Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
55m-Short Cavity VCSELs for highspeed optical fiber telecommunication with stacked
active region
Diploma Thesis
Alexander Andrejew
December 2012
Contents
Abstract..
1. Introduction.
2. Theory..
10
2.3. Distributed-Bragg-Reflector......... 12
3. Design of High-Speed VCSELs......
19
19
21
24
26
31
39
44
46
54
6. Conclusion...
59
Acknowledgments.....
63
References.........
65
Appendix...
68
Abstract
Near-infrared, indium phosphide (InP) based, vertical-cavity surface emitting lasers
(VCSEL) with emission wavelength at 1.55m are excellent light sources for data transfer in the
telecom industry, especially they are very attractive for the upcoming Fiber-To-The-Home
applications and integration on Silicon. During this work single-mode VCSELs with emission
wavelength around 1.55m were fabricated. In these devices innovative stacked active regions
were used, the devices showed differential quantum efficiency of above 80% and a high output
power of around 4 mW (for 5m device). Additionally cutoff frequency of 12 GHz was
observed. For the devices with conventional single active region the record-high differential
quantum efficiency of around 60% and cutoff frequency of 15 GHz were observed.
1. Introduction
In the resent years the III\V-semiconductor based devices have become an essential part
of modern life. Such devices can be found in different applications ranging from everyday items,
such as CD\DVD-players, to highly sophisticated solar cells for space exploration. One type of
these devices is a semiconductor laser diode. After the introduction of the first semiconductor
laser diodes in 1962 their performance was greatly improved. The laser threshold current density
was reduced by almost a factor of four (see Figure 1.1), and also the excellent performance at
room temperature and beyond was achieved. These improvements made the usage of laser diodes
in different applications feasible, such as CD\DVD-players, laser pointers or beamers. In the
industry laser diodes are often used for material processing or as pump lasers for high power gas
lasers. Relatively new application for laser diodes is fiber-optic communication.
bandwidth up to some gigahertz, wireless LAN and satellite broadcasting operate at frequencies
up to 30 GHz; however a single optical fiber transmitting light in the range between 1.3 and 1.6
m can theoretically reach a bandwidth of around 43000 GHz. This makes the fiber-optic
communication the method of choice for the future data transfer. For the intercontinental
communication the fiber communication is already standard, many countries are also starting to
develop and introduce the fiber network to increase the bandwidth. The conventional optical fiber
consists of a core and cladding, due to a difference of refractive index (the core has a higher
refractive index as the cladding) total reflection occurs on the boundary between both and the
fiber acts as a waveguide. The material of choice for such fibers is silicon dioxide (SiO2) for both
the core and the cladding while core is being doped with Germanium, for example, to increase
the refractive index. The silicon dioxide is mainly used because it is a rather cheap material,
available in huge quantities; also the material data for SiO2 is well known and can be controlled
very precisely. However the usage of silicon dioxide puts some requirements on the wavelength
of the transmitted light, since an error-free transmission on a long distance is only possible, if the
light isnt absorbed by the fiber. According to the Figure 1.2a the minimum of absorption is at
1.55 m (the so called Third Window), which also became the standard wavelength for the longdistance telecommunication. The other important wavelength is 1.3 m (the Second Window),
where the second absorption minimum is situated and also the dispersion is equal zero for
standard single mode fiber (see Figure 1.2b).
b)
a)
Since both wavelengths are in near-infrared domain the most developed material system
based on gallium arsenide cant be used (see Figure 1.3), the indium phosphide (InP) based
devices on the other hand can easily cover the spectral range, necessary for fiber-optic
telecommunication, resulting in rapid development of InP-based material system. In fact today
this material system has a very well established technology, allowing the production of highly
sophisticated devices.
Figure 1.3: Band gap energy and lattice constant of various III/Vcompounds at room temperature (adopted from Tien, 1988).
One such device is vertical cavity surface emitting laser (VCSEL). Compared to an edgeemitting laser diode, the VCSEL is an inherently single-mode device, without any need of
gratings, which is an essential requirement for optical telecommunication. VCSELs also have low
threshold current, which is an important factor for energy saving. Also the testing of VCSELs is
much easier and cheaper compared to edge-emitting lasers, since on-wafer testing is possible.
Small dimensions of VCSELs on the other hand allow to process large numbers of devices on a
single wafer, reducing the production cost of a single device. These advantages make VCSEL the
perfect device for optical telecommunication.
Especially this is the case for the arising Fiber-To-The-Home application, where the aim
is to connect each household directly to the optical network. For that a large quantity of cheap
laser diodes is necessary, which makes high speed VCSELs with emission wavelength at 1.55 m
highly desirable. The other approach to reduce the price of the end device is the integration of
4
such devices with silicon-based electronics and waveguides, where low power consumption and
small size are more important than high output power, which can also be achieved by using
VCSELs. Another advantage of a VCSEL is a circular beam profile, which allows easier fiber
coupling compared to the edge emitting laser diodes, minimizing the coupling losses. These facts
make the development of such devices and improvement of their performance a very important
task for the optical semiconductor research.
The goal of this thesis was to develop high speed VCSELs with emission wavelength
around 1.55 m suitable for telecommunication purposes. During this work the innovative design
with stacked active regions was introduced for the first time. To investigate the performance of a
new design a reference sample was also processed for comparison. To compare both devices
emission wavelength, thermal performance, output power, laser threshold and high-frequency
behavior were measured; furthermore, internal parameters such as cutoff frequency, diffusion
broadening, differential quantum efficiency and wall-plug efficiency were extracted and
evaluated.
The outline of this thesis is as follows: In the 1st Chapter the motivation and the objectives
are introduced, the 2nd Chapter deals with basic laser physics, 3rd Chapter gives a brief overview
about the design of the devices and the 4th Chapter presents the device fabrication, finally in the
5th Chapter the device results are presented, followed by the conclusion in the 6th Chapter.
2. Theory
2.1.
Einstein Relations
The light emission in semiconductor takes place via the recombination of the electron
from conduction band with the hole from valence band, in the process a photon with the energy
equal to the band gap energy is emitted. This process is called spontaneous emission. The
counteracting process is called absorption, there a photon is absorbed by a valence electron and
this electron is stimulated to get to the conduction band (this is possible only if the photon energy
is equal or larger than band gap). Einstein however introduced a third possibility, namely
stimulated emission, where a photon is used to stimulate a recombination of a carrier pair and the
second photon identical to the incoming one is generated (a simplified model is shown in Figure
2.1). The stimulated emission is essential for semiconductor laser diodes, as it makes lasing
operation possible at all.
(2.1)
The occupation probability is given by the Fermi-Dirac distribution for indistinguishable particles
that obey the Pauli exclusion principle
(2.2)
where F1 is the quasi-Fermi level for the valence band at non-equilibrium. Similarly for
conduction band
(2.3)
(2.4)
where B21 is the transition probability, f2 the probability that E2 is occupied, [1 f1] the
probability E1 is empty, and P(E21) the photon density.
Additionally electrons can spontaneously relax from E1 to E2, the rate for this spontaneous
emission is
[
(2.5)
Assuming thermal equilibrium F2 = F1, and the rate of the upward transition must be
equal to the total rate of the downward transition:
(2.6)
Now using equations (2.1), (2.4), (2.5) and (2.6) the photon density can be described as
[
[
(2.7)
( )(
[
[
)]
]
(2.8)
where is the refractive index. Equating (2.7) and (2.8) and setting (2.2) and (2.3) in gives
(2.9)
and
(2.10)
For lasing it is necessary to have the stimulated emission and as the absorption and the
stimulated emission both need photons with energy E21, the rate of the stimulated emission must
exceed the rate of the absorption
(2.11)
[
(
]
(
(2.12)
)
(2.13)
(2.14)
The equation (2.14) means that the splitting of the Fermi levels must be larger than the
photon energy for lasing to occur and is called Bernard-Duraffourg condition.
2.2.
Optical Resonator
The simplest one-dimensional laser is that of an optical gain medium placed between two
highly reflective optical mirrors. This is the so-called Fabry-Prot laser shown schematically in
Figure 2.2 [3].
The necessary condition for lasing is that the optical field is exactly the same in amplitude
and phase after one cavity roundtrip. This so called oscillation condition is
(2.15)
with propagation constant, r2 and r1 field reflectance of the mirrors, L resonator length
(2.16)
(2.18)
mode gain,
internal loss. Now from the equation (2.15) the amplitude condition can be
derived:
(2.19)
(2.20)
The right hand side of this equation can be interpreted as mirror losses of both facets distributed
over the cavity length, which means
(2.21)
The phase condition is derived from the phase of the oscillation condition:
(2.22)
(2.23)
And the spacing between two modes is
(2.24)
where
(2.25)
As can be seen from equation (2.24) the mode spacing decreases with length, which is
also the main reason, why a VCSEL with an emission wavelength of 1.55 m and an effective
resonator length of around 5 m is inherently a single mode laser with mode spacing of about 60
nm.
11
2.3.
Essential parts of any laser are the mirrors. The easiest way to make such mirrors for
semiconductor laser diodes is used in edge-emitting lasers, where the cleaved facets of the
semiconductor material act as mirrors due to the difference in refractive index on the boundary
between air and semiconductor material. The reflectivity of such mirrors can be easily calculated
using the following formula
(
(2.26)
where n2 is the effective refractive index of the semiconductor material and n1 the refractive
index of the outer medium. Assuming the refractive index of the semiconductor n2 = 3.5, and for
air as outer medium (n1 = 1) the resulting reflectivity is around 0.3, this means that only 30% of
light are reflected and 70% are out coupled. In this case mirror losses are quite high; however by
increasing the resonator length by cleaving longer laser diodes one can decrease them (mirror
losses per resonator length unit) according to the equation (2.20). In reality the relative mirror
losses are not changing, but the gain volume increases and so is the gain, until it is high enough to
cover for the mirror losses. This approach is impossible for VCSELs, since a VCSEL has a
constant gain volume, which is equal to the volume of the active region, hence another approach
is used one increases the reflectivity of the mirrors. The common way to do this is to introduce
Distributed Bragg Reflectors, which in the case of VCSELs consist of a number of layers of two
alternating materials with different refractive indices.
indices of the semiconductor material, both mirror materials and the outer medium respectively,
12
denotes the resulting reflectivity of the DBR. The DBR takes advantage of the partial
reflections on the boundary between two materials with different refractive indices increasing the
resulting reflectivity with each pair. To describe such optical system it is useful to introduce the
so called two-port network (Figure 2.4), which is also often used in electronics. The idea behind
it is to characterize the system by using two inputs (
and
and
a)
b)
) (
(2.27)
is called transfer matrix and its elements T-parameters (in general complex
numbers).
From the equations (2.27) the expression for the transfer matrix of a cascade shown in
Figure 2.4b) networks can be easily derived:
(
(2.28)
Using this method one can calculate the transfer matrix of a complex system by splitting it
into smaller components and then multiplying the corresponding matrices. In the case of a DBR
shown in Figure 2.3 the components are on one hand the transitions between two materials, on
the other hand propagation in a material of certain thickness:
13
b)
a)
Figure 2.5: Two-port networks for a DBR
The following matrix can be derived for a boundary layer as shown in Figure 2.5a using
Fresnel equations:
(
(2.29)
(2.30)
For the propagation in a layer with refractive index n and thickness d (Figure 2.5b) the
transfer matrix can be described as follows:
(
(2.31)
For a layer stack in a DBR one should note that the sign of the amplitude reflection
changes for subsequent discontinuities due to change of sign of the refractive index change [5].
From this the necessary layer thickness for maximum reflectivity at a wavelength
can be
derived as:
(2.32)
The equation (2.30) can be now written as:
(
(2.33)
Using the equations (2.29), (2.30) and (2.33) the transfer matrix for one pair of a DBR in
Figure 2.3 can be written as:
14
(2.34)
| |
(2.38)
These formulas are valid for any combination of refractive indices and any number of
pairs:
n1=2.5, n2=1.5
n1=1.5, n2=2.5
N pairs
12.34%
0.5
20.40%
0.15%
1
61.73%
93.00%
5
99.20%
98.85%
5.5
98.20%
97.42%
6
99.71%
99.58%
6.5
99.35%
99.06%
7
99.90%
Table 2.1: Comparison of the reflectivity of a DBR for different
number of pairs (ns=3, n0=1)
From Table 2.1 can be derived that the best reflectivity is achieved by starting with low
refractive index material and using integer number of pairs. Also it can be seen that in this
configuration an additional layer at the end (half-pair) with low index material can reduce the
15
reflectivity, acting as an antireflection coating. In fact by varying the thickness of this layer
between 0 and
In this way the out coupling DBR or the Top-DBR of a VCSEL is designed, the necessary
reflectivity is around 99.5%: lower reflectivity would increase the mirror losses to much; too high
a reflectivity would decrease the output power dramatically. The Bottom-DBR on the other hand
is designed to have as high a reflectivity as possible (higher than 99.9%). It also has a slightly
different structure the final layer of the mirror is gold and the mirror is called hybrid mirror.
(
|
))
(2.39)
accommodate for the light penetration in the gold layer and the related phase shift. With the
refractive indices used in Table 2.1 (ns = 3, n1 = 1.5, n2 = 2.5) and n0 = nAu,eff and applying only 3
DBR-pairs a reflectivity of 99.95% can be reached for a hybrid mirror.
16
The calculations for the transfer matrices derived above can be applied not only to design
simple Distributed Bragg Reflectors, as described in Figure 2.3, but in general to any
combination of layers with arbitrary thickness and refractive index. In this way it is possible to
design structures, that will act as band-pass or band-stop filters, however it should be noted that
such designs are difficult to calculate, which requires the use of sophisticated simulation tools.
17
a)
b)
for the layers and due to the strong band bending, tunneling of electrons from the valence band of
the p-side to the conduction band of the n-side can be achieved in reverse bias. In this case, the
BTJ structure operates as backward diode. This means that electrons are generated in the
conduction band and holes in the valence band, which can be viewed as a conversion of electrons
into holes. As a result one can use n-doped materials on the p-side of the laser, for example. This
is also applied in the InP-VCSEL: since electrons have a higher mobility in InP compared to
holes, n-doped InP has lower resistivity, which reduces the series resistance of the device and
improves its thermal properties, the most important advantage is the reduced optical losses in nmaterial, compared to p-material.
The main role of a BTJ however is still creating the aperture for the current flow, for that
the n++-doped layer is partially removed only leaving a small disc in the middle of the future
mesa. The BTJ is then overgrown with n-doped InP: on the n++-part the p++/n++-backward diode
is operated in reverse bias, which ensures conducting, on the part where the n++-layer was
removed a normal reversed bias p++/n-diode is fabricated (between p++-layer of the BTJ and n-InP
overgrowth), therefore no current flows there. This behavior can be also deduced from Figure
3.2, where the band diagram for both cases is depicted. To characterize the BTJ structure it is
useful to introduce the measure called blocking ratio (the ratio between current flowing in the
conducting backward diode and the current flowing in the blocking pn-diode); in a well-designed
VCSEL blocking ratios of around ten thousand can be achieved.
