Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
LONGM
N PHYSICS TOPICS
LONGMAN
PHYSICS
TOPICS
back cover
LONGMAN
PHYSICS
TOPICS
General Editor:
John L. Lewis
ELECTRONS
AND ATOMS
John L. Lewis
to electrometer
mass spectrometers
are also used
11 plants to provide
a continuous
oosition of the materials going
Illustrated
by T. H. McArthur
~~~
LONGMAN
111~~lrllfll~~III~nlllll
N25702
_._~J
LONGMAN
GROUP
LIMITED
APPENDIX
London
A ssociated companies,
throughout
the world
jusi
1972
ACKNOWLEDGEMENTS
Frc
The author and publisher are grateful to the following for permission to reproduce photographs:
Cavendish Laboratory, Cambridge,
page 42: Esso, pages 26 (above) and 30: Geological Survey Museum
Crown , page 7 (centre); Philip Harris Ltd, page 31; Kodansha
Ltd, page 9 (left and right); Gunter Lutzow, page 34 (left and
right); Mullard Ltd, pages 25, 57 (left and right) and 58 (above);
Mr H. E. C. Powers (retired, Tate and Lyle Ltd), page 7 (left);
Science Museum, London, pages 20 (all photos), 43, 50 (all photos)
and 60 (above and below right); Telequipment
Oscilloscopes by
courtesy of Teltronix U.K. Ltd, page 53 (left and right); Teltron
Ltd, pages 22, 24, 26 (below), 27, 28 (above and below) and cover
photographs.
The photograph
on page 8 (above) is from Martin,
Thirteen Stops to the A tom (H arrap), and on page 60 (above and
below left) from Aston, Mass Spectra and Isotopes (Arnold).
coli
smr
the
dif"
of
heir
4 X 11
T~
one,
aton
with
ChbJ
35.51
part
'n
Nier
The
meas
--------------~
smeter
I
NOTE
TO THE
TEACHER
----------------,-
-,-------
ICONTENTS I
WHY DO WE BELIEVE
6
6
7
7
IN ATOMS?
I APPENDIX
9
10
10
11
reg
as
on
tha
as
diff
Ast,
mv
disr
of
12
13
13
14
MC~
Ast.
sam
spec
I
THE EVIDENCE
FOR CHARGED
PARTICLES
A new model
Ions in liquids
Ions produced
Ions produced
Ions produced
THE THERMIONIC
of the atom
by a flame
by radioactive radiations
by a hot filament
EFFECT
The diode
Uses of the triode
Other experiments
Conclusion
THE MILLIKAN
with thermionic
vacuum tubes
EXPERIMENT
The experiment
The theory of the experiment
Result of the experiment
Conclusion
THE MASS OF THE ELECTRON
15
15
16
POS:I
ene:
T'
off
elec'
gun
acce
dire!
ion
I
17
17
17
18
19
21
22
22
25
25
29
30
31
32
33
33
34
34
35
36
38
38
awa
hot filament
ELECTRON
GUN
--',
39
39
39
40
40
Cathode rays
Measurement of e/ m
The electron as a constituent
MODELS OF THE ATOM
photographic
plate
ELECTRONS AT WORK
of all matter
42
42
44
45
46
46
48
50
51
52
52
56
57
59
WHY DO WE
BELIEVE IN
ATOMS?
wd
can'
ate
':'More detail is
included here than
will be necessary
for an O-level
course. It is included
for general interest.
T I'
'U.
APPENDIX:
MASS
SPECTROMETERS~::
ficl.
ena
J
deft
mat
a d:
slos
disr
thrr
ver'
pas'
deft!
appl
field,
1
ions
~I
H'I
on t
the [,
,I
P hot
shos
t igNe and i6Ne are isotopes of neon they both have the same place in the
periodic table and are the same as far
as chemical properties are concerned.
Both have 10 electrons round the
nucleus and a charge of + 10 units on
the nucleus. Each nucleus therefore
contains 10 protons.
The nucleus of
2Ne, however, has 10 neutrons whereas
that of 22Ne has 12, thereby accounting
for the difference in mass. In ordinary
neon, there are 9 parts of 2Ne to 1
part of 22Ne and this gives an average
mass of 20.2 units.
T'ii
gas
heav
ence
same
wore!
mass!
'isos
para,
1
you ',
----
--------
WHY DO WE
BELIEVE
IN
ATOMS?
--
EARLY SPECULATIONS
The first ideas about a particulate
nature of matter
came from the Greek philosopher Democritus, as recorded by the Roman poet Lucretius in his work De
Rerum Natura. But these ideas were little more than
speculations as they were unsupported by experimental
evidence. The rival speculation that matter was made
up of four basic elements - earth, air, fire and water was preferred to any idea of atoms for nearly two
thousand years.
