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EXTENDED MATERIAL SAFETY DATA SHEET


IN ACCORDANCE WITH REGULATIONS (EC): 1907/2006, 1272/2008,
453/2010

BARIUM CARBONATE
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1 Product identifier
Product name
Chemical name
Index number
EC number
CAS number
REACH Registration number

:
:
:
:
:
:

Barium carbonate
Barium carbonate
056-003-00-2
208-167-3
513-77-9
01-2119489177-25-0016

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Manufacture of barium carbonate
Industrial use of barium carbonate in the manufacture of other barium substances
or formulation of barium
carbonate containing preparations
Industrial use of barium carbonate to remove sulfate (use as reactive processing aid)
Industrial use of barium carbonate in the manufacture of glass, ceramic and electroceramic materials or
glazes, frits and enamels
Industrial use of barium carbonate in welding electrode coating
Industrial use of barium carbonate in the preparation of slurry
Industrial use of barium carbonate in the manufacture of pyrotechnical products
Welding in industrial settings
Professional use of barium carbonate in the manufacture of pyrotechnical products
Welding in professional settings

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Please refer to section 16 for a complete list of identified uses for which an
exposure scenario is provided as an annex.
Uses advised against:

Not available

1.3 Details of the supplier of the safety data sheet


Details of the supplier of the
safety data sheet

GLASS SERVICE, a.s.


Rokytnice 60
755 01 Vsetn
CZECH REPUBLIC

e-mail address for a competent :


info@gsl.cz
person responsible for the safety data sheet
1.4 Emergency telephone number
Europe-wide emergency number: 112
See Section 16.9 for the list of telephone numbers of poison centers in the European
Economic Area.

SECTION 2: HAZARDS IDENTIFICATION


2.1 Classification of the substance or mixture
Chemical identity
Chemical formula

:
:

Monoconstituent substace
BaCO3

The classification information given below is based on the proposed alternative


classification according to the criteria of Regulation (EC) No 1272/2008 and Directive
67/548/EEC, resulting from the data evaluation prepared for the REACH registration
dossier for barium carbonate in 2010. The harmonised classification and labelling as
listed in the Annexes of Regulation (EC) No 1272/2008 is not given here, but in
section 16 of this SDS.
Classification according to regulation (EC) No. 1272/2008
Acute Tox. 4 (Route of exposure: oral)

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2.2 Label elements


Hazard pictograms :

Signal word

Warning

Hazard statements
H302 Harmful if swallowed.
Precautionary statements :
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel
unwell.
2.3 Other hazards
PBT :
vPvB :

The substance or mixture does not meet the criteria for PBT or vPvB in
accordance with Annex XIII
The substance or mixture does not meet the criteria for PBT or vPvB in
accordance with Annex XIII

Other hazards which do not result in classification:

No other hazards identified

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.1 Substance
Substance identifier

: Barium carbonate
: REACH : 01-2119489177-25-0016
EC slo : 208-167-3
CAS slo : 513-77-9
INDEX : 056-003-00-2

Concentration

: 99 % w/w

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3.2 Mixtures
Not relevant, barium carbonate is a substance.

SECTION 4: FIRST AID MEASURES


4.1 Description of first aid measures
General advice

No special advice must be considered.

Eyes

No special care must be taken.

Inhalation

No special care must be taken.

Skin

No special care must be taken.

Ingestion

IF SWALLOWED: Rinse mouth; immediately call a POISON


CENTER or doctor/physician.

4.2 Most important symptoms and effects, both acute and delayed
Eyes
Inhalation
Skin
Ingestion

:
:
:
:

Not relevant
Not relevant
Not relevant
Barium carbonate is harmful if swallowed.

4.3 Indication of any immediate medical attention and special treatment needed
Follow the advises given in section 4.1.

SECTION 5: FIREFIGHTING MEASURES


5.1 Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media :

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None

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5.2 Special hazards arising from the substance or mixture


Special exposure hazards in a fire: Not combustible.
5.3 Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.

SECTION 6: ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures
6.1.1 For non-emergency personnel : Sweep up to prevent slipping hazard. Avoid
dust formation.
6.1.2 For emergency responders

: Follow the advises given in section 6.1.1.

