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BARIUM CARBONATE
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1 Product identifier
Product name
Chemical name
Index number
EC number
CAS number
REACH Registration number
:
:
:
:
:
:
Barium carbonate
Barium carbonate
056-003-00-2
208-167-3
513-77-9
01-2119489177-25-0016
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Manufacture of barium carbonate
Industrial use of barium carbonate in the manufacture of other barium substances
or formulation of barium
carbonate containing preparations
Industrial use of barium carbonate to remove sulfate (use as reactive processing aid)
Industrial use of barium carbonate in the manufacture of glass, ceramic and electroceramic materials or
glazes, frits and enamels
Industrial use of barium carbonate in welding electrode coating
Industrial use of barium carbonate in the preparation of slurry
Industrial use of barium carbonate in the manufacture of pyrotechnical products
Welding in industrial settings
Professional use of barium carbonate in the manufacture of pyrotechnical products
Welding in professional settings
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Version 3
Please refer to section 16 for a complete list of identified uses for which an
exposure scenario is provided as an annex.
Uses advised against:
Not available
:
:
Monoconstituent substace
BaCO3
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Version 3
Signal word
Warning
Hazard statements
H302 Harmful if swallowed.
Precautionary statements :
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel
unwell.
2.3 Other hazards
PBT :
vPvB :
The substance or mixture does not meet the criteria for PBT or vPvB in
accordance with Annex XIII
The substance or mixture does not meet the criteria for PBT or vPvB in
accordance with Annex XIII
: Barium carbonate
: REACH : 01-2119489177-25-0016
EC slo : 208-167-3
CAS slo : 513-77-9
INDEX : 056-003-00-2
Concentration
: 99 % w/w
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Version 3
3.2 Mixtures
Not relevant, barium carbonate is a substance.
Eyes
Inhalation
Skin
Ingestion
4.2 Most important symptoms and effects, both acute and delayed
Eyes
Inhalation
Skin
Ingestion
:
:
:
:
Not relevant
Not relevant
Not relevant
Barium carbonate is harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
Follow the advises given in section 4.1.
None
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Version 3
6.2 Environmental precautions : Barium carbonate should not be released into the
environment.
6.3. Methods and material for containment and cleaning up
Sweep up and shovel into suitable containers for disposal.
Keep in suitable, closed containers for disposal.
Avoid dust formation.
Please refer to Section 7 on how to store barium carbonate.
6.4 Reference to other sections
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Guidance on how to comply with these DNELs and PNECs is given in the attached
Exposure Scenarios.
8.2 Exposure controls
Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where
dust is formed. Refer to protective measures listed under Section 7. Apply technical
measures to comply with the occupational exposure limits.
Detailed information on exposure controls, e.g. engineering controls and individual
protection measures is given in the attached exposure scenarios (see Annex).
8.2.1 Appropriate engineering controls
Ensure adequate ventilation. Provide appropriate exhaust ventilation at places
where dust is formed. Refer to protective measures listed under Section 7. Apply
technical measures to comply with the occupational exposure limits.
Detailed information on exposure controls, e.g. engineering controls is given in the
attached exposure scenarios (see Annex).
8.2.2 Individual protection measures, such as personal protective equipment
Detailed information on individual protection measures is given in the attached
Exposure Scenarios in the annex of this SDS.
8.2.3 Environmental exposure controls
Please refer to the Annex - exposure scenarios
Odour
Odour threshold
pH
Melting point/
freezing point
Initial boiling point/
and boiling range
Flash point
Evaporation rate
:
:
:
:
:
:
:
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Flammability (solid)
Upper/lower flammability :
or explosive limits
Vapour pressure
:
Vapour density
:
Relative density
:
Solubility(ies)
:
Partition coefficient:
:
n-octanol/water
Auto-ignition temperature :
Decomposition
temperature
Viscosity
Explosive properties
Oxidising properties
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Version 3
Description of effects
Barium carbonate is classified as harmful if swallowed.
Oral, rat, gavage (Read-across - barium chloride)
LD50 = 1690 mg/kg bw
Dermal
According to SIAR 2008 an LD50 >1895 mg/kg was stated in
the NIAR report 2008 (based on barium carbonate)
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Inhalation
Based on the technical properties of barium carbonate, the
performance of an acute inhalation toxicity test is neither
technically feasible nor scientifically relevant for this type
of compound.