THE EVIDENCE
Granulated sugar
Fluorite
FROM
CRYSTALS
A lum crystal
-~
WHY DO WE
BELIEVE IN
ATOMS?
ELECTRON
AT WORK
A monochrome
.1
Cleaving a polystyrene
model
Bnt
hon
replittL
firstl
Tli
television tube
television
troll.
at tJ
As tl
the s
dark
I
B:d
to tl:
a'm
film
sequ
THi~
l
Anon
is th.
hot
anod
the
prop:
anod
out .~
like
mucr
WHY
DO WE
BELIEVE
IN
ATOMS?
X-RAY
DIFFRACTION
BY CRYSTALS
'
'N TUBE
Ibasically a cathode-ray tube with
first moves the spot horizontally
rd then causes it to fly back very
d the line time-base and is just like
Ioscilloscope. The other is called
md this operates at the same time,
,re slowly down the screen until it
,e top again. In this way the spot
,f the screen as shown below. In
I
C~O, -
~;:-:,,=-=-=-====-=-==-=~-
directions for
interference
--------,~-.========~---,--- - - - ~ - - ".:-:,,==-=-==-=-=-=~----------~------~,=-=-=~~--
I~
---
--
X-rays
~_-_-_-_-_-_.2.(_-_-_-_-_--~-'~-:
.~~~~~~~==~~~~.~'-,,~-
lead
photographic
plate
WHY DO WE
BELIEVE IN
ATOMS?
ELECTRONS
AT WORK
11
I
osci
sen,
SOLID
TO LIQUID
TO GAS
----
--
-----
COIl
volt'
r esi:
cud
pasi
that
o
,
sCOITl
rect:
up.
2V
50 HZ'i
a.c.
d.c.
01
Scl
swit
will
Wh~
and
som
It w
AC
belo
conn
~-~-~---
,l.
WHY DO WE
BELIEVE IN
ATOMS?
d.c. voltage
'applied to plates
a.c. voltage
applied to plates
------
If the diameter
(1)3
4
:3'[ 4" mm '
If x is the thickness
2 X 10-6mm
or 2x 1O-7cm
EVIDENCE
FROM
BROWNIAN
MOTION
11
rapidly in a random fashion. This important experiment gives us direct evidence that gases, such as air,
consist of randomly moving small particles, too small
to be seen, though their effect is clearly visible in the
experiment when they buffet around the much larger
smoke particles in a random manner.
WHY DO WE
BELIEVE IN
ATOMS?
~~~~~=====~~=~=~.
12
the
and
oscill
not focussed
Bel
I
usual,
a por
the b
and
will
focussed
FOCUf
not focussed
Ins'
lng p
the 0
the VI
to bel
if it n
volt 21
and f
order'
for a:
A vol
volt/em
10.
20
.0.5
-0.2
EVIDENCE
:-RAY OSCILLOSCOPE
FROM
DIFFUSION
Ising
deflecting
plates
Iii
J:l
,~~-L:5rLJ------------------ccelerati
ng
node
fluorescent screen
POWERFUL
CHEMISTRY
EVIDENCE
FROM
WHY DO WE
BELIEVE IN
ATOMS?
MODELS OF
THE ATOM
thosmod:
inste
dista'
knov
ener~
the p,
belox
dista:
I
CONCLUSION
All this evidence - and much
the atomic model of matter.
that it is correct and see where
let us try to find out what is
THE'
I
The i'
claim
the fiC]
which'
I
Physic
the uh
14
----
-------
_.-
--
------
--_._---
THE EVIDENCE
FOR CHARGED
PARTICLES
CHANICAL
MODEL
,I
/\ /\ \/
-7
-7
~~
[!][!]
+++
+++++++
+++++
~[!J
15
THE EVIDENCE
FOR CHARGED
PARTICLES
An electroscope can be charged positively by connecting the plate to the positive terminal of a battery
or a power supply, at the same time connecting the
outer case to the negative terminal. (This should give
you a clue as to how you could confirm that a cellulose
acetate strip is positively charged and a polythene rod
negatively charged.) A high voltage is necessary to get
the leaf to rise. When the leaf is fully up there may be
a potential difference of 1000 or more volts, though it
depends on the design of the electroscope.
