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SBs CLASS TEST

Electrostatics, current electricity, solution, coordination compound, solid state chemistry, indefinite integration, matrix
determinant, relation, first order derivatives
Time:3hrs

FM:72

Group-A
1 mark each
1. i. How much work is done in moving q C of charge
between two points seperated by a distance r on an
equipotential surface?
ii. Which of the following is the unit of electric flux?
(a) Vm1 (b) Vm
(c) Vm2 (d) Vm2
iii. If a is a 3 x 3 non-singular matrix and k is a real
number, which one of the following is value of det
(kA)?
(a) k det(A)

(b) |k| det(A)

(c) k2 det(A)

(d) k3 det(A)

iv. Which one of the following is the derivative of x with


respect to log x?
(a) 1/x2

v.

(b) x

(c) log x

(d) ex

sin log x
x dx
(a) cos log x c

(b) sin log x c

(c) sin log x c

(d) cos log x c

vi. On dissolving sugar in water at room temperature


solution feels cool to touch.
Under which of the following cases dissolution of
sugar will be most rapid?
(a) Sugar crystals in cold water.
(b) Sugar crystals in hot water.
(c) Powdered sugar in cold water.
(d) Powdered sugar in hot water.

vii. Considering the formation, breaking and strength of


hydrogen bond, predict which of the following
mixtures will show a positive deviation from Raoults
law?
(a) Methanol and acetone.
(b) Chloroform and acetone.
(c) Nitric acid and water.
(d) Phenol and aniline.

viii. Give an example of a material used for making


semipermeable membrane for carrying out reverse
osmosis.
ix. Which of the following is not a characteristic of a
crystalline solid?
(a) Definite and characteristic heat of fusion.
(b) Isotropic nature.
(c) A regular periodically repeated pattern of
arrangement of constituent particles in the entire
crystal.
(d) A true solid

x. Which of the following arrangements shows


schematic alignment of magnetic moments of
antiferromagnetic substances?

(a)

(b)

(c)

(d)

xi. Which of the following oxides shows electrical


properties like metals?
(a) SiO2

(b) MgO

xii. Cations are


__________.

present

(c) SO2(s) (d) CrO2


in

the

interstitial

sites

in

(a) Frenkel defect


(b) Schottky defect
(c) Vacancy defect
(d) Metal deficiency defect

xiii. Schottky defect


__________.

is

observed

in

crystals

when

(a) some cations move from their lattice site to


interstitial sites.
(b) equal number of cations and anions are missing
from the lattice.

(c) some lattice sites are occupied by electrons.


(d) some impurity is present in the lattice.

xiv. The total number of tetrahedral voids in the face


centred unit cell is __________.
(a) 6
(b) 8
(c) 10
(d) 12

xv. A glass slab is introduced between the plates of a


parallel plate capacitor. Does the capacitance of the
capacitor increase, decrease or remain unchanged?
xvi. Write true or False:
If E XY E X E Y , then X and Y are independent.
xvii. Write true or False:

EX2

1
2

EX

xviii. Write the formula for the coordination compound


tetraammineaquachloridocobalt (III) chloride.

Group-B
2 marks each

2.

1 3
(i) If A
and
2 2
AX 4 X .

x
X , then show that
x

(ii) How does sprinkling of salt help in clearing the


snow covered roads in hilly areas? Explain the
phenomenon involved in the process.
(iii) Why does table salt, NaCl, sometimes appear
yellow in colour?
(iv) When two capacitances are connected in series
and in parallel, the equivalent capacitances are 5 F
and 1.2 F respectively. Find their capacitances.

(v) The inensity of an electric field is E 5i 3j 2 k

units. Calculate the electric flux passing through 200


unit area in the YZ plane.

Group-C
4 marks each
3. Solve by Crammers rule:

x 3y 3
y 3z 7
z 4x 2
4. A relation R is defined on as follows:

a, b R c, d ad bc .
Is the relation (a) reflexive, (b) symmetric, (c) antisymmetric, (d) transitive?
[1 + 1 + 1 + 1]
5. Define electric intensity and potential at an electric
field. How are they related? The electric potential in
certain situation is found to depend on x only and is
given by V(x) = ax bx3; a, b are constants. Find the
position on the X-axis where the electric intensity is
zero.
[1 + 1 + 2]
OR
What do you mean by electric dipole? Find an
expression for the force and torque acting on an
electric dipole when placed in a uniform electric
field.
[1 + 3]
6. State the Raoults law of relative lowering of vapour
pressure of solvent.
12 g of solid solute is dissolved in 90 g of water. At
100oC vapour pressure of the solution is 750 mm Hg.
Calculate the relative molecular mass of the solute.
(Assume the solute in water does not undergo
association or dissociation.)
[2 + 2]
OR
For water, Kb = 0.52 oC/m, Kf = 1.86 oC/m.
20 g of glucose is dissilved in 100 g of water. (i) If it
is cooled to 10oC, find the mass of ice freezed out.
(ii) If it is heated to 105oC, find the mass of resulting
solution.
[2 + 2]
7. Deduce the relation between current density and drift
velocity. Also deduce Ohms law.
[2 + 2]
Grouop-D
6 Marks
8. (i) State Gauss law in electrostatics and apply it to
show that the electric intensity inside a hollow
spherical charged conductor is zero.
(ii) The surface density of a positively charged long
vertical plate is Cm2. A metallic ball of mass M
and charge +q is attached to the plate by means of a
thread. Find the angle made by the thread with the
plate in equilibrium.
(iii) Two point charges +q and q are separated by a
distance x. Identify the zero potential surface for the
system.
[(1 + 2) + 2 + 1]
OR

(i) A parallel plate capacitor is charged by a battery


and disconnected. A dielectric slab is then introduced
between the plates leaving no gap. Determine the
changes that would occur in the values of the charge,
capacitance, potential difference and the energy
stored in the capacitor.
(ii) The equivalent capacitance of two capacitors
connected in series and in parallel are Cs and Cp
respectively. Determine the capacitance of each
capacitor.
[4 + 2]
9. Two random variables X and Y are jointly distributed
according to
1
2i 1 , for i 1, 2;
4
1
P X i , for i 0,1
2
and
P Y i

P X 0, Y 2 p.
Compute the correlation coefficient between X and Y.
10. Evaluate (Any two):

a
dx
ax

(i)

sin

(ii)

cos x log cosec x cot x dx

(iii)

(iv)

dx
x 1 x 1

sin

11
3

x cos

1
3

x dx

11. (i) Determine the relationship between atomic radius


and edge of a unit cell of a body centred cubic
crystal.
3

(ii) Cr NH 3 6 is paramagnetic while Ni CN 4


is diamagnetic. Explain why?
OR

Draw isomers of the complex ion Co en 2 Cl2 .

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