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2.
4.
5.
2
3
-1
(b) tan
4 kg
6.
3
2
7
-1 4
(d) tan
5
4
Water is flowing at a speed of 1.5 ms1 through a
horizontal tube of cross-sectional area 102 m2 and you are
trying to stop the flow by your palm. Assuming that the
water stops immediately after hitting the palm, the minimum
force that you must exert should be (density of water = 103
kgm3)
(a) 15 N
(b) 22.5 N
(c) 33.7 N
(d) 45 N
A block A of mass 4 kg is placed on another block B of mass
5 kg, and the block B rests on a smooth horizontal table. If
the minimum force that can be applied on A so that both the
blocks move together is 12 N, the maximum force that can be
applied to B for the blocks to move together will be:
(a) 30 N
(b) 25 N
(c) 27 N
(d) 48 N
Two bodies of masses 1 kg and 4 kg are connected to a
vertical spring, as shown in the figure. The smaller mass
executes simple harmonic motion of angular frequency 25
rad/s, and amplitude 1.6 cm while the bigger mass remains
stationary on the ground. The maximum force exerted by the
system on the floor is (take g = 10 ms2)
(c)
3.
tan -1
1 kg
(a) 20 N
(b) 10 N
(c) 60 N
(d) 40 N
A cylinder of mass Mc and sphere of mass Ms are placed at
points A and B of two inclines, respectively (See Figure). If
they roll on the incline without sipping such that their
accelerations are the same, then the ratio
tan -1
sin qc
is:
sin q s
MC
qC
qS
(a)
(b)
15
14
8
15
(d)
7
14
Indias Mangalyan was sent to the Mars by launching it
into a transfer orbit EOM around the sun. It leaves the earth
at E and meets Mars at M. If the semi-major axis of Earths
orbit is ae = 1.5 1011 m, that of Mars orbit am = 2.28 1011
m, taken Keplers laws give the estimate of time for
Mangalyan to reach Mars from Earth to be close to:
(c)
7.
8
7
2
(c) PoToR In 2
(d) PoToR
13. Modern vacuum pumps can evacuate a vessel down to a
pressure of 4.0 1015 atm. at room temperature (300 K).
Taking R = 8.0 JK1 mole1, 1 atm = 105 Pa and NAvogadro =
6 1023 mole1, the mean distance between molecules of
gas in an evacuated vessel will be of the order of:
(a) 0.2 mm
(b) 0.2 mm
(c) 0.2 cm
(d) 0.2 nm
14. A particle which is simultaneously subjected to two
perpendicular simple harmonic motions represented by; x =
a1 cos wt and y = a2 cos 2 wt traces a curve given by:
Mars orbit
O
am
ae
Sun
Earths orbit
8.
9.
10.
(a)
1 -
R
a2
(a)
a1
a2
(b)
12.
(c)
a1
Po To R
Po - a
a2
x
2d
(b) 1 -
R
R -d
R+d
(d)
R+d
R -d
Water of volume 2 L in a closed container is heated with a
coil of 1 kW. While water is heated, the container loses
energy at a rate of 160 J/s. In how much time will the
temperature of water rise from 27C to 77C? (Specific heat
of water is 4.2 kJ/kg and that of the container is negligible).
(a) 8 min 20 s
(b) 6 min 2 s
(c) 7 min
(d) 14 min
The equation of state for a gas is given by
PV = nRT + aV, where n is the number of moles and a is a
positive constant. The initial temperature and pressure of
one mole of the gas contained in a cylinder are T o and Po
respectively. The work done by the gas when its temperature
doubles isobarically will be:
(a)
O a1
(c)
11.
(b)
Po To R
Po + a
(d)
15. A
a1
a2
x
transverse
wave
is
represented
by
10 2p 2p
sin t x
p
l
T
For what value of the wavelength the wave velocity is twice
the maximum particle velocity?
(a) 40 cm
(b) 20 cm
(c) 10 cm
(d) 60 cm
=
y
3
16. The magnitude of the average electric field normally present
in the atmosphere just above the surface of the Earth is
about 150 N/C, directed inward towards the center of the
Earth. This gives the total net surface charge carried by the
Earth to be:
[Given eo = 8.85 1012 C2/N-m2, RE = 6.37 106 m]
(a) + 670 kC
(b) 670 kC
(c) 680 kC
(d) + 680 kC
17. Three capacitors, each of 3 mF, are provided. These cannot
be combined to provide the resultant capacitance of:
(a) 1 mF
(b) 2 mF
(c) 4.5 mF
(d) 6 mF
18. A d.c. main supply of e.m.f. 220 V is connected across a
storage battery of e.m.f. 200 V through a resistance of 1W.
The battery terminals are connected to an external resistance
R. The minimum value of R, so that a current passes
through the battery to charge it is:
(a) 7 W
(b) 9 W
(c) 11 W
(d) Zero
19. The mid points of two small magnetic dipoles of length d in
end-on positions, are separated by a distance x, (x > > d).
The force between them is proportional to xn where n is:
N
23.
4
, and the divers eyes are 15 cm below the surface of
3
water. Then the radius of the circle is:
is
(a) 15 3 5 cm
24.