ELECTROSTATIC
CHARGE
CURRENT ELECTRICITY
MODELS OF
THE ATOM
SOOI
cea
ato
orbi
AND
I
I
I
('
"
Th
mod:
essen'
the ni,
any G
corre
assun
with
energ
from'
Typic'
oppos
MaD
toy th.
tiserne
contai
mea
unfort
IS
ments
a moe
1926 i
cussed
I
IIONsl
1 proton
0 neutron
A NEW MODEL
1
1 proton
1 neutron
OF THE ATOM
8 protons
8 neutrons
a negative part
of the atom
16
a neutral atom
8 protons
9 neutrons
a positively charged
atom with a
negative part removed
117
92 protons
1146 neutrons
238
1
EL OF THE ATOM
Ins moving in orbits round the
Iattractive:
it was similar to the
hat each planet was kept in orbit
ce whereas in the atom it was the
(en the orbiting negative electron
r--------!1
11
:1----------,
i'/US.
a neutral atom
with a negative part
added leaving
the whole negative
anode
cathode
~----1+
=--=---
IONS
IN LIQUIDS
COl
the
.
SIZ'
for
.
mg
cell
SUt
size of atom
("-'1 Q-,om)
3 X'
Thi
ofl
vol
nU'
,
the,
5 k
is (j
by ,
Hyl
carl
ural
eler
one,
ally,
,
nWIlI
IONS
PRODUCED
18
----
-----
pos:
heli
8, .'
BY A FLAME
----
wit
MODELS OF
THE ATOM
193~
prot
app:
char
and,
atom
clcc
has:
tons,
that,
mas:
,
:'phere, positively
charged,
with
Imbedded in it: the 'plum pudding'
iccepted until Rutherford replaced
I
'rticles
IONS PRODUCED
RADIATIONS
BY RADIOACTIVE
will discharge
it, showing
J. J. THOMSON
AND THE
ELECTRON
The "
had
men
mass
hydr
'prim
THE'
OF )',
Th(,
the s
tube
was rr
the el'
matte,
his w
electr.
electr'
In
in 19([~
Royal'
TrinitJ
in 194
he was
his dis
r
---
~- -
--~ ~-~
-~-
Ie
OF elm
his experiments in
c were deflected
.etween plates d and e. The defleca the screen was measured." A
I
by describing
and
.s from a cathode
IONS
PRODUCED
BY A HOT FILAMENT
in this series.
made measurements
of the charge e.
21
THE
THERMIONIC
EFFECT
cathode
shadow
Crookes' Maltese-cross
tube
Mag:
Th
in th
the
these!
Gem
aethe
their,
hithe,
that,
whol,
of m:
first
betw;
not t'
studio'
theor'
I
ro-~500V 1
r------'
year
wer:
It ~)
His'
THE DIODE
1-------1
whe
Sir'
that'
due
trav,
radi
Thomson's
original apparatus
':'In th:d
which et
11
Plate voltage
VA/volt
-200
-150
-100
- 50
50
100
150
200
250
300
350
400
450
500
Current fA/
milliampere
0.0
0.0
0.0
0.0
0.0
0.2
To investigate
what is happening
a voltage is
applied between the plate and the filament. These
readings are typical for such a tube.
0.6
1.6
2.2
2.5
2.6
2.7
2.8
2.8
2.8
300
200
100
100
200
300
400
500
VA/V
either
'S
study of cathode rays that J. J.
suggest the existence of electrons.
[he was born the German physicist
roduced a vacuum pump capable of
S,; much
lower than had ever been
rch a pump enabled Geissler's friend
, that electricity could flow through
rLtowhich electrodes had been fixed,
-----------
THE
THERMIONIC
EFFECT
-----
%
9998
9976
002
004
020
~Li
79
~Li
921
9000
027
200
I"IB
973
800
950
989
074
=O - 25V
1.1
42
9962
0016
I
?N
}-----j
Current lm.A
+8
0.8
+4
0.6
o
0.4
-4
0.2
-8
0.04
038
f~Cl
755
gCl
245
METERS
he fine-beam tube can also be
'e ions in order to enable us to
lof atoms. The important difference
Ic fields necessary to produce the
be very much greater.
Mass
enable this to be done are disstail in the Appendix on page 59.
THE
THERMIONIC
EFFECT
OTHER EXPERIMENTS
WITH
THERMIONIC
VACUUM
TUBES
You have probably seen the Maltese-cross tube. The
charge given off by the hot filament is accelerated
towards the anode, and passes through the hole in it.
A metal Maltese cross is fixed in the beam.
When the filament is heated to white heat, but before
the accelerating voltage is applied, an optical shadow
of the cross will be seen on the end of the tube due to
the light from the filament. When the voltage is applied
the end of the tube glows with a distinctive green glow
produced when the electrons hit the glass which is
coated with a fluorescent
material such as barium
platinocyanide.
A sharp image of the Maltese cross will
be apparent on the screen: the cross has obstructed the
electron flow.