-5.0
-5.0
++
p -AlInGaAs BTJ
-5.5
++
Ec (eV)
Efn (eV)
Ev (eV)
Efp (eV)
++
p -AlInGaAs BTJ
-5.5
n-InP
Energy (eV)
Energy (eV)
n -InGaAs BTJ
-6.0
n-InP
-6.5
-7.0
Ec (eV)
Efn (eV)
Ev (eV)
Efp (eV)
-6.0
-6.5
-7.0
-7.5
-7.5
-8.0
-8.0
0
40
80
120
160
200
40
80
120
160
200
Position (nm)
Position (nm)
b)
a)
Figure 3.2: Band diagram of a BTJ structure a) conducting, b) blocking at reverse bias of
0.1V
20
3.2.
The optical design is the key point for developing a laser diode. In a VCSEL it plays an
even greater role than in edge-emitting laser diodes. First of all the cavity has to be designed
according to the desired wavelength, since the cavity length defines the wavelength (it must be a
multiple of the half-wavelength in the medium (compare to equations 2.23)), however a cavity is
normally designed larger than half-wavelength in the medium, since current spreading layers are
necessary between BTJ and the contact to ensure homogeneous pumping of the BTJ.
Also the position of the active region and the tunnel junction need to be adjusted to the
standing wave pattern. The BTJ consists of highly doped layers, in particular InGaAs, which is
strongly absorbing for the desired wavelength (
),
therefore to minimize its influence on the laser performance the BTJ needs to be placed in the
minimum of the field. The active region on the other hand is placed in the maximum to increase
the confinement factor and hence the mode gain. The confinement factor of VCSEL can be
calculated as follows:
|
(3.1)
The x- and y-dimensions are defined only by the aperture, which means
and
, for the fundamental mode. For the z-dimension however the overlap of the active
region with the standing wave pattern needs to be taken into account and can be approximated as
[9]:
(3.2)
the QWs. Also while designing the VCSEL one should consider that the resonator length
isnt
equal to the cavity length, since a significant part of the field penetrates into the mirrors, as can
be seen in Figure 3.3. The penetration depth can be approximated as follows [10]:
21
(3.3)
where
and
and
, which is definitely
not the case for a small number of pairs. Taking into account the penetration depth in the mirrors
the effective resonator length can be written as:
(3.4)
1.0
Refractive Index
0.8
2.0
0.6
0.4
1.5
0.2
1.0
2.5
0.0
0
500
1000
1500
2000
Position (nm)
Figure 3.3: E-field pattern and refractive index of a 5-pair DBR
There are two main possibilities to realize the mirrors: one is to use epitaxially grown
semiconductor materials, another is to use evaporated dielectric and semiconductor materials.
Both methods have their own advantages and disadvantages. Epitaxial mirrors, for example,
allow easier processing and are grown in the same epitaxial step as the cavity. The crucial
advantage of the epitaxial mirror grown below the cavity is that one can easily measure the cavity
length (by measuring the wavelength dependent reflection and analyzing the reflection spectrum)
and adjust it by the following layers, to correct the position of the standing wave pattern. Also it
is possible to grow doped mirrors, which act as current spreading layers. In general epitaxial
22
mirrors have also a better quality, since crystalline materials are used. However epitaxial mirrors
also have some disadvantages. The semiconductor materials used in epitaxial mirrors need to be
lattice matched to the substrate, which limits the materials of choice; furthermore the materials
which are absorbing for the desired wavelength need to be avoided. Thus the material
compositions that can be used are normally quite limited and also the possible difference of
refractive index is comparatively small, which demands a high number of pairs to reach the
necessary reflectivity. This increases the total thickness of the mirror, which impairs thermal
performance of the VCSEL, since the thermal conductivity of the mirror decreases. Also the
doped mirrors are absorbing due to the free-carrier absorption.
The evaporated dielectric mirrors on the other hand can have a very high refractive index
contrast, therefore a smaller number of pairs can be used, which reduces the penetration depth
and the effective resonator length (and therefore increases the resonance frequency (see Chapter
3.3)). Also the choice of the material isnt restricted by the lattice, thus only the absorption needs
to be taken into account. The layers produced in this way are however amorphous, and the
sticking of the mirrors is a known issue as well. Another aspect is that the dielectric materials in
general have a much lower thermal conductivity compared to binary semiconductors (compared
to ternary and quaternary materials isnt necessarily the case), which affects the thermal
performance of the device, also the complexity of the process increases with the application of
dielectric mirrors. For the high-speed application however the dielectric mirrors are preferred.
n1
n2
N pairs
R (%)
dmirror (m)
Lpen (m)
Mirror
dielectric
1.5
2.5
6
99.71
2.48
0.411
epitaxial
3.2
3.5
32
99.57
7.42
1.286
Table 3.1: Comparison between dielectric mirror and epitaxial mirror (Wavelength = 1.55m,
Reflectivity R >99.5%, ns = 3, n0 = 1)
Finally the Figure 3.4 shows the cross-section and the standing wave pattern of a short
cavity VCSEL with two dielectric mirrors (Bottom-DBR is a hybrid one) and active region (AR)
placed at the field maximum and BTJ at the field minimum.
23
3.3.
(3.5)
where
rate,
(3.6)
these rate equations small-signal frequency response can be deduced [4], which is also the
operation mode needed for optical telecommunications:
(3.7)
24
with
:
(3.8)
Also from this expression the first possibilities to increase the resonance frequency and thus also
the cut-off frequency can be derived: increase photon density (output power), decrease photon
lifetime. The photon lifetime on the other hand can be described as [12]:
(
(3.9)
This means that a smaller resonator length will result in a lower photon lifetime.
The frequency response described above is only valid in the case where parasitics of the
laser diode are neglected, and thus only describes the intrinsic response of the laser. For the real
device however parasitcs need to be taken into account.
25
(3.10)
(3.11)
where
is the
influence of parasitics on the frequency response. Finally the total frequency response can be
deduced as:
(3.12)
3.4.
As mentioned before the resonance frequency increases with the output power, which
means that a laser diode with higher maximum output power should have a better high speed
performance. During this thesis stacked active regions were utilized to improve the performance
of the VCSEL. The stacked active region means that a series circuit of two or more separate
active regions is employed in the laser diode. In this composition the p-side of one active region
is connected to the n-side of the next one; therefore a conversion between holes and electrons is
necessary, which is achieved by using the tunnel junction as described in Section 3.1. From the
electrical point of view the electrons first enter the n-side of the first active region (AR),
recombine there and thus enter the p-side of this AR, and then the same electrons are carried to
the tunnel junction and tunnel to the n-side of the second AR, where they again recombine. This
process continues until the electrons reach the final p-cladding. Since the current flowing through
the stacked AR is the same that flows through the single AR, one can increase the output power
of the laser diode by the factor equal to the number of ARs in a stack. However since each of the
ARs has a certain voltage drop induced by the band gap, the stack has also the higher voltage
drop (a stacked active region consisting of two active regions has twice the voltage drop
26
compared to a single one). For the laser diode it means that for the same output power the current
is reduced by the number of active regions in a stack, compared to the single AR with the same
total number of QWs, at the same time the voltage drop increases by the same factor. At the first
glance this doesnt have any advantages, since the input power (
however for the laser diode and especially for the VCSEL it is expected to improve the
performance greatly.
To understand the advantages of the stacked active region, first of all one has to consider
the structure of the active region of a laser diode. In general a multiple of quantum wells (QW)
separated by barriers are used as an active region, this increases the density of states at desired
lasing energy (since the spacing between the energy levels in the quantum well is much higher
compared to bulk material). The Figure 3.6 shows the modal gain of an active region with
different number of QWs as a function of injection current, the higher gain means higher output
power, the points in the graph mark the optimum condition for laser performance for a given
number of QWs. For a higher number of QWs the optimum output power is higher, however the
threshold current density also increases. For desired performance the ideal number of QWs can
be estimated from the mentioned behavior. For the InP-based VCSELs this number was found to
be around 5-7 QWs. The number of QWs also determines the thickness of the active region and
therefore also the relative confinement factor (see equations (3.2)): the higher the number of
QWs, the lower is the overlap of the active region with the maximum of the standing wave
pattern.
The stacked active region creates a possibility to increase this overlap without decreasing
the number of quantum wells, since each part of the active region is placed at a separate
maximum of the field. The comparison between stacked and single AR can be seen in Figure 3.7:
where an active region consisting of 8 QWs (QW thickness 10 nm, barrier thickness 10 nm,
the material wavelength is assumed to be
maximum (a), then the same active region is separated in two parts 4 QWs each and each part is
placed at a separate field maximum (b). For these imaginary active regions a relative confinement
factor of around 1.73 and 1.91, respectively, can be calculated. Therefore the stacked active
region in this case improves the relative confinement factor by around 10%, thus increasing the
modal gain (
).
Another advantage of the stacked active region can be derived from the fact that the same
output power can achieved using lower injection current. The maximum output power of a laser
diode is determined by the heating of the active region, induced by the current flow. The
dissipated power can be described by the simple equation
-5.2
-5.4
-5.6
0.5
-5.8
-6.0
-6.2
-6.4
-6.6
0
100
200
300
-5.2
Normalized E-Field
-5.0
-5.4
-5.6
0.5
-5.8
-6.0
-6.2
-6.4
-6.6
0.0
400
100
200
300
400
500
600
700
Normalized E-Field
1.0
1.0
-5.0
0.0
800
Position (nm)
Position (nm)
b)
a)
Figure 3.7: Schematic Structure of a) single and b) stacked active region with 8 QWs in
total each (Note: the necessary BTJ at position 400nm in figure b) is left off)
On the other hand however the stacked active region also has some drawbacks. First of all
the epitaxial growth is more challenging compared to common design, since two or more active
28
regions and BTJs need to be placed at the corresponding nodes and anti-nodes of the standing
wave pattern. Although the absorption in the BTJ is minimized by placing it in the field
minimum, it isnt equal zero, which means that increasing the number of BTJs also increases the
internal losses slightly. Another aspect is the cavity design: for a given thickness of the current
spreading layers in the VCSEL one increases the cavity thickness by introducing stacked active
regions (each active region in the stack increases the cavity thickness by half-wavelength in the
medium), which reduces the resonance frequency of the device (see equations (3.8) and (3.9)).
The main problem in the design introduced above is assumed to be caused by the tunnel junctions
separating the active regions. Since these BTJs are not structured, each of them is expected to
introduce an additional current spreading, which can reduce the performance of the whole device.
29
estimated by measuring the peak height and position at a given excitation power and comparing it
to the previous successful epitaxial runs). After the verification the actual processing of the
VCSEL starts.
The first step is to define the aperture of the future devices, thus the top layer of the BTJ is
removed leaving only small areas where both layers are still present. To define the structures
optical lithography is used, for that the sample is first cleaned with hot Acetone and Propanol and
an HCl-Dip (short etching (30s) in a diluted hydrochloric acid) to remove the native oxide is
performed and the residual water is removed by heating out the sample, subsequently the sample
is coated by a resist and exposed leaving only small circles (diameter 2 to 30m) unexposed.
After the development this circles cover the areas where the BTJ apertures of the devices will be
present. The uncovered parts are then etched using Reactive Ion Etching System Oxford
PlasmaLab 100. Since the layer that needs to be etched is around 12 15nm, a very slow etch
rate is essential, which is achieved by using the gas mixture of methane, nitrogen and hydrogen
(weakly reactive gases) and low excitation power. Since it is not possible to use in-situ control for
this etching, the etch time is estimated by calibrating the etch rate beforehand. After the etching
the etch depth is verified using Dektak step profiler. Finally the resist can be removed and the
sample is cleaned before further processing. The next step is the epitaxial overgrowth of the
sample, therefore it has to be ensured that the sample is contamination-free, otherwise the device
performance will suffer. For that all the steps mentioned before are performed with extreme care
and using separate tools, especially the final cleaning step. During the overgrowth the n-doped
InP current spreading layer (the doping is varied depending on the standing wave pattern) and the
heavily n-doped p-side InGaAs contact layer are grown.
After the second epitaxy first of all the alignment marker etched in the previous step are
freed to ensure easier alignment of the next step. This is done by using optical lithography and
subsequently etching the overgrown layers on top of the alignment marker (wet-chemical
selective etching: phosphoric acid for InGaAs and hydrochloric acid for InP). In the next step the
contact layer is removed on top of each BTJ by using selective wet-chemical etching with
phosphoric acid. This step is necessary to avoid the high losses caused by the contact layer and
therefore needs a very precise alignment (for some devices there is no alignment tolerance at all).
The other reason for the precise alignment is that the alignment marker for all the following steps
32
are created in this step, which means the misalignment of this step will be carried to all the other
steps.
In the next step the mesas of the future devices are defined, for that first a silicon oxide
hard mask is produced, by using optical lithography, followed by silicon oxide (SiO2) deposition
(evaporation in this case) and the Lift-Off procedure, where the oxide layer on top of the resist is
removed. The evaporation system is used, because it allows growing relatively thick layers
without any quality loss (compared to e. g. sputtering), before the evaporation an HCl-Dip is
performed to remove the native oxide and ensure better sticking of the evaporated material (this
is the standard procedure before any material deposition and is used very often during the
complete process). For the mesa etching the same dry etching system as for the BTJ is used. In
both steps dry etching is preferred since it offers anisotropic etching profile (e.g. no under etch).
For this step another gas composition is used: methane, hydrogen and chlorine, and also the
excitation power are higher, because a higher etch rate is desired (etch depth around 1.5 2m).
The chlorine is chemically highly reactive therefore a hard mask is necessary (resist reacts with
chlorine and also due to high temperature the resist burns in, which impedes the following resist
removal). Also the in-situ control with mass spectrometer is used during the etching: the mass
fraction of the arsine and phosphine is measured at the outlet, which helps defining whether
phosphorous (InP) or arsenic (InGaAs, AlInGaAs) layer is etched at the given time. The goal is to
etch all the epitaxial layers and stop in the InP buffer layer grown at the start of the first epitaxy.
For this etching the process parameters have to be chosen very carefully; first of all the
etch rate must be high so the etching isnt too long, on the other hand it has to be low enough to
resolve all the layers (especially when using stacked active regions, since there are layers of
around 80 nm, that need to be resolved). The most important factor is the homogeneity of the
etching, in the case of too high inhomogeneity it is not possible to use the in-situ control and the
point to stop the etching cant be distinguished. If this happens one can etch down into the
substrate removing the necessary etch stop, which makes further processing more difficult and
more dangerous, especially the substrate removal. Small dummies of similar structure are used
for testing, the behavior on a full wafer however is different. The Figure 4.1 shows the mass
fraction of Arsine (AsH3) and Phosphine (PH3) in the outlet during the etching for three different
samples. For the first sample (Figure 4.1a) an imperfect process was used: the inhomogeneity
was found to be around 20% (400 nm) and it was impossible to stop the etching in the desired
33
buffer layer. After improving the parameters and experimenting with different other gas mixtures,
a much better parameter set was found (Figure 4.1 b) and c) shows the etching where each part of
the VCSEL is resolved perfectly, which allows to stop the etching in the desired layer) that
resulted in the inhomogeneity of around 2-3%.
a)
1E-7
n-InP overgrowth
n-InP cladding
1E-8
p-cladding + AR
n-InGaAs CL
1E-9
Arsine
Phosphine
1E-10
0
100
200
300
n-InP overgrowth
InP buffer
1E-7
2.n-InP cladding
InP buffer
1E-8
1.p-cladding + 1.AR 2.p-cladding + 2.AR
n-InGaAs CL
1E-9
Arsine
Phosphine
1E-10
0
400
1.n-InP cladding
100
200
300
c)
b)
Figure 4.1: Output of the mass spectrometer during the mesa etching for three different
samples: a) imperfect; b),c) optimized parameter set
After the dry etching an additional lithography step covers the mesa with a slightly bigger
circle and the buffer layer is selectively wet-chemically etched away, resulting in a much
smoother surface compared to the dry etching, which improves the further processing. After the
etching the hard mask is removed (selective dry etching of SiO2) and the sample is ready for
further processing.