6.2 Environmental precautions : Barium carbonate should not be released into the
environment.
6.3. Methods and material for containment and cleaning up
Sweep up and shovel into suitable containers for disposal.
Keep in suitable, closed containers for disposal.
Avoid dust formation.
Please refer to Section 7 on how to store barium carbonate.
6.4 Reference to other sections

For more information on exposure


controls/personal protection or disposal
considerations, please check section 7, 8 and
13 and the Annex of this safety data sheet.

SECTION 7: HANDLING AND STORAGE


7.1 Precautions for safe handling
7.1.1 Recommendations
Wash with water thoroughly after handling. Advice on general occupational
hygiene. Wash with water thoroughly after handling; do not eat, drink or smoke
when using this product.

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7.1.2 Advice on general occupational hygiene


Avoid ingestion. General occupational hygiene measures are required to ensure
a safe handling of the substance. These measures involve good personal and
housekeeping practices (i.e. regular cleaning with suitable cleaning devices), no
eating, drinking and smoking at the workplace and wearing standard working
clothes and shoes unless otherwise stated. Wash hands after use. Remove
contaminated clothing and protective equipment before entering eating areas.
Shower and change clothes at end of work shift. Do not wear contaminated
clothing at home.
7.2 Conditions for safe storage, including any incompatibilities
Keep in properly labelled containers.
Keep in suitable, closed containers.
Avoid dust formation.
7.3 Specific end use(s)
Please check the identified uses in Section 16 and Annex of this eSDS.
For more information please see relevant exposure scenario (Annex to this
eSDS) or contact supplier.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1 Control parameters
8.1.1 Workers
Long-term exposure local effects:
DNEL inhalation = 0.72 mg/m3 BaCO3
(DNEL calculated from the IOEL value of 0.5 mg Ba/m3) General population
Long-term exposure local effects:
DNEL inhalation = 0.14 mg/m3 BaCO3
(DNEL calculated from the IOEL value of 0.5 mg Ba/m3)
8.1.2 Environment
PNEC aquatic (freshwater) = 227.8 mg Ba/L, i.e., 327.3 mg BaCO3/L
PNEC STP = 50.1 mg Ba/L, i.e., 72 mg BaCO3/L
PNEC sediment (freshwater) = 792.7 mg Ba/kg dw, i.e., 1138.9 mg BaCO3/L
PNEC soil = 207.7 mg Ba/kg dw, i.e., 298.4 mg BaCO3/L
PNEC values are derived using the information provided in section 12.

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Guidance on how to comply with these DNELs and PNECs is given in the attached
Exposure Scenarios.
8.2 Exposure controls
Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where
dust is formed. Refer to protective measures listed under Section 7. Apply technical
measures to comply with the occupational exposure limits.
Detailed information on exposure controls, e.g. engineering controls and individual
protection measures is given in the attached exposure scenarios (see Annex).
8.2.1 Appropriate engineering controls
Ensure adequate ventilation. Provide appropriate exhaust ventilation at places
where dust is formed. Refer to protective measures listed under Section 7. Apply
technical measures to comply with the occupational exposure limits.
Detailed information on exposure controls, e.g. engineering controls is given in the
attached exposure scenarios (see Annex).
8.2.2 Individual protection measures, such as personal protective equipment
Detailed information on individual protection measures is given in the attached
Exposure Scenarios in the annex of this SDS.
8.2.3 Environmental exposure controls
Please refer to the Annex - exposure scenarios

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical properties
Appearance

Odour
Odour threshold
pH
Melting point/
freezing point
Initial boiling point/
and boiling range
Flash point
Evaporation rate

:
:
:
:

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:
:
:

solid; white powder at room temperature and


under atmospheric pressure (handbook data)
odourless (handbook data)
not applicable
not applicable
not applicable (decomposes at 1380C at
atmospheric pressure, handbook data)
not applicable (decomposes at 1380C at
atmospheric pressure, handbook data)
not applicable (inorganic solid)
not applicable

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Flammability (solid)

Upper/lower flammability :
or explosive limits
Vapour pressure
:

Vapour density
:
Relative density
:
Solubility(ies)
:
Partition coefficient:
:
n-octanol/water
Auto-ignition temperature :