15 3
15 7
cm
(d)
cm
7
3
Using monochromatic light of wavelength l, an
experimentalist sets up the Youngs double slit experiment
in three ways as shown.
If she observes that y = b, the wavelength of light used is:
s1
Central fringe
O
(Fringe width b)
s2
(Screen)
s1
Transparent
mica sheet of
thickness
t = 1.8 m m
m = 1.6
Central fringe
y (Fringe
width b )
O
d
s2
(Screen)
Lis t II
(1) 700 nm to
1 mm
(2) 1 nm to
400 nm
s1
Central fringe
(Fringe width = b)
d
s2
2D
(b) 15 3 7 cm
(c)
x
(a) 1
(b) 2
(c) 3
(d) 4
20. The magnetic field of earth at the equator is approximately 4
105 T. The radius of earth is 6.4 106 m. Then the dipole
moment of the earth will be nearly of the order of:
(a) 1023 A m2
(b) 1020 A m2
16
2
(c) 10 A m
(d) 1010 A m2
21. When the rms voltages VL, VC and VR are measured
respectively across the inductor L, the capacitor C and the
resistor R in a series LCR circuit connected to an AC source,
it is found that the ratio VL : VC : VR = 1 : 2 : 3. If the rms
voltage of the AC sources is 100 V, the VR is close to:
(a) 50 V
(b) 70 V
(c) 90 V
(d) 100 V
22. Match List I (Wavelength range of electromagnetic spectrum)
with List II (Method of production of these waves) and select
the correct option from the options given below the lists.
List I
25.
(a) 520 nm
(b) 540 nm
(c) 560 nm
(d) 580 nm
The focal lengths of objective lens and eye lens of a Galilean
telescope are respectively 30 cm and 3.0 cm. telescope
26.
27.
28.
29.
30.
A.B
Y
(a) AND (A = 1, B = 1, Y = 1)
(b) OR (A = 1, B = 1, Y = 0)
(c) NOT (A = 1, B = 1, Y = 1)
(d) XOR (A = 0, B = 0, Y = 0)
A transmitting antenna at the top of a tower has height 32 m
and height of the receiving antenna is 50 m. What is the
maximum distance between them for satisfactory
communication in line of sight (LOS) mode?
(a) 55.4 km
(b) 45.5 km
(c) 54.5 km
(d) 455 km
An n-p-n transistor has three leads A, B and C. Connecting
B and C by moist fingers, A to the positive lead of an ammeter,
and C to the negative lead of the ammeter, one finds large
deflection. Then, A, B and C refer respectivily to:
(a) Emitter, base and collector
(b) Base, emitter and collector
(c) Base, collector and emitter
(d) Collector, emitter and base.
32.
37.
38.
40.
p=
nRT
n
-a .
V - nb
V
41.
nRT
V
when,
(a) temperature is sufficient high and pressure is low.
(b) temperature is sufficient low and pressure is high.
(c) both temperature and pressure are very high.
(d) both temperature and pressure are very low.
33.
0
The standard electrode potentials E
M + /M
) of four metals
(a)
1
of the original amount
4
(b)
1
of the original amount
8
(c)
1
of the original amount
16
1
of the original amount
32
A current of 10.0 A flows for 2.00 h through an electrolytic
cell containing a molten salt of metal X. This results in the
decomposition of 0.250 mol of metal X at the cathode. The
oxidation state of X in the molten salt is: (F = 96,500 C)
(a) 1 +
(b) 2 +
(c) 3 +
(d) 4 +
The energy of an electron in first Bohr orbit of H-atom is
13.6 eV. The energy value of electron in the excited state of
Li2+ is:
(a) 27.2 eV
(b) 30.6 eV
(c) 30.6 eV
(d) 27.2 eV
The temperature at which oxygen molecules have the same
root mean square speed as helium atoms have at 300 K is:
Atomic masses: He = 4 u, O = 16 u)
(a) 300 K
(b) 600 K
(c) 1200 K
(d) 2400 K
The standard enthalpy of formation of NH3 is 46.0 kJ/mol.
If the enthalpy of formation of H2 from its atoms is 436 kJ/
mol and that of N2 is 712 kJ/mol, the average bond enthalpy
of N - H bond in NH3 is:
(a) 1102 kJ/mol
(b) 964 kJ/mol
(c) + 352 kJ/mol
(d) + 1056 kJ/mol
The amount of oxygen in 3.6 moles of water is:
(a) 115.2 g
(b) 57.6 g
(c) 28.8 g
(d) 18.4 g
The gas evolved on heating CaF2 and SiO2 with concentrated
H2SO4, on hydrolysis gives a white gelatinous precipitate.
The precipitate is:
(a) hydrofluosilicic acid
(b) silica gel
(c) silicic acid
(d) calciumfluorosilicate
(d)
39.
PART B : CHEMISTRY
31.
42.
5
43. Chloro compound of Vanadium has only spin magnetic
moment of 1.73 BM. This Vanadium chloride has the formula:
(a) VCl2
(b) VCl4
(c) VCl3
(d) VCl5
44. An octahedral complex of Co3+ is diamagnetic. The
hybridisation involved in the formation of the complex is:
(a) sp3 d 2
(b) dsp 2
(c) d2 sp 3
(d) sp3 d
45. Which of the following is not formed when H2S reacts with
acidic K2Cr2O7 solution?
