Max Marks:360

KEY SHEET

Physics :
1) 1

2)

3)

4)

5)

6)

7)

11) 1

12) 1

13) 1

14) 1

15) 1

16) 2

17) 3

21) 2

22) 2

23) 3

24) 1

25) 3

26) 4

8)

9)

10) 4

18) 4

19) 2

20) 1

27) 2

28) 3

29) 3

30) 3

Chemistry :
31)1

32)3

33)3

34)2

35)2

36)3

37)1

38)1

39)2

40)1

41)2

42)4

43)1

44)3

45)3

46)1

47)4

48)4

49)2

50)3

51)1

52)1

53)2

54)3

55)1

56)2

57)3

58)1

59)4

60)2

32) 3

33) 1

34) 2

35) 1

36) 4

37) 2

38) 2

39) 2

40) 3

41) 2

42) 2

43) 2

44) 2

45) 4

46) 3

47) 3

48) 1

49) 2

50) 4

51) 2

52) 1

53) 1

54) 2

55) 2

56) 1

57) 1

58) 3

59) 1

60) 4

ps

31) 3

.i

Mathematics :

te

SOLUTIONS
Conceptual
c

ud

1.
2.

ys

PHYSICS:

107
3 108
1
f =
;
l =
2p = 60p
= 107 ;
2p
107
LC
2 (8.5 - 0.8)g
2 (2.5 - 0.8)g
v0 = r 2
; v0 = r 2
; = 17/77
g
h
g
h

4.

5.

ww
w

3.

.s
t

w=

B
is dimensionless
kT
[B] = [kT]
Also
[I] = [AT2]
[A] = [IT2]
[AB2] = [IK2]
Process AB and CD are isothermal
V

W = nRT ln f

Vi

Dotted lines are isochoric lines as they pass through origin

V
f is same for both process
Vi

WAB = nRT1 ln f

Vi

WCD = nRT2 ln f

Vi
So, T1/T2 = 2
6.

7.

8.
9.

4
10- 7
= r = x 2 0.5 10- 10
2
x 2 = 103 n = 31
R

Rt
R
T YA t YA
250N
R

2 Conceptual
1

[ Q = (mTh - mRa - ma ) c 2 = 5.49MeV ]

10.

4 Conceptual
11.
3 Conceptual

By COM we can say that both the fragments have same linear momentum

.i

12.

ps

ww
w

.s
t

ud

15.

te

14.

ys

13.

k
m
A
P2
1
we have k =
k when P is same 1 = 2 = 2
2m
m
k2 m1
A1
Charge conservation is violated in [2, 3, 4] ; nucleon conservation is violated in (4), (1) is correct
1.5 - 0.6
1
R=
= 150
6 10- 3
angular momentum
J
=
=
where mR 2 is the moment of inertia of the ring
2
2
mR
mR
magnetic moment of loop
r
Q 2 Q
r
2
n

m= nIA = (1) w
R = 2 wR

2p
( n is normal to plane outward
)
r r r
Q
1 Q
Q J
Torque t = m B
=
= R 2 2
wR 2 B (up the plane)
B =

(J) (B)

2
2 m
2 mR
1
= 105 7.5 104 0.1= 3.75 1010 N upward along the plane
2
Pressure of gas inside the balloon is same as the pressure of surrounding. Also gas inside the balloon
obeys isothermal process, then
(P0 + gh) V1 = P0V2

16.

17.

V2 = (1 +

103 10 40
) 0.09 = 0.45 m3
5
10

l
l 1 ml 2
mg sin 300 +
w2 ;
=
2
2 2 3
18.

19.

Qgain = Qcost
10 80 = 50 m 1
800 = 50 + m
800
m=
= 16 gm
50
2 Conceptual

w = 3 10rod / s

20. longest Emin

for Balmer longest is for n = 2 3
for Lyman longest is for n = 1 2

21.
22.

23.