Skin
Based on available data, the classification criteria for skin
corrosion/irritatio
irritation are not met.
n
(Read-across - barium chloride dihydrate)
Skin irritation: not irritating (in vitro study, EU method B.46,
Reconstructed human epidermis)
Serious eye
Based on available data, the classification criteria for eye
damage/irritation
irritation are not met.
Eye irritation: not irritating (Test material: barium
carbonate; OECD 405, rabbit)
Respiratory or skin
Based on available data, the classification criteria for
sensitisation
sensitisation are not met.
Respiratory sensitisation:
not sensitising
Based on an industry survey, during long-year industrial
practice no cases of hypersensitivity were observed till now
by workers exposed exclusively to bariumcarbonate. Thus,
no classification as respiratory sensitizer according to
regulation (EC) 1272/2008 is required.
Skin sensitisation:
(Read across -barium chloride dihydrate)
not sensitising (OECD 429, LLNA, mouse)
Germ cell
Based on available data, the classification criteria for germ
mutagenicity
cell mutagenicity are not met.
(Read across - barium chloride dihydrate)
(i) Gene mutation (OECD 476, mouse lymphoma cells):
negative
(ii) Bacterial reverse mutation assay (Ames test, OECD 471,
S. Typhimurium): negative
(iii) in vitro mammalian chromosome aberration test (OECD
473, Chinese hamster ovary (CHO)): negative
Based on available data, the classification criteria for
Carcinogenicity
carcinogenicity are not met.
(Read-across- barium chloride dihydrate)
Oral, 104 -105 weeks, rats
There was no evidence of carcinogenic activity.
No classification of the substance as CMR substance is
required.
Reproductive toxicity The decision on classification and labelling will be
Issue date: 01/12/2010
Revision date: 01/06/2015
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STOTsingle
exposure
STOTrepeated
exposure
Based on available data, the classification criteria for STOTrepeated exposure are not met.
Oral, rats, oral in drinking water
(Read-across - barium chloride dihydrate)
Average NOAEL: 132 mg/kg bw/day for barium carbonate
Target organs: cardiovascular / haematological: lymph
nodes
urogenital: kidneys
No classification and labelling of barium carbonate
according to regulation (EC) 1272/2008 as specific target
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Aspiration hazards
11.1.2 Mixtures
Not relevant
11.1.3 Information on likely routes of exposure
The primary routes of human exposure to barium are from inhalation of aerosols and
ingestion of food and drinking water containing barium.
11.1.4 Symptoms related to the physical, chemical and toxicological characteristics
Not available
11.1.5 Delayed and immediate effects as well as chronic effects from short and longterm exposure
Not available
11.1.6 Interactive effects
Not available
11.1.7 Absence of specific data
Not available
11.1.8 Mixture versus substance information
Not relevant
11.1.9 Other information
Not available
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Reference
Egeler and Kiefer,
2010a
Biesinger and
Christensen, 1972
Egeler and Kiefer,
2010b
Reliable chronic toxicity test results: tests were conducted according to OECDguidelines, using Barium chloride dihydrate/barium nitrate as test substance:
Test Organisms
Aquatic toxicity data
Invertebrates/freshwate
r Daphnia magna
Endpoint
Value
21d-NOEC
2.9 mg Ba/L
(reproduction) (4.2 mg BaCO3/L)
Reference
Biesinger and
Christensen,
1972
McDonald et
al, 1988
Egeler and
Kiefer, 2010b
Invertebrates/marine
7d-NOEC
10 mg Ba/L
Cancer anthonii
(14.4 mg BaCO3/L)
Algae
34.3 mg Ba/L
72h-NOEC
Pseudokirchneriella
(growth rate) (49.3 mg BaCO3/L)
subcapitata
No reliable data on toxicity of Ba for fish were identified. PNEC freshwater was
based on the available aquatic toxicity data, and on information on typical and
baseline levels of Ba in the aquatic compartment.
Sediment toxicity data
No reliable acute/chronic sediment data for barium were available. PNEC
derivation was based on the equilibrium partitioning method, taking into account
the PNECfreshwater (see section 8.1.2), the sediment KD given in section 12.4, and
information on typical and baseline levels of Ba in the sediment compartment.