(a) CrSO4
(b) Cr2(SO4)3
(c) K2SO4
(d) S
46. Which of the following has unpaired electron(s)?
(a) N2
(b)
48. The number and type of bonds in C22 - ion in CaC2 are:
(a) One s bond and one p-bond
(b) One s bond and two p-bond
(c) Two s bond and two p-bond
(d) Two s bond and one p-bond
49. The form of iron obtained from blast furnace is:
(a) Steel
(b) Cast Iron
(c) Pig Iron
(d) Wrought Iron
50. The correct statement about the magnetic properties of
[Fe(CN) 6 ] 3
and
[FeF 6 ] 3
is
(Z = 26) :
(a) both are paramagnetic.
(b) both are diamagnetic.
(c) [Fe(CN)6]3 is diamagnetic, [FeF6]3 is paramagnetic.
(d) [Fe(CN)6]3 is paramagnetic, [FeF6]3 is diamagnetic.
51. Which one of the following reactions will not result in the
formation of carbon-carbon bond?
(a) Reimer-Tieman reaction
(b) Friedel Crafts acylation
(c) Wurtz reaction
(d) Cannizzaro reaction
52. In the hydrocarboration - oxidation reaction of propene with
diborane, H2O2 and NaOH, the organic compound formed
is:
(a) CH3CH2OH
(b) CH3CHOHCH3
(c) CH3CH2CH2OH
(d) (CH3)3COH
53. The major product of the reaction
NaNO /H SO
2 2 4
OH
OH
(b)
O
(c)
O-2
(c) N 22 +
(d) O 22 47. In the following sets of reactants which two sets best exhibit
the amphoteric characters of Al2O3. xH2O?
Set 1: Al2O3.xH2O (s) and OH (aq)
Set 2: Al2O3.xH2O (s) and H2O (l)
Set 3: Al2O3.xH2O (s) and H+ (aq)
Set 4: Al2O3.xH2O (s) and NH3 (aq)
(a) 1 and 2
(b) 1 and 3
(c) 2 and 4
(d) 3 and 4
NH2
(a)
(d)
54.
55.
56.
57.
N
H
For the compounds
CH3Cl, CH3Br, CH3I and CH3F,
the correct order of increasing C-halogen bond length is:
(a) CH3F < CH3Cl < CH3Br < CH3I
(b) CH3F < CH3Br < CH3Cl < CH3I
(c) CH3F < CH3I < CH3Br < CH3Cl
(d) CH3Cl < CH3Br < CH3F < CH3I
Allyl phenyl ether can be prepared by heating:
(a) C6H5Br + CH2 = CH CH2 ONa
(b) CH2 = CH CH2 Br C6H5ONa
(c) C6H5 CH = CH Br CH3 ONa
(d) CH2 = CH Br C6H5 CH2 ONa
In a nucleophilic substitution reaction:
DMF
R Br + Cl - R Cl + Br - ,
which one of the following undergoes complete inversion
of configuration?
(a) C6H5CHC6H5Br
(b) C6H5CH2Br
(c) C6H5CHCH3Br
(d) C6H5CCH3C6H5Br
In which of the following pairs A is more stable than B?
A
B
(a)
(b)
(c)
6
Ph 3C , ( CH3 )3 C
(d)
58.
65.
( CH2 C = CH CH2 ) n
66.
CN
Cl
59.
60.
67.
68.
69.
PART C : MATHEMATICS
61.
62.
63.
64.
(a)
{z : z
= 1}
(c)
{z : z 1}
(b)
{z : z = z}
(d)
{z : z
= 1, z 1}
and
are the roots of the equation, ax2 + bx + 1 =
b
a
0 (a 0, a, b, R), then the equation,
If
) (
(a)
(b)
ab 2 and a 2 b
(c)
2
1
and b
2
1
ab and ab
70.
3
2
and b- 2
a
If a, b, c are non-zero real numbers and if the system of
equations
(a 1)x = y + z,
(b 1)y = z + x,
(c 1)z = x + y,
has a non-trivial solution, then ab + bc + ca equals:
(a) a + b + c
(b) abc
(c) 1
(d) 1
If B is a 3 3 matrix such that B2 = 0, then det.
[(I + B)50 50B] is equal to:
(a) 1
(b) 2
(c) 3
(d) 50
The number of terms in the expansion of
(1 + x)101 (1 + x2 x)100 in powers of x is:
(a) 302
(b) 301
(c) 202
(d) 101
The sum of the digits in the units place of all the 4-digit
numbers formed by using the numbers 3, 4, 5 and 6, without
repetition, is:
(a) 432
(b) 108
(c) 36
(d) 18
Given an A.P. whose terms are all positive integers. The sum
of its first nine terms is greater than 200 and less than 220. If
the second term in it is 12, then its 4th term is:
(a) 8
(b) 16
(c) 20
(d) 24
If the sum
-
(d)
3
2
5
2
1 +2
7
2
1 + 22 + 32
k
, then k is equal to:
21
(a) 120
(b) 180
(c) 240
(d) 60
to
1 - cos 3x
9 2
71. If f(x) is continuous and f = , then lim f
x
0
2
9
x2
is equal to:
9
2
(b)
2
9
(c) 0
(d)
8
9
(a)
d 2 y d 2 x
7
x
3 4
74. If f ( x ) = + - 1 , x R , then the equation f(x) =
5 5
0 has :
(a) no solution
(b) one solution
(c) two solutions
(d) more than two solutions
75.