Conceptual
Force of buoyancy FB = A[x0 + (L x)w]g
Weight W = LAsg
For equilibrium FB = W
LAsg = A[x0 + (L x)w]g
Ls = x0 + (L x) w
x
x r - r s 1000 - 800 2
s = (0 w) + w
= w
=
=
L
L r w - r 0 1000 - 300 7
1(main scale)
1(main scale)
Least count =
; 0.1 mn =
N
20
1 Main scale division = 2mm
Since area vector rotates in xy plane, therefore flux is due to by only.
At any instant
(t) = r2 By cos t
|Eind| = r2 By sin t
k (2Q) kQ
Field will be uniform at the outside and, E =
=
(4a ) 2 8a 2

26.

I maximum 100 104 A 0.01A

ps

25.

.i

24.

longest Balmer > longest Lyman

te

V I g G R

ys

10 0.01100 R
R 900

.s
t

ud

27.

ww
w

The Boolean expression of the given circuit X = A.B

= A+ B
(Using De morgan theorem )
=A+B
(Using Boolean identity)
This is same as the Boolean expression of OR gate.
Alternative method
The truth table of the given circuit is as shown is the table
A
B
A
B

0
0
0
1
1
0
1
1
This is same as that of OR gate .
28.
Conceptual
29.
Conceptual
30.
Conceptual

31.

1
1
0
0

1
0
1
0

Chemistry

A.B

X = A.B

1
0
0
0

0
1
1
1

CH3
|

CH2
C
CH2
CH2 C

H C
H2

H
|
O

CH 3
|

CH 2 C CH 2
CH 2
CH

CH 2

O H

CH 3
|

CH 2 C CH 2
CH 2
CH

n
ud

CH3
OH

-H+

.i
ys

CH2OH

ps

CH3
O
H H

CH3

te

CH2OH

CH2OH

SN

CH 2

.s
t

32. Conceptual
33. Conceptual

34. p nitrophenol (III) > phenol (I) > p cresol (II).

O2
35. SiC 4 NaOH
Na2 SiO3 Na2CO3 2 H 2O
36. Conceptual

ww
w

37.

O
O

Cl

Br Mg
Cl

THF

1 mole

Mg Br

Cl

O M gBr

H
O
Cl

OH

38. Conceptual
39. Conceptual

40. - NO2 is a meta directing group. As it is also a deactivating group so no chance of

introduction of second Br atom.
41

CH 2 O CH 2 CH 3
2 NaH B2 H 6
2 NaB2 H 4

42. Conceptual

43. A is CH3 CHO, which then undergo aldol condensation to give compound B.
O
||

OH
|

.CH 3 C H
CH 2CHO
CH
CCH 2CHO

3
NaOH

|
H

|
H

44. Conceptual
X 1A
100 1
45.
=

1
1- X A 200 4
8 x1 A = 1- x1A
1
x1A =
9
1
8
Pm = 100 + 200 = 188.8 Torr
9
9

46. As same charges are present at nearest position (less stable)

CuSO4 4 NH 3 Cu NH 3 4 SO4

.i

47.

2B

K1 1

K2 2

ys

Where

te

K1

K2

ps

48.

2C

0.5 2 0.5 2

1
3

.s
t

Finally 0.5 2 1.5

ud

A 2 B 2C
2
0
0

0.5 1 2 3.5

50. Conceptual

51. Conceptual
52. 3 cis & 3 trans isomers
H

ww
w

49. Conjugate base is week conjugate acid strong

Cl

C C

i)

C C
CH 3

CH 3

ii)

Cl

CH 3

iv)
53. Conceptual

54. For isobaric process

Cl

Cl

iii)
H
C

CH 3

ii

C2 H 3

C C
CH 2 Cl

CH 3

H
C2 H 3

C2 H 5

S nCP log

T2
T1

55.
NaNO2 /HCl

0
5
C

NH2

56.
57.
58.
59.

