Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Saurabh Priyadarshi
M.Sc. (Geology), MMEAI, MGMI, QCI
Chief Geologist
IPL.
spgetsmail@gmail.com
________________________________________________________________________________
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KP/COAL/004/16 August2012
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Abstract
Coal is generally analysed to determine its physical, chemical, thermal, mechanical properties like size consist,
proximate values, ultimate values, calorific value and HGI.
Calorific Value (CV) is an important thermal property of coal which indicates the amount of heat energy that
could be liberated on combustion of a specific quantity. The other important thermal properties of coal are
plastic, agglutinating and agglomerating indices. These analyses enable determination of suitable end use
industry like metallurgical, thermal or cement.
This knowledge piece is a scientific compendium ranging from energy or calorie entrapment in coal to its
variation with rank, definition and determination of CV, units of expression and interunit conversion of CV,
understanding effect of analyses bases of CV , role of CV in evolution of coal grading system ,impact of
moisture on CV and impact of CV on coal quantity required for power generation and cost.
Key Words: Coal, Calorific Value, Rank, kcal/kg, UHV, GCV, AR, AD GCV, UHV, Calorimeters.
_________________________________________________________________________________
1. Energy Entrapment.
Coal originates from plant debris buried some
280-350 millions years ago in swamps. The
contemporaneous solar energy irradiated the
plants causing photosynthesis which promoted
cellular entrapment of energy in form of carbon,
hydrogen, nitrogen and oxygen.
content, hardness
descending order.
and
Calorific
Each coal
composition.
has
specific
type
value
in
chemical
Lignite,
Sub-bituminous,
Bituminous and
Anthracite.
4. Determination of CV
Each of the above coal type has a specific
degree of coalification / rank, maturity, carbon
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4.1.3. Why
GCV/HHV?
Plant
4.1.2. Difference
UHV/LHV/NCV
between
of CV
Laboratory.
than
less
4.1.1. Procedure.
Objective of Test
UHV/LHV/NCV
Because
Test
Facility
is
Expression of Heat
(CV/Heat Units )
(i)
GCV/HHV
5. Expression of CV.
NCV/LHV/UHV
GCV/HHV
and
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KP/COAL/004/16 August2012
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System
Eg:
Unit
Acronym
f-p-s
Btu/lb
2.
MKS
MJ/kg
3.
MKS
kcal/kg
4.
MKS
kJ/kg
kcal/kg
MJ/kg
0.004187
kcal/kg
MJ/kg
1.8
kJ/kg
4.187
kcal/kg
238.8
Btu/lb
429.9
kcal/kg
Braces
MJ/kg
Btu/lb
MAF
By Factor
Btu/lb
DB
MF
To
AD
From
AR
Superscripts:
0.5556
Btu/lb
MJ/kg
0.002326
kJ/kg
Kcal/kg
kJ/kg
.23884
GCV
(Kcal/kg)
NCV
(Kcal/kg)
Equation:
GCV=NCV+53H
(ii)
Where H = % of hydrogen
present in the coal sample
including hydrogen of
moisture and of water of
constitution.
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Quality
Average quality
4
5
Key Consumers
Key Parameter
monitored by
Consumers
Derivation 1
Derivation 2
Study Observations
Approximately 85% of coal came
from underground and rest from
open cast mines.
Qualities of Underground coals were
superior.
Ash%=:20-25; Moisture%=2-5; GCV
(kcal/kg) = 5000-5550.
Railways(steam locomotives)
Loss of heat by steam engines
through ash in coal.
The constant 8900 came from the
highest dmmf CV of coking coals of
Jharia coalfield.
The factor 138 comes from low
moisture and ash level.
SN
1
in
(iii)
SN
Characteristics
Drift origin.
(iv)
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KP/COAL/004/16 August2012
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Coalfield
Weighted
NB: India continued with the UHV system even after the GOI instituted two
major studies well up to December 2011.
Average
9. UHV System Coal Grading System in India.
Moist%
Ash%
Ash+Moist%
GCV
60%RH
60%RH
60%RH
kcal/kg
UHV
kcal/kg
Min Max Avg Min Max Avg Min Max Avg Min Max Avg
WCL
1.5
9.1 5.3 18.9 60.8 39.9 27.4 65.7 46.6 2104 5379 3742 167 5119 2476
SECL
2.2
9.1 5.7 15.0 43.2 29.1 21.0 50.0 35.5 3555 6345 4950 2000 6002 4001
NCL
5.2
10 7.6 17.4 42.4 29.9 24.6 48.0 36.3 3541 5545 4543 2276 5505 3891
MCL
2.5
8.3 5.4 30.0 52.8 41.4 34.8 57.8 46.3 2585 4460 3523
CCL
0.8
8.4 4.6 23.5 46.5 35.0 27.1 52.0 39.6 3280 5635 4458 1724 5160 3442
SCCL
4.5
8.9 6.7 17.1 46.5 31.8 24.9 41.6 33.3 3311 5681 4496 1779 5464 3622
A
B
6000
5000
4950
4543
3742
4001
2476
3622
SECL
NCL
874.5
WCL
1015.5
2152
1370.5
3442
652.5
1000
3523
3891
949
2000
4496
4458
3000
1265.5
kcal/kg
4000
MCL
CCL
SCCL
CoalMines
Intra Mine Diff between GCV and UHV(kcal/kg)
Exceeding 5600
but not
exceeding 6200
Exceeding 4940
but not
exceeding 5600
Exceeding 4200
but not
exceeding 4940
Exceeding 3360
but not
exceeding 4200
Exceeding 2400
but not
exceeding 3360
Exceeding 1300
but not
exceeding 2400
Corresponding
Ash%
+
Moisture %
at (60% RH &
O
40 C)
Not exceeding
19.5
19.6 to 23.8
23.9 to 28.6
28.7 to 34.0
34.1 to 40.0
40.1 to 47.0
47.1 to 55.0
Gross
Calorific
Value GCV (Kcal/
Kg)
(at 5% moisture
level)
Exceeding 6454
Exceeding 6049
but not exceeding
6454
Exceeding 5597
but not
exceeding. 6049
Exceeding 5089
but not Exceeding
5597
Exceeding 4324
but not exceeding
5089
Exceeding 3865
but not
exceeding. 4324
Exceeding 3113
but not exceeding
3865
NB: 1.Coal from Assam, Arunachal Pradesh, Meghalaya, and Nagaland are
not graded. 2. Coking coal used for steel industry grade-I (ash<15%) and
grade-II (ash 15-18%).3. Further classification for semi-coking, weakly coking
coal is done on ash %age and UHV.