sin8 x - cos8 x
(1 - 2sin 2 x cos2 x )
dx is equal to:
(a)
(a)
(b)
1
- sin 2x + c
2
(c)
(c)
1
- sin x + c
2
In (1 + 2x )
1 + 4x 2
p
In2
4
dx , equals:
p
In2
8
(b)
p
p
In2
In2
(d)
16
32
Let A = {(x, y): y2 4x, y 2x 4}. The area (in square
units) of the region A is:
(a) 8
(b) 9
(c) 10
(d) 11
If the differential equation representing the family of all circles
(c)
2
2
touching x-axis at the origin is x - y
(a)
(c) 2x
84.
1
2
(d)
x - 3 y -1 z - 2
=
=
1
2
3
and has the largest distance from the origin is:
(a) 7x + 2y + 4z = 54
(b) 3x + 4y + 5z = 49
(c) 4x + 3y + 5z = 50
(d) 5x + 4y + 3z = 57
A line in the 3-dimensional space makes an angle q
0 < q with both the x and y axes. Then the set of all
2
values of q is the interval:
dy
= g ( x ) y , then
) dx
(b)
2x2
85.
(d)
1 2
x
2
86.
1
.
4
a
b
Then, the foot of perpendicular from the origin on the variable
line,
(b)
1
2 2
4
Equation of the plane which passes through the point of
intersection of lines
(a)
p
0,
4
(b)
(c)
p p
4 , 2
p p
(d) ,
3 2
g(x) equals:
1
x
2
1
2
x -1 y - 2 z - 3
=
=
and
3
1
2
- sin x + c
(a)
83.
1
2
78.
82.
1
sin 2x + c
2
(d)
77.
81.
x y
+ = 1 , lies on:
a b
87.
p p
6 , 3
P ( A B ) = 0
(c) P ( A B ) = 0
(d) P(A) + P(B) = 1
8
88.
89.
to:
p q
( p q 0 ) , then cot 4 + 2 is equal
(a)
p
q
(b)
q
p
(c)
(d) pq
pq
90. The contrapositive of the statement I go to school if it does
not rain is
(a) If it rains, I do not go to school.
(b) If I do not go to school, it rains.
(c) If it rains, I go to school.
(d) If I go to school, it rains.
(b)
4.
(c)
Dt 1
=
t
90
momentum)
= 10 1.5 = 15 N
Minimum force on A
= frictional force between the surfaces
= 12 N
Dl 0.1
=
l
20
4 kg
5 kg
Dg
%=?
g
As we know,
Smooth table
l
g
t = 2p
4p l
g=
or,
Dg
Dt
Dl
= +2
g
l
t
amax =
5.
1
0.1
+ 2
=
20
90
= 0.027
\
2.
(c)
Dg
% = 2.7%
g
From question,
Horizontal velocity (initial),
ux =
or,
1
(10) 4
2
50 = 2uy 20
or,
uy =
3.
(a)
40
= 20m/s
2
(c)
or,
1 2
gt
2
7
Angle q = tan1
4
For 1 m length of horizontal tube
Mass of water M = density volume
= 103 area length
= 103 102 1 = 10 kg
Dp
Therefore minimum force =
(rate of change of
Dt
m
K
2p
m
= 2p
w
K
1
1
=
[Q m = 1kg; w = 25 rad / s ]
25
K
or, K = 625 Nm1.
The maximum force exerted by the system on the floor
=
Mg + Kx + mg
=
4 10 + 625 1.6 102 + 1 10
=
40 + 10 + 10
=
60 N
(d) As we know,
or,
uy 2 +
70
= 35m / s
2
u y 35 7
tan q =
=
=
u x 20 4
12N
= 3m / s 2
4kg
6.
Acceleration, a =
For cylinder, a c =
mg sin q
I
m+
r2
M c .g. sin qc
Mc +
2
1 McR
2 R2
10
=
M c .g. sin qc
Mc +
or,
2
g sin qc
3
For sphere,
Ms g sin qs
I
M s + s2
r
Ms g sin qs
=
12. (a)
13. (b)
14. (b)
2 MR 2
Ms +
5 R2
5
a s = g sin qs
7
given, ac = as
2
5
g sin qc = g sin qs
3
7
5
g
sin qc 7
15
=
=
sin qs 2
14
g
3
(c)
8.
(c)
(d)
lateral strain ( b )
longitudinal strain ( a )
i.e,
y = 2n (1+ s)
Hence, n < y < k
As we know,
x = x0 ebt/2m
From question,
40b
....(i)
-
bt
Similarly, 5 = 10e 2m
....(ii)
Solving eqns (i) and (ii) we get
t @ 142 s
Acceleration due to gravity changes with the depth,
g = g 1 -
R
Pressure, P = rgh
Hence ratio,
y= 2
x d
is 1 -
y R
a2
x
a1
Given, amplitude a = 10 cm
wave velocity = 2 maximum particle velocity
wl
aw
=2
2p
p
l = 4a = 4 10 = 40 cm
Given,
Electric field E = 150 N/C
Total surface charge carried by earth q = ?