34
a)
b)
c)
d)
sticks better to SiO2 then to semiconductor. The same is done after the planarization with BCB to
ensure better sticking of the resist. After the planarization the layers on top of the mesa need to be
removed to enable electrical contacting and deposition of the mirror, which is done by
lithographically defining the necessary areas and selectively etching through BCB and SiO2
layers. Now the contact rings comprised of titanium (for better sticking to semiconductor),
platinum (diffusion barrier for gold) and gold are evaporated and structured using Lift-Off
procedure. This step is known to cause problems, since the inner part of the ring frequently isnt
removed, therefore a spray Lift-Off with acetone is used (the sample is sprayed with Acetone
stream). After the contacts the dielectric Bottom-DBR is evaporated. The materials used are
aluminum fluoride AlF3 (n=1.34) and zinc sulfide ZnS (n=2.28), the mirror is concluded by
100nm of gold to create a hybrid DBR (for the mirror 3.5 Pairs of dielectric materials are used
reaching the power reflectivity of around 99.95%, the reflection spectrum of the DBR can be
found in Figure 4.3). The final structuring step on the bottom side of a VCSEL is the device
definition, where stripes are etched in the BCB to create lines separating each VECSEL from its
neighbors and also the vias for the contacting of the back side. Now finally the Ti-Pt-Au layer
stack is evaporated and additional 50 60m of gold are electroplated on the sample,
encapsulating the devices and creating the pseudo-substrate. The thickness is controlled by
weighting the sample during the electroplating.
1.000
1.0
Power Reflectivity
Power Reflectivity
0.999
Bottom-DBR
Top-DBR
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
Bottom-DBR
Top-DBR
0.998
0.997
0.996
0.995
0.994
0.993
0.992
0.991
0.1
0.0
1.0
1.2
1.4
1.6
1.8
2.0
2.2
0.990
1.40
2.4
1.45
1.50
1.55
1.60
1.65
Wavelength (m)
Wavelength (m)
b)
a)
36
1.70
After the electroplating the process continues on the back side of the wafer, where the
future top side of the devices will be. First the InP substrate is removed by selectively etching it
with hydrochloric acid with different concentration (first HCl:H2O=4:1 , at the end HCl:H2O=2:1,
to make the stopping on the InGaAs etch stop easier). Afterwards the etch stop and the buffer
layer are removed, allowing access to the devices from the InP substrate side (now the top side).
The further steps on this side are similar to the ones on the back side: first the contact layer is
removed in the middle of the mesa and then the contact pads for the top side are evaporated.
Additionally some gold (1 1.5m) is electroplated on top of the pads to improve the heat
dissipation and the contacting of the devices. Finally as the last step the Top-DBR is evaporated
using the same materials as for the Bottom-DBR (AlF3 and ZnS); here 5 pairs are used with
reflectivity of around 99.4%.
37
a)
b)
c)
d)
38
4
Active Region
Real index
Intensity
BTJ
Active Region
Real index
Intensity
BTJ
0
0
1000
2000
3000
4000
5000
1000
Position (nm)
2000
3000
4000
5000
Position (nm)
a)
b)
Figure 5.1: Refractive index profile and standing wave pattern of a) the single AR device,
b) the stacked AR device
According to equation (3.2) the relative confinement factor
1.97 for the single AR and stacked AR devices, respectively, which also resulted in the reduction
of the simulated threshold gain from 527.56cm-1 to 492.95cm-1.
To verify the quality of the structured BTJ the blocking ratio of both devices was
experimentally determined. Figure 5.2 shows the comparison of the measured current for the
blocking part and the conducting part of the tunnel junction for both devices. The blocking ratio
was extracted at the threshold voltage of the device and was found to be around 35000 for the
single AR device and 10000 for the stacked AR device. The single AR device has a higher
39
blocking ratio, however blocking ratios of around 10000 are large enough for excellent current
confinement, therefore the difference of the blocking ratios on hand doesnt have a huge impact
on laser characteristics of the investigated VCSELs.
35K
10000
30K
1000
25K
10
20K
1
15K
0.1
10K
0.01
D=50m
D=100m
blocking
conducting
5K
1E-3
1E-4
0K
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1
11K
solid
dash
100
D=50m
D=100m
blocking
conducting
10K
9K
8K
7K
10
6K
1
5K
0.1
4K
0.01
3K
2K
1E-3
1E-4
0.0
Blocking Ratio
100
solid
dash
1000
Blocking Ratio
10000
1K
0.2
0.4
Voltage (V)
0.6
0.8
1.0
1.2
1.4
1.6
1.8
0K
2.0
Voltage (V)
a)
b)
Figure 5.2: Blocking ratio of a) the single AR device, b) the stacked AR device (the green
line marks the threshold voltage)
5.1.
To compare the performance of both devices first of all the L-I-V characteristics of the
devices were measured. The L-I curve was measured using thermo-electrically cooled InAs
detector, subsequently the I-V characteristic was recorded using four-point measurement setup to
improve measurement accuracy. The measurements were done at room temperature (20C) on a
copper heatsink in continuous wave (CW) mode.
Figure 5.3 shows the comparison of the L-I-V curves for both devices at room
temperature for VCSELs with 4m (a) and 5m (b) BTJ diameter. Furthermore characteristic
optical and electrical parameters were extracted. Table 5.1 shows a summary of these parameters.
40
1.5
1.5
1.0
0.5
U0 = 0.95V
1.77V
Rs = 74.1
80.9
Uth = 0.98V
1.91V
Ith = 0.69mA
1.62mA
d = 57.6%
80.3%
PRO= 3.31mW
3.12mW
0.0
2
1.0
Voltage (V)
2.0
2.0
Single AR (1 x 6 QW)
Stacked AR (2 x 3 QW)
2.5
2.5
3.0
CW @ RT
DBTJ = 5m
3.5
Single AR (1 x 6 QW)
Stacked AR (2 x 3 QW)
3.0
4.0
3.0
CW @ RT
DBTJ = 4m
0.5
2.5
3.0
2.0
2.5
2.0
1.5
1.5
1.0
0.5
0.0
0.0
10 11 12 13
U0 = 0.95V
1.77V
Rs = 55.8
62.4
Uth = 0.97V
1.88V
Ith = 0.92mA
1.87mA
d = 54.5%
78.4%
PRO= 3.88mW
3.92mW
1.0
Voltage (V)
3.5
0.5
0.0
9 10 11 12 13 14 15
Current (mA)
Current (mA)
b)
a)
Figure 5.3: L-I-V curves for both devices
Device
DBTJ [m]
V0 [V]
Rs [Ohm]
Vth [V]
Ith [mA]
PRO [mW]
d [%]
Single AR
Stacked AR
Single AR
Stacked AR
4
4
5
5
0.95
1.77
0.95
1.77
74.1
80.9
55.8
62.4
0.98
1.91
0.97
1.88
0.69
1.62
0.92
1.87
3.31
3.12
3.88
3.92
57.6
80.3
54.5
78.4
(5.1)
The series resistance is slightly higher in the case of the stacked AR device, because of the
additional tunnel junction and additional p-cladding of the second AR, which has a considerably
higher resistivity compared to the n-InP overgrowth.
Unexpectedly, the threshold current wasnt halved and also the maximum output power
didnt increase. To further investigate this behavior the lateral current spreading for the devices
was estimated. For that purpose the threshold current and current density were investigated for
both devices.
6000
Stacked AR device
Single AR device
0.5
2*sqrt(Ith/) (mA )
Stacked AR device
Single AR device
4000
2000
3
D = 6.65m
D = 1.25m
0
2
10
12
14
16
18
20
10
12
14
16
18
20
b)
a)
Figure 5.4: a) Threshold current density as a function of BTJ diameter, b) Model for linear
extraction of the lateral current spreading
The Figure 5.4a shows the threshold current density for different BTJ diameters. In the
ideal case, where the BTJ area is equal to the pumped area of the AR, one expects an
independency of the threshold current density from the aperture diameter. However, it is not the
case here, especially for the stacked AR device. Presumably, this is caused by the current
spreading at the interface between the highly doped p++-BTJ layer and the low doped p-cladding.
For the stacked AR device this behavior is further enhanced by the second BTJ. To calculate the
corresponding current spreading a simple linear model is assumed (
threshold current density can be written as:
42
) and the
(5.2)
and
(5.3)
measured data and the linear approximation for both devices and the estimated values for the
threshold current density and the current spreading can be found in Table 5.2.
Device
Single AR
Stacked AR
D [m]
1.25
6.65
Jth [A/cm2]
2944
1633
fact that both active regions of the stacked AR device arent completely identical, due to growth
inaccuracy. The achieved results however are in good comparison with the results of the other
groups: the stacked AR VCSELs shown in [21] achieved the differential quantum efficiency up
to 51% for a stack of 3 active regions, which is still clearly inferior to results achieved in this
thesis. The segmented laser presented in [20] achieved the differential quantum efficiency of
409% for 12 segments and 126% for 3 segments, compared to 42.4% for unsegmented laser.
These results were however obtained for pulsed mode operation and are expected to deteriorate
for CW operation (342% for 12 segments or 28.5% per segment, which is also inferior to the ones
mentioned above). The differential quantum efficiency for a stacked device, similar to the one
mentioned in this thesis, were achieved in [22], however for an edge-emitting laser diode: for a
single AR device 50%, for stacked AR device (3 ARs in series) 125% (42% per AR).
5.2.
4.5
4.5
-10C
0C
10C
20C
30C
40C
50C
60C
70C
80C
85C
3.5
3.0
2.5
2.0
1.5
-10C
0C
10C
20C
30C
40C
50C
60C
70C
80C
85C
4.0
4.0
1.0
0.5
0.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
10
12
14
16
Current (mA)
10
12
14
Current (mA)
a)
b)
this figure one can easily deduce the optimum temperature of operation. The lowest threshold
current for the single AR device was found to be around 30C, for the stacked AR device
around 0C. Both devices were designed for room temperature operation, which is definitely the
case for the single AR device, for the stacked AR device the optimum temperature shifted
towards low temperatures, due to the detuning of the cavity length compared to the gain
maximum, most likely caused by the growth inaccuracy. Both devices show similar relative
threshold current in the range between 10C and 20C (see Figure 5.6b), which allows an errorfree comparison in this range.
4.5
4.5
4.0
4.0
2.4
3.5
2.2
3.0
3.0
2.0
2.5
2.5
2.0
2.0
1.5
1.5
1.0
1.0
1.0
0.5
-20 -10
0.5
0.8
-20 -10
10
20
30
40
50
60
70
80
Ith/Ith,min
3.5
Pmax(mW)
Ith(mA)
2.6
Stacked AR
Single AR
Stacked AR
Single AR
1.8
1.6
1.4
1.2
90
Temperature (C)
10
20
30
40
50
60
70
80
90
Temperature (C)
a)
b)
Figure 5.6: a)Threshold current and maximum output power of both devices, b)Normalized
threshold current as a function of temperature
Both devices also achieved reasonable output power even at high temperatures (above
1.5mW at 85C heatsink temperature for the single AR device, which is superior to previously
fabricated SC VCSELs [17], and considerably higher than maximum CW operation up to 35C
for devices mentioned in [23] and 0.4mW output power at 70C for the VCSELs described in
[24]), the Figure 5.6a however shows that the stacked AR device has a slightly worse thermal
performance, since the maximum power drops faster for this device. This is mainly caused by the
smaller mode-gain offset of the stacked AR device. Also the effect is enhanced by the additional
high current spreading at the BTJ before the second AR, which increases the current density in
the first AR.
45
5.3.
Further insight about the operation of the laser can be attained by analyzing the spectral
data of the devices. Figure 5.7 shows the comparison between the spectral responses of both
devices (measured at 20C at roll-over for a BTJ diameter of 5m, dashed line shows the PL
response measured before processing). The wavelength of the main mode was found to be
1522.2nm and 1535.2nm for the single AR device and for the stacked AR device, respectively.
The difference of the wavelength indicates that the lasers have a slightly different cavity length,
the excellent laser performance however shows that the detuning of the standing wave pattern is
neglectable. The PL and lasing peak position at room temperature evince that both devices were
designed with the same mode-gain offset. The optimum operation temperature for the stacked AR
device is however at 0C (compared to 30C of the single AR device), which implies higher
active region temperature and higher mode-gain offset.
1460
1470
1480
1490
1500
1.0
Single AR
Stacked AR
-10
-20
T = 20C
I = IRO
0.8
-30
-40
0.6
-50
0.4
-60
-70
1490
1500
1510
1520
1530
1540
Normalized PL Response
Wavelength PL (nm)
1450
0.2
1550
BTJ diameter (Figure 5.9). The devices with BTJ diameter above 5m of both devices have a
relatively low SMSR and cant be considered single mode anymore, the comparison between
both devices also gets difficult in this range since the fiber coupling becomes an issue. On the
other hand the comparison between the 5m devices shows that the device with single active
region has a much higher SMSR, which can also be caused by the fabrication inaccuracy, the
other possibility is the effect of higher broadening, which increases the current density
dramatically in the first AR, thus changing the single-mode performance, as investigated in [25].
Wavelength (nm)
-20
-30
4m
5m
6m
9m
-10
-10
T = 20C
I = IRO
-40
-50
-60
-70
1505
1510
1515
1520
1525
1530
-20
-30
4m
5m
6m
9m
T = 20C
I = IRO
-40
-50
-60
-70
1520
1525
Wavelength (nm)
1530
1535
1540
1545
Wavelength (nm)
a)
b)
Figure 5.8: Spectra for the different BTJ diameter of a) single AR device, b) stacked AR
device
60
Stacked AR
Single AR
SMSR (dB)
50
T = 20C
I = IRO
40
30
20
10
0
4
10
DBTJ (m)
Figure 5.9: SMSR vs. BTJ diameter
47
11
For some laser applications wavelength tuning is desired, therefore the tuning dependency
on the heatsink temperature and on the applied current (the easiest methods of wavelength
tuning) was investigated.
The Figure 5.10 shows the spectra measured at different temperatures. The behavior is
further analyzed by plotting the wavelength and SMSR as the functions of temperature (Figure
5.11). For both devices the linear temperature tuning coefficient around 0.085nm/K was
calculated, which is slightly lower than a typical one of 0.1nm/K. The SMSR was found to
increase with temperature, especially for the stacked AR device (Figure 5.11b).
