INDIAN ASSOCIATION OF CHEMISTRY TEACHERS

NATIONAL STANDARD EXAMINATION IN CHEMISTRY 2011-2012

1.

Ans.
Sol.

The number of water molecules present in 0.20 g sample of CuSO4.5H2O (molar mass = 249.7) is (A) 1.2 1021
(B) 2.14 1021
22
(C) 2.14 10
(D) 1.2 1023
[B]
249.7 gm of CuSO4 .5H2O contain 5 6.023 1023 molecule
?0.2g of CuSO4 .5H2O contain

5 u 6.023 u 10 23
0.2
249.7

= 2.14 1021
2.

Ans.
Sol.

The group that has the species correctly listed in the order of decreasing radius is (A) Cu2+, Cu+, Cu
(B) V, V2+, V3+
(C) F , Br , I
(D) B, Be, Li
[B]
1
Cationic radii v
effective nuclear charge
size =

3.

V ! V 2 ! V 3
z eff n
size p

Ans.

The number of isomers of dibromobiphenyl (Biphenyl C6H5-C6H5) is (A) 8

(B) 10
(C) 12
(D) 14
[C]

4.

The enthalpies of decomposition of methane (CH4)(g) and ethane (C2H6)(g) are 400 and 670 kJ mol 1,

Ans.
Sol.

respectively. The 'HC-C in kJmol 1 is (A) 270

(B) 70
(C) 200
(D) 240
[B]
CH4 oC + 4H
'H = 400 KJ/mol
?'H = (6 B. E)R (6 B. E)P
400 = 4 C H
?CH = 100 kJ/mol
In C2H6 o2C + 6H

'H = 670 kJ/mol

?'H = [CC + 6 CH]R [0]

670 = CC + 6 100
5.

?CC = 70 kJ/mol
The correct formula for hexaaminecobalt (III) nitrate is -

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(A) [Co3(NH3)] (NO3)3

(B) [Co3(NH3)6](NO3)3

(C) [Co(NO3)3].6NH3

(D) [Co(NH3)6](NO3)3

Ans.

[D]

Sol.

Formula of hexaammine cobalt (III) nitrate

[Co(NH3)6]+3 + NO3 [Co(NH3)6](NO3)3

6.

For the reaction PCl3(g) + Cl2(g)

1

PCl5(g), Kc is 26 at 250C Kp at the same temperature is -

(R = 8.314 J K mol )
(A) 4.6 10

(B) 5.7 10

(C) 6.0 10

(D) 8.3 10

Ans.

[C]

Sol.

kP = kC (RT)'ng
kP = 26 (8.314 523)
kP =

7.

26
= 5.9 10
4348.2

Curved arrows are used in Organic chemistry to show the movements of electrons in the mechanism of a
reaction. The correct product of the following reaction is -

O
O

O
(A)

(B)

O
(C)

O
(D)

Ans.

[C]

8.

Denaturation of protein due to change in pH could be due to (A) loss of van der Waal's interaction

(B) hydrophobic interaction

(C) change in ionic interaction

(D) breaking of covalent bonds

Ans.

[C]

9.

The initial activity of a radionuclide is 9750 counts per min and 975 counts after 5 min. The decay constant
of the radionuclide in min 1 is about (A) 0.23
(B) 0.46
(C) 0.69
(D) 0.99
[B]

Ans.

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Sol.

K=
=

a
2.303
log
t
(a  x )

2.303
9750
log
5
975

= 0.46
10.

Ans.
Sol.

According to VSEPR theory the shape of IF5 molecule will be (A) tetrahedral
(B) trigonal bipyramid
(C) square pyramid
(D) trigonal planar
[C]
:IF5
? sp3d2
F

F
I
F

Square pyramid
11.

The formal charges on the atoms underlined are -

C6H 5  C { N  O
(A) C = 0, N = 1, O = + 1
(C) C = 0, N = +1, O = 1
Ans.

[C]

Sol.

 :
C6H5C{N O
..

FC = valance e
For C : FC = 4
For N : = 5

Ans.
Sol.

1
(bonded e ) (non-bonded)
2
1
8=0
2

1
(8) = 0 + 1
2

For O : FC = 6

12.