According to Gausss law.
f=
8 = 10e 2m
10. (a)
15. (a)
or,
16. (c)
9 1 3
= +
y k n
y
= 2 cos wt
a2
Poissons ratio, s =
Also,
2 103 4.2 50
840
500 s = 8 min 20s
t=
x
= cos wt
a1
9.
From question,
In 1 sec heat gained by water
= 1 KW 160 J/s
= 1000 J/s 160 J/s
= 840 J/s
Total heat required to raise the temperature of water
(volume 2L) from 27c to 77c
= mwater sp. ht Dq
= 2 103 4.2 50 [Q mass = density volume]
And, 840 t = 2 103 4.2 50
or,
i.e.,
7.
2R 2
ac =
as =
or,
McR 2
11. (a)
q
= EA
0
q = 0 E A
= 0 E p r2.
= 8.85 1012 150 (6.37 106)2.
; 680 Kc
As electric field directed inward hence
q = 680 Kc
17. (d) Possible combination of capacitors
(i) Three capacitors in series combination
or,
3F
1
1 1 1
= + +
Ceq 3 3 3
3F
3F
11
\
21. (c)
1
= 1mF
Ceq
(ii)
3F
M @ 1023 Am2
Given, VL : VC : VR = 1 : 2 : 3
V = 100 V
VR = ?
As we know,
V = VR2 + ( VL - VC )
3F
22. (d)
23. (d)
Given, =
3F
Ceq = 3 + 3 + 3 = 9 F
(iii) Two capacitors in parallel and one is in series
4
3
h = 15 cm
R= ?
3F
R
3F
3F
Ceq = 2F
(iv) Two capacitors in series and one is in parallel
O
18. (c)
Ceq = 4.5 F
Given, emf of cell E = 200 V
Internal resistance of cells = 1 W
D. C. main supply voltage V = 220 V
External resistance R = ?
E-V
r =
R
V
\
19. (d)
20. (a)
m0 M
4p d3
4 10-5 =
or,
16 R2 = 9 R2 + 9 h2
or,
25. (d)
4p 6.4 10
6 3
R +h
3
4
7R2 = 9 h2
3
3
R=
h=
15cm
7
7
Given t = 1.8 106 m
= 1.6
n = 2 (from figure)
Applying formula ( 1) t = nl
(1.6 1) 1.8 106 = 2l
MD =
4p10-7 M
sin C =
24. (b)
1
Force 4
r
In the given question,
Force x n
Hence, n = 4
Given, B = 4 105 T
RE = 6.4 106 m
Dipole moment of the earth M = ?
1
=
m
or,
20
1=
R
220
R = 11 W.
In magnetic dipole
B=
sin 90
=m
sin C
f0
fe
fe
1 -
D
30
3
1 -
3 25
= 10
22
= 8.8 cm
25
[Q D = 25 cm]
12
26. (d)
27. (b)
En =
13.6
n
Z2 =
A. B
A
B
29. (b)
Y = AB.AB = AB + AB = AB + AB = AB
In this case output Y is equivalent to AND gate.
Given : hR = 32 m
hT = 50 m
Maximum distance, dM = ?
d=
Mol. mass
Mol. mass
or V =
V
d
Volume of solution V =
Now molarity (M) =
36. (c)
=
30. (c)
2Rh T + 2Rh R
Given
13.6
9 = 30.6 eV
4
28. (a)
Applying, dM =
35. (b)
120
W
= 2M
=
Mol. mass V ( lit ) 60 1
Given t1 2 = 15 minutes
Total time (T ) = 1 hr = 60 min
From T = n t1 2
n=
60
=4
15
CHEMISTRY
31. (d)
\
32. (d)
1
5
Number of atoms B = 5 =
2
2
(Since atom B is missing from one of the face centered
point)
Formula of ionic compound = AB5/2 = A2B5
37. (c)
n2 a
P + 2 (V - nb ) = nRT
V
34. (a)
at eq. (1 0.5)
Now KC =
(0.5) (0.5)
( 0.5)1/2 ( 0.5)1/2
0.5
=1
33. (c)
N 1
=
N0 2
1
1
= =
2
16
1
Number of atoms A = 8 = 1
8
Given P = nRT - a n
v - nb
v
1120
= 1000 ml or = 1 litre
1.12
or
38. (c)
x 96500
M
i t
10 2 60 60
x=
=
=3
W 96500
96500 0.250
M
E = 13.6
50
= 0.5
Q a =
100
= -13.6
Z2
n2
( 3) 2
( 2 )2
13
=
39. (d)
Vrms =
Vrms(O
2)
3RTO2
M O2
\
40. (b)
-13.6 9
= -30.6 eV
4
3RT
M
= Vrms(He)
=
48. (d)
3RTHe
M He
or
TO 2
M O2
THe
M He
300 32
= 2400K
4
1
3
NH 3 ;
Given N 2 + H 2
2
2
TO 2 =
49. (b)
50. (a)
51. (d)
DHf ( NH3 ) =
1
3
DH N - N + DH H - H - DH N - F
2
2
1
3
( -712 ) + ( -436 ) - DH N - F
2
2
On calculation
-46 =
41. (b)
DH N - F = - 964 kJ / mol
1 mole of water contains = 16 gm of O2
\
3.6 mole of water contains
= 16 3.6 = 57.6 g
42. (d)
52. (c)
53. (b)
54. (a)
56. (c)
hydrolysis
C6H5
m = n ( n + 2)
C Br + Cl
DMF
Cl C
57. (d)
45. (a)
46. (b)
47. (b)
C6H5
CH3
H3C
1.73 = n ( n + 2 )
\
44. (c)
B H
H 2O2 ,NaOH
2 6
CH3CH = CH 2
CH3CH 2CH 2OH
55. (a)
CaSiF6
43. (a)
Polymerisation
1, 3-Butadiene
Styrene
(d 2 sp 3 )
(p 2 p y )2 (p 2 p z )2 (p* 2 p y ) 2 ( p* 2 p z )1
59. (c)
60. (b)
CHI3 + CH3COOK
CH3COCH3 + 3I2 + 4KOH
+ 3HI + 3H2O
Poly-ene. e.g
14
For first equation ax 2 + bx + c = 0 ,
we have
3 CH CH
C6 H 6
acetylene
Benzene
3 CH3 C CH
Propyne
CH3
a+b=
a.b =
CH
HC
Mathematics
61.