Decomposition
temperature
Viscosity

Explosive properties

Oxidising properties

non-flammable (anion and cation, both incapable of


further reaction with oxygen)
Non-explosive. barium carbonate exhibits no
chemical groups indicating explosive properties.
not applicable (study does not need to be
conducted for solids with a melting point above
300C (decomposition temperature: 1380 C))
not applicable
4.31 (room temperature, 20 C, handbook data)
14 mg/L (20C, handbook data)
not applicable (inorganic substance)
not applicable (self-ignition is not considered to be
of relevance for this substance, since this would
require heat to be developed either by reaction of
this substance with oxygen or by exothermic
decomposition and which is not lost rapidly enough
to the surroundings)
1380C (handbook data )
not applicable (property of fluids, barium carbonate
is a solid at room temperature (ca. 20C))
not applicable (substance is void of any chemical
structures commonly associated with explosive
properties)
not applicable (substance does not contain
a surplus of oxygen or any structural groups known
to be correlated with a tendency to react
exothermally with combustible material

9.2 Other information


Particle size distribution:
Barium carbonate standard: MMAD 24.22 m GSD 4.87 m
Barium carbonate standard: D50 2.32 m (Laser diffraction)
Barium carbonate fine powder: MMAD 39.93 m GSD 2.28 m
Barium carbonate fine powder: D50 14.6 m (Laser diffraction)
The reason of the high D50 value of barium carbonate fine powder in relation to the
standard powder of barium carbonate is (i) that the measurement was performed
without previous suspension in a solvent (ii) and the substance agglomerates.

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SECTION 10: STABILITY AND REACTIVITY


10.1 Reactivity
Contact with acids liberates CO2.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
When barium carbonate decomposes it forms barium oxide.
10.4 Conditions to avoid
Not applicable
10.5 Incompatible materials
Incompatible with acids
10.6 Hazardous decomposition products
Barium oxide

SECTION 11: TOXICOLOGICAL INFORMATION


11.1 Information on toxicological effects
11.1.1 Substances
The information provided in this section is consistent with the information
provided in the REACH chemical safety report (CSR) for barium carbonate. During
development of the CSR all available toxicological data have been considered and
evaluated for relevance and reliability. Non-reliable data have not been considered
in the assessment.
Toxicity endpoints
Acute toxicity

Description of effects
Barium carbonate is classified as harmful if swallowed.
Oral, rat, gavage (Read-across - barium chloride)
LD50 = 1690 mg/kg bw
Dermal
According to SIAR 2008 an LD50 >1895 mg/kg was stated in
the NIAR report 2008 (based on barium carbonate)

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Inhalation
Based on the technical properties of barium carbonate, the
performance of an acute inhalation toxicity test is neither
technically feasible nor scientifically relevant for this type
of compound.
Skin
Based on available data, the classification criteria for skin
corrosion/irritatio
irritation are not met.
n
(Read-across - barium chloride dihydrate)
Skin irritation: not irritating (in vitro study, EU method B.46,
Reconstructed human epidermis)
Serious eye
Based on available data, the classification criteria for eye
damage/irritation
irritation are not met.
Eye irritation: not irritating (Test material: barium
carbonate; OECD 405, rabbit)
Respiratory or skin
Based on available data, the classification criteria for
sensitisation
sensitisation are not met.
Respiratory sensitisation:
not sensitising
Based on an industry survey, during long-year industrial
practice no cases of hypersensitivity were observed till now
by workers exposed exclusively to bariumcarbonate. Thus,
no classification as respiratory sensitizer according to
regulation (EC) 1272/2008 is required.
Skin sensitisation:
(Read across -barium chloride dihydrate)
not sensitising (OECD 429, LLNA, mouse)
Germ cell
Based on available data, the classification criteria for germ
mutagenicity
cell mutagenicity are not met.
(Read across - barium chloride dihydrate)
(i) Gene mutation (OECD 476, mouse lymphoma cells):
negative
(ii) Bacterial reverse mutation assay (Ames test, OECD 471,
S. Typhimurium): negative
(iii) in vitro mammalian chromosome aberration test (OECD
473, Chinese hamster ovary (CHO)): negative
Based on available data, the classification criteria for
Carcinogenicity
carcinogenicity are not met.
(Read-across- barium chloride dihydrate)
Oral, 104 -105 weeks, rats
There was no evidence of carcinogenic activity.
No classification of the substance as CMR substance is
required.
Reproductive toxicity The decision on classification and labelling will be
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STOTsingle
exposure