(B) C = 1, N = + 1, O = 1
(D) C = +1, N = 0, O = 1

1
(2) + 6 = 1
2

The number of D-particles emitted per second by a radioactive element reduces to 6.25% if the original value
is 48 days. The half-life period of the element in days is (A) 3
(B) 8
(C) 12
(D) 16
[C]
2.303
100
log
K=
48
6.25

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2.303
log 24
48

2.303 u 4 u 0.3
= 0.0575
48

t1/2 =

13.

Ans.
Sol.

0.693
0.693
=
= 12
k
0.0575

The compound that does not have a S-bond is (A) SO2

(C) O2
[B]
F
F
F
SF6
S
F
F
F
S
SO2
O
O
O
SO3
O2

14.

(B) SF6
(D) SO3

S
O

O
O=O

Is mass spectrometry a compound is bombarded with high energy electrons to break it into smaller
fragments, which are recorded in the form of their masses (m/Z). For example butane gives fragments like
m/z 58, 43, 29, 15, etc. The mass spectrum of an unknown compound is shown below -

43
intensity

15

29

72
57

m/z

Ans.
15.

Ans.
Sol.

The likely compound among the following is (A) CH3COCl

(C) CH3CH2COOH
[D]

(B) CH2=CHCH2CH2OH
(D) CH3COCH2CH3

The solubility of calcium phosphate is S mol dm 3. Hence, the solubility product is (A) S5
(B) 27S3
(C) 54S4
(D) 108S5
[D]
Ca3 (PO4)2
?ksp = 108 55

16.

The number of valence electrons in an atom with the configuration 1s2 2s2 2p6 3s2 3p2 is -

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(A) 6

(B) 5

(C) 4

(D) 2

Ans.

[C]

17.

The elevation in boiling point of a solution containing 13.44g of CuCl2 in 1 kg of water is (Kb = 0.52 K/kg mol 1)
(A) 0.05

(B) 0.10

(C) 0.16

(D) 0.21

Ans.

[C]

Sol.

' Tb = Kb

= 0.52

w A u 1000
i
MA u w B

13.44 u 1000
u 0.3
134.5 u 1000

= 0.16
18.

The configuration of the carbon atoms C2 and C3 in the following compound are respectively -

HOOC
H

OH

HO

H
CHO

Ans.

(A) R, R

(B) S, S

(C) R, S

(D) S, R

[A]

COOH

H
Sol.

3
3

HO1

OH

CHO
2

19.

0.1 dm3 of 0.1 M acetic acid is titrated against 0.1 M NaOH. When 50 cm3 of 0.1 M NaOH are added, the pH
of the solution will be (pKa = 4.74)

Ans.
Sol.

(A) 2.37

(B) 4.74

(C) 1.34

(D) 5.74

[B]

CH3COOH + NaOH oCH3COONa + H2O

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Initial Meq
10
Final
5
Resulting solution is an acidic buffer
?pH = pKa + log

5
0

0
5

[Salt]
5
= 4.74 + log
[Acid]
5

pH = 4.74
20.

Ans.
Sol.

21.

Ans.
22.

The IUPAC name of complex [Cu(en)2(H2O)2]+ is (A) ethylene diamine Cu(II) dihydrate
(B) diaquobis(ethylenediamine) Cu(II) ion
(C) diaqobisdiethylamine Cu(II) ion
(D) diaquobis(ethylenediamine) cuprate (II)
[B]
[Co(en)2(H2O)2]+
Diaqua bis(ethylene diamine)Cu(II) ion
Two protein molecules with the same average molecular mass (molecular weight) can absorb different
amount of ultraviolet radiation due to difference in the content of (A) tyrosine
(B) glutamic acid
(C) lysine
(D) methionine
[A]
Each of the following options contains a structure and a description indicating the existence of given
structure. The correct option for methyl 3-hydroxypent-2-enoate is (A)

(C)

COOCH3 YES
OH
OH

NO

(B)

(D)

COOCH3 NO
OH
OH

COOCH3

YES
COOCH3

Ans.

[B]

23.

Major product of mononitration of the following compound is

O
O

(A)

(B)
NO2

NO2
O
O

(C)

O
O

NO2

(D)

O 2N
Ans.

[D]

24.

If a z b z c and D = E = J = 90, the crystal system is -

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(A) monoclinic

(B) triclinic

(C) hexagonal

(D) orthorhombic

Ans.

[D]

25.

The electronic spectrum of [Ni(H2O)6]++ shows a band at 8500 cm 1 due to dd transition. [Ph4As]2[NiCl4]
will have such a transition in cm 1 at (A) 3778

(B) 8500

(C) 4250

(D) 850

26.

