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CH1020

Practice Problems 1

CH1020 Practice Problems 1


(Pressure measurements, ideal gas law)
1. How would a gas differ from a liquid with respect to each of the following
properties:
a. density
b. compressibility
c. ability to mix with other substances of the same phase to form homogeneous
mixtures?

2. A. Both a liquid and a gas are moved to larger containers. How does their
behavior differ? Explain the difference on molecular terms. B. Although water
and carbon tetrachloride, CCl4(l), do not mix, their vapors form homogeneous
mixtures. Explain. C. The densities of gases are generally reported in units of
g/L, whereas those for liquids are reported as g/mL. Explain the molecular basis
for this difference.

3. Consider two people of the same mass standing in a room. One person is standing
normally, and the other is standing on one foot. A. Does one person exert a
greater force on the floor than the other? B. Does one person exert a greater
pressure on the floor than the other?

4. Rationalize the following observations:


a. Aerosol cans will explode if heated
b. You can drink through a soda straw
c. A thin-walled can will collapse when the air inside is removed by a vacuum
pump
d. Manufacturers produce different types of tennis balls for high and low
elevations.
5. Explain why the height of mercury is independent of the diameter of the mercury
column.
6. How high in meters must a column of water be to exert a pressure equal to that of
a 760 mm column of mercury?
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CH1020

Practice Problems 1

7. A gauge on a compressed gas cylinder reads 2200 psi (pounds per square inch; 1
atm = 14.7 psi). Express this pressure in each of the following units?
a. atmospheres
b. megapascals (Mpa)
c. torr

8. If the atmospheric pressure is 0.975 atm, what is the pressure of the enclosed gas
in each of the following cases:

h = 52 cm

h = 67 mm

h = 10.3 cm

9. A balloon is filled to a volume of 7.00 x 102 mL at a temperature of 20.0oC. The


balloon is then cooled at constant pressure to a temperature of 1.00 x 102 K. What
is the final volume of the balloon?

10. Complete the following table for an ideal gas


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CH1020

Practice Problems 1

P(atm)
7.74 x 103Pa

V(L)
12.2 mL

n(mol)
_______

T
25oC

__________

43.0 mL

0.421 mol

223 K

455 torr

_______

4.4 x 10-2 mol

331oC

745 mm Hg

11.2 L

0.401 mol

_____

11. A person accidentally swallows a drop of liquid oxygen, O2(l), which has a
density of 1.149 g/mL. Assuming the drop has a volume of 0.050 mL, what
volume of gas will be produced in the persons stomach at body temperature
(37oC) and a pressure of 1.0 atm?

12. A bicycle tire is filled with air to a pressure of 100.psi at a temperature of 19oC.
Riding the bike on asphalt on a hot day increases the temperature of the tire to
58oC. The volume of the tire increases by 4.0%. What is the new pressure in the
bicycle tire?

13. A container is filled with an ideal gas to a pressure of 40.0 atm at 0oC.
a. What will be the pressure in the container if it is heated to 45oC?
b. At what temperature would the pressure be 1.50 x 102 atm?
c. At what temperature would the pressure be 25.0 atm?

14. A compressed gas cylinder contains 1.00 x 103 g of argon gas. The pressure
inside the cylinder is 2050. psi (pounds per square inch) at a temperature of 18oC.
How much gas remains in the cylinder if the pressure is decreased to 650.psi at a
temperature of 26oC?

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