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KIMIA
8.10- 8.16
Raymendo Sinaga
(14/364772/PA/16059)
Alaika Rizazuam
(14/365016/PA/16078)
Swasti Nilam N
(14/365602/PA/16103)
Herbi Yuliantoro
(14/365603/PA/16104)
Anggun Setya P
(14/365612/PA/16105)
Krisfian Tata
(14/365615/PA/16106)
Pratyangga Surya Dyaninggar
(14/365626/PA/16110)
Rosy Amalia Kurnia P
(14/365630/PA/16113)
Aqidatul Izza
(14/365632/PA/16115)
Hamid Rohma S
(14/365633/PA/16116)
Mawaddah Rimala
(14/367629/PA/16281)
1
CARNOT CYCLE
WITH AN IDEAL
GAS
If an ideal gas is used as the
working substance in a Carnot
engine, the application of first
law to each step can be written
as
table.
Step General
Case
1
U
1=Q1-W1
2
U2=-W2
Ideal gas
0=Q1-RT1 ln
(v2/v1)
U3=Q1-W3
U4=-W4
0=Q2-RT2 ln
(V4/V3)
=
Rayme
ndo
Sinaga
2
=
=
ln
(
)-
them. Hence
W= RT1 ln ( )
) - RT2 ln (
Raymendo
Sinaga
Alaika Rizazuam
Alaika Rizazuam
Equation (8.21)
shows
that
the
total
work
produced
depends on the difference in
temperature between the two
reservoirs [compare to Eq. (8. 1
8)] and the volume ratio V2/V1
(the compression ratio). The
efficiency is a function only of
the
two temperatures [compare to
Eq. (8. 1 9)] . It is apparent
from
Eq.
(8.22)
that
if
the
efficiency is to be unity,
either
the
cold
reservoir must be at T2 = 0 or
the hot reservoir must have T1
equal
to
infinity.
Neither
Alaika Rizazuam
THE CARNOT
REFRIGERATOR
A refrigerator is a heat
engine operated in
reverse,
more or
less
Swasti Nilam N
Swasti Nilam N
Swasti Nilam N
Heat
Pump
Aqidatul Izza
10
h
p
S
i
n
c
e
hp
Aqidatul Izza
11
Heat
Engine
Menerima heat/panas
dari source bertemperature
tinggi
Mengubah sebagian panas ini
menjadi kerja/work
Melepaskan sisa panas ke
sink bertemperature rendah
Beroperasi pada suatu siklus
12
I
t
i
s
i
m
p
o
s
s
i
b
l
e
f
o
r
a
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h
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c
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.
K
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v
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P
l
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t
a
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T
h
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i
c
s
:
13
Thermal Efficiency
Thermal efficiency (t) adalah
fraksi dari total heat input
(Qin) yang dikonversi menjadi
kerja output (Wnet,out)
W
net,out
=
tQin
h
Untuk closed
system : Wnet,out =
Qin - Qout
(kJ)
14
Atau:
=1
Q
L
Q
out
th
Qin
t QH
h
QL = heat transfer dari heat
engine ke reservoir temperature
rendah
QH = heat transfer dari reservoir
temperature tinggi ke heat
engine
15
DEFINITION
OF ENTROPHY
The second law of thermodynamics
leads to the definition of a state
property of the system, the
entropy. It is characteristic of a
state property that the sum of the
changes of that property in a cycle
is zero.
The second law defines some new
property whose changes sum to zero
in
a cycle
Anggun
Setya P
16
dan
=
"
"
!
S
o
:
+!
=0
"
!
Anggun Setya P
"
(8.27
)
=0
17
"
I ! =0,
f
The quantity is the
differential of some property
of state. This
property is called the
entropy of the system and is
given the
symbol S :
dS "&'(
Anggun Setya P
18
GENERAL
PROOF
We have shown that
has a
cyclic integral equal to
zero only for cycles that
involve only two
temperatures. The
result can be generalized to
any cycle. Consider a Carnot
engine.
Then in a cycle
KRISFIAN TATA A P
KRISFIAN TATA A P
KRISFIAN TATA A P
KRISFIAN TATA A P
and
KRISFIAN TATA A P
We
have
to
find
numbers
(temperatures) such that by dividing
each term in Eq. (8.37) by a proper
number we can obtain a sum in
which
the
positive
terms
predominate.
24
d
0
Q
(8.39)
'
T
We distinguish two cases :
Case I. The
d
engine E' is
<
Q
reversible.
'
If
we
assume
that
for E
d
Q >0
'
T
25
system
d
Qr =0
ev
cycles)
(all rerversible
(8.40)
(8.41)
26
d
0
Q<
cycles).
T
(all irreversible
(8.
42)
Rosy
Amali
a
Kurni
aP
27
Hamid Rohma S
28
Hamid Rohma S
29
Mawaddah Rimala
30
=
=
*1
(*11
2
=
*2)
1
*1
Untuk mesin
pendingin carnot
*
2
*
2
entropi
=
,="&'(
,=
perubahan
= 1
(*
1
+
*2
)
=
2
*-.
31
Tanya
jawab
Fauzy : heat pump,
menggunakan usaha
untuk
memndahkan kalor.
Semakin dikit usha
efisiensi
meningkat, apakah
dapat Heat engine,
sebagian kalor dialirkan
ke resevoir rendah,
terjadi secara siklus,
bagaimana?
Dewanti: calusius,
sistem terislasi mencapai
kesetimbangan dan
entropi maksimum,
syaratnya
apa?
Jolang: refrigerator,
reaitasnya refrigerator
ake
gas freon, fungsinya
apa? Pas habis,
pendinginannya
berubah, mengapa?
32