In the conductometric titration of silver nitrate against KCl, the graph obtained is -

(B)

(C)

volume of KCl

Conductance

volume of KCl

(D)

volume of KCl

Conductance

(A)

Conductance

[A]

Conductance

Ans.

volume of KCl

Ans.

[B]

Sol.

AgNO3 + KCl oAgCl(p) + KNO3

27.

The product obtained from the following sequence of reactions is NaBH

HgSO

4 o B
H3CC{CH  4 o A  
H 2SO 4

(A) propanal

(B) 2-propanol

(C) 1-propanol

Ans.

[B]

28.

The compound in which Mn has oxidation state of +3 is

(A) KMnO4

(B) K2[Mn(CN)6]

(C) MnSO4

(D) CsMn(SO4)2.12H2O

Ans.

[D]

29.

The SI units of viscocity is

(A) Nsm2

(B) Ns2m

(C) Nsm

(D) propane

(D) Ns 2m

Ans.

[C]

30.

If titration of an amino acid present in the solution yielded pI (isoelectric point) value of 10.80, the amino

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acid present in the solution may be

(A) glycine

(B) arginine

(C) histidine

Ans.

[B]

31.

In the coordination compound, Na2[Pt(CN)4], the Lewis acid is (A) [Pt(CN)4]2

(B) Na+

(D) proline

(C) Pt2+

Ans.

[C]

32.

The product (P) of the following reaction is

CH3

(D) CN

Lewis acid

+ ICl  o P

Cl
I

(A)

(B)
H 3C
CH3

Cl

(C)

(D)
H 3C

Ans.

[B]

33.

The correct order of dipole moment for the following molecules is -

OH

Cl
NO2

CH3
Cl

CH3

(I)

(II)

(III)

(A) I = II = III

(B) I < II < III

(C) I > II > III

Ans.

[C]

34.

Lead dissolves most readily in dilute (A) acetic acid

(B) sulphuric acid

(C) phosphoric acid

(D) sodium hydroxide

Ans.

[A]

35.

The degrees of freedom for the system CaCO3(s)

(A) 1

(B) 2

(D) II < III < I

CaO(s) + CO2(g) are (C) 3

Ans.

[A]

36.

Semipermeable nature of the cell membrane can be attributed to the presence of -

(D) 4

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Ans.
37.

Ans.
Sol.

(A) protein and DNA

(C) polysaccharide and lipid
[B]

(B) lipid and protein

(D) DNA and lipid

The emf of the cell (Zn | ZnSO4 (0.1M) || CdSO4 (0.0.1M) | Cd) is
(E0 Zn2+| Zn = 0.76 V, E0 Cd2+| Cd = 0.40 V at 298 K)
(A) + 0.33 V
(B) + 0.36 V
(C) + 1.13 V
[C]
Ecell = 0.76 + 0.4 = 4.16
Emf = Ecell
= 1.16

(D) 0.36 V

0.059
[ Zn 2 ]
log
n
[Cd  2 ]

0.059
0.1
log
2
0.01

= 1.16 0.03 log 10 = 1.13 V

38.

Ans.
39.

The nitrogen compound formed when Ca(CN)2 reacts with steam or hot water is
(A) N2O
(B) NO
(C) NO2
(D) NH3
[D]
The order of acidities of the H-atoms underlined in the following compounds is in the order
(I) Ph-CH2CH3 (II) Ph-C{CH

Ans.
40.

(III) Ph-CH=CH2 (IV)

(A) IV > II > I > III

(C) III > IV > I > II
[A]

CH2

(B) II > IV > III > I

(D) I > III > II > IV

Ans.

The half time for a second order reaction with equal concentrations of the reactants is 35 seconds. 99%
reaction will be completed in
(A) 69s
(B) 138s
(C) 1733s
(D) 3465s
[D]

Sol.

For second order t1/2 =

Let initial is 100 ?
?t=

1
= 35
Ka

1
= 35 100
K

1 x

K a (a x )

99
= 3500

100 u1
= 3465 sec

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41.

The 'd' orbitals will be split under square planar geometry into (A) two levels

(B) three levels

Ans.

[C]

42.

Rotational spectra of molecules are observed in -

(C) four levels

(A) UV region

(B) Visible region

(C) Near infrared region

(D) Far infrared region

Ans.

[D]

43.