-10
-20
-30
20C
30C
40C
50C
60C
-10
DBTJ = 5m
I = 6mA
-40
-50
-60
-70
1505
1510
1515
1520
1525
1530
20C
30C
40C
50C
60C
-20
-30
DBTJ = 5m
-40
I = 6mA
-50
-60
-70
1520
1525
Wavelength (nm)
1530
1535
1540
1545
Wavelength (nm)
a)
b)
1537
55
Single AR
Stacked AR
1535
DBTJ = 5m
1534
I = 6mA
0.0877nm/K
SMSR (dB)
Wavelength (nm)
1536
1533
1522
1521
1520
50
45
DBTJ = 5m
I = 6mA
0.0813nm/K
1519
Stacked AR
Single AR
1518
40
290
300
310
320
330
340
290
Temperature (K)
300
310
320
330
340
Temperature (K)
a)
b)
The dependence of the wavelength on the applied current was also analyzed, for that the
spectra at the constant temperature were measured (see Figure 5.12). From these measurements
the wavelength- and SMSR-current behavior were extracted, as shown in Figure 5.13. For the
wavelength tuning the model
parameters are a and b, since they define the tuning behavior: for the single AR device they were
0.041 and 0.099, respectively, and for single AR device 0.021 and 0.140. From the parameters
one can see that the wavelength is tuned stronger for the stacked AR device, which implies that
more heat is generated in the device. Since the current tuning is based on the internal heating of
the device, one can estimate the temperature increase in the cavity between operation at threshold
and at roll-over: 70K, which implies that excellent performance even above 90C can be
expected. The SMSR on the other hand decreases with applied current, due to current-crowding
(compare to [25]). The wavelength tuning is further investigated by plotting the wavelength as a
function of dissipated power (input power minus optical power), which is shown in Figure 5.14.
One can see that both devices have the same wavelength-power coefficient of 0.3nm/mW. This
shows that the same heat is generated at the same dissipated power in the device. For the stacked
AR device, however, lower heating was expected, which is not the case due to high current
spreading caused by the unstructured BTJ.
-10
1mA
3mA
5mA
7mA
9mA
11mA
13mA
15mA
-10
-20
-30
-40
-50
T = 20C
DBTJ= 5m
-60
-70
-80
1505
1510
1515
1520
1525
-20
-30
-40
-50
Wavelength (nm)
T = 20C
DBTJ= 5m
-60
-70
-80
1520
1530
2mA
4mA
6mA
8mA
10mA
12mA
14mA
1525
1530
1535
1540
1545
Wavelength (nm)
a)
b)
49
50
T = 20C
DBTJ= 5m
Stacked AR
Single AR
1540
45
a = 0.041
b = 0.099
SMSR (dB)
40
1530
1525
1520
a = 0.022
b = 0.140
35
30
25
T = 20C
DBTJ= 5m
20
Stacked AR
Single AR
15
1515
10
0
10
12
14
16
Current (mA)
10
12
14
Current (mA)
a)
b)
1540
Single AR
Stacked AR
1538
1536
Wavelength (nm)
Wavelength (nm)
= a*I + b*I + c
1535
0.292nm/mW
1534
1532
1530
1524
1522
0.306nm/mW
1520
1518
1516
0
10
15
20
25
50
30
16
5.4.
The most important feature needed for optical telecommunication is the High Speed
Performance of the laser diode (since it directly influences the transfer rates). Therefore it also
needs to be investigated for the processed devices. To examine the high speed properties of the
VCSEL first of all the small signal modulation performance was verified. For that the SParameters were measured (the Figure 5.15 shows the simplified measurement setup). The
measurements are carried out at different values of the bias current and constant heatsink
temperature. The current applied to the VCSEL is then directly sinusoidally modulated and the
response is measured by the high-bandwidth photo diode (f3dB = 40GHz), the data is compiled
using the network analyzer. The parameters of interest are the S11 and S21, since they describe
the electrical power reflected and the power transmitted by the VCSEL.
a)
b)
51
Figure 5.16 shows the typical measured data on both parameters. The S11
-3
-3
Response (dB)
Response (dB)
-6
-9
T = 35C
-12
1.27mA
2.03mA
3.29mA
5.06mA
7.34mA
10.12mA
13.40mA
-15
-18
-21
-6
-9
T = 35C
-12
2.18mA
2.30mA
2.73mA
3.65mA
4.94mA
6.59mA
8.61mA
11mA
-15
-18
-21
-24
-24
0
10
12
14
16
18
20
Frequency (GHz)
10
12
14
16
18
20
Frequency (GHz)
a)
b)
As can be seen, the stacked AR device (Figure 5.17b) shows very irregular behavior at
some currents, which results in a wrong fit and complicates the parameter extraction. This also
shows, that the applied model doesnt describe the stacked AR device properly. Presumably, this
can be caused by the fact that the ARs have different current densities, which should result in
different resonance frequencies. The extracted parameters can be found in Table 5.3, the
maximum 3dB cut-off frequency was found to be around 15GHz for single AR device and
12GHz for stacked AR device.
52
I [mA]
1.27
2.09
3.29
5.06
7.34
10.12
13.4
[GHz]
19.45
26.51
37.72
54.45
78.08
104.06
105.57
fr [GHz]
3.18
6.23
9.64
12.49
16.35
17.95
18.10
fp [GHz]
11.35
6.22
7.24
8.43
7.64
10.4
8.68
I [mA]
2.18
2.3
2.73
3.65
4.94
6.59
8.61
11
[GHz]
25.79
25.82
49.02
65.63
82.11
97.70
111.61
119.16
fr [GHz]
3.64
4.17
8.02
11.38
14.48
18.13
19.64
18.42
fp [GHz]
19.04
18.20
4.89
7.21
7.21
7.18
7.27
7.71
a)
b)
Table 5.3: Extracted values of the relaxation-resonance frequency, intrinsic damping and parasitic
roll-off frequency for a)single AR b)stacked AR device
The achieved values are in good comparison with the previous ones from [17], which
results in an excellent high frequency performance.
The Figures 5.18 and 5.19 depict the high speed behavior of the both devices with the
maximum cut-off frequency and at the roll-over, respectively. In the Figure 5.18a one can easily
see the deviation between the measured data and the assumed model for the stacked AR device.
Figures 5.18b and 5.19b show the impedance Z of the devices (as real and imaginary part)
derived from the parameter S11. From the corresponding fits one can extract the values for R, C
and Rm mentioned in Chapter 3.3, which are given in the Table 5.4.
80
60
Resistance (Ohm)
Response (dB)
-3
-6
-9
-12
-15
-18
T = 35C
-21
Single AR
Stacked AR
Re(Z)
40
20
-20
Single AR
Stacked AR
Im(Z)
-24
0
Rm
10
12
14
16
18
-40
20
Frequency (GHz)
10
12
14
16
18
20
Frequency (GHz)
a)
b)
Figure 5.18: a) Modulation Response with the maximum cut-off frequency, b) the
corresponding impedance Z of the devices with the associated fits (Theat sink = 35C)
53
80
60
Resistance (Ohm)
Response (dB)
-3
-6
-9
-12
-15
-18
T = 35C
-21
Single AR
Stacked AR
Rm
Re(Z)
40
20
-20
Single AR
Stacked AR
Im(Z)
-24
-40
0
10
12
14
16
18
20
Frequency (GHz)
10
12
14
16
18
20
Frequency (GHz)
a)
b)
R []
C[pF]
Rm []
Device
R []
C[pF]
Rm []
50.73
0.527
7.34
Single AR
48.34
0.513
6.97
66.62
0.529
8.27
Stacked AR
54.43
0.519
7.34
a)
b)
Table 5.4: Extracted values for the electrical model of a VCSEL a)at maximum cut-off frequency
b)at roll-over
Device
Single AR
Stacked AR
As expected both devices have nearly the same parasitic capacitance of the blocking part
of the BTJ, since the structured BTJ is identical in both devices, also the contact resistance Rm is
nearly the same. On the other hand the resistance R is higher for the stacked AR device, which
also indicates the higher current spreading and higher layer resistance (additional p-cladding).
In general the high speed performance of the stacked AR device was found to be inferior
to the one of the single AR device, which is caused by the much higher current spreading and the
related degeneration of the laser performance, especially the temperature performance.
5.5.
Within the framework of this thesis the stability of the SC-VCSELs was investigated. One
of the issues of the SC-VCSELs is related to the dielectric mirror. The mirror is amorphous and is
evaporated partially on gold contact and partially on crystalline semiconductor, therefore the
sticking of the mirror is rather poor, which can cause problems in further handling of the device,
54
since the mirror could pop off rendering the device useless. Another problem can be caused by
the external heating of the VCSEL chip, since the mirror could degenerate, e. g. due to oxidation
of the mirror materials. These issues can occur especially while packaging, bonding and soldering
the VCSEL chips (which is necessary for any application), since the chips need to be exposed to
high temperatures. Thus the temperature stability of the VCSELs processed during this work was
studied, for that, a small piece of the sample (stacked AR) was heated on the hot plate in air for
10 minutes, the temperatures used were 180C, 240C and 300C. Optical inspection showed that
the mirrors were still intact and no visible change could be found, also after each heating step the
L-I-curve and spectrum at room temperature of the same device (4m BTJ diameter) were
measured. Figure 5.20 shows the achieved results. As one can see from the L-I-curves the
maximum output power of the device is reduced with each heating step, at the same time the
threshold current also goes down. The spectra show that after the first step (180C) the peak
position doesnt change, after the subsequent ones (240C, 300C) on the other hand the lasing
wavelength experiences a small blue-shift, which indicates the change of the optical cavity
length. The change of the threshold current is most significant after the 180C heating. The
power degrades strongly after the last heating step.
3.5
2.5
04_03
D = 4m
Reference
10min @ 180C
10min @ 240C
10min @ 300C
3.0
T = 20C
2.0
1.5
1.0
0.5
0.0
0
-40
-60
-80
1510
10
Current (mA)
04_03
D = 4m
Reference
10min @ 180C
10min @ 240C
10min @ 300C
1515
1520
1525
1530
Wavelength (nm)
a)
b)
Figure 5.20: L-I-curves (a) and spectra (b) of the device after exposing it to different
temperatures (D = 4m, T = 20C)
The simplest explanation for the change seen in the L-I-characteristic is the increase of
the mirror reflectivity (mirror losses and out coupled power are reduced). In this case one can
apply an anti-reflection coating on top of the mirror to achieve the previous reflectivity, thus
55
verifying the change in the mirror reflectivity. As the anti-reflection coating sputtered silicon
dioxide was used, to achieve the necessary reflectivity the layer was deposited in multiple steps
and the L-I-characteristic was measured after each step, which are depicted in Figure 5.21.
The maximum anti-reflection effect can be reached by applying a /4-layer of low index
material, for sputtered SiO2 it is around 260nm, which is also evident from the data in Figure
5.21. From the L-I-measurements one can deduce that the threshold current of the reference
(before the heating) of around 2.5mA could be achieved, the maximum output power however
remained lower (2.25mW compared to 3.25mW). This together with the spectral measurements
in Figure 5.20b shows that both the mirror reflectivity and the cavity change after the heat
treatment.
2.25
04_03
D=4m
Reference
64.8nm SiO2
2.00
123.9nm SiO2
1.75
Power (mW)
183.1nm SiO2
1.50
269.5nm SiO2
334.2nm SiO2
1.25
T = 20C
1.00
0.75
0.50
0.25
0.00
0
10
Current (mA)
Figure 5.21: L-I-curves after applying a SiO2 layer of different thickness on top of the mirror
The result of the investigation is that the heat treatment doesnt destroy the mirror; the
performance of the device drops slightly, also the mirror reflectivity increases. The changes
observed after heating the device at 300C for 10 min are a blue-shift of 5nm and the reduction of
the maximum output power by approximately 30% (at the same threshold current, adjusted by the
anti-reflection coating). For the 180C heating step one can assume that only the mirror
56
reflectivity increases, thus improving mirror quality. With the anti-reflection layer it was possible
to reverse the decrease of the threshold current, the measured relative increase of the output
power was even higher. The Table 5.5 shows the relative change (decrease after heating, increase
after applying anti-reflection coating) of the threshold current and maximum output power for
both cases.
After 10min@180C
Ith [%]
Pmax [%]
- 17.8
-16.5
57
6. Conclusion
During this thesis indium phosphide based short cavity vertical-cavity surface emitting
lasers with emission wavelength around 1.55m suitable for optical fiber telecommunication
were produced.
The devices described in this thesis were designed for high speed performance at room
temperature. The devices utilized a 3-cavity and a structured buried tunnel junction for defining
the aperture, also dielectric DBRs were used as mirrors to further reduce the effective cavity
length. Two different types of active regions were implemented in the devices: a single active
region and a stacked active region. The impact of this innovative active region on the device
performance was analyzed. In both active regions heavily compressively strained quantum wells
were used to increase the differential gain of the devices.
The number of quantum wells in the AR plays a crucial role in the VCSEL design: on one
hand the number of QWs has to be sufficient to provide enough gain, on the other hand the
increasing number of quantum wells also increases the threshold and decreases the overlap of the
AR with the maximum of the standing wave pattern. For the device with the single active region
6 QWs were chosen, placed at a single standing wave pattern maximum, which resulted in a
relative confinement factor of around 1.84. The device showed excellent performance up to 85C
(limited by the measurement setup). The lasers had the low threshold current and high output
power: 0.9mA and 3.9mW for 5m device respectively, which is one of the best values to date:
3mW for the same device reported in [17], 1mW for 8m device [19]. The differential quantum
efficiency was found to be around 58%, which is record high for this wavelength for single AR
device (previously achieved values: 50% for an edge emitting laser [22], 38% for a VCSEL [17]).
At 85C heatsink temperature the devices still had a reasonable performance with maximum
output power of 1.5mW (1.3mW at 80C [17], 0.4mW at 70C [24]). The thermal wavelength
tuning coefficient was found to be around 0.8nm/K. The high speed performance of the devices
was evaluated and resulted in the maximum cut-off frequency of 15 GHz at 35C heatsink
temperature, which is the same as the devices of the same structure introduced in [17].
To optimize the device performance, the stacked active region was introduced for the first
time in a SC-VCSEL. Compared to the single AR device mentioned above, 6 identical QWs were
59
used, however they were divided in two active regions with 3 QWs each separated by a tunnel
junction. Both active regions were placed at two different maxima of the standing wave pattern,
thus increasing the relative confinement factor to 1.94. Furthermore such structure should reduce
the threshold current (compared to the single active region with the same total number of QWs)
by a factor of two, at the expense of increasing the voltage drop by the same factor.
The measured threshold current of the stacked AR device wasnt halved, but in fact was
found to be twice as large compared to the reference (single AR device), the reason was found to
be the unusually high current spreading (6.65m compared to the 1.25m of the single AR
device), caused by the additional tunnel junction between the active regions. The extracted
threshold current density (taking into account the broadening) was found to be 1633 A/cm2 for
the stacked AR device and 2944 A/cm2 for the single AR device, which means that the current is
indeed halved, as assumed. The maximum output power of the stacked AR device was measured
to be the same as the one of the single AR device (due to current spreading before the second AR
in the stack). The differential quantum efficiency has been increased due to stacking 80% (40%
per AR). The reported values range from 125% (42% per AR) for a stack of 3 ARs in an edge
emitting laser [22], to 51% (17% per AR) for a stack of 3 ARs in a VCSEL [21]. The temperature
performance of the stacked AR device was slightly inferior to the one of the reference, due to the
different pumped area of two ARs, and therefore increased current density in the first AR.
Presumably this also caused the deterioration of the side-mode suppression ratio, and the slightly
lower cut-off frequency of 12 GHz.
Furthermore the thermal stability of the SC-VCSELs was investigated during this thesis.