10. Conversion
Under UHV system UHV-GCV- NCV can be
converted from one to another using the
following equations:
Useful
Heat
Value (UHV)
(Kcal/Kg)
UHV=
8900138(A+M)
Exceeding 6200
(v)
(vi)
(vii)
(viii)
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Table 9: Differences.
SN
1
Grade
2.1
2.2
2.3
Kcal/kg
GCV( Min)
GCV(Max)
G1
7000
G2
6701
7000
G3
6401
6700
G4
6101
6400
G5
5801
6100
G6
5501
5800
G7
5201
5500
G8
4901
5200
G9
4601
4900
10
G10
4301
4600
11
G11
4001
4300
12
G12
3700
4000
13
G13
3400
3700
14
G14
3101
3400
15
G15
2801
3100
16
G16
2501
2800
17
G17
2201
2500
the
are
the
the
UHV Regime
The figure 8900 in the
formula {UHV= 8900 138(A+M)}
came
from
highest dmmf CV of coking
coals of Jharia coalfield
only.
Coal quality presumably
consistent.
Ash%:
20-25
Moisture%:
2-5
GCV(kcal/kg):
50005550
Figure 138 in the formula
{UHV= 8900 - 138(A+M)}
applicable to low range of
moisture and ash.
Coal primarily consumed
by
steam
engine
of
railways-one of the most
inefficient steam generation
equipment.
UHV determined indirectly
by deducting ash and
moisture.
UHV employed in India
only for coal grading.
>20-45
6-11
35005000
Weightage factor of 138 is
not applicable to present
day high range of moisture
and ash.
Coal consumed by modern
industries which use more
efficient stoker fired system.
Due
to
narrow
GCV
bandwidth
consumers can chose coals of desired
grade and not end up paying for a coal in
large grade band.
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Rs/MT
Grade
7000.00
GCV(New ) Min
GCV(New ) Max
6000.00
UHV(Old) Max
UHV(Old) Min
kcal/kg
5000.00
GCV(Old) Min
GCV(Old) Max
4000.00
3000.00
2000.00
1000.00
0.00
G1
G2
G3
G4
G5
G6
G7
G8
Total Moisture(TM) %
Inherent Moisture (%)
Surface Moisture (%)
Calorific Value
GCV(kcal/kg)
Remarks
Point of
Release
(PoR)
12.0
2.0
10.0
4000
1. TM and
GCV are
determined
in lab.
2. TM and
GCV are
reported
on
AR
basis.
Point of Consumption
(PoC)
8.0
2.0
6.0
PoC
{(100-TM )/(100-TM
PoR
PoR
}*GCV
(ix)
={(100-8)/(10012)}*4000
=4181.81
1. TM and GCV are
determined in lab.
Coal is spread out and
air dried to remove
Surface Moisture.
2. GCV is determined
by
applying
Total
Moisture
Correction
and reported on AD
basis.
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cost
per
unit
of
10765/20000=.538 kg /hr
electricity
(xii)
(xiv)
15. Conclusion
This KP is a one stop shop for all those who wish to
know and those who need to specifics of mineral
exploration, mine planning, geology, quality control
and HSE. The present article is yet another
contribution to the KYC (KYC (KNOW YOUR COAL)
series.
Efficiency of 38%.
(x)
_______________________________________
References.
1. IKA Working of Bomb Calorimeter.
2. Properties of Coal.
3. Coal Conversion facts.
4. Coal Initiative Report.
5. CFRI Diamond Jubilee Conference.
6.2nd Ver. Coal Price 2012.
7. Tables and Graphs.
8. Revised Coal Price.
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KP/COAL/004/16 August2012
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Expression
CV
Calorific Value
HGI
1g
one gram
oC
percent
GCV
HHV
NCV
LHV
UHV
(f-p-s
foot-pound-second
MKS
Btu
MJ
Mega Joule
Lb
pound
Kg
kilogram
kJ
kilo Joule
SI
System Internationale
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