The pair of cations which cannot be separated by H2S in a 0.3N acid solution is (A) Al+++, Hg++

(B) Bi+++, Pb++

(C) Zn++, Cu++

(D) Ni++, Cd++

(D) five levels

Ans.

[B]

44.

Structural features of proteins secreted outside the cells may be stabilised by presence of (A) hydrogen bond

(B) disulfide bond

(C) hydrophobic force

(D) phospho-diester bond

Ans.

[B]

Sol.

Most secreted protein and extra cellular domains of membrane protein contain disulphide bond. These
covalent bonds are important for the proper folding and stability of secretary protein.

45.

The COC bond angle in dimethyl ether is (A) 10928'

Ans.

(B) 110

(C) 120

(D) 180

[B]

:O:
CH3 110 CH3
Large size of methyl group. So bond angle greater than 109 28'
46.

Dimethyl glyoxime forms a square planar complex with Ni2+. This complex should be
(A) diamagnetic

(B) paramagnetic having 1 unpaired electron

(C) paramagnetic having 2 unpaired electrons

(D) ferromagnetic

Ans.

[A]

Sol.

Ni+2 + 2DMgH OH


o [Ni (DMg)2]
Square planar dsp2
Ni+2 = [Ar] 3d8

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3d

4s

4p

Ni+2 =
3d

4s

4p
2

dsp
n = 0 ?diamagnetic
47.

A 0.056 M solution of benzoic acid, C6H5COOH, is titrated with a strong base. [H+] of the solution when half
of the solution is titrated before the equivalence point is (Ka of benzoic acid = 6.3 10 5)
(A) 6.3 10 5 M

Ans.

[A]

Sol.

[H+] = Ka

(B) 1.8 10 3 M

(C) 7.9 10 3 M

(D) 2.6 10 2 M

(C) ONC

(D) CN

[Acid]
[Salt ]

= 6.3 10 5

0.056
0.056

= 6.3 10 5 M
48.

The formula of the isothiocyanate ion is (A) OCN

(B) SCN

Ans.

[B]

49.

The compound that is chiral is (A) 3-methyl-3-hexene

(B) 4-chloro-1-methylcyclohexane

(C) 2-phenylpentane

(D) 1, 3-diisopropylbenzene

Ans.

[C]

50.

The monomer/s of the following polymer is/are

(CH2CH(CH3)CH2CH(CH3)CH2CH(CH3))n
(A) ethylene

(B) propylene

(C) 2-butene

(D) ethylene + propylene

Ans.

[B]

51.

Of the interhalogen compounds, ClF3 is more reactive than BrF3, but BrF3 has higher conductance in the
liquid state. The reason is that
(A) BrF3 has higher molecular weight
2

(C) BrF3 dissociates into BrF and BrF more easily

(B) ClF3 is volatile

(D) ClF3 is most reactive

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Ans.

[C]

Sol.

High E.N difference in Br & F

?high polarity
?Ions form easily

52.

An element X is found to combine with oxygen to form X4O6. If 8.40 g of this element combine with 6.50 g
of oxygen, the atomic weight of the element in grams is (A) 24.0

(B) 31.0

Ans.

[B]

Sol.

6.5 g oxygen combine with 8.4 g

? 96 g oxygen combine with
? At. wt of one X =

53.

(C) 50.4

(D) 118.7

8.4 u 96
= 124.06
6.5

124.06
= 31.0
4

Synthesis of RNA in a cell would be affected adversely due to shortage of

(A) sulfate

(B) acetate

Ans.

[D]

54.

The most abundant element in the earth's crust is (A) aluminium

(B) oxygen

(C) oxalate

(D) phosphate

(C) silicon

(D) iron

Ans.

[B]

55.

A beaker is heated from 27C to 127C, the percentage of air originally present in beaker that is expelled is
(A) 50%

(B) 25%

(C) 33%

Ans.

[B]

Sol.

n1T1 = n2T2

56.

The product (C) of the following sequence of reactions is

(D) 40%

i ) AlCl3
+ CH2=CH2 (

o A Cl
2 (lim)

o B aq
NaOH
o C
( ii ) H 2O

hQ

OH
(A)

(B)

HO

OH

HO
(D)

(C)

Cl
Ans.

[D]

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IAPT has given (c) as the correct answer to this question.

But the most appropriate answer to this question should be (d). For more details refer the solution given below.
OH
Cl

+ CH2 = CH2

57.