The results show that heating of the device at 180C for 10 min improved the mirror reflectivity,
which was verified by subsequent deposition of the anti-reflection coating, further heating at
240C and 300C caused a 5nm blue-shift of the lasing wavelength and the reduction of power by
30%, which shows that the heating steps needed for packaging, bonding and soldering of the
VCSELs shouldnt pose a danger for the device.
During this thesis the first experiment of integrating stacked active region in the existing
SC-VCSEL design was carried out, which showed degrading of the laser parameters, mainly
caused by the diffusion broadening at the additional tunnel junction between the active regions.
One possibility to improve this behavior would be to structure this tunnel junction (identical to
60
the tunnel junction for the aperture), which would make an additional overgrowth necessary. The
major drawback of this solution is that one active region would be grown on the structured BTJ,
which results in inferior optical quality. Another approach is to structure the whole structure by
etching through both active regions, which would eliminate the diffusion broadening. The
problem here is on one hand the non-radiative surface recombination, on the other hand the
degradation of the active region, caused by the etching process. Another less cardinal concept is
to improve the tunnel junction between the active regions. First of all one could try to reduce the
doping which should greatly reduce the diffusion broadening, another possibility is to adjust the
thickness of the BTJ layers in a way that the space charge region caused by the p ++/n++-junction
would be the same as the thickness of the highly doped layers.
61
Acknowledgements
At this point I would like to express my gratitude to all the people, who contributed to the
successful competition of this thesis:
Prof. Dr. M.-C. Amann for providing the possibility to write this thesis at his chair E26
for Semiconductor Technology at the Walter Schottky Institut and to get the profound
knowledge about high speed laser diodes for optical telecommunication
Michael Mueller for his excellent supervision, his dedication and willingness to help
during processing of the devices, proof-reading of this thesis, his permanent support and
for sharing his knowledge and experience in the field of the High Speed VCSELs
Stephan Sprengel for his versatile support during this thesis, and willingness to answer
my questions and discuss the obtained results,
VERTILAS front-end team for helping with various processing steps during VCSEL
fabrication
Gerhard Boehm for the first-rate epitaxial growth of the structures used in this thesis,
Dr. Ralf Meyer for his support and his excellent organizational work at the chair,
the entire staff of the E26, Tobias Gruendl, Christian Grasse, Daniela Huber and,
especially, the cleanroom technicians Linda, Edith and Sepp for always being ready to
help and many useful tips,
63
References
[1] Z. Alferov, Double heterostructure lasers: early days and future perspectives, Selected
Topics in Quantum Electronics, IEEE Journal of , vol.6, no.6, pp.832-840, Nov.-Dec.
2000
[2] H. C. Casey, Jr, M. B. Panish, Heterostructure Lasers, Academic Press, Inc., 1978
[3] M.-C. Amann, Optoelectronics 1 Lecture notes, Munich, 2008
[4] L. A. Coldren, S. W. Corzine, Diode Lasers and Photonic Integrated Circuits ,
A Wiley-Interscience Publication, 1995
[5] M.-C. Amann, Single-Mode and Tunable Laser Diodes, Academic Press, 1999
[6] W.
Hofmann,
InP-based
long-wavelength
VCSELs
for
high-speed
optical
65
[22] J. K. Kim, E. Hall, O. Sjlund, and L. A. Coldren, Epitaxially-stacked multiple-activeregion 1.55m lasers for increased differential efficiency, Appl. Phys. Lett. 74, 3251
(1999)
[23] D. Feezell, D. A. Buell, and L. A. Coldren, InP-Based 1.31.6-um VCSELs With
Selectively Etched Tunnel-Junction Apertures on a Wavelength Flexible Platform,
Photonics Technology Letters, IEEE , vol.17, no.10, pp. 2017- 2019, Oct. 2005
[24] M.R. Park, O.K. Kwon, W.S. Han, J.H. Kim, S.H.K. Park, H.W. Song, V.H. Lee, S.J.
Park, B.S. Yoo, All-monolithic InAlGaAs/InP VCSELs for 1.3 ~ 1.5 m wavelength
ranges,
Optical
Fiber
Communication
Conference,
2005.
Technical
Digest.
67
mit aktiver
Zone
R_serie
6,3
ja
R_spread
68,9
Widerstandberechnung
Verluste ()
0,0145
1/cm
Schichtdicken
Dielec.-DBR
Resonator
cb
vb
vb_hh
vb_lh
vb_so
ja
ja
2296,4
1469,1
current spr.
P-side
847,0
kritisch
nm (phy.)
d_MB
790
(nm)
nm (phy.)
2,2706E+11
d_Exp
1,7 x
#REF!
(nm)
nm (phy.)
d_PB
#REF! x
(nm)
(m)
Chrissi
EC
1,555
Simul.Tool
-5,41
EV
(eV)
0,797
-6,76
0,7973
0,797
Nr.
76
4,800
InP high doped 2e18
1141
76
1410
nm
1100
nm
L1 L2
8,0
quantum wells
barriers
Material
ZnS
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
n_In_100P_100_10E18
1
n_In_100P_100_50E17
1
n_In_100P_100_50E18
1
n_In_100P_100_50E18
1
n_In_100P_100_80E17
1
n_In_100P_100_50E18
1
n_In_100P_100_50E18
1
n_In_100P_100_80E17
1
n_In_100P_100_10E18
1 748Ga_20.2974771961542In_52.263949
1
QW
1 748Ga_20.2974771961542In_52.263949
1
QW
1 748Ga_20.2974771961542In_52.263949
1
QW
1 748Ga_20.2974771961542In_52.263949
1
QW
1 748Ga_20.2974771961542In_52.263949
1
QW
1 748Ga_20.2974771961542In_52.263949
1
QW
1 748Ga_20.2974771961542In_52.263949
1 748Ga_20.2974771961542In_52.263949
1
p_Al_47.74In_52.26As_100_80E17
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
p_Al_47.74In_52.26As_100_20E18
1 _Al_5.53Ga_44.21In_50.26As_100_20E
1
TK_p
1
TK_n
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_50E17
1
n_In_100P_100_50E18
1
n_In_100P_100_50E17
1
n_In_100P_100_50E17
1
n_In_100P_100_50E18
1
n_In_100P_100_50E17
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
Au
x_Al
y_Ga
z_In
u_As
v_P
w_Sb
n -Doping
p -Doping
(cm-1)
C (cm)
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
3,1610
3,1632
3,1437
3,1437
3,1619
3,1437
3,1437
3,1619
3,1610
3,3344
3,5110
3,3344
3,5110
3,3344
3,5110
3,3344
3,5110
3,3344
3,5110
3,3344
3,5110
3,3344
3,3344
3,1985
3,5591
3,1954
3,5591
3,1954
3,5591
3,1954
3,5591
3,1954
3,7954
3,1954
3,8284
3,1954
3,7954
3,8284
3,5591
3,7954
3,5591
3,8284
3,5591
3,1988
2,7937
3,1649
3,1649
3,1649
3,1649
3,1649
3,1632
3,1437
3,1632
3,1632
3,1437
3,1632
1,3435
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
0,5613
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
1,91E-05
8,10E-06
1,45E-04
1,45E-04
1,44E-05
1,45E-04
1,45E-04
1,44E-05
1,91E-05
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
2,36E-07
1,12E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,83E-02
3,17E-02
1,19E-06
1,19E-06
1,19E-06
1,19E-06
1,19E-06
8,10E-06
1,45E-04
8,10E-06
8,10E-06
1,45E-04
8,10E-06
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
9,84E+00
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
3,0
1,3
22,9
22,9
2,3
22,9
22,9
2,3
3,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
17,7
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,2
58,5
44,2
58,5
44,2
58,5
4454,0
4990,5
0,2
0,2
0,2
0,2
0,2
1,3
22,9
1,3
1,3
22,9
1,3
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,92E-03
4,97E-03
8,85E-04
8,85E-04
3,46E-03
8,85E-04
8,85E-04
3,46E-03
2,92E-03
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
2,20E-01
6,50E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
1,10E-03
5,55E-05
1,83E-02
1,83E-02
1,83E-02
1,83E-02
1,83E-02
4,97E-03
8,85E-04
4,97E-03
4,97E-03
8,85E-04
4,97E-03
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
8,1162
35,3798
8,1162
35,3798
8,1162
35,3798
8,1162
35,3798
8,1162
35,3798
0,0149
0,0821
0,0135
0,0053
0,1281
0,0053
0,0135
0,0593
0,0149
1,1209
0,0908
0,3065
0,0908
0,3065
0,0908
0,3065
0,0908
0,3065
0,0908
0,3065
0,0908
0,3065
0,1313
0,6239
0,0005
0,0060
0,0010
0,0054
0,0016
0,0047
0,0021
0,0040
0,0026
0,0034
0,0031
0,0027
0,0036
0,0020
0,0042
0,0013
0,0047
0,0007
0,0052
0,0039
0,0001
0,0365
0,0851
0,5486
0,3470
0,2743
0,0744
0,0169
0,0744
0,0744
0,0169
0,0744
35,3798
20,7776
35,3798
20,7776
35,3798
20,7776
32,3330
9,7819
0,000
0,000
1,000
0,000
1,000
0,000
169,9
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
10
0,000
0,000
1,000
0,000
1,000
0,000
InP
11
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+18
10,0
InP
12
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
83,1
13
InP
13
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
14
InP
14
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
InP
15
0,000
0,000
1,000
0,000
1,000
0,000
8,00E+17
186,2
16
InP
16
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
17
InP
17
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
18
InP
18
0,000
0,000
1,000
0,000
1,000
0,000
8,00E+17
33,7
InP
19
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+18
10,0
20
Barriere
20
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
10,0
21
QW
21
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
22
Barriere
22
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
23
QW
23
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
24
Barriere
24
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
25
QW
25
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
26
Barriere
26
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
27
QW
27
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
28
Barriere
28
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
23
QW
23
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
24
Barriere
24
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
25
QW
25
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
26
Barriere
26
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
27
Barriere
27
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
3,0
28
InAlAs
28
0,477
0,000
0,523
1,000
0,000
0,000
8,00E+17
48,28
29
InGaAlAs
29
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,1
30
InAlAs
30
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,9
31
InGaAlAs
31
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,2
InAlAs
32
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,8
33
InGaAlAs
33
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,3
34
InAlAs
34
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,7
35
InGaAlAs
35
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,4
36
InAlAs
36
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,6
37
InGaAlAs
37
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,5
38
InAlAs
38
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,5
39
InGaAlAs
39
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,6
40
InAlAs
40
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,4
41
InGaAlAs
41
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,7
42
InAlAs
42
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,3
43
InGaAlAs
43
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,8
44
InAlAs
44
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,2
45
InGaAlAs
45
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,9
46
InAlAs
46
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,1
47
InGaAlAs
47
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
1,0
48
TK_p
48
0,055
0,442
0,503
1,000
0,000
0,000
1,50E+20
18,0
TK_n
49
0,000
0,468
0,532
1,000
0,000
0,000
1,50E+20
InP
50
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
10,0
InP
51
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
23,3
52
InP
52
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
150,5
53
InP
53
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
95,2
InP
54
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
75,2
InP
52
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
75,2
InP
53
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
95,9
54
InP
54
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
75,2
55
InP
55
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
75,2
InP
56
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
95,9
InP
57
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
AlF3
58
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
59
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
60
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
61
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
62
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
63
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
64
0,000
0,000
1,000
0,000
1,000
0,000
264,4
Au
65
0,000
0,000
1,000
0,000
1,000
0,000
80,0
8
9
10
11
12
15
19
32
1555
1555
1555
1555
l/4
l/2
l/4
l/4
49
50
51
54
1555
1555
l/4
l/2
52
53
56
1555
1555
l/2
l/2
57
58
59
60
61
62
63
64
65
1555
1555
1555
1555
1555
1555
1421
180
/4
/4
/4
/4
/4
/4
/4
15
Auenr. (m)
5
n !!!
BTJ (m)
d(nm)
500
vb(so)
EVsh
p
712
712
nm
nm
400
nm
vb(lh)
nm
-6,87
Thickness(nm)
AlF3
1543
ZnS
1555 nm
4,600
InP low doped 5e17
5484
Gasb high doped 2e18
3928
5,600
spreading layer top
688,8
5,800
spreading layer bottom
554,8
0
100
200
300
spreading layer top_VCSEL
299,9
Series1
spreading layer Series2
bottom_VCSEL vb(hh)
#REF!
394283
/4
/4
/4
/4
/4
/4
/4
/4
/4
/4
4,400
Status
nm (phy.)
0,9 x
Substrat
InP
6
Comment
4,200
5,0E-04
3,0 x
443,0
4,000
1469
a/aGes (pm)
nm (phy.)
2,5 x
Temperatur (K)
300
dGes (nm)
nm (phy.)
1,73 x
current spr.
N-side
overgrowth
1555
1555
1555
1555
1555
1555
1555
1555
1555
1555
1352,9
Energy(eV)
Semic.-DBR
289,3
11,0
75,2
121522,7430
311098,2220
121522,7430
311098,2220
121522,7430
311098,2220
121522,7430
311098,2220
121522,7430
311098,2220
3782,3196
2514,3267
1147,2395
448,1404
1750,3458
448,1404
1147,2395
4480,8853
3782,3196
285175,4022
37613,6343
111396,6415
37613,6343
111396,6415
37613,6343
111396,6415
37613,6343
111396,6415
37613,6343
111396,6415
37613,6343
111396,6415
111396,6415
32876,7579
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
558,1626
28,1163
9275,9785
9275,9785
9275,9785
9275,9785
9275,9785
2514,3267
448,1404
2514,3267
2514,3267
448,1404
2514,3267
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
mit aktiver
Zone
R_serie
8,8
ja
R_spread
87,0
Widerstandberechnung
Verluste ()
0,0280
1/cm
Schichtdicken
Dielec.-DBR
p-Cladding-Dicke angepasst
nach Simu Stehwellenfeld!!!!!!!!!
cb
vb
vb_hh
vb_lh
vb_so
Resonator
ja
ja
1352,9
2296,4
1461,8
current spr.
P-side
600,6
nm (phy.)
d_MB
1037
(nm)
nm (phy.)
d_Exp
2,7167E+12
(nm)
nm (phy.)
d_PB
#REF! x
Substrat
InP
kritisch
1,2 x
Temperatur (K)
300
4,400
Status
nm (phy.)
0,9 x
#REF!
4,200
4,1E-04
2,99 x
464,3
4,000
1462
a/aGes (pm)
nm (phy.)
2,5 x
current spr.
N-side
overgrowth
dGes (nm)
nm (phy.)
1,73 x
Energy(eV)
Semic.-DBR
532638
(nm)
(m)
Chrissi
EC
1,555
Simul.Tool
-5,41
EV
(eV)
0,797
-6,76
0,7973
0,797
1555 nm
4,600
InP low doped 5e17
4,800
InP high doped 2e18
n
1543
p
76
1141
76
EVsh
-6,87
8,0
quantum wells
3 barriers
Comment
1555
1555
1555
1555
1555
1555
1555
1555
1555
1555
/4
/4
/4
/4
/4
/4
/4
/4
/4
/4
Nr.