25
THE
THE
THE
THERMIONIC
EFFECT
MASS
ATOM
OF
MA
The
page
hydr
byaj
pass'i
It is
hydr
rt
Ions.
a h\;
It is interesting
':'C/ kg
usual
hydrl
the
corn
prot:
and
the
more
W
J
TH
In Y'
SUbSI'
mole
mole
28 g,
As
mole
2 X 1.
mole
26
= ( nte) X vt = nev
discussed the force on the con7L, and this therefore equals Bnev.
ctrons in this length. Therefore the
loving charge is Bev.
1
THE
THERMIONIC
EFFECT
OF elm
mv'
r
e : 2V
m - B2r2
, THE ELECTRON
elm. The Millikan experiment told
10-19 coulomb. From these two we
e ofm.
.60 X 10-19
9 X 10-:1l kg
.76xl011
bly agree that it is remarkable to be
Juething as small as this.
Another
interesting
tube is illustrated
below, in
which there is a vertical screen set inside the tube at a
slight angle. The anode has a horizontal slit in it.
This results in a horizontal line along the centre of the
screen when the electron beam strikes it. (Can you see
27
THE MASS OF
TH E ELECTRON
two c
the el
and
suspe
in wa
the b
wire
Whefj
iF
J\
lmg
deflecting
voltage
~
from the drawings opposite why the screen is inclined?)
Above and below the screen are two horizontal plates.
If a potential difference is applied between the plates
so that the lower plate is positive relative to the top,
there will be a downwards electric force on the moving
negative charge, which will move in a curved path.
As the force is a constant downward force (as long as
the electrons are in the field) and as the electrons
initially move in a horizontal direction, the path will
be a parabola, exactly as it is a parabolic path for a
ball moving horizontally
under the influence of a
constant downward gravitational force.
oomlllm911
parabolic path
circular path
= BIL
mg = F = BIL
B = mg
IL
balan
(a rid
adjust
mass
currc
measi
Ho
badly
a wire
in the
folIo
at time
after ti
COJ
Suppr
charg
it is
speed
1m
the el
Awh,
some
v. In
THE ELECTRONS
:~TIC FIELD
I
DUE
:ay
In some
on the strength of the
fCO find out more about it we have
force on a current-carrying
conumetic field.
~r the experiment on the left. The
as at right angles to the magnetic
ltion of the current. It is found that
In the current and the length of the
ld. In other words,
no field applied
source
F=BIL
(in newtons), I is the current (in
ength (in metres) and B is a force
Ion the strength of the field. In later
ueasure of the strength of the field.
asure this force constant B? The
hown below. There are the same
field applied
Drawing
inclined
to show
CONCLUSION
This sequence
of experiments
tells us:
THE MILLIKAN
EXPERIMENT
THE MASS OF
TH E ELECTRON
Ri
illust
unif
the
In a
the
the e
Ther
roun
diam
SUPli
the
COUhi
electl
b e ,:i.,;1.
Gmv2
kine
Thus
and t
THE MILLIKAN
EXPERIMENT
'1M TUBE
-I.
I
THE EXPERIMENT
Millikan did his first experiment in 1913 with two metal
plates 16 mm apart. He sprayed oil drops through a
small hole in the top plate and in the process some
would
become
charged
by friction.
They were
illuminated
from the side and viewed through a
microscope as they fell under gravity. The fall of the
charged drops could be controlled by voltages applied
between the plates. His experiment
achieved two
things: it showed that electric charge always appeared
as a definite multiple of a single basic charge and it
enabled that basic charge to be measured.
upward force
due to electric field
charged drop
downward force
due to gravity
"
The apparatus
above is a school version of the
Millikan apparatus. :;: In this a potential difference V
applied between the plates is adjusted so that the
upward electrical force on a charged drop is exactly
equal and opposite to the downward force due to
gravity, and the drop neither rises nor falls.
Concentrating
on the one drop, it is briefly irradiated
by a radioactive source (Millikan used X-rays for this
31
THE MILLIKAN
EXPERIMENT
THE THEORY
F= Vq
d
Note that this agrees with what we found in the
experiment with the metallised sphere described at the
beginning of this section, namely that the greater V
the greater is the force F.
In the Millikan experiment with the oil drop, the
upward electric force is balanced by the downward
force due to gravity, namely mg.
32
From
For
consta
the sari
listed
I
REStJ
I
We ha.
we mu'
columnl
OF THE EXPERIMENT
Thus:
THE MILLIKAN
EXPERIMENT
mg= Vq
d
Withl
the last
values:
an intej.~
out to
whole-Ill
In ot
definite
and we
This co
'juice'.
I
From tr
the actul
be 1.60 II
is that i
charge
I.
F THE EXPERIMENT
Irence between the plates is V, we
~y transferred in taking charge q
~,to the top plate is Vq (from the
as 1 joule per coulomb).