N 2Cl

Conceptual

Conceptual
Condensation polymerization
Conceptual

60. Conceptual

Mathematics
61.

R(b c) a bc

.i
ps

0 b c sin A 1

te

.s
t

ud

A 900 and b = c
Hence, triangle is right isosceles
Since
and
are unit vectors and equally inclined to each other.
is are equilateral triangle and

ww
w

62.

b c

ys

2R sin A bc
bc
sin A
2 bc
Now sin A 1
bc

1
2 bc

Area of the base

If

is the centroid of the

then

is a right angled triangle and

Volume of the tetrahedron

Let

64.

Let

be the required angle, then

ps

.i

63.

of the line of the common perpendicular (or SD) to the

te

be the

ys

two given lines. Then, we have

or

Also,

ww
w

of SD are

.s
t

ud

solving, these, we get

and

is a point on first line and

is a point on second line, then

and two lines are said to be skew lines or non

intersecting lines if they do not lie in the same plane.
65.

66.

10 3 2 4
s1 s2 s3 4

No. of non negative integral solutions of s1 s2 s3 4 is 4 3 1 c31 6c2

67.

A-event that sum 5 occurs, B-sum 7 occurs

,probability that neither a sum 5 or 7 occur

Probability of equal number of W and L is

f x kx c

ys

69.

te

ps

.i

68.

ud

f 0 1 c 1

.s
t

f ' x k 1

1 x
1 1 x 2 dx
1

70.
71.

72.

ww
w

f x 1 x

1
1

1 1 x 2 dx 20 1 x 2 dx 2

1 1

1 2

2 1 2

1 2

1 1 5
2

Let equation of variable circles is x 1 y 1 x 2 y 3 0 equation of common

chord of variable circle and given circle is
S S 1 0 x 2 y 3 1 6 x 0 common chords always pass though point of
intersection of 1 6x = 0 & x + 2y 3 = 0.
Let the numbers be 1,2,3,4,....., n and the erased number be x then 1 x n
2

n n 1
x
7
2
35
Now,
n 1
17

n n 1
n n 1
n
1
7
2
2

35
n 1
17
n 1
n
7 n2
35
2
17
2
n
7 n2
35
2
17
2
14
n 70 n 2
17
n 69 or 70

69 x 70
x
7
2
at n = 69 ;
35 x 7
68
17
at n = 70 ;
xI

We have to de- arrange 5 objects to 6 places

No. of ways = 44 44 4 9 9 32 2 2 1 1
= 256
x2 y2

1
9
4
x cos y sin
Equation of Tangent,

1 --------- (1)
3
2
2 1 cos
2 1 cos
T 3,
at x 3 y

sin
sin

Let P be the point on ellipse

ud

2 1 cos
2 1 cos

T 1 3,

sin
sin

.s
t

at x 3 y

ys

te

ps

74.

.i

73.

ww
w

T1

x 3

P
T

x3

Circle with TT 1 as diameter, x 2 y 2 x1 x2 K y1 y2 y x1 x2 y1 y2 0

x 2 y 2 5 y 0

It passes through 5, 0
75.

Let Tr 1 20Cr .x 20 r 2 y kx a y b
r

TS 1 20Cs .x 20 s 2 y kx a 1 y b 1
s

For given condition rs=1

and 20C1 s .21 s 20Cs .2 s S 13
r=14 a=6

76.

a,b,c are in.G.P b 2 ac

ax 2 2bx c 0 can be written as

ax c

c
It is common root
a

c
in given equation
a

Subsitute x
77.

Let ABCD be the given rectangle

and EFGH be the required reactangle
A = area of EFGH
b sin a cos a sin b cos

78.

1 2
1
a b 2 sin 2 ab a 2 b 2
2
2

ab

g x x 24 . 1 x x 2 . 6 x 5 5 x 4 4 x 3 dx
6

x 4 x5 x 6 . 6 x 5 5 x 4 4 x 3 dx

.i

Put t x 6 x5 x 4
t7
t dt C
7
6

x5 x 4
7

g 1 3

ys

But it passes through (0,0) C 0

7

80.