(d)
P = {( a, b) : sec a - tan b = 1}
For reflexive :
2
sec a - tan a = 1
For symmetric :
sec2 b tan2 a = 1
L.H.S
62.
(d)
2
1
Now, from (1) & (3)
-b -3
=
a
2
c
2
=
a
1
3
x + 2 = 0 or 2 x 2 + 3x + 4 = 0
2
from this, we get a = 2, b = 3; c = 4
or a : b : c = 2 : 3 : 4
64.
(a)
Let
1
a b
b= -
and
w - wz
w - wz
=
\
1- z
1- z
be the roots of ax 2 + bx + 1 = 0
a + b
b
= -a
=
ab
1
b
1
a = ab
a
a+ b
x( x + b3 ) + (a3 - 3abx) = 0
w - wz
w - wz
=
1- z
1- z
w - wz - wz + wzz = w - wz - wz + wzz
( w - w)(| z |2 ) = w - w
+3
ab
)(
a + b + (ab)3/ 2 = 0
2
3/2
3/2
3/2
x - a + b + 3 ab ( a + b ) - 3 ab ( a + b ) x + (ab) = 0
|z|2 = 1 (QIm w 0)
|z| = 1 and z 1
\ The required set is {z : |z| = 1, z 1 }
Let a, b be the common roots of both the equations.
x2 + (b3 - 3ab) x + a3 = 0
Putting values of a and b, we get
x2 + - a + b
w+w| z| = w+w| z|
(b)
3
&
2
x2 +
w - wz
Clearly z 1 and
is purely real
1- z
63.
...(4)
c=2
putting these values in first equation, we get
w - wz = k (1 - z ), k R
...(3)
-3
2
b
3/ 2
=
a
1
(true " a)
...(2)
a.b=
1, 3, 5-Trimethyl benzene
c
a
a+b=
CH3
CH
CH3
...(1)
-b
a
65.
(b)
15
(a - 1) x - y - z = 0
- x + (b - 1) y - z = 0
- x - y + (c - 1) z = 0
For non-trivial solution, we have
a -1
-1
-1
-1
b -1
-1
-1
-1
c -1
69.
(c)
=0
9
(2a + 8d ) = 9( a + 4d )
2
Given that S9 is more than 200 and less than 220
200 < S9 < 220
200 < 9 (a + 4d) < 220
200 < 9 (a + d + 3d) < 220
Putting value of (a + d) from equation (1)
200 < 9 (12 + 3d) < 220
200 < 108 + 27d < 220
200 108 < 108 + 27d 108 < 220 108
92 < 27d < 112
Possible value of d is 4
27 4 = 108
Thus, 92 < 108 < 112
Putting value of d in equation (1)
a + d = 12
a = 12 4 = 8
4th term = a + 3d = 8 + 3 4 = 20
S9 =
R2 R2 R3
a - 1 -1
-1
-c
-1
-1 c - 1
=0
C2 C2 C3
a -1
-1
b+c
-c
-1
-c
c -1
=0
Apply R3 R3 R1
a -1
0
-a
-1
b + c -c
-c
=63+64+65+66
= 6 [3 + 4 + 5 + 6]
= 6 [18]
= 108
Let a be the first term and d be the common
difference of given A.P.
Second term, a+ d = 12
...(1)
Sum of first nine terms,
=0
70.
(a)
abc - bc - ab - ac = 0
66.
67.
68.
(a)
(c)
(b)
ab + bc + ca = abc
det [(I + B)50 50B]
= det [50C0 I + 50C1 B + 50C2 B2 + 50C3 B3 + ...
