Figura2: Sistema tpico de remocin de humedad del gas
natural usando absorcin a base de glicol.
En los sistemas de adsorcin generales, el gel de slice:
Puede manejar fcilmente una amplia gama de velocidades de flujo de alimentacin y amplias variaciones. Tiene un alto rango de caudales.
Se adapta fcilmente a los cambio de condiciones de operacin
Ofrece disponibilidad instantnea (despus del primer ciclo todava ofrece gas acondicionado segn las especificaciones. Son fciles de operar y tienen poco mantenimiento (se puede controlar a distancia). No consume energa durante la operacin en reposo. Tienen relativamente pequea demanda de energa durante la regeneracin (71 000 Btu frente a 102000 Btu en esta comparacin de adsorcin de slica gel frente a absorcin de TEG).
Water in Liquid Form
Whereas water vapor is easily adsorbed by silica adsorbents, the presence of water droplets in natural gas streams poses additional problems. For instance, water droplets create a hydraulic hammer effect, and lead to localized overheating, which causes the adsorbent materials to break down. This leads to higher pressure drop and channeling-reducing the overall performance of the unit. In addition to the use of an inlet separator to maximize water-droplet removal, a guard layer (equal to about 10-20% of bed volume) of specialized, water-stable adsorbent can be added on top of the main adsorbent bed. This water stability can be imparted using tempering, i.e. heating to high temperatures over a long time, however, this process reduces greatly water adsorption capacity. Water stable Sorbead adsorbents are produced according to precision manufacturing procedure, without resorting to tempering having full liquid water stability and high capacity. This often allows for smaller vessels and longer lifetimes of the main bed. Use of water stable Sorbead as a guard bed is common in such applications such as LNG units, where the main adsorbent isnt even a silica gel, but a molecular sieve. REMOVING HEAVY HYDROCARBONS FROM NATURAL GAS Heavy hydrocarbons, which can condense out of a natural gas stream, are another common cause of plugging in gas-transmission pipelines and valves, and they can foul related equipment such as gas-separation membranes. Such constituents are typically described in terms of the hydrocarbons and water vapor from natural gas. The design of as silicabased system for heavy hydrocarbon removal is more complicated than that of a system for the removal of water only. For instance, different grades of silica gel may be required. The system must be designed to accommodate the adsorption of more than one component. And much shorter cycle times (as short as 45-60 minutes) are typically required, as are often three or more adsorption vessels instead of two (further discussion of this is beyond the scope of this article; for more information, consult your adsorbent supplier). Several non-absorption related technologies including low-temperature separation (LTS), turbo expansion, and mechanical refrigeration are also used to remove heavy hydrocarbons from natural gas streams (additional discussion of these technologies can be found in Reference). Today, silicabead adsorption offers a cost-effective alternative to these approaches. REMOVING NITROGEN FRM NATURAL GAS In addition to water vapor and heavy hydrocarbons, natural gas streams also contain unwanted nitrogen. Nitrogen is inert, so its presence depresses
the fuel value of natural gas; as such, it is typically removed to residual
levels around 4%.
This typical cost comparison of the moisture-removal processes shown in
figures 1 and 2 (the use of adsorption via silica gel beads, versus absorption using TEGG), shows that the TEG-based method is generally only cost-effective at relatively small flowrates in this case.
Depicted is a typical adsorption cycle for the removal of heavy
hydrocarbons from natrual gas.
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