Ian electric force F on the charge
calculate the energy transferred
d, where d is the distance apart
Idly we measure in SI units, so that
td F in newtons. The energy translJS be in newtons X metres, i.e. in
is 1 newton X 1 metre.) Thus Fd
fives us an expression for the force
rnamely
mg=B1
d
THE MILLIKAN
EXPERIMENT
RESULT
that Vq = mgd.
in a particular apparatus mgd is a
would expect Vx q always to have
us now look again at the voltages
OF THE EXPERIMENT
Charge q
Vxq
1 805
904
905
604
1 805
1 808
1 810
1 812
1 808
1800
452
450
449
361
303
301
226
2
3
4
4
4
5
6
6
8
1 796
1 805
1 818
1 806
1 808
CONCLUSION
From this type of experiment it is possible to calculate
the actual charge on the electron, and this is found to
be l.60 X 10-19 coulomb. But the most significant thing
is that it confirms the existence of this basic unit of
charge and that all charges are direct multiples of it.
33
THE MASS OF
TH E ELECTRON
THE FINE-BEAM
l' fine
beam
~
300V::
---L-
,:\
:
I
I
rt]
conical
anode
filament
THE MILLIKAN
EXPERIMENT
THI~
MillS
plat:
sma~
wou
illu 'rlr
.]
mlCli
char
betv
thin;
as a,
erial
TUBE
upward force
due to electric field
charged drop
downward force
due to gravity
Tl
Mill
appl
UpW
equa
grav
C(:
bYB.I
I
34
-~--------
THE MASS OF
THE ELECTRON
,
se under the influence of this extra
rHt for the spring
must be lowered
.hc sphere back to the middle again.
voltage applied, the greater is this
the charged sphere, and the more the
lowered. Similarly if the potential
"sed, there will be a force downwards
d the greater the voltage the greater
,inciple is used in the Millikan experismall charged drop is used instead of
aere.
THE SPEED
OF ELECTRONS
THE MASS OF
THE ELECTRON
DUE
by pu
CUL
acros:
right
upwalf
the fie
the be:
I
no field
F=BIL
where F is the force (in newtons), I is the current (in
amperes), L is the length (in metres) and B is a force
constant dependent on the strength of the field. In later
work B is used as a measure of the strength of the field.
How can we measure this force constant B? The
apparatus used is shown below. There are the same
field applied
I
Drawing
inclined
to show
CON
This
se
(l) tha:
(2) that
experrn
(3) thai
and rna
in this
On t'
given d
have be
which
words,
imports
I
-=36
battery to
provide current
through coil
--I
I
THE MASS OF
TH E ELECTRON
iF
= BIL
i.,
~
~
= F = BIL
B = mg
mg
7\
IL
-lA
watching
here
n electrons
B
at time 0
L
A
after time t
L
circular path
./
=(
nte) X vt = nev
We have already discussed the force on the conductor as being BIL, and this therefore equals Bnev.
But there are n electrons in this length. Therefore the
force on a single moving charge is Bev.
CALCULATION
THE
THERMIONIC
EFFECT
T~,I
expe
from
ano~il
tube
cylin
term
a me;
the
becol
l
OF elm
35 that v=
Substituting
2~e.
we find that
mv'
r
e : 2V
m-
B2 2
THE MASS
OF THE ELECTRON
to be
Ani
whicJI
slight
This
scree]
I
THE MASS
THE ATOM
OF
MASS
OF THE PROTON
Charge of electron
Mass of electron
9 X 10-31 kg
Mass of proton
1.67
Mass of electron
Mass of proton
1840
THE AVOGADRO
10-27 kg
CONSTANT
6 X lO>' molecules
per mole
39
---
---
--
--
--
--
THE MASS OF
THE ATOM
MASS
SPECTROMETERS
THE
THERMIONIC
EFFECT
USE
The fl
the g
throul
for
prone
ment.
have
desigr
electr.
and
a trioValfor
place.
robust
heat a
I
ISOTOPES
By using mass spectrometers we can find the masses of
individual atoms and it was such work that showed
the existence of isotopes - atoms which have the same
chemical properties
(in other words have the same
place in the periodic table) but different masses.
The chemists tell us, for example, that chlorine has a
relative atomic mass of 35.5. The mass spectrometer
reveals that it is normally a mixture of chlorine with
mass 35 and chlorine with mass 37, giving merely an
average value of 35.5.
Large numbers of naturally occurring isotopes are
known to exist, of which the following are examples.
(When denoting an isotope as ~f25U, the lower number
is the atomic number, that is, the place in the periodic
table; the upper number is the relative atomic mass.)
The percentages give the relative abundance of each.
40
OTH
THE
You
charge
towarr
A met
Whe'
the ac.
of the
the ligJ
the em
produc
coated
platina'
be app
electro.