L1 L2
Material
ZnS
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
n_In_100P_100_10E18
1
n_In_100P_100_50E17
1
n_In_100P_100_50E18
1
n_In_100P_100_50E18
1
n_In_100P_100_80E17
1
n_In_100P_100_50E18
1
n_In_100P_100_50E18
1
n_In_100P_100_80E17
1
n_In_100P_100_10E18
1 4242748Ga_20.2974771961542In_52.26394937957
1
QW
1 4242748Ga_20.2974771961542In_52.26394937957
1
QW
1 4242748Ga_20.2974771961542In_52.26394937957
1
QW
1 4242748Ga_20.2974771961542In_52.26394937957
1 4242748Ga_20.2974771961542In_52.26394937957
1
p_Al_47.74In_52.26As_100_80E17
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
TK_p
1
TK_n
1
n_In_100P_100_10E18
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1 4242748Ga_20.2974771961542In_52.26394937957
1
QW
1 4242748Ga_20.2974771961542In_52.26394937957
1
QW
1 4242748Ga_20.2974771961542In_52.26394937957
1
QW
1 4242748Ga_20.2974771961542In_52.26394937957
1 4242748Ga_20.2974771961542In_52.26394937957
1
p_Al_47.74In_52.26As_100_80E17
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
p_Al_47.74In_52.26As_100_20E18
1
p_Al_5.53Ga_44.21In_50.26As_100_20E18
1
TK_p
1
TK_n
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_10E17
1
n_In_100P_100_50E17
1
n_In_100P_100_50E18
1
n_In_100P_100_50E17
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
ZnS
1
AlF3
1
Au
x_Al
y_Ga
z_In
u_As
v_P
w_Sb
n -Doping
p -Doping
(cm-1)
C (cm)
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
3,1610
3,1632
3,1437
3,1437
3,1619
3,1437
3,1437
3,1619
3,1610
3,3344
3,5110
3,3344
3,5110
3,3344
3,5110
3,3344
3,3344
3,1985
3,5591
3,1954
3,5591
3,1954
3,5591
3,1954
3,5591
3,1954
3,9017
3,1954
3,9017
3,1954
3,9017
3,9017
3,5591
3,9017
3,5591
3,9017
3,5591
3,1988
2,7937
3,1610
3,1649
3,1649
3,3344
3,5110
3,3344
3,5110
3,3344
3,5110
3,3344
3,3344
3,1985
3,5591
3,1954
3,5591
3,1954
3,5591
3,1954
3,5591
3,1954
3,7954
3,1954
3,8284
3,1954
3,7954
3,8284
3,5591
3,7954
3,5591
3,8284
3,5591
3,1988
2,7937
3,1649
3,1649
3,1649
3,1649
3,1649
3,1632
3,1437
3,1632
1,3435
2,2878
1,3435
2,2878
1,3435
2,2878
1,3435
0,5613
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
1,91E-05
8,10E-06
1,45E-04
1,45E-04
1,44E-05
1,45E-04
1,45E-04
1,44E-05
1,91E-05
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
2,36E-07
1,12E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,83E-02
3,17E-02
1,91E-05
1,19E-06
1,19E-06
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
1,66E-07
2,36E-07
2,36E-07
1,12E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,81E-04
3,71E-04
2,83E-02
3,17E-02
1,19E-06
1,19E-06
1,19E-06
1,19E-06
1,19E-06
8,10E-06
1,45E-04
8,10E-06
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
0,00E+00
9,84E+00
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
3,0
1,3
22,9
22,9
2,3
22,9
22,9
2,3
3,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
17,7
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,3
58,4
44,3
58,4
44,3
58,4
44,2
58,5
44,2
58,5
44,2
58,5
4454,0
4990,5
3,0
0,2
0,2
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
17,7
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,3
58,5
44,2
58,5
44,2
58,5
44,2
58,5
4454,0
4990,5
0,2
0,2
0,2
0,2
0,2
1,3
22,9
1,3
0,0
0,0
0,0
0,0
0,0
0,0
0,0
0,0
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,92E-03
4,97E-03
8,85E-04
8,85E-04
3,46E-03
8,85E-04
8,85E-04
3,46E-03
2,92E-03
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
2,20E-01
6,50E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
1,10E-03
5,55E-05
2,92E-03
1,83E-02
1,83E-02
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
7,43E-02
2,20E-01
2,20E-01
6,50E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
3,37E-02
2,61E-02
1,10E-03
5,55E-05
1,83E-02
1,83E-02
1,83E-02
1,83E-02
1,83E-02
4,97E-03
8,85E-04
4,97E-03
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
2,40E-01
8,1162
35,3798
8,1162
35,3798
8,1162
35,3798
8,1162
35,3798
8,1162
35,3798
0,0149
0,0821
0,0135
0,0053
0,1281
0,0053
0,0135
0,0968
0,0149
1,1209
0,0908
0,3065
0,0908
0,3065
0,0908
0,3065
0,1313
0,8434
0,0005
0,0060
0,0010
0,0054
0,0016
0,0047
0,0021
0,0040
0,0026
0,0034
0,0031
0,0027
0,0036
0,0020
0,0042
0,0013
0,0047
0,0007
0,0052
0,0039
0,0001
0,0058
0,2204
0,0365
1,1209
0,0908
0,3065
0,0908
0,3065
0,0908
0,3065
0,1313
0,8830
0,0005
0,0060
0,0010
0,0054
0,0016
0,0047
0,0021
0,0040
0,0026
0,0034
0,0031
0,0027
0,0036
0,0020
0,0042
0,0013
0,0047
0,0007
0,0052
0,0039
0,0001
0,0365
0,0851
0,5486
0,3470
0,2743
0,0744
0,0169
0,0744
35,3798
20,7776
35,3798
20,7776
35,3798
20,7776
32,3330
9,7819
0,000
0,000
1,000
0,000
1,000
0,000
169,9
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
10
0,000
0,000
1,000
0,000
1,000
0,000
InP
11
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+18
10,0
InP
12
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
83,1
13
InP
13
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
14
InP
14
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
InP
15
0,000
0,000
1,000
0,000
1,000
0,000
8,00E+17
186,2
16
InP
16
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
17
InP
17
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
30,0
18
InP
18
0,000
0,000
1,000
0,000
1,000
0,000
8,00E+17
55,0
InP
19
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+18
10,0
20
Barriere
20
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
10,0
21
QW
21
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
22
Barriere
22
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
23
QW
23
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
24
Barriere
24
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
25
QW
25
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
26
Barriere
26
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
27
Barriere
27
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
3,0
28
InAlAs
28
0,477
0,000
0,523
1,000
0,000
0,000
8,00E+17
65,2662367
29
InGaAlAs
29
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,1
30
InAlAs
30
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,9
31
InGaAlAs
31
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,2
32
InAlAs
32
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,8
33
InGaAlAs
33
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,3
34
InAlAs
34
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,7
InGaAlAs
35
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,4
36
InAlAs
36
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,6
37
InGaAlAs
37
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,5
38
InAlAs
38
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,5
39
InGaAlAs
39
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,6
40
InAlAs
40
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,4
41
InGaAlAs
41
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,7
42
InAlAs
42
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,3
43
InGaAlAs
43
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,8
44
InAlAs
44
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,2
45
InGaAlAs
45
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,9
46
InAlAs
46
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,1
47
InGaAlAs
47
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
1,0
48
TK_p
48
0,055
0,442
0,503
1,000
0,000
0,000
1,50E+20
18,0
49
TK_n
49
0,000
0,468
0,532
1,000
0,000
0,000
1,50E+20
11,0
50
InP
50
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+18
10,0
InP
51
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
60,458
InP
52
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
10,0
53
Barriere
53
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
10,0
54
QW
54
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
55
Barriere
55
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
56
QW
56
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
57
Barriere
57
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
58
QW
58
0,087
0,203
0,710
1,000
0,000
0,000
1,00E+16
6,1
59
Barriere
59
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
7,0
60
Barriere
60
0,274
0,203
0,523
1,000
0,000
0,000
1,00E+16
3,0
61
InAlAs
61
0,477
0,000
0,523
1,000
0,000
0,000
8,00E+17
68,3356989
62
InGaAlAs
62
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,1
63
InAlAs
63
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,9
64
InGaAlAs
64
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,2
65
InAlAs
65
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,8
66
InGaAlAs
66
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,3
67
InAlAs
67
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,7
InGaAlAs
68
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,4
69
InAlAs
69
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,6
70
InGaAlAs
70
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,5
71
InAlAs
71
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,5
72
InGaAlAs
72
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,6
73
InAlAs
73
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,4
74
InGaAlAs
74
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,7
75
InAlAs
75
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,3
76
InGaAlAs
76
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,8
77
InAlAs
77
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,2
78
InGaAlAs
78
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
0,9
79
InAlAs
79
0,477
0,000
0,523
1,000
0,000
0,000
2,00E+18
0,1
80
InGaAlAs
80
0,055
0,442
0,503
1,000
0,000
0,000
2,00E+18
1,0
81
TK_p
81
0,055
0,442
0,503
1,000
0,000
0,000
1,50E+20
18,0
TK_n
82
0,000
0,468
0,532
1,000
0,000
0,000
1,50E+20
11,0
InP
83
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
10,0
InP
84
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
23,3
InP
85
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
150,5
InP
86
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
95,2
InP
87
0,000
0,000
1,000
0,000
1,000
0,000
1,00E+17
75,2
InP
88
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
75,2
InP
89
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+18
95,9
InP
90
0,000
0,000
1,000
0,000
1,000
0,000
5,00E+17
AlF3
91
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
92
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
93
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
94
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
95
0,000
0,000
1,000
0,000
1,000
0,000
289,3
ZnS
96
0,000
0,000
1,000
0,000
1,000
0,000
169,9
AlF3
97
0,000
0,000
1,000
0,000
1,000
0,000
264,4
Au
98
0,000
0,000
1,000
0,000
1,000
0,000
80,0
4
5
6
7
8
9
10
11
12
15
19
35
51
52
68
1555
1555
1555
1555
1555
1555
l/4
l/2
l/4
l/4
l/4
l/4
82
83
84
1555
l/4
85
86
87
1555
l/2
88
89
1555
l/2
90
91
92
93
94
95
96
97
98
1555
1555
1555
1555
1555
1555
1421
180
/4
/4
/4
/4
/4
/4
/4
15
Auenr. (m)
5
n !!!
AlF3
BTJ (m)
d(nm)
ZnS
500
vb(so)
289,3
75,2
121522,7430
311098,2220
121522,7430
311098,2220
121522,7430
311098,2220
121522,7430
311098,2220
121522,7430
311098,2220
3782,3196
2514,3267
1147,2395
448,1404
1750,3458
448,1404
1147,2395
4480,8853
3782,3196
285175,4022
37613,6343
111396,6415
37613,6343
111396,6415
37613,6343
111396,6415
111396,6415
32876,7579
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
558,1626
28,1163
1477,4686
9275,9785
9275,9785
285175,4022
37613,6343
111396,6415
37613,6343
111396,6415
37613,6343
111396,6415
111396,6415
32876,7579
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
17078,8541
13202,1935
558,1626
28,1163
9275,9785
9275,9785
9275,9785
9275,9785
9275,9785
2514,3267
448,1404
2514,3267
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
311098,2220
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0 VER30c
Tunnelkontakt strukturieren
OK Anlage / Material
Digitalkamera
Chemie / DI-Wasser
HCl : H2O = 1 : 5
80ml : 400ml
Ofen mit N2
ber Lackschleuder
Lackschleuder; Hotplate
/
AZ5214
Maske VER30c
Aceton, Propanol
MA6 /
Maske VER30c
Litho Enwicklerbank /
2 Quarzglser;
AZ400K : H2O = 1 : 4
Mikroskop /
saubere Objekttrger
Barrel - Etcher
Prozessschritt
Parameter Prozess
Pinzette "1. Mesa" / auskochen
Flat nach unten
Wafer fotografieren
HCl-Dip
(Oxidentfernung fr
Lackhaftung)
H2O abdampfen
Belackung
Positivprozess
1. Mesa
Maske reinigen
Belichten
Positivprozess
1. Mesa
Entwicklung
Positivprozess
1. Mesa
1,80 s
50 s - 120 s
20 s
5s
20 s
Sichtkontrolle
+Foto
Lackreste veraschen
nach Litho
ECR - RIE
(Modul 3)
Dummy M2595
Stoppuhr
Regenerieren 3 Zyklen
Ultraschall; Hotpl. /
Acet. / Prop. VLSI
Quarzglas AI
Quarzglas AII
Quarzglas AIII
Quarzglas P
Glasdose fr Wafer
Entlackung
1. Mesa
Mundschutz!
Glser reinigen: H2O + Aceton (200C)
Ultraschall kaltes Aceton
Ultraschall kaltes Aceton
heies Aceton
heies Propanol
Wafer in Glasdose wechseln
alpha - Step /
saubere Objekttrger
berhhung
Tunnelkontakt
Mikroskop /
saubere Objekttrger
Sichtkontrolle
+Foto
Barrel - Etcher
Stoppuhr
MBE-Termin; Chemie/
HCl : H2O = 1 : 2
80ml : 160ml
in kleines Quarzglas;
groes Quarzglas H2O;
heies DI-Wasser im
Erlmeierkolben
Lackreste veraschen
vor Endreinigung
Endreinigung
und
Einschleusen in die
MBE
Pos
1
2
3
4
5
Entwicklungszeit:
____________
M4456: 28+39s
Trockentzung
Tunnelkontakt
Bemerkungen
Layer 5
(N2:H2:CH4 =
1:54:16 sccm)
MW = 31%
HF = 28 W
5 min @ 10%
3 min @ 10%
3 min @ 200C
1 min @ 300C
k Bereich, unkorrigiert
Mundschutz! - MDZ-Foto ganzen Wafer genau berprfen!!
10% 600 W Mundschutz / extra Uhrglas
30 min Sauerstoffplasma
Mundschutz!
3 x Splen der Schleuder
Auskochen Substratreinigunspinzette Ac
25 s HCl - Dip kl. Glas
5 s Stoppglas Wasser
50 s Kaltwasserschleudern
50 s Heiwasserschleudern
tztiefe(nm)
minimale tztiefe:
____________
tztiefe Soll:
____________
tztiefe Ist:
12.1nm
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0
VER3z
Prozessschritt
MBE-Termin
berwachsung
berwachsung
Chemie / DI-Wasser
HCl-Dip
HCl : H2O = 1 : 5
(Oxidentfernung fr
Lackhaftung)
40ml : 200ml
Ofen mit N2
H2O abdampfen
ber Lackschleuder
Lackschleuder; Hotplate
90 C /
Belackung
AZ5214
Image Reversal
MA6 /
Maske VER3z
Hotplate 125 C
Lackvernetzung
MA6
Flood-Exposure
Litho Enwicklerbank
AZ400K : H2O = 1 : 4
Mikroskop
Barrel - Etcher
alpha - Step
HCl : H2O = 1 : 5
40ml : 200ml
H3PO4 : H2O2 : H2O = 1
:1:8
50ml : 50ml : 400ml
HCl : H2O = 2 : 1
160ml : 80ml
25-50nm/s@RT
Entwicklung
IR-Prozess
Sichtkontrolle
+Foto
Lackreste veraschen
nach Litho
Lackdicke
HCl-Dip
+
nasschemische
tzung
Kontaktschicht
Prozess
Sichtkontrolle
+Foto
Hotpl. /Aceton /
Propanol
Spritze Entlackung
Glser AI, AII, P
Mikroskop
Entlackung
Image Reversal
Sichtkontrolle
+Foto
tztiefe
Kontaktschicht+InPHeatspreader
1
2
3
4
5
Bemerkungen
Regrowth-Nr.:
____________
30 s DIP
20 s H2O
Wasserstrahl
150 C Stickstoff!!
10 min
2x 40 s N2 abblasen
Lackauftrag
Programm 4 schleudern (1000/3000rpm fr 2/40s)
90 s @ 90 C Hotplate
Beschr. VERxx links oben
1,8 s Belichten SOFT-Kontakt; 0,35 WEC
sonst klebt Maske!!