postponed till the results from testing


(two-generation study and prenatal developmental study)
are available. As test substance barium chloride will be
used, read across to barium carbonate is envisaged.
NOAEL based on a screening study conducted with barium
chloride dihydrate (oral in drinking water) in rats could be
derived for effect on fertility.
Fertility impairment in female rats: NOAEL of 179.5 mg
Ba2+/kg bw/d; relates to 258 mg
barium carbonate/kg bw/day
Fertility impairment in male rats: NOAEL of 201.5 mg
Ba2+/kg bw/d; relates to 290 mg
barium carbonate/kg bw/day
Developmental toxicity: no NOAEL could be derived.
Based on the available data, the classification criteria for
STOT-single exposure are not met.
Oral
The classification criteria according to regulation (EC)
1272/2008 as specific target organ toxicant (STOT) single
exposure, oral are not met since no reversible or
irreversible adverse health effects were observed
immediately or delayed after exposure
Inhalation
The performance of an acute inhalation toxicity test is
neither technically feasible nor scientifically relevant for
this type of compound. The test material can safely be
assumed to have a very low potential for human inhalation
hazard during handling or application. No effects are
expected at the guidance value, inhalation for a Category 1
classification of 1 mg/L/4h and at the guidance value,
oral for a Category 2 5 mg/L/4h - > 1 mg/L/4h.

STOTrepeated
exposure

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Based on available data, the classification criteria for STOTrepeated exposure are not met.
Oral, rats, oral in drinking water
(Read-across - barium chloride dihydrate)
Average NOAEL: 132 mg/kg bw/day for barium carbonate
Target organs: cardiovascular / haematological: lymph
nodes
urogenital: kidneys
No classification and labelling of barium carbonate
according to regulation (EC) 1272/2008 as specific target
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Aspiration hazards

organ toxicant (STOT) repeated exposure, oral is


necessary, since the guidance value for a Category 1
classification of C<10 mg BaCO3/kg bw/day, and the
guidance value for a Category 2 classification of 10 <C <100
mg BaCO3/kg bw/day are not met
No hazard expected

11.1.2 Mixtures
Not relevant
11.1.3 Information on likely routes of exposure
The primary routes of human exposure to barium are from inhalation of aerosols and
ingestion of food and drinking water containing barium.
11.1.4 Symptoms related to the physical, chemical and toxicological characteristics
Not available
11.1.5 Delayed and immediate effects as well as chronic effects from short and longterm exposure
Not available
11.1.6 Interactive effects
Not available
11.1.7 Absence of specific data
Not available
11.1.8 Mixture versus substance information
Not relevant
11.1.9 Other information
Not available

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SECTION 12: ECOLOGICAL INFORMATION


12.1 Toxicity
Reliable acute aquatic toxicity test results: tests were conducted according to OECDguidelines, using Barium chloride dihydrate as test substance:
Test Organisms
Endpoint
Value
Freshwater fish
>97.5 mg Ba/L
96h-LC50
Danio rerio
(>140.1 mg BaCO3/L)
Invertebrates
14.5 mg Ba/L
48h-EC50
(20.8 mg BaCO3/L)
Daphnia magna
72h-ErC50
Algae
>34.3 mg Ba/L
Pseudokirchneriella
(> 49.3 mg BaCO3/L)
subcapitata
No reliable data for the marine environment were identified

Reference
Egeler and Kiefer,
2010a
Biesinger and
Christensen, 1972
Egeler and Kiefer,
2010b

Reliable chronic toxicity test results: tests were conducted according to OECDguidelines, using Barium chloride dihydrate/barium nitrate as test substance:
Test Organisms
Aquatic toxicity data
Invertebrates/freshwate
r Daphnia magna

Endpoint

Value

21d-NOEC
2.9 mg Ba/L
(reproduction) (4.2 mg BaCO3/L)

Reference
Biesinger and
Christensen,
1972
McDonald et
al, 1988
Egeler and
Kiefer, 2010b