I
------
iH
9998
I~GO
9976
1"12S
,,0 n
11
~~O}Pb
15
iH
002
1~70
004
114Sn
[)O
08
~,?:?Pb
236
1.~80
020
115S
:;0 n
OA
~,?;Pb
226
I}GS
,,0 n
155
~~028Pb
523
TgNe
9000
1_17Sn
,,0
91
nNe
027
118Sn
225
1_19S
n
.,0
98
1_20Sn
,,0
285
~Li
79
~Li
921
lOB
s
200
\IB
800
2C
lG
3C
16
4N
17
?N
989
1 1
9962
[)O
76Ne
nS
973
950
liS
074
1_22Sn
,,0
55
nS
42
\204Sn
68
f~S
0016
~;J24U
0006
~~}U
0720
~~}'U
99274
038
r~CI
755
nCI
245
I ~O---50ov-1t----roooJ
1_
+4
0.6
o
0.4
-4
0.2
-8
0.04
41
J. J. THOMSON
AND THE
ELECTRON
Plate voltage
VA/volt
-200
-150
-100
- 50
0.6
1.6
2.2
2.5
2.6
2.7
450
500
2.8
2.8
2.8
anode
cathode
to pump
42
r-"---
300
It
millie
1
filammade
one
tyres
air ali1
only
know
is no~
only
woul,
Th,
plate
RAYS
To
app 11
readir
I
CATHODE
Discharge tube
0.0
0.0
0.0
0.0
0.0
0.2
50
100
150
200
250
300
350
400
1. J. Thomson
Rutherford
Current fA/
milliampere
negar
l
this
ing tl~
Bu
that i
plate
trav9
relati
expel
I
cathode
Crookes' Maltese-cross
tube
Thomson's
original apparatus
43
J. J. THOMSON
AND THE
ELECTRON
MEASUREMENT
OF elm
and
this el
ION
If a pi
chargcharg
a CUD
the e
charge
filamel
hot fil
the h1i
impor
greate
I
undeflected
44
of the charge
e.
it, showing
J. J. THOMSON
AND THE
ELECTRON
-~---~-----------
---~
~I
MODELS OF
THE ATOM
an impenetrable
sphere,
positively
charged, with
negative electrons embedded in it: the 'plum pudding'
model, which was accepted until Rutherford replaced
it by another.
NUCLEAR
source of o: particles
MODEL
OF THE ATOM
negs
),
microscope
------
,
\
I
I
f
,
,
,
\
-.
46
\
\
--t-----'e
,
....
the
they'
_-----' ",,"
,//
IOf\j
RAI
I
A m:
to b
Simi
ins are
attracted
to the negative
ions to the
I(the anode). At the electrodes they
ir charge or are neutralised by the
attery.
lectrodes are used in a solution of
:~e movement of the ions leads to a
oper on the cathode and the chemical
es place at the anode when the
it leads to the copper being taken
has an important
application
in
'the impure metal can be made the
uJper is deposited on the cathode.)
'j,f ions in a liquid solution is also
Ising a current through water conhuric acid. Positive and negative ions
msible for carrying
the current
. The positive ions are attracted to
'e they are neutralised by the current
producing hydrogen. The negative
Ie anode, where they give up their
iemical action produces oxygen. The
ren and oxygen, bubble up from the
anode respectively,
and can be
atus similar to that shown on the left.
MODELS OF
THE ATOM
size of atom
IO
('"V10- m)
CEO BY A FLAME
_.
--
<
------
-------
-----
-----
MODELS OF
THE ATOM
1
1
2
1
16
8
1 proton
neutron
1 electron
outside nucleus
1 proton
1 neutron
1 electron
outside nucleus
8 protons
8 neutrons
8 electrons
IIONsl
I
The c
strips,
to the
not m1
same
positiv
We
it as J
sornetl
""1
outside nucleus
'-6
a neutral I
17
8
8 protons
9 neutrons
8 electrons
outside nucleus
17
The:
usually
or the
92 protons
92 electrons
negative
outside nucleus
ionisati
knockel
It is j
this, br
discuss,
need fo
146 neutrons
238
Nuclei
OF THE ATOM
anode
cathode
L------1+
-=--=--
Early i
(distille:
became
it. Sim
water
it. We
that PC(j
through
MODELS OF
THE ATOM
IG CHARGE
TRICITY
electrons moving
up and down
in aerial
--------')
radiation
is emitted
AND
//
-,
.... -(---
//
'e,
I
I
\
\
I
I
I
\
\
\
,-,
I
/
-7--
electron
in orbit
view of
electron orbit
sideways on
why is no radiation
emitted?
THE EVIDENCE
FOR CHARGED
PARTICLES
50
THE WAVE-MECHANICAL
or
MODEL
YOUI
beet
a ny
then
a ce
willi
huns
polY
IS se.
lose
I
BD.:
I
polyi
aced
This
posit
char!
unli]
com!'1
cellr
l
+++
[!][!]
