c l o s e l y as p o s s i b l e .
TABLE I A
STANDARD
ELECTRODE
POTENTIALS
AQUEOUS
SOLUTION,
IM-RESPECTIVE METAL I O N , 25OC, AT EQUILIBRIUM
i
!Metal (High p u r i t y )
StandardElectrodePotential
'Magnesium2+
~Aluminum3+
:Zinc2+
i Chr omium3+
Iron'+
!Cadmium2+
';Tin2+
Lead2+
Hydrogen'
Copper2+
Silver+
/Mercury2+
Platinum'+
IGold'
(v)
'2.37
-1.67
-O. 76
-O. 7 4
'O. 44
'O. 40
'O. 1 4
'O. 13
0.00
+O. 34
+O. 80
'0. 85
+l.2
+l.69
30.5 P o l a r i z a t i o n , The p o l a r i z a t i o no fe l e c t r o d e si na ne l e c t r o l y t e
solution occurs because of
a f i l m of oxide or other
compound o r g a s on t h e
e l e c t r o d es u r f a c e s .T h e s ec h a n g e sr e d u c et h ep o t e n t i a ld i f f e r e n c e
relative t o t h e open c i r c u i t p o t e n t i a l s * 2 a n d l e s s e n t h e c o r r o s i o n
rate.
Suchchangesincreasetheresistanceoftheexternalcircuitanddiminish
currentflow;andintensifyordiminish
with g a l v a n i c c u r r e n t , o r w i t h
is a meansbywhich
a p p l i e dc u r r e n t .E l e c t r o d ep o l a r i z a t i o nb e h a v i o r
t h e c o m p a t i b i l f t y ofcoupleddissimilar
metals i n s o l u t i o n c a n b e
e s t a b l i s h e d .P o l a r i z a t i o nm e a s u r e m e n t sc a np r o v i d ei n f o r m a t i o n
as t o t h e
e f f e c t s of r e l a t i v e areas o f a n o d e a n d c a t h o d e a n d e f f e c t s o f c h a n g e s
i n p o t e n t i a l on t h e c o r r o s i o n .
Polarizationofgalvanicelectrodes
is i l l u s t r a t e d i n F i g u r e
When t h e a n o d e , c a t h o d e , o r b o t h p o l a r i z e , t h e c o n t r o l
i s anodic,
20
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1A.
f l I L - S T D - B A 7 BN O T I C E
L GD m 7 7 7 7 7 3 3 0 0 3 5 3 3 3 3 m
MIL-STD-889B
7 J u l y 1976
c a t h o d i c ,o rm i x e d ,r e s p e c t i v e l y .G a l v a n i cc o r r o s i o na n dc u r r e n tf l o w
are p o l a r i z a t i o n and r e s i s t a n c ec o n t r o l l e d .
When t h e e l e c t r o d e s do n o t
p o l a r i z e ,r e s i s t a n c eo ft h ec i r c u i t ,t h es o l u t i o np a t h
(R,) and t h e
metallic p o r t i o n (Rm) c o n t r o l t h e r e a c t i o n .
AL
AY3DIC
COl4TKOL
I-
z
W
I"
O
p.
RESlSTlHCE
MrXED
FIGURE 1A.
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$- c - -
Types of p o l a r i z a t i o na n dc o n t r o li ng a l v a n i cc o r r o s i o n .
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No reproduction or networking permitted without license from IHS
MIL-STD-889B
7 J u l y 1976
30.7 R e s i s t a n c ea n dg a l v a n i cc u r r e n t .I n
a p o l a r i z e dg a l v a n i c c i r c u i t ,
r e s i s t a n c e i s c o n t r i b u t e d by t h e p o r t i o n o f t h e e l e c t r o l y t e b e t w e e n t h e
(Re, i n t e r n a l p a t h ) and by t h e f i l m s o f r e a c t i o n p r o anodeandcathode
d u c t s formed on t h e e l e c t r o d e s u r f a c e s
(Rm, metallic path),whichimpede
i o ne x c h a n g ea n dr e d u c ec u r r e n tf l o w ,T h e r e f o r e ,t h et o t a lr e s i s t a n c e ,
R, of t h ec i r c u i t i s expressed as R =
4I nt h ep o l a r i z e ds y s t e m ,
as t h e r e s i s t a n c e i n c r e a s e s , t h e p o t e n t i a l s o f t h e a n o d e a n d c a t h o d e
a p p r o a c he a c ho t h e ru n t i l
a s t e a d y state r e a c t i o n i s a t t a i n e d . The limitingcurrentcorrespondswiththeintersection
of t h e p o l a r i z a t i o n c u r v e s .
T h i s is t h e maximum c u r r e n t o b t a i n a b l e i n t h e s y s t e m i f c o n s t a n t c o n d i t i o n s are maintained.
&.
cat-
30.9
22
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Provided by IHS
No reproduction or networking permitted without license from IHS
23
--`,```,,`,`````,``,`,`,```,,`,`-`-`,,`,,`,`,,`---
Provided by IHS
No reproduction or networking permitted without license from IHS