Soil toxicity data
Earthworms
Kuperman et
258 mg Ba/kg dw
Eisenia fetida,
al, 2008
(370.7 mg BaCO3/kg dw)
Enchytraeus crypticus
Issue date: 01/12/2010
Revision date: 01/06/2015
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Athropods
211 mg Ba/kg dw
Kuperman et
Folsomia candida
(303.1 mg BaCO3/kg dw)
al, 2008
No reliable data on toxicity of Ba for terrestrial plants or soil micro-organisms were
identified. PNEC derivation was based on the equilibrium partitioning method,
taking into account the available terrestrial toxicity data, and information on typical
and baseline levels of Ba in the terrestrial compartment.
Toxicity data for micro-organisms (for STP): test was conducted according to OECDguidelines, using Barium chloride dihydrate as test substance:
Test Organisms
Activated sludge
Endpoint
3hEC50
3h-NOEC
(respiration
inhibition)
Value
500.6 mg Batotal/L
500.6 mg Batotal/L
(719.2 mg BaCO3/L)
Reference
Egeler et al, 2010
For an overview of PNECs for the different compartments check section 8.1.2.
Conclusion on the environmental classification and labelling:
The acute reference value (ARV) for BaCO3 is 20.8 mg/L, based on the ARV for Ba (i.e.,
14.5 mg Ba/L). This acute reference value exceeds solubility of the compound.
Therefore there is no acute classification for this compound. The chronic reference
value is 4.17 mg BaCO3/L, i.e., > 1 mg/L, and therefore no chronic classification is
required. Additionally , there is no evidence for bioaccumulation or biomagnification
in the environment (see section 12.3) Consequently, BaCO 3 has no environmental
classification.
12.2 Persistence and degradability
Abiotic degradation and biodegradation are not relevant for elemental, inorganic
substances like BaCO3.
12.3 Bioaccumulative potential
Aquatic compartment
Absence of bioaccumulative potential:
BCF for fish: 37.6 99 L/ kg wet weight
Terrestrial compartment
No reliable data.
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KD-value (L/kg)
3,478
Log KD
3.54
Suspended particulate
matter (spm)
5,217
3.72
Soil
60.3
1.78
Reference
Salminen et al. (2005;
FOREGS data)
Estimated data (ratio of 1.5
on
KD, sediment)
Crommentuyn et al. (1997)
The estimated value for spm value is supported by KD values that were reported for
spm by Popp and Laquer (1980) for N-American Rivers (range of Log KD:2.65-3.91)
and the value derived by Li et al (1984) for the River Hudson (log KD: 3.78).
12.5 Results of PBT and vPvB assessment
Not relevant for inorganic substances.
12.6. Other adverse effects
Toxicity to birds: Based on available public literature elevated Ba-levels in eggs may
result in deformations of the feet and malpositioning of the embryo in the egg.
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:
:
16.4 A key or legend to abbreviations and acronyms used in the safety data sheet
-AF - Assessment factor
-BAF - Bioaccumulation factor
-CLP - Regulation (EC) No 1272/2008 of the European Parliament and of the Council
of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006
-DNEL - Derived no-effect level
-DSD - Council Directive 67/548/EEC (Dangerous Substances Directive)
-EC50 - Concentration of the substance that causes 50 % reduction of a certain effect
on test organisms
-EWC - European Waste Catalogue
-LC50 -Concentration of the substance that causes 50 % mortality of the test
population
-LD50 - Lethal dose of the substance that causes 50 % mortality of the test population
-NOAEL- No observed adverse effect level
-NOEC - No observed effect concentration
-PBT/vPvB - Persistent, bioaccumulative and toxic/ very persistent and very
bioaccumulative
-PEL - Permissible exposure limit
-PNEC - Predicted no-effect concentration
Issue date: 01/12/2010
Revision date: 01/06/2015
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16.10 Disclaimer
GLASS SERVICE, a.s. provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is
intended only as a guide to the appropriate precautionary handling of the material by
a properly trained person using this product. Individuals receiving the information
must exercise their independent judgment in determining its appropriateness for
a particular purpose. Furthermore, this safety data sheet (including its Annex) is
made up based on the legal requirements as set by Regulation (EC) 1907/2006
(REACH) based on information as is available per August 1, 2010. Further information
received following the time scale as foreseen by REACH and the guidance policies as
described in the REACH Implementation Programs will be added when it becomes
available.
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