30 s Image Reversal Bake
MDZ Justage an
rechtes Objektiv
17s Flood-Exposure
15 s Entwicklung - kleine Lcher sichtbar
5 s Stoppglas Wasser
20 s Wasserstrahl
Entwicklungszeit:
_____________
M5262: 17s
MDZ-Foto
Mesen-Foto
55% 250 W
3 min Sauerstoffplasma
k Bereich, unkorrigiert
_______________
10 s HCl
nasschemische
tzung InP-Schicht
Mikroskop
alpha - Step
Belichten
Image Reversal
Parameter
30 s Wasserglas
Abzug!! 31.5nm/s
M5263:
M5264:
MDZ-Foto
Mesen-Foto
3 min @ RT Spritze kaltes Aceton
3 min @ 200C Spritze heies Aceton
1 min @ 300C heies Propanol
MDZ-Foto
Mesen-Foto
k Bereich, unkorrigiert
tztiefe Soll:
____________
tztiefe Ist:
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0
VER31c
Kontaktschicht
OK Anlage / Material
Prozessschritt
Chemie / DI-Wasser
HCl-Dip
(Oxidentfernung fr
HCl : H2O = 1 : 5
Lackhaftung)
80ml : 400ml
Ofen mit N2
H2O abdampfen
ber Lackschleuder
Lackschleuder; Hotplate
/
Belackung
AZ5214
Positivprozess
MA6 /
Maske VER31c
Litho Enwicklerbank /
AZ400K : H2O = 1 : 4
Mikroskop
Belichten
Positivprozess
Entwicklung
Positivprozess
Sichtkontrolle
+Foto
Barrel - Etcher
Lackreste veraschen
nach Litho
HCl : H2O = 1 : 5
40ml : 200ml
H3PO4 : H2O2 : H2O =
1:1:8
50ml : 50ml : 400ml
HCl-Dip
+
nasschemische
tzung
Kontaktschicht
Mikroskop
Sichtkontrolle
+Foto
Hotpl. /Aceton /
Propanol
Spritze Entlackung
Glser AI, AII, P
Mikroskop
alpha - Step
Entlackung
Pos. Prozess
Sichtkontrolle
+Foto
tztiefe
Kontaktschicht
Parameter Prozess
Bemerkungen
30 s DIP
20 s H2O
Wasserstrahl
150 C Stickstoff!!
10 min
2x 40 s N2
Lackauftrag
Programm 4
120 s @ 115 C
10 min
abblasen
Glaspipette!
schleudern (1000/3000rpm fr 2/40s)
Hotplate auf Kreuzschlitz-Carrier
Abkhlen
50 s - 120 s Entwicklung
5 s Stoppglas Wasser
20 s Wasserstrahl
Entwicklungszeit:
____________
M5262: 60s
tztiefe Soll:
____________
t ti f I t
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0 VER33B
SiO2-Maske fr Chlor-Prozess
OK Anlage / Material
Prozessschritt
Parameter
Prozess
2x 40 s N2 abblasen
Lackauftrag
Programm 4 schleudern (1000/3000rpm fr 2/40s)
90 s @ 90 C Hotplate
Lackschleuder; Hotplate
90 C /
AZ5214
Belackung
Image Reversal
MA6 /
Maske VER33B
Belichten
Image Reversal
Hotplate 125 C
Lackvernetzung
MA6
Flood-Exposure
17 s Flood-Exposure
Litho Enwicklerbank
AZ400K : H2O = 1 : 4
Entwicklung
IR-Prozess
Mikroskop
Barrel - Etcher
Lackreste veraschen
nach Litho
55% 250 W
3 min Sauerstoffplasma
Chemie / DI-Wasser
HCl : H2O = 1 : 5
40ml : 200ml
HCl-Dip
(Oxidentfernung fr
Haftung SiO2)
30 s DIP
5 s Stoppglas Wasser
20 s Wasserstrahl
P-Anlage /
SiO2-Tiegel
Mikroskop
Dektak
Barrel - Etcher
Stoppuhr
Chlortzung:
Sichtkontrolle
+Foto
Aufdampfung
SiO2-Maske
SiO2 Lift-Off
Sichtkontrolle
+Foto
Dicke tzmaske
Lackreste veraschen
nach Lift-Off
Bemerkungen
Entwicklungszeit:
____________
M5262: 17s
JM-Foto
Mesen-Foto
5 /s 100 nm
10 /s 1000 nm mit Dummy dabei (Sicherheit)
in Excel-Sheet nachschauen ->SC
3 min kaltes Aceton; Di-LO -M Glas, SiO2-Spr.
3 min @ 200C heies Aceton
1 min @ 300C heies Propanol
direkt vor
Schleusung
p-Anlage
kein pre-Dummy;
eher dicker
Eigene Spritze!!
JM-Foto
Mesen-Foto
k Bereich, unkorrigiert:_________ x 1,037 = Maske
I
10% 600 W
15 min Sauerstoffplasma
Probe
M4456
M4595
Rauhigkeit
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske: VER33bz
0-
Prozessschritt
RIE
(Modul 1)
Trockentzung
Tunnelkontakt
alpha - Step
tztiefe ChlorProzess
Mikroskop
Sichtkontrolle
+Foto
Parameter
Prozess
Bemerkungen
JM:
____________
JM-Foto
Mesen-Foto
Lackschleuder;
Hotplate /
AZ5214
Belackung
Positivprozess
MA6 /
Maske VER33bz
Belichten
Positivprozess
Litho Enwicklerbank /
AZ400K : H2O = 1 : 4
Entwicklung
Positivprozess
Mikroskop
Sichtkontrolle
+Foto
Lackreste
veraschen
nach Litho
HCl-Dip
+
nasschemische
tzung
Kontaktschicht
Barrel - Etcher
HCl : H2O = 1 : 5
40ml : 200ml
H3PO4 : H2O2 : H2O
=1:1:8
50ml : 50ml : 400ml
HCl : H2O = 2 : 1 (1 :
1)
160ml : 80ml
25-50nm/s@RT
Mikroskop
Hotpl. /Aceton /
Propanol
Spritze Entlackung
Glser AI, AII, P
Mikroskop
abblasen
50 s - 120 s Entwicklung
5 s Stoppglas Wasser
20 s Wasserstrahl
Sichtkontrolle
+Foto
Entlackung
Pos. Prozess
Sichtkontrolle
+Foto
Abzug!! 31.5nm/s
M5263:
M5264:
MDZ-Foto
Mesen-Foto
3 min @ RT Spritze kaltes Aceton
3 min @ 200C Spritze heies Aceton
1 min @ 300C heies Propanol
MDZ-Foto
Mesen-Foto
k Bereich, unkorrigiert
tztiefe
Kontaktschicht
Entwicklungszeit:
____________
alpha - Step
2x 40 s N2
Lackauftrag
Programm 4
120 s @ 115 C
10 min
tztiefe Soll:
____________
tztiefe Ist:
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0-
Plasmalab 80plus
(Anlage 4)
Chemie / DI-Wasser
HF : H2O = 1 : 2
Prozessschritt
Prozess
SiO2-Maske
entfernen (nass)
10 s DIP
5 s Stoppglas Wasser
JM-Foto
Mesen-Foto
Mikroskop
Sichtkontrolle
+Foto
alpha - Step
tztiefe
Chlor-Prozess
HCl-Dip
SiO2-Sputtern
(Haftung BCB)
DIP
Stoppglas Wasser
Wasserstrahl
Protokoll fhren;
Ziel 400nm: Peile 450 an.
(2x Dummy)
Spin-Kurve
tztiefe (m):
____________
Sputterdicke
Dummy:
_______________
BCB-U/min.:
____________
Lackschleuder; Hotplate
40 s N2
130 C /
Haftvermittler BCB Adh-P-Auftrag
Adhesion BCB
Programm 4
aufschleudern
Chuck!
120 s @ 130 C
Lackschleuder mit Papier
40 s N2
auslegen
BCB-Auftrag
BCB
Dry-etch-BCB
2x
aufschleudern
abblasen
Glaspipette
schleudern (1000/3000rpm fr 2/40s)
Hotplate
abblasen
abgeschnittene Glaspipette schleudern
(1000/1000/7000rpm fr 2s/40s/4s)
Ofen ber
Entwicklerbank mit N2
Programm 1
1h
1h
1h
bis unter 100 C; Wafer auf Filterpapier
(alternativ!!)
HF-Schutzkleidung
Drehzahl BCB
bestimmen
Bemerkungen
SiO2-Maske
entfernen (trocken)
Chemie / DI-Wasser
HCl : H2O = 1 : 5
40ml : 2000ml
Sputteranlage /
SiO2-Target
Parameter
Sputteranlage /
SiO2-Target
Probe
M4456
BCB
hard cure
SiO2-Sputtern
(Haftung BCB)
SiO2 400nm
50 C - 150 C
150 C - 250 C
250 C
cooldown
SiO2 100nm
428 105-112
BCB U/min
1000/1000/1000
Prozess-Nr.:
____________
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0 VER34B
Belackung
MAP 1275
MA6 /
Maske "Randweg 2mm"
Belichten
Rand weg MAP
Litho Enwicklerbank
AZ400K : H2O = 1 : 3
2 Glser
MA6 /
Maske VER34b
Litho Enwicklerbank
AZ400K : H2O = 1 : 3
DekTak
Mikroskop
Prozessschritt
Entwickeln
Rand weg MAP
Belichten
MAP 1275
Entwickeln
MAP 1275
Lackdicke
BCB-Mesen tzen
Sichtkontrolle
+Foto
Chemie
Entlackung
DekTak - Step
Dicke BCB
Barrel-Etcher
Mikroskop
40 s N2
Lackauftrag
2500 (2850)
rpm
20min @RT
abblasen
abgeschnittene Glaspipette
Programm (1000 f. 2s, 2500 rpm f. 40
s
Ausgasen (wg Rissbildung)
zentrisch justieren
300 s Belichten Soft-Kontakt; 0 WEC
90-120s Entwicklung
5 s Stoppglas Wasser
20 s Wasserstrahl
GUT justieren
15 s Belichten Hard-Kontakt; 0,4 WEC
90s - 105 s
5s
20 s
m
Sichtkontrolle
+Foto
Plasmalab 80plus
(Anlage 4)
Mikroskop
Parameter Prozess
Entlacken
+Foto
Sichtkontrolle
+Foto
10 s
300 s
200 s
300 s
Entwicklung
Stoppglas Wasser
Wasserstrahl
Bereich, unkorrigiert:_________ x
1,0237 =
alphaprofil-Foto
Mesen-Foto
Bemerkungen
M4456: 2800
M4173: 3000
evtl. 2500 ->
Parasitics
Entwicklungszeit:
____________
M5262: 90s
Entwicklungszeit:
____________
M5262: 50s
Maske Ist:_______
Justage OK??
Lack veraschen
siehe PlasmalabSiO2
Protokoll
BCB
SiO2 tzen - Programm "Mesen BCB"
JM-Foto
Mesen-Foto
Mesen mssen
frei sein!
Offset Ist:_______
________ BCB ist
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0 VER35B
p-Kontaktring
OK Anlage / Material
Prozessschritt
Chemie / DI-Wasser
HCl-Dip
HCl : H2O = 1 : 5
(Oxidentfernung fr
Lackhaftung)
40ml : 200ml
Ofen mit N2
H2O abdampfen
ber Lackschleuder
Lackschleuder; Hotplate
90 C /
Belackung
AZ5214
Image Reversal
MA6 /
Maske 2mm Randweg
MA6 /
Maske VER35B
Belichten
Image Reversal
Belichten
Image Reversal
40 s N2 abblasen
Lackauftrag
Programm 4 schleudern (1000/3000rpm fr 2/40s)
90 s @ 90 C Hotplate
3 s Soft-Kontakt
Beschr. VERxx links oben
1,8 s Belichten Hard-Kontakt; 0,4 WEC
30 s Image Reversal Bake
MA6
Flood-Exposure
17 s Flood-Exposure
Litho Enwicklerbank
AZ400K : H2O = 1 : 4
Entwicklung
IR-Prozess
Barrel - Etcher
Lackreste veraschen
nach Litho
Chemie / DI-Wasser
HCl : H2O = 1 : 5
40ml : 200ml
VT118 /
Pt-Tiegel
HCl-Dip
(Oxidentfernung vor
Metallisierung)
Infineon-Lift-Off
Ti-Pt-Au
Lift-Off
Mikroskop
Barrel - Etcher
Stoppuhr
Sichtkontrolle
+Foto
Aufdampfung
p-Kontakt
Sichtkontrolle
+Foto
Lackreste veraschen
nach Lift-Off
Bemerkungen
30 s DIP
20 s H2O
Wasserstrahl
150 C Stickstoff!!
10 min
Lackvernetzung
Mikroskop
Prozess
Hotplate 125 C
Parameter
Alignment an Mesen
am Waferrand!!!
Entwicklungszeit:
____________
M5262: 16s
alle Mesen da??
55% 250 W
3 min Sauerstoffplasma
30 s
5s
20 s
30 nm
80nm
300nm
20min
DIP
Stoppglas Wasser
Wasserstrahl
Ti, Pt schrg rotierend 30, Au
senkrecht wegen berlapp BTJ-Loch
mit Innenradius KR
Einweichen
sprhen bis weg
direkt vor
Schleusung VT118
Kontakt-Ring-Foto
15% 600 W
6 min Sauerstoffplasma
kein Ultraschall
(Metall-Brsel)
Rckseite frei?
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0 VER36m
Dielektrischer Spiegel
OK Anlage / Material
Prozessschritt
Parameter
Prozess
40 s N2 abblasen
Lackauftrag
Programm 4 schleudern (1000/3000rpm fr 2/40s)
90 s @ 90 C Hotplate
Lackschleuder; Hotplate
90 C /
AZ5214
Belackung
Image Reversal
MA6 /
Maske VER36m
Belichten
Image Reversal
Hotplate 125 C
Lackvernetzung
MA6
Flood-Exposure
17 s Flood-Exposure
Litho Enwicklerbank
AZ400K : H2O = 1 : 4
Entwicklung
IR-Prozess
Bemerkungen
Entwicklungszeit:
____________
Mikroskop
Barrel - Etcher
p-Anlage /
ZnS-Tiegel + Dummy
Dummy
ZnS
TF neu:
__________
p-Anlage /
CaF2-Tiegel + Dummy
Dummy
CaF2
TF neu:
__________
Chemie / DI-Wasser
HCl : H2O = 1 : 5
40ml : 200ml
p-Anlage /
ZnS-, CaF2-, Au-Tiegel
HCl-Dip
(Oxidentfernung vor
Metallisierung)
Aceton; Prop.-Fl.