(i) AlCl3
(ii) H 2 O

CHCH3

CHCH3

CH2CH3
Cl /

aq
.NaOH
o

2


o

The strongest, but the most reactive bond among the following is (A) C=N
(B) C=C
(C) C{C

(D) C=O

Ans.

[C]

58.
Ans.

Radioactive inert gas is (A) technetium

(B) radon
[B]

59.

The IUPAC name of the following compound is -

(C) xenon

(D) curium

OC2H5
O
O

Ans.
60.

Ans.
Sol.

(A) 3-methoxy ethylpropanoate

(C) 1, 4-diethoxybutane
[B]

(B) ethyl 4-methoxybutanoate

(D) ethoxy 3-methoxybutyrate

Excess of silver nitrate is added to a water sample to determine the amount of chloride ion present in the
sample. 1.4 g of silver chloride is precipitated. The mass of chloride ion present in the sample is
Molar masses (g. mol 1); AgNO3 169.91, AgCl
143.25
(A) 0.25 g
(B) 0.35 g
(C) 0.50 g
(D) 0.75 g
[B]
143.25 AgCl obtained from 169.91 g AgNO3
then 1.4 g AgCl obtained from 169.91 g Ag NO3
=

169.91
u 1.4 1.66 g
143.25

In 169.91 g of sample chlorine is 35.5 g

?1.66 g of sample chlorine
=
61.

The best nucleophile among the following is (A) H2O

Ans.

35.5
u 1.66 0.35 g
169.91

(B) CH3SH

(C) Cl

(D) NH3

[B]

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62.

The wavelength of a moving body mass 0.1 mg is 3.31 10

29

m. The kinetic energy of the body in J would

be (A) 2.0 10
Ans.

[D]

Sol.

(B) 1.0 10
6.62 u 10 34

2 u 0.1 u 10

2mKE

2 u 10 7 u KE

u KE

(C) 4.0 10

(D) 2.0 10

3.31 u 10  29

2 u 10 5

?2 10 7 KE = 4 10

10

KE = 2 10
63.

6

Ans.

Secondary structures could be formed in nucleic acid similar to protein due to formation of (A) covalent bond
(B) ionic bond
(C) co-ordinate bond
(D) hydrogen bond
[D]

64.

The following titration curve represents the titration of a

acid with a

base -

pH 7
mL added
Ans.
65.
Ans.
66.

Ans.
Sol.

67.
Ans.

(A) strong, strong

[A]

(B) weak, strong

The element with the lowest electronegativity is (A) S

(B) I
[C]

(C) strong, weak

(D) weak, weak

(C) Ba

(D) Al

Oxalic acid, H2C2O4, reacts with permanganate ion according to the balanced equation
5H2C2O4(aq) + 2MnO4 (aq) + 6H+(aq)
2Mn2+(aq) + 10CO2(g) + 8H2O(l).
The volume in mL of 0.0162 M KMnO4 solution required to react with 25.0 mL of 0.022 M H2C2O4 solution
is(A) 13.6
(B) 18.5
(C) 33.8
(D) 84.4
[A]
Equivalent of KMnO4 Eq. of H2C2O4
N1V1 = N2V2
0.0162 5 V1 = 0.022 2 25
V1 = 13.6 ml
The element that has the highest tendency to catenate is (A) silicon
(B) germanium
(C) sulphur
[C]

(D) boron

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68.

Ans.
69.

Ans.
70.
Ans.
71.

Ans.
Sol.

The isotope of carbon which is used in carbon dating (a method to estimate the age of an ancient sample
containing carbon) is (A) carbon-12
(B) carbon-13
(C) carbon-14
(D) carbon-15
[C]
Electronic configurations for the atoms of four elements are given below. The configuration that indicates
colourless aqueous solution is (A) 2,8,14,2
(B) 2,8,16,2
(C) 2,8,18,2
(D) 2,8,13,1
[C]
The number of stereoisomers of compound CH3CH=CHCH(Br)CH3 is (A) 2
(B) 3
(C) 4
(D) 6
[C]
At 445C, Kc for the following reaction is 0.020.
2HI(g)
H2(g) + I2(g)
A mixture of H2, I2 and HI in a vessel at 445C has the following concentrations :
[HI] = 2.0 M, [H2] = 0.50 M [I2] = 0.10 M. The statement that is true concerning the reaction quotient, Qc is (A) Qc = Kc; the system is at equilibrium
(B) Qc is less than Kc; more H2 and I2 will be produced
(C) Qc is less than Kc; more HI will be produced
(D) Qc is greater than Kc; more H2 and I2 will be produced
[B]
[H 2 ] [I 2 ]
Q=
[HI]2
0.5 u 0.1
= 0.0125
2u 2
? Q < KC and forward reaction.