+++++++
+++++
~.[!]
'n
mvel
insu
leaf,
leaf
If
of a
POSil
leaf
brou
leaf
MODELS OF
THE ATOM
.~
.0
....
.
-0
.?
i5
co
.0
0.
distance
THE FUTURE
The important thing to realise is that no one would
claim that the wave-mechanical
model of the atom is
the final correct one, but it provides a convenient model
which fits the known facts as at present observed.
Physicists are now much too modest to think they know
the ultimate truth.
51
ELECTRONS
AT WORK
THE CATHODE-RAY
OSCILLOSCOPE
focussi ng
anode
deflecti ng
plates
:-1
I
------------------
control
grid
L7
OJ-
- -------------------
accelerati ng
anode
fluorescent screen
The'
mot
aver
ture
tern]
diff,:
bro.
expl
sigh!
spec,
part
a co
If'
the
l
500
AI
lead:
with
evid,'
matt
" For this treatment,
Theory.
pard
one.
PO\\)
CH~
So fd
consi
has t
we fii
m aq
Th
of h.j
of so'
bines
find
that
They
11
'~----
------------
---
not focussed
focussed
not focussed
volt/em
2
10.
.0,5
20
0,2
0.1
.--~---------
ELECTRONS
AT WORK
WHY DO WE
BELIEVE IN
ATOMS?
spr
dot
acr
ane
are!
enc
ma),
do (
I
Ife
no voltage
applied
d.c. voltage
applied to plates
a.c. voltage
applied to plates
I
Incorporated
in an oscilloscope is a time-base circuit.
This applies a steadily increasing
voltage to the
X-plates (those that deflect the spot horizontally) so
that the spot sweeps across the screen at a steady rate
until, at a certain point, the voltage flies back to its
original value and the spot consequently returns rapidly
to its starting point. The flyback time should be as short
as possible; it is also usual for an internal arrangement
to reduce or 'suppress' the flyback trace so that it is not
visible. (You can sometimes see the flyback trace if the
brightness is turned up to its maximum value.) The
If ti
R,
it is,
SIze
leas'!
to
Ther
is in'
But
the r
M,
aton
num
I
YOUI
expel
air, 11
pow:
I
---'--.---
ELECTRONS
AT WORK
(i)
110 TO GAS
~)erty of matter is that a solid turns
fficient heat energy is given to it;
mergy is supplied, it turns to gas.
'el of matter made of particles say
M THE Oil-DROP
.experirnent, you took a very small
cross) and put it on the surface of a
had been dusted with lycopodium
sut into a thin film on the surface.
of "continuous juice' and not of
expect the layer of oil to go on
(iii)
(iv)
(ii)
o
o
o
a.c.
d.c.
01
School oscilloscopes
usually also have an AC/DC
switch on the front panel. In the DC position the spot
will be deflected by both a d.c. voltage and an a.c. one.
When in the AC position a d.c. voltage has no effect
and the spot is only deflected by an a.c. signal." In
some ways it is inaccurately named an AC/DC switch:
it would be more correct to call it an 'AC only/ric and
AC switch'! To illustrate
its use, consider the circuit
below in which an a.c. and d.c. voltage in series are
connected to the input. In the DC switch position both
rll~.g
CJ
L-
~~O
88
55
X_!I~
ELECTRONS
AT WORK
the a.c. and d.c. voltages will deflect the spot, so that
the trace will be as shown on the left. In the AC switch
position only the a.c. voltage acts, so the trace is as
on the right.
There is usually one more facility on school oscilloscopes - a Z-input on the back of the oscilloscope.
An input voltage here is superimposed
on the grid
inside the tube (see page 24) and this changes the
number of electrons streaming through the anode.
This affects the brightness of the spot on the screen.
If, for example, an alternating
voltage at 20 Hz is
applied to this input, the brightness of the spot will
vary 20 times a second. This facility is of considerable
importance in the next device using electron streams,
the television tube.
THE TELEVISION
WHY DO WE
BELIEVE IN
ATOMS?
Yen
regi
by (I
slit I
whic
inte:
slits,
stru:
when
tion
TUBE
"~,~========~~~==~~==~==~~-----,,~======~~~==~~~~~~==~~--~~,,~,======~--~~~~==~~====~=--~==~"~~~~~~~~~~====~~----
--====~==~,~,==~-=~=-~-=--~-===~~---===~==~,~~~~~~~~~~~~
"~'~~~~~~~==~~~--
--==~==~~==~,,--~--~==~======~-~==~====~~~-~~~,?)==~~==~~==~-"
56
-
---
-.--
..