+ 50C50 B50 B50 50B]
{All terms having Bn, 2 n 50
will be zero because given that B2 = 0}
= det [I + 50B 50B] = det [I] = 1
Given expansion is
(1 + x)101 (1 x + x2)100
= (1 + x) (1 + x)100 (1 x + x2)100
= (1 + x) [(1 + x) (1 x + x2)]100
= (1 + x) [(1 x3)100]
Expansion (1 x3)100 will have 100 + 1 = 101 terms
So, (1 + x) (1 x3)100 will have 2 101 = 202 terms
With 3 at unit place,
total possible four digit number (without repetition)
will be 3 ! = 6
With 4 at unit place,
total possible four digit numbers will be 3! = 6
With 5 at unit place,
total possible four digit numbers will be 3! = 6
With 6 at unit place,
total possible four digit numbers will be 3! = 6
Sum of unit digits of all possible numbers
2n + 1
n(n + 1)(2 n + 1)
6
6
n(n + 1)
1
1
Let nth term, an = 6 n n + 1
Sum of 20 terms, S20 = a1 + a2 + a3 + .... + a20
1 1
1 1
1 1
S20 = 6 - + 6 - + 6 - + ...
1 2
2 3
3 4
1
1 1
1 1
1
+6 - + 6 - + 6 -
18 19
19 20
20 21
1 1 1 1 1
S20 = 1 - 2 + 2 - 3 + 3 - 4 + ...
1
1 1
1 1
1
+
+
+
-
18 19 19 20 20 21
1 120
S20 = 6 1 - =
21 21
k
21
.....(1)
.....(2)
16
On comparing (1) and (2), we get
k = 120
71.
(b)
9
2
Given that f =
2
9
73.
(b)
x2
1 - cos 3x
lim
lim f
=
2
x
0
1
cos
3
x
x0
x2
= lim
x0
2 3x
2sin
2
9 2 4
.x .
1
4
9
lim
=
2 x0 2 3 x
sin
4
1
lim
x
0
9 2
2 3x
sin
2
3x
2
lim1
2
x 0
=
3x
9
sin 2
2
lim
x 0 3 x 2
at x =
(d)
3
+a+b = 0
2
sin x
= 1
lim
x
0
3
+a-2 = 0
2
a=2
2 1 2
.
=
9 1 9
Given that, y = enx
Differeniating both sides with respect to x
= n.nenx = n2enx
dx 2
y = enx
nx = logey
1
2=12=1
2
74.
(b)
3
4
f (x) = + - 1
5
5
Put f (x) = 0
x
.......(1)
3
4
+
5
5
...... (2)
=1
3x + 4x = 5x
For x = 1
31 + 41 > 51
For x = 3
33 + 43 = 91 < 53
Only for x = 2, equation (1) Satisfy
So, only one solution (x = 2)
(b)
Let I =
1
log y
n
Differentiating x with respect to y
75.
x=
dx
1 1
= .
dy
n y
Again differentiating with respect to y
3
4
0 = + -1
5
5
d y
3
1
=
2
2
2a + b = 2
dy
= nenx
dx
Again differentiating w.r.t 'x',
-1
1
d 2 x 1 -1
= - 2 nx
. 2 =
2 =
2
n y
dy
ny
ne
1
, f (x) = 0
2
1
1
0 = 6 + 2a + b
2
2
72.
sin8 x - cos8 x
1 - 2sin 2 x cos 2 x dx
...1)
17
1 - 2sin 2 x cos2 x
(c)
dx
p
4
1/ 2
Let I =
1 + 4x
1/ 2
dx or
ln(1 + 2 x)
1 + (2 x )
dx
p
4
1
[ln 2 - ln(1 + tan q)]d q
2
I=
dx
2dx
sec qd q
= sec 2 q or dx =
dq
2
also when x = 0 q = 0
and when x =
p
4
\I=
1 + tan q
p
4
p 4
1
ln 2q
-I
2
0
I=
2I =
sec qd q
2
1 p
ln 2
2 4
p
p
ln 2 or I = ln 2
8
16
Area of shaded portion
2I =
77.
p
4
(b)
1
ln(1 + tan q)
sec 2 qd q
2 1 + tan 2 q
0
p
4
1
ln(1 + tan q)d q
2
...(1)
y2 = 4x
4
3
2
1
(Q 1 + tan2 q = sec2 q)
I=
1
p
I + I = ln 2 - 0
2
4
1
p
q = 45or
2
4
ln(1 + tan q)
p
4
1
1
ln 2.d q - ln(1 + tan q)d q
2
2
I=
Put 2x = tanq
I=
1
2
ln
dq
2
1 + tan q
0
I=
- sin 2 x
1
+ c = - sin 2 x + c
2
2
ln(1 + 2 x)
1 + tan q + 1 - tan q
1
ln
dq
2
1 + tan q
I=
= - cos 2x dx =
76.
p
4
dx
(4, 4)
1 2 3 4
1
2
p
4
I=
ln 1 + tan - q d q
2
4
tan - tan q
14
4
I = ln 1 +
dq
p
2
1 + tan tan q
0
4
p
4
I=
1
1 - tan q
dq
ln 1 +
2
1 + tan q
4 y2
y + 4
dy - -2 dy
2
4
1 y2
+ 4 y
2 2
-2
1 y3
4 3
4
-2
1
1 64 8
[{8 + 16} - {2 - 8}] - 4 3 + 3
2
= 15 6 = 9 sq units
18
78.