Invertebrates/marine
7d-NOEC
10 mg Ba/L
Cancer anthonii
(14.4 mg BaCO3/L)
Algae
34.3 mg Ba/L
72h-NOEC
Pseudokirchneriella
(growth rate) (49.3 mg BaCO3/L)
subcapitata
No reliable data on toxicity of Ba for fish were identified. PNEC freshwater was
based on the available aquatic toxicity data, and on information on typical and
baseline levels of Ba in the aquatic compartment.
Sediment toxicity data
No reliable acute/chronic sediment data for barium were available. PNEC
derivation was based on the equilibrium partitioning method, taking into account
the PNECfreshwater (see section 8.1.2), the sediment KD given in section 12.4, and
information on typical and baseline levels of Ba in the sediment compartment.
Soil toxicity data
Earthworms
Kuperman et
258 mg Ba/kg dw
Eisenia fetida,
al, 2008
(370.7 mg BaCO3/kg dw)
Enchytraeus crypticus
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Athropods
211 mg Ba/kg dw
Kuperman et
Folsomia candida
(303.1 mg BaCO3/kg dw)
al, 2008
No reliable data on toxicity of Ba for terrestrial plants or soil micro-organisms were
identified. PNEC derivation was based on the equilibrium partitioning method,
taking into account the available terrestrial toxicity data, and information on typical
and baseline levels of Ba in the terrestrial compartment.
Toxicity data for micro-organisms (for STP): test was conducted according to OECDguidelines, using Barium chloride dihydrate as test substance:
Test Organisms
Activated sludge

Endpoint
3hEC50
3h-NOEC
(respiration
inhibition)

Value
500.6 mg Batotal/L
500.6 mg Batotal/L
(719.2 mg BaCO3/L)

Reference
Egeler et al, 2010

For an overview of PNECs for the different compartments check section 8.1.2.
Conclusion on the environmental classification and labelling:
The acute reference value (ARV) for BaCO3 is 20.8 mg/L, based on the ARV for Ba (i.e.,
14.5 mg Ba/L). This acute reference value exceeds solubility of the compound.
Therefore there is no acute classification for this compound. The chronic reference
value is 4.17 mg BaCO3/L, i.e., > 1 mg/L, and therefore no chronic classification is
required. Additionally , there is no evidence for bioaccumulation or biomagnification
in the environment (see section 12.3) Consequently, BaCO 3 has no environmental
classification.
12.2 Persistence and degradability
Abiotic degradation and biodegradation are not relevant for elemental, inorganic
substances like BaCO3.
12.3 Bioaccumulative potential
Aquatic compartment
Absence of bioaccumulative potential:
BCF for fish: 37.6 99 L/ kg wet weight
Terrestrial compartment
No reliable data.

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12.3.1 Secondary poisoning


Based on the available information there is no indication of a bioaccumulation
potential, hence, secondary poisoning is not considered relevant.
12.4. Mobility in soil
Taking in account the relative low KD value for barium, the barium ions release by
barium carbonate are leachable through normal soil and are mobile in sediment. The
following typical log KD-values have been determined for different environmental
compartments:
Compartment
Sediment

KD-value (L/kg)
3,478

Log KD
3.54

Suspended particulate
matter (spm)

5,217

3.72

Soil

60.3

1.78

Reference
Salminen et al. (2005;
FOREGS data)
Estimated data (ratio of 1.5
on
KD, sediment)
Crommentuyn et al. (1997)

The estimated value for spm value is supported by KD values that were reported for
spm by Popp and Laquer (1980) for N-American Rivers (range of Log KD:2.65-3.91)
and the value derived by Li et al (1984) for the River Hudson (log KD: 3.78).
12.5 Results of PBT and vPvB assessment
Not relevant for inorganic substances.
12.6. Other adverse effects
Toxicity to birds: Based on available public literature elevated Ba-levels in eggs may
result in deformations of the feet and malpositioning of the embryo in the egg.

SECTION 13: DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods
Waste from residues / unused products:
In accordance with local and national regulations. Use a solution of sodium or
magnesium sulphate or possibly a dilute solution of sulphuric acid to form a sulphate
precipitate. Can be landfilled, when in compliance with local regulations.

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Packaging treatment: Containers that cannot be cleaned must be treated as waste or


must be incinerated in a suitable incineration plant holding a permit delivered by the
competent authorities.

SECTION 14: TRANSPORT INFORMATION


14.1 UN number
Not regulated
14.2 UN proper shipping name
Not regulated
14.3 Transport hazard class(es)
Not regulated
14.4 Packing group
Not regulated
14.5 Environmental hazards
Not regulated
14.6 Special precautions for user
Not regulated
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not regulated

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SECTION 15: REGULATORY INFORMATION


15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
Regulation EU 1907/2006 (REACH)
Regulation EU 1272/2008 (CLP)
Regulation EU 453/2010
15.2 Chemical safety assessment
A chemical safety assessment has been carried out for the substance.