------
Ifl
small
cryst:
tive ill
those
---
-_.--"
'--
-.--
-- ----...
ELECTRON
AT WORK
A monochrome
television tube
television
The intensity of the spot at any point can be controlled by the voltage applied to the grid, as happens
at the Z-input to the oscilloscope described above.
As the number of electrons reaching the screen varies,
the spot changes its brightness. The different bright and
dark spots build up a complete picture.
Because of the persistence of vision no gaps appear
to the viewer between one picture and the next and so
a 'moving picture' is seen in the same way that a cine
film appears as a 'movie' even though made of a
sequence of 'still' pictures.
model
ELECTRONS
AT WORK
WHY DO WE
BELIEVE IN
ATOMS?
was
will
~U~(I
lllSl~
muc
L
of a
I
EA[
The'
cam
cord
Renl
spec
evidup
was
thou'
anode
high
TH'
voltage
filament
cathode
target
58
Granulated sugar
who
FluOf
APPENDIX:
MASS
SPECTROMETERS::~
':'More detail is
included here than
will be necessary
for an O-level
course. It is included
for general interest.
,MODELS
I
THE
MASS
SPECTROGRAPH
photographic
plate
t ~gNe and f6Ne are isotopes of neon they both have the same place in the
periodic table and are the same as far
as chemical properties are concerned.
Both have 10 electrons round the
nucleus and a charge of + 10 units on
the nucleus. Each nucleus therefore
contains 10 protons.
The nucleus of
2Ne, however, has 10 neutrons whereas
that of 22Ne has 12, thereby accounting
for the difference in mass. In ordinary
neon, there are 9 parts of 2Ne to 1
part of nNe and this gives an average
mass of 20.2 units.
THE,
Mas
The'
Mas!
Isotr
1.1.11
Catr
Mea:
The'
Positive-ray parabolas
MOD1
Nue!'
Thomson's
positive-ray
The
The
The
apparatus
Aston's
60
of germanium
mass spectrometer
(right)
ELEC
The
The
The
APPEll
Mass spectrogram
(below)
----~I
6
6
7
7
9
10
10
11
A.TOMS?
ystals
~rystals
I
I-drop experiment
aian motion
,.:1 from a consideration
12
13
13
14
bm chemistry
I
PARTICLES
'electrostatics
and current electricity
I
,llame
iilioactive radiations
mot filament
vith thermionic
22
22
25
25
atom
vacuum tubes
MODERN
MASS
SPECTROMETERS
15
15
16
17
17
17
18
19
21
of
lion
,RGED
I APPENDIX
accelerating voltage
L
for electron gun
I--r-------i
r-- --1
29
Ir<!J1ENT
tperiment
ment
I
~CTRON
bctrons
ctrons due to the magnetic field
I
.ctron
30
31
32
33
33
34
34
35
36
38
38
hot fi lament
ELECTRON
GUN
stream of ions
ION
GUN
61
I APPENDIX
NOTE
TO THE
TEACHER
Thi'
Nuf
toge
sho-
whir
usef
the I
wha
inch]
subj:
with
in th
that
style'
very
will
I
that
to electrometer
At
Nuf~;
back
ideas!
findiJ
Even with a fine hole, the stream of ions from the ion
gun may splay out through a small angle, but the orbits
will focus sharply after a half circle, as shown on the
left, provided the splay is not too great.
The point at which the beam focuses depends upon
the mass M of the ions: there will be different points
for different values of M, so that a photographic film
will show the existence of different isotopes.
As in the fine-beam tube the kinetic energy of the
ions = !MV2 = Ve
where V is the accelerating voltage applied to the ions.
62
L
!D
and representatives
APPENDIX
=Bev
From these equations
Mv2
=--
it follows,
~ _ 2V
M B2r2
Ne20
Ne22
1000
voltage V
I APPENDIX
abundancies.
For this reason the Nier mass spectrometer is a very useful tool for analysis.
Small Nier mass spectrometers
have in recent years
been sent high in the atmosphere by rockets to study
the upper atmosphere.
At a height of 150 km, the
spectrometer
opens to admit a sample of the atmosphere (already at very low pressure) and it is then
V'
ion gun
PHY
EI
A:
accelerating
voltage V
~(
LONGMAN
Joh
/~
Sen it;
and)",
to electrometer
Nuffi;
Illus[
~ JIll '
l:
~/I
LON!D
64
/
--
..
~-
hs
. Arc)
Heafford
oolnough
renee Bragg
Science D. D. Lindsay
de F. R. McKim
Shire
s of the cross
the cathode
the shadows
f electrons is
de visi ble by
tagnetic field,
ight-angles to
ists of several
ich are green,
to these than
blue.
LONGMAN
PHYSICS
TOPICS