72.

Ans.
73.

The order of decreasing stability is -

(I)

(II)

(III)

(IV)

(A) IV > I > II > III

[A]

(B) I > IV > III > II

(C) I > II > IV > III

(D) IV > II > I > III

Ans.

The number of amino acid residues found in a protein that is synthesized from a RNA molecule with 120
nucleotides is (A) 120
(B) 80
(C) 40
(D) 60
[C]

74.

Hypochlorous acid ionizes as HOCl (aq)

H+(aq) + OCl (aq).

OCl (aq) + H2O(l)

HOCl(aq) + OH (aq)

Ka for this reaction at 25C is 3.0 10 8 (Kw = 1.0 10

14

at 25C)

Hence, Kh for HOCl is -

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(A) 3.3 10
Ans.

[A]

Sol.

Kh

Kw
ka

(B) 3.0 10

10 14
3 u 10 8

10
1
10 6 =
10
3
3
Kh = 3.3 10

75.

(C) 3.0 106

(D) 3.3 107

Einsteinium has 11 electrons in the 4f subshell. The number of unpaired electrons in the subshell is (A) 3

(B) 4

(C) 7

Ans.

[A]

76.

The order of reactivity of ammonia with the following compounds is -

(D) 11

(I) CH2=CHBr

(II) CH3CH2COCl

(III) CH3CH2CH2Cl

(IV) (CH3)3CBr

(A) IV > II > I > III

(B) II > IV > III > I

(C) III > IV > II > I

(D) I > IV > II > III

Ans.

[B]

77.

The freezing point of a solution containing 8.1g of HBr in 100 g of water, assuming the acid to be 90%
ionized is [H=1, Br=80, Kf for water = 1.86 K kg mol 1]
(A) 0.85C

Ans.

[B]

Sol.

i 1
n 1

0.9 =

i 1
2 1

i = 1.9

(B) 3.53C

(C) 0C

(D) 0.35C

('Tf)obs = i ('Tf)theo.
= 1.9 kf

WA u1000
M A u WB

= 1.9 1.86

8.1 u 1000
81 u 100

('Tf)obs = 3.53
?T' = 3.53C
78.

The reaction of 50% aq KOH on an equimolar mixture of 4-methylbenzaldehyde and formaldehyde followed
by acidification gives OH
OH
(A)

OH

(B)

H3C

+HCOOH
H3C
(C
)

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COOH

COOH
(D)

+CH3OH

OH

Ans.

H3C
[B]

79.

Iodide ion is oxidized by acidified dichromate ions as shown in this equation.

Cr2O72 (aq) + 9 I (aq) + 14 H+(aq) o 2Cr3+(aq) + 3I3 (aq) + 7H2O (l). These data were obtained when

Ans.

the reaction was studied at a constant pH. The order of the reaction with respect to Cr2O72 (aq) and I (aq)
are [I ] M
Rate, M.s I
Experiment
[Cr2O72 ], M
1
0.0050
0.0125
0.00050
2
0.010
0.0125
0.0010
3
0.0150
0.0250
0.0060
2
(A) first order with respect to both Cr2O7 and I
(B) second order with respect to both Cr2O72 and I
(C) second order with respect to Cr2O72 and first order with respect to I
(D) first order with respect to Cr2O72 and second order with respect to I
[D]

Sol.

k[Cr2O72 ]m [I  ]n

0.0005 = k[0.005]m [0.0125]n

0.0010 = k [0.01]m [0.0125]n
0.006 = k[0.015]m [0.025]n
equation (1)/(2)
1 1
=
2 2

.(1)
.(2)
.(3)

m=1

equation (2)/(3)

80.

1
6

2 1

3 2

1
4

1

2

1
6

2 1
u
3 2

?n = 2

The number of atoms per unit cell and the number of the nearest neighbours in a body centred cubic structure
are (A) 4, 12

(B) 2, 6

(C) 9, 6

Ans.

[D]

Sol.

1
No. of per unites cell of BCC = 8 u  1 u 1 2 ?and C.No. = 8
8

(D) 2, 8

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