Let f x x3 3x 1

x
and y = sinx. By using this graph Find the no. of solutions
100

ud

Draw the graphs, y

.s
t

79.

Then f 1 x 3 x 2 1

Let f 1 x 0 x 1 and f(1) f(1) < 0

Conceptual
f(x) is symmetric about y = x

ww
w

81.
82.

te

ps

Required area = 2x f x x dx
0

0
3
= 2 2 2 2

= 2 sin xd sin x dx

83.

2
1
2
1

x
dy

dx
y

Tangent equation is x12 x y12 y x13 y13

x12 x y12 y a 3

Since, it passes through x2 , y2

x12 x2 y12 y2 a 3

and

x13 y13

a3

1
2

K 3

x23 y23

a3

By solving (1), (2), (3) we get result

84.

eia + eib = (cos a + i sin a )+ (cos b + i sin b )= eig

Let a = eia , b = eib , c = eig then a + b = c . Also

ab = c 2 e

i 2g )

sin (a + b )= sin 2g .

The given expression is the coefficient of x4 in

4

86.

= e(

C0 (1 + x)404 4C1 (1 + x)303 + 4C2 (1 + x)202 4C3 (1 + x)101 + 4C4

i.e.

in [(1 + x)101 1]4

i.e.

in (101C1x + 101C2 x2 + .. + 101C101 x101)4 = (101)4

option (B) is correct.

R = {(x, y ): x 2 - 4 xy + 3 y 2 = 0, x, y N }

85.

i(a + b )

1 1 1
+ = .
a b c

ps

.i

Let x N , x 2 - 4.x.x + 3x 2 = 0
\ (x, x ) R \ R is reflexive .

we have (3) - 4(3)(1)+ 3(1) = 9 - 12 + 3 = 0 or (3,1) R

2

Also 12 - 4(1)(3)+ 3(3) = 1- 12 + 27 0 .

ys

\ (1,3) R , \ R is not symmetric.

Again (9,3) R because

92 - 4(9)(3)+ 3(3) = 108 - 108 = 0 .

ud

te

and (3,1) R because (3) - 4(3)(1)+ 3(1) = 12 - 12 = 0

2

.s
t

and (9,1) R if 92 - 4(9)(1)+ 3(1) = 0

if 84-36=0 which is not possible.
\ (9,3),(3,1) R and (9,1) R \ R is not transitive .
\ Relation R is reflexive but neither symmetric nor transitive.
As lines are perpendicular to each other C moves on a circle with AB as diameter.
Now P, mid-point of AB (which is fixed) when joined with C is median.

87.

ww
w

Centroid is moving at a constant distance

Locus is a circle

1
PA from P.
3

6 1
A is point of intersection of x + 4y + 2 = 0 and x y + 1 = 0 i.e., ,
5 5
9 6
B is point of intersection of 4x y + 6 = 0 and x + y + 3 = 0 i.e., ,
5
5

 3 7
P , therefore locus is
2 10

3
7 17

x y
2
10
50

Let n be even , f x as x .
88.
Let C 3 2i be the centre of the circle z 3 2i 4 . Join the origin to C and let it meet the circle
in A and B ( see figure).
B
3
O

2
C
A

.i

Least value of z OB
CB OC

te

ps

4 32 22
4 13
Maximum value of z OA 4 13

ud

.s
t

90.

The inverse of p : q is : p q the contra positive of : p q is : q p .

[Contra positive of p q is : q : p ]
Give that , mean = 21 and median = 22 .
we know, mod e = 3median - 2mean .
mod e = 3 (22)- 2 (21) = 66 - 42 = 24

ww
w

89.

ys

The absolute difference between the maximum and minimum values of z is 2 13