SECTION 16: OTHER INFORMATION


16.1 Issue/Revision dates
16.2 Version
16.3 Explanation of changes

:
:
:

01/12/2010 21/03/2014 01/06/2015


3
Annex II of Regulation 453/2010 implemented
instead of Annex I

16.4 A key or legend to abbreviations and acronyms used in the safety data sheet
-AF - Assessment factor
-BAF - Bioaccumulation factor
-CLP - Regulation (EC) No 1272/2008 of the European Parliament and of the Council
of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006
-DNEL - Derived no-effect level
-DSD - Council Directive 67/548/EEC (Dangerous Substances Directive)
-EC50 - Concentration of the substance that causes 50 % reduction of a certain effect
on test organisms
-EWC - European Waste Catalogue
-LC50 -Concentration of the substance that causes 50 % mortality of the test
population
-LD50 - Lethal dose of the substance that causes 50 % mortality of the test population
-NOAEL- No observed adverse effect level
-NOEC - No observed effect concentration
-PBT/vPvB - Persistent, bioaccumulative and toxic/ very persistent and very
bioaccumulative
-PEL - Permissible exposure limit
-PNEC - Predicted no-effect concentration
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-REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the


Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation
and Restriction of Chemicals
-STOT - Specific Target Organ Toxicity
16.5. Key literature references and sources for data
Not available
16.6 Indication of which of the methods of evaluating information referred to in
Article 9 of Regulation (EC) No 1272/2008 was used for the purpose of classification
Relevant only for mixtures. Barium carbonate is a substance.
16.7 List of relevant H statements
H302: Harmful if swallowed
16.8 Advice on any training appropriate for workers to ensure protection of human
health and the environment
Not available
16.9 List of telephone numbers of poison centers in the European Economic Area
AUSTRIA (Vienna Wien) +43 1 406 43 43; BELGIUM (Brussels Bruxelles) +32 70 245
245; BULGARIA (Sofia) + 359 2 9154 409; CZECH REPUBLIC (Prague Praha) +420 224
919 293; DENMARK (Copenhagen) 82 12 12 12; ESTONIA (Tallinn) 112; FINLAND
(Helsinki) +358 9 471 977; FRANCE (Paris) +33 1 40 0548 48; GERMANY (Berlin) +49
30 19240; GREECE (Athens Athinai) +30 10 779 3777; HUNGARY (Budapest) 06 80 20
11 99; ICELAND (Reykjavik) +354 525 111, +354 543 2222; IRELAND (Dublin) +353 1
8379964; ITALY (Rome) +39 06 305 4343; LATVIA (Riga) +371 704 2468; LITHUANIA
(Vilnius) +370 5 236 20 52 or +370 687 53378; MALTA (Valletta) 2425 0000;
NETHERLANDS (Bilthoven) +31 30 274 88 88; NORWAY (Oslo) 22 591300; POLAND
(Gdansk) +48 58301 65 16 or +48 58 349 2831; PORTUGAL (Lisbon Lisboa) 808 250
143; ROMANIA (Bucharest) +40 21 3183606 SLOVAKIA (Bratislava) +421 2 54 77 4166;
SLOVENIA (Ljubljana) + 386 41 650 500; SPAIN (Barcelona) +34 93 227 98 33 or +34 93
227 54 00 bleep 190; SWEDEN (Stockholm) 112 or +46 8 33 12 31 (mon-fri 9.0017.00); UNITED KINGDOM (London) 112 or 0845 4647 (NHS Direct).

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16.10 Disclaimer
GLASS SERVICE, a.s. provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is
intended only as a guide to the appropriate precautionary handling of the material by
a properly trained person using this product. Individuals receiving the information
must exercise their independent judgment in determining its appropriateness for
a particular purpose. Furthermore, this safety data sheet (including its Annex) is
made up based on the legal requirements as set by Regulation (EC) 1907/2006
(REACH) based on information as is available per August 1, 2010. Further information
received following the time scale as foreseen by REACH and the guidance policies as
described in the REACH Implementation Programs will be added when it becomes
available.

Issue date: 01/12/2010


Revision date: 01/06/2015

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