(c)
1
1
a2
(0, a)
(0, 0)
80.
= x12 + y12
b2
1 1
1
Q 2 + 2 = 4 ,
b
a
(d)
x 2 + y 2 + a 2 - 2ay = a2
2
x + y - 2ay = 0
Differentiate both side w.r.t 'x', we get
...(1)
P (5, 3)
Q (8, 3)
dy
dy
2 x + 2 y - 2a
=0
dx
dx
R (2, 0)
dy
dy
x+ y -a
=0
dx
dx
x+ y
dy
dx
dy
dx
=a
Equation of RQ is x 2y = 2
...(1)
at y = 0, x = 2 [R (2, 0)]
as PQ is parallel to x, y-coordinates of Q is also 3
Putting value of y in equation (1), we get
Q (8, 3)
dy
y dx + x
x + y - 2y
=0
dy
dx
2
( x2 + y 2 )
8 + 5 + 2 3 + 3
,
Centroid of DPQR =
= (5, 2)
3
3
dy
dy
- 2 y2
- 2 xy = 0
dx
dx
dy
(x + y - 2 y )
= 2xy
dx
2
x 2y = 2
81.
dy
= 2xy g ( x) y
dx
Hence, g(x) = 2x
(c) Let the foot of the perpendicular from (0, 0) on the
x y
variable line + = 1 is ( x1 > y1 )
a b
Hence, perpendicular distance of the variable line
x y
+ = 1 from the point O (0, 0) = OA
a b
O (0, 0)
(d)
2
2
(x - y )
79.
-1
1
x12
y12
C (3, 5)
r
X
...(i)
( x - 3)2 + ( y - 5) 2 = ( 34 - P)2
+
a 2 b2
A
(x1, y1, 0)
x x
+ = 1
a b
34 - P < 5
19
34 P < 25
P>9
...(ii)
Also if the circle does not touch or intersect x-axis
the radius r < x-coordinate of centre C.
and
82.
(a)
x2
(c)
y2
Let
84.
0-b 0-b
=1
- ae - 0 ae - 0
85.
(c)
(a, 0)
(0, b)
b -b
= 1
ae
ae
e2 =
1-
b
2
Q e = 1 - 2
a
b2
a2
q=
(a)
r r
| 2a + b | = 16 + 9 + 24 cos q = 25 = 5
There are 2n observations x1, x2, ..., x2n
2n
2ni
xi + 5n.
i=1
1
e2 =
2
Given equation of lines are
x -1
y -2 z-3
=
=
3
1
2
p
2
i =1
b2
1 1
e2 = 1 - 2 = 1 - =
2 2
a
(c)
p p
q= ,
4 2
r r
Given | 2a - b | = 5
r
r
r r
(2 | a |)2 + | b |2 -2 | 2a || b | cos q = 5
r
r
Putting values of | a | and | b | , we get
So, mean =
b2
b2 1
1= 2 2 2 =
2
a
a
83.
86.
p
2
(2 2) 2 + (3) 2 - 24cos q = 25
cosq = 0
b2 = a2e2
2
...(2)
B (0, b)
F1
(a, 0) (ae, 0) F2(ae, 0)
x -3
y -1 z - 2
=
=
1
2
3
i = n +1
xi - 3n
2n
i =1
i = n +1
xi + 5n +
xi - 3n =
2n
xi + 2n
i =1
20
2n
2n
x
xi + 2n
= i +1
2n
2n
i =1
i =1
So, it increase by 1.
Let A and B be two events such that
Mean =
87.
(d)
for, sin a =
p 2p
,
3 3
There are three values of a between [0, 2p]
a=
P(A B) = P(A B)
and P(A B) = P (A) + P (B) P(A B)
1
2
89.
(b)
cosecq =
p-q
p+q
, sin q =
p+q
p-q
2
2 pq
p - q
=
cos q = 1 - sin 2 q = 1 -
p + q
( p + q)
p q
cot + =
4 2
q
q
cos - sin
2
2
=
q
q
cos + sin
2
2
Also, we know
P(A B) = P(A) + P (B) P(A B)
= P(A B) + P(A B) P(A B)
88.
(c)
= P(A B)
which is true from given condition
Hence, option (a), (b) and (c) are correct.
2 sin 3a 7sin2a + 7 sina 2 = 0
2 sin2a (sina 1) 5 sina (sina 1)
+ 2 (sina 1) = 0
(sin a 1) (2 sin2 a 5 sina + 2) = 0
sin a 1 = 0 or 2 sin2 a 5 sina + 2 = 0
sin a = 1 or sin a =
a=
cos - sin
cos + sin
2
2
2
2
q
q
q
q
cos + sin cos + sin
2
2
2
2
5 25 - 16 5 3
=
4
4
p
2
or sin a =
=
1
,2
2
Now, sin a 2
p
q
q
cot cot - 1
cot - 1
4
2
2
=
q
p
q
cot + cot
cot + 1
4
2
2
90.
(b)
cos q
q
q
q
q
sin 2 + cos2 + 2sin cos
2
2
2
2
2 pq / ( p + q )
cos q
=
=
( p - q)
1 + sin q
1+
p+q
pq
=
p
q
p