Spritze MgF2, Glas DiE
Pt Lift-Off
Mikroskop
Lackreste veraschen
nach Litho
Aufdampfung
Spiegel
Sichtkontrolle
+Foto
alpha - Step
Dicke Spiegel
Barrel - Etcher
Stoppuhr
Ofen mit N2
ber Lackschleuder
Mesen-Foto
Sichtkontrolle
+Foto
Lackreste veraschen
nach Lift-Off
Tempern Spiegel
55% 250 W
3 min Sauerstoffplasma
30 s
5s
20 s
3.5
_______ nm
DIP
Stoppglas Wasser
Wasserstrahl
Paare ZnS / CaF2 + 100 nm Au
Stoppbandmitte
direkt vor
Schleusung
p-Anlage
249,8nm CaF2
147,2nm ZnS
225,1nm CaF2
kein Ultraschall
Rckseite frei?
Spiegel-Foto
JM-Foto
k Bereich, unkorrigiert:_________ x 1,037 Ist:
Mitte Wafer =
_________ nm
Soll: _______ nm
10% 600 W
nicht gemacht
15 min Sauerstoffplasma
fr M4456
180 C Stickstoff!!
60 min
nicht gemacht
fr M4456
10
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0 VER37A
alpha - Step
Mikroskop
Prozessschritt
Belackung
MAP 1275
Belichten
Rand weg MAP
Entwickeln
Rand weg MAP
Belichten
MAP 1275
Entwickeln
MAP 1275
Lackdicke
Sichtkontrolle
+Foto
Plasmalab 80plus
(Anlage 4)
BCB-VIA tzung
Auge / Mikroskop
Aceton / Prop.-Flasche
Spritze MgF2
Glas DiE-lo
Sichtkontrolle
+Foto
Entlackung
MAP 1275
alpha - Step
Dicke BCB
Mikroskop
Ofen mit N2
ber Lackschleuder
Sichtkontrolle
+Foto
Tempern BCB
+ Spiegel
VT118
Aufdampfung
Au-Substrat Basis
Parameter Prozess
40 s N2 abblasen
Lackauftrag abgeschnittene Glaspipette
2850 rpm
20min @ Ofen mit Stickstoff
100C
zentrisch justieren
300 s Belichten Soft-Kontakt; 0 WEC
3 min Entwicklung mit 2 Glsern
5 s Stoppglas Wasser
20 s Wasserstrahl
Bemerkungen
evtl. langsamer
spinnen
Entwicklungszeit:
____________
M4456: 60+70s
justieren
40 s Belichten Hard-Kontakt; 0,4 WEC
ca. 65 s Entwicklung 1 Glas
5 s Stoppglas Wasser
20 s Wasserstrahl
Entwicklungszeit:
____________
M4456: 65s (mehr->
berentwickelt, z.B
85s)
Maske Ist:_______
M4456: 7,5um
Lack
SiO2
BCB
SiO2 tzen - Programm "BCB VIA"
Programm
VERTILAS
JM-Foto
Wafer spiegelt
alphaprofil VIA,
VIA + Mesen-Foto
150 C Stickstoff!!
60 min
30 nm Ti, Pt, Au schrg rotierend 30; 100nm Au
80nm @ 0.5nm/s, 580nm Au @ 1.5nm/s
680nm
Vorsicht!
Spiegel! / BCB!
11
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0
Galvanik
OK
Prozessschritt
Crystall Bond 509, GlasSlip mit Loch, Glas-Slip
klein ohne Loch, Scale,
Hotplate
Goldbad NEU
ansetzen
Puramet Goldbad
Goldbad
auffrischen
Start Galvanik
Bemerkungen
Hotplate 150C fr Wafer
200C fr CoverSlip auf Alublock
Mglichst keine Crystall-Bond-freien
Blasen zw. Glasplatte u. Coverslip
sowie Wafer & Glasplatte
mb=______________
ma=______________
Wafer mit & ohne
Glasplatte wiegen
11 g
198 ml
252ml
2ml
8min @ 30%
Au-Salz
H2O
Konzentrat Paramet 402
Ergnzer
US
Bad max. 2x
verwenden;Glser &
Lffel absplen &
neutralisieren
4,3 g
30 ml
no
2ml
5min @ 30%
Au-Salz
H2O
Konzentrat Paramet 402
Ergnzer
US
Bad max. 2x
verwenden;Glser &
Lffel absplen &
neutralisieren
weight Wafer
before & after
clueing
Puramet Goldbad
Parameter
Hotplate 150C
50-60m goal-thickness
<12mA/Wafer speed (start 1mA -- je 1min x2)
(mittel) 0.092 m/mA*h
End Galvanik
scale
weight Wafer
Aceton, Folie, AcetonGlas
Mikroskop
Remove Crystall
Bond
determine Gold-thickness
d=mass/density*Area
A=20cm2, density=19.3g/cm3
1 day in Aceton-glas upside-down
picture 50x
Control, Picture
scale
m=_____________
Weight Wafer
12
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0
Substrat-Ablsung / n-KS-tzung
OK Anlage / Material
Lackschleuder
AZ 5214
Prozessschritt
Belackung
AZ 5214
Surebank, Flowbox,
Magnetrhrer
Substrat-tzung
Parameter Prozess
40 s N2 abblasen
Lackauftrag
1000 rpm 2s Programm 4
3000 rpm 10s nach 10s abbrechen
18 min in Glas I HCL:H20 4:1 (400ml:100ml)
ca. 10 min in Glas II bis vereinzelt durchgetzt
in Glas III HCL:H20 2:1 (160ml:80ml)
bis vollstndig entfernt
Mikroskop
Etch-Stop-/
Buffer-LayerRemoval
DekTak
HINWEIS
ACHTUNG
Lackschleuder; Hotplate
/
AZ5214
MA6 /
Maske VER310b F&E
Litho Enwicklerbank /
AZ400K : H2O = 1 : 4
Dektak
Mikroskop /
saubere Objekttrger
HCl : H2O = 1 : 5
40ml : 200ml
H3PO4 : H2O2 : H2O =
1:1:8
50ml : 50ml : 400ml
Mikroskop
Belichten
Positivprozess
Entwicklung
Positivprozess
Lackhhe
2x 40 s N2
Lackauftrag
Programm 4
120 s @ 115
C
abblasen
schleudern (1000/3000rpm fr 2/40s)
Hotplate auf Kreuzschlitz-Carrier
Abkhlen
Entwicklungszeit:
____________
M5262: 50s
nicht berentw. >KS
Sichtkontrolle
+Foto
HCl-Dip
+
nasschemische
tzung
Kontaktschicht
Sichtkontrolle
+Foto
Entlackung
Dektak
Mesen plan?
Before BufferRemoval: remove
edge ridge
h=___________
hsoll=dInP-Bufferdbertzung
Rckseite belackt
lassen
Belackung
Positivprozess
am Ort von
Mikrorissen kann
ein pyramidenfrmiger Grat
stehen bleiben
Rckseite belackt
lassen
Chemie
Hhe bertzung
bestimmen
NICHT auf
Hotplate!!!
Ausgasen lassen
(5min)
Sichtkontrolle
Surebank, Flowbox,
Magnetrhrer
Bemerkungen
M5262: 15s
13
Stoppbandmitte:
0 nm
Basis: M5263,M5264
berw.:
Maske:
0 VER310m F&E
n-Kontakt Pads
OK
Prozessschritt
Skalpell, Metallsockel,
Cleaveplatz
Chemie / DI-Wasser
HCl : H2O = 1 : 5
40ml : 200ml
VT118 /
Ti-Tiegel
Mikroskop
Multimeter
Lackschleuder; Hotplate
90 C /
AZ5214
MA6 /
Maske VER310m F&E
Hotplate 125 C
MA6
Litho Enwicklerbank
AZ400K : H2O = 1 : 4
Mikroskop
Barrel - Etcher
Chemie / DI-Wasser
HCl : H2O = 1 : 5
80ml : 400ml
VT118 /
Ti-, Pt-, Au-Tiegel
Ac. / Prop.
Gasmaske
Sprhflasche Infineon
Mikroskop
remove ridges at
the edge of the
wafer and at
dislocations
HCl-Dip
(Oxidentfernung
vor Metallisierung)
Parameter
Bemerkungen
Dektak-Kontrolle
30 s
5s
20 s
40 nm
DIP
Stoppglas Wasser
Wasserstrahl
Ti 30 rotierend
Aufdampfung TiSchicht
Control, Picture
Test Conductivity
Belackung
Image Reversal
Belichten
Image Reversal
Lackvernetzung
Flood-Exposure
Entwicklung
IR-Prozess
Sichtkontrolle
+Foto
Lackreste
veraschen
nach Litho
HCl-Dip
Aufdampfung
n-Kontaktring & pad
Lift-Off
Sichtkontrolle
+Foto
Kein veraschen von
Lackresten
wichtig fr
anschlieendes
Lackaufspinnen &
Alignen
direkt vor
Schleusung VT118
dicke je nach Rauhigkeit Chlortzung
M4456: 40nm
picture 50x
Leitfhigkeit an gegenberliegenden
Enden des Wafers test.
2x 40 s N2 abblasen
Lackauftrag
Programm 4 schleudern (1000/3000rpm fr 2/40s)
90 s @ 90 C Hotplate
Beschr. VERxx RECHTS UNTEN??? Ausrichtung an
1,8 s Belichten Hard-Kontakt; 0,35 WEC
"Fadenkreuz" &
VCSELN. Bei
schlechter Chlortzung schwierig
30 s Image Reversal Bake
17s Flood-Exposure
15 s Entwicklung - kleine Lcher sichtbar
5 s Stoppglas Wasser
20 s Wasserstrahl
Pad-VCSEL-Foto
Alignmentmarken-Foto
55% 250 W
3 min Sauerstoffplasma
Entwicklungszeit:
____________
M5262:16s
30 s DIP
20 s H2O
Wasserstrahl
20 nm Ti 10 - 30 rotierend aufgedampft:
100nm Pt 10% (CAR-Einst. 2027) bei Substrat300nm Au tztiefe <100nm
20% (1850) <-> 100-200nm
30% (1675)<-> >200nm
>15min kopfber in Acetonbad; danach
Absprhen
Hinweis: nur Temperaturen <100C
anwenden
Pad-VCSEL-Foto
Alignmentmarken-Foto
Gold wird evtl. oxidiert
(Oxidentfernung fr
niedrigeren
Kontaktwiderstand)
Substrattztiefe
entspricht
Hhenunterschied
zw. SiO2/BCB &
epitakt. Spiegel
kein Ultraschall;
Alternativ auch
Standard Metall-LiftOff mit Spritze mgl
14
Stoppbandmitte:
0 nm
Basis: M4173
berw.: M4195
Maske:
VER312b F&E
Prozessschritt
Lackschleuder; Hotplate
/
AZ5214
Lackschleuder; Hotplate
100 C /
AZ5214
MA6 /
Maske VER312b F&E
Litho Enwicklerbank /
AZ400K : H2O = 1 : 4
Mikroskop
Barrel - Etcher
Dektak
Photolack, Waferhalter
Linda (Klammern),
passende glasscheiben,
Pipette
Galvanikaufbau, fr
Heatsink verwendeten
Ansatz verwenden
Dektak
Mikroskop
Ac. , Prop.
Spritze Metall
Entlackung
Glser Metall AI, AII, P
HF-Behlter,
Schutzkleidung,
HF:H2O=1:9
(25ml : 225ml)
Mikroskop
Belackung
Positivprozess
Belackung
Rckseite
Parameter
2x 40 s N2
Lackauftrag
Programm 4
120 s @ 115 C
10 min
2x 40 s N2
Lackauftrag
Programm 4
100 s @ 100 C
Belichten
Positivprozess
4,0 s
Entwicklung
Positivprozess
50 s - 120 s
5s
20 s
Sichtkontrolle
+Foto
Lackreste
veraschen
nach Litho
Sichtkontrolle
+Foto
Sichtkontrolle
+Foto
Differenz Lackoberflche zu
Padoberflche messen
Teflon-Halter
(Wafer mit Fotolack ankleben)
Lackhhe
HF-Dip
Chuck evtl.
reinigen!
Mit Rckseite
auf vorgeheizte
Siedesteinde legen
vorher reinigen
Entwicklungszeit:
M5262 :40s
____________
55% 250 W
3 min Sauerstoffplasma
Wafer einbauen
Entlackung
Kontaktpadseite
zuerst belacken
Pad-Foto
Lackhhe
Galvanik ansetzen,
starten
Bemerkungen
abblasen
h_vorher=______
Dauer:________
Strom:________
M4456: 99+57min
910nm
h_nachher=
______________
Zeit=__________
M5262: 6s
15
Stoppbandmitte:
0 nm
Basis: M4173
berw.: M4195
Maske:
VER33B F&E
Dielektrischer Spiegel
OK Anlage / Material
Prozessschritt
Parameter
Prozess
Chemie / DI-Wasser
HCl-Dip
HCl : H2O = 1 : 5
(Oxidentfernung vor
Metallisierung)
40ml : 200ml
Ofen mit N2
Wasser verdampfen
ber Lackschleuder
Lackschleuder; Hotplate
90 C /
Belackung
AZ5214
Image Reversal
MA6 /
Maske VER33b F&E
Belichten
Image Reversal
Hotplate 125 C
Lackvernetzung
MA6
Flood-Exposure
17 s Flood-Exposure
Litho Enwicklerbank
AZ400K : H2O = 1 : 4
Entwicklung
IR-Prozess
20 s
5s
20 s
100C
10 min
Bemerkungen
DIP
Stoppglas Wasser
Wasserstrahl
Stickstoff!!
40 s N2 abblasen
Lackauftrag
Programm 4 schleudern (1000/3000rpm fr 2/40s)
90 s @ 90 C Hotplate
Beschr. VERxx rechs unten
2 s Belichten Hard-Kontakt; 0,4 WEC
Entwicklungszeit:
____________
Mikroskop
Barrel - Etcher
p-Anlage /
ZnS-Tiegel + Dummy
Dummy
ZnS
TF neu:
__________
p-Anlage /
CaF2-Tiegel + Dummy
Dummy
CaF2
TF neu:
__________
HCl-Dip
(Oxidentfernung vor
Metallisierung)
Chemie / DI-Wasser
HCl : H2O = 1 : 5
40ml : 200ml
p-Anlage /
ZnS-, CaF2-, Au-Tiegel
Aceton; Prop.-Fl.
Spritze MgF2, Glas DiE
Pt Lift-Off
Mikroskop
Dektak
Barrel - Etcher
Stoppuhr
Ofen mit N2
ber Lackschleuder
Mesen-Foto
Sichtkontrolle
+Foto
Lackreste veraschen
nach Litho
Aufdampfung
Spiegel
Sichtkontrolle
+Foto
Dicke Spiegel
Lackreste veraschen
nach Lift-Off
Tempern Spiegel
55% 250 W
3 min Sauerstoffplasma
20 s
5s
20 s
3.5
_______ nm
DIP
Stoppglas Wasser
Wasserstrahl
Paare ZnS / CaF2 + 100 nm Au
Stoppbandmitte
direkt vor
Schleusung
p-Anlage
kein Ultraschall
Rckseite frei?
Spiegel-Foto
JM-Foto
k Bereich, unkorrigiert:_________ x 1,015 Ist:
Mitte Wafer =
_________ nm
S ll
10% 600 W
15 min Sauerstoffplasma
NEIN
nicht ntig