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Name: A.N.M.Ashrafuzzaman.
Roll: 200306040
Group: A2
Partners Roll: 200306045
Department: EEE
Objective:
The objective of this experiment is to determine the
strength of Commercial Hydrochloric acid by using
standard Sodium Hydroxide solution .As Sodium Hydroxide
is itself a secondary standard substance, not a primary
standard substances so it should be standardized by the
standard Oxalic-acid solution.
Theory:
The strength determination of both commercial
Hydrochloric acid and NaOH is done by means of presence
of a suitable indicator, a chemical substance that detects the
end point of a reaction by changing its color, the volumetric
analysis in which a standard solution is added in another
solution to reach its end point and to determine the
strength of that solution is called titration.
The reaction between NaOH and Oxalic acid is
COONa + 2H2O
Phenolphthalein
And the reaction between HCl and NaOH is NaOH + HCl > NaCl + H2O
Indicator Methyl
Orange
Apparatus:
1. Conical flask, 2. Burette, 3. Pipette,
4. Volumetric flask, 5. Stand, 6. Funnel
Chemical Reagents:
1. Standardized NaOH solution
2. HCl solution
3. Distilled water
4. Oxalic Acid
5. Phenolphthalein
6. Methyl Orange
Experimental Data:
Standardization of
Oxalic Acid solution
NaOH
solution
Burette
reading
in ml
Numb Volum
er of
e of
Obser- NaOH
in
Initial
vation
ml
Readi
ng
01
02
03
10
10
10
0.3
10.4
20.1
Final
Readi
ng
10.4
20.1
29.9
Volume
of
Acid
in
ml
10.1
9.7
9.8
with
standard
Avera
ge
Readi
ng
in
ml
Streng
th
Of
NaOH
N
9.867
0.0986
7
Burette
reading
in ml
Volume
of
Avera
ge
Streng
th
Obser- Volum
e of
Initial
vation NaOH Readi
in
ng
ml
01
02
03
10
10
10
Acid
in
ml
Final
Readi
ng
1.9
21.3
5.9
21.3
40.6
24.9
19.4
19.3
19.0
Readi
ng
in
ml
Of
HCl
N
19.233
0.0513
acid
X S
acid
= V
base
X S
base
concentrated
XS
concentrated
=V
dilute
Here,
V HCl(concentrated) = 2.1 ml
S HCl(concentrated) = ?
V HCl(dilute)
= 100 ml
S HCl(dilute)
= 0.0513 N
so, S HCl(concentrated) = ( 100 X 0.0513 ) / 2.4
= 2.1376 N
XS
dilute
Percentage of error:
Percentage of error
= (known value observed value) X 100 known
value
= ( 4.5 - 4.2752 ) X 100 / 4.5
= 4.995%
so, Percentage of error = 4.995%
Discussion:
The following causes can be assumed for the possible cause
of error.
1)
2)