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Solution
d
In the lecture notes it was shown that dt
hri = hpi
m . Here we will proceed in an
analogous manner. First we note that
Z
d
d
hpx i =
px dV
dt
dt
Z
px + px
dV
=
t
t
Z
2
= i~
dV,
(1.1)
t x
xt
where the integral is taken over all space. The time evolution of a wave function
is governed by the Schr
odinger equation. That is say,
~2 2
+ V = i~
.
2m
t
(1.2)
~2 2
+ V = i~
2m
t
(1.3)
Therefore
and
~2 2 V
+
+V
= i~
.
2m
x
x
x
xt
As we substitute Eqs. (1.3) and (1.4) into Eq. (1.1), we obtain
d
hpx i
dt
Z "
=
=
=
(1.4)
!
!#
~2 2
~2 2
V
+V
+
V
dV
2m
x
2m
x
x
x
Z
Z
2
~2
2
V
dV
dV
2m
x
x
x
2 Z
~
2
V
2
dV
.
(1.5)
2m
x
x
x
Now we have to show that the first term at the last line vanishes. For that
purpose, we state the identities
=
+ 2
,
(1.6)
x
x
x
=
+
.
(1.7)
x
x
x
By employing these identities and the divergence theorem, we obtain
Z
Z
2
dV =
dV
x
x
x
x
Z
(1.8)
dA.
=
x
x
If this surface integral vanishes, our result is proved.
Z a
un (x)T un (x) dx,
=
0
where the last equality follows from the fact that un (x) vanishes if x
/ (0, a).
On the other hand, if x (0, a),
!
r
2
~2 2
n
T un (x) =
sin
x
2m x2
a
a
r
n
~2 n2 2 2
sin
x
=
2m a2
a
a
~2 n2 2
un (x).
(2.3)
=
2m a2
Thus
hun |T |un i =
~2 n2 2
2m a2
(2.4)
We recall that we have normalized the functions un (x) (cf. lecture notes). Thus
the integral at the right-hand side is equal to unity. It immediately follows that
hun |T |un i =
n 2 2 ~2
.
2ma2
(2.5)
un (x)V
(2.6)
The second integral vanishes because V (x) = 0 when x (0, a). However, both
the first and the last integral are undefined because the integrands are undefined
(the integrands are of the form 0). However, when we consider the infinite
potential well as a limiting case of the finite potential well, we obtain the result
that there is no contribution to the expectation value of potential energy from
the outside of the well 1 . Therefore we set the first and the last integral equal
to zero. We obtain the result that the expectation value of potential energy
vanishes. That is,
hun |V |un i = 0.
(2.7)
1 You may want to return to this point after the finite potential well has been discussed in
the lectures.
3. An Eigenvalue Problem
Let us consider the eigenvalue equation
d2
A = 2 ,
dx
= u,
Au
r2
i ,
i .
(3.3)
= C1 er1 x + C2 er2 x
= C1 ei x + C2 ei x
= C1 cos x + i sin x + C2 cos x i sin x
= A cos x + B sin x.
(3.4)
Let us next consider the solutions we obtain for certain values of A and B.
A = 0 and B = 0
We obtain the zero function, which is not considered to be an eigenfunction.
A C arbitrary and B = 0
For the resulting eigenfunctions u(x) = A cos x the boundary conditions read
(3.5)
cos a = 0.
This implies that
+ n
2
2
2
(1 + 2n) .
4a2
(3.6)
A = 0 and B C arbitrary
For the resulting eigenfunctions u(x) = B sin x the boundary conditions read
(3.7)
sin a = 0.
This implies that
= n
2 2
n .
a2
(3.8)
A 6= 0 and B 6= 0
It is only a minor task to show that the eigenvalues must now be of the form
(3.6) and of the form (3.8). Therefore we have to find out whether there are
n1 , n2 {1, 2, 3, } satisfying
2
2 2
2
(1
+
2n
)
=
n
1
4a2
a2 2
1 + 2n1 = 2n2 .
(3.9)
We see that the left-hand side is odd for all n1 , whereas the right-hand side is
even for all n2 . Therefore there are no eigenvalues that are of the form (3.6)
and of the form (3.8).
Summary
The eigenvalues n and the corresponding eigenfunctions un :
n
n
=
=
2
4a22 (1 +
2
a2 n :
2n) :
un (x) =
un (x) =
A cos n x,
B sin n x.
SII = SII
+ SII
.
(4.2)
When the energy of the particle is greater than the step height, there is no
probability flow towards the negative x-axis inside the step. On the other hand,
when the energy of the particle is smaller than the step height, there is no probability flow to either direction deep inside the step (near the surface the flows
to opposite directions cancel out resulting in a zero net flow). To summarize,
in both cases deep inside the step
+
SII = SII
.
(4.3)
II = N |SI |,
+
+
III
= N |SII
|,
(4.5)
where N is the density of the incoming particles and the probability current
densities are measured far away from the step (at the so called asymptotical
regions mentioned in the lecture notes).
The conservation of probability reads
SI = SII .
(4.6)
Now
R+T
+
II
III
+
II+
II+
+
N |SI | N |SII
|
+
N |SI+ |
N |SI+ |
SI + SII
,
SI+
(4.7)
+
where the last equality holds because we consider SII
to be measured deep inside
the step [cf. Eq. (4.3)]. By using the conservation of probability [Eq. (4.6)], we
obtain
R+T
=
=
SI + SI+ + SI
SI+
1.
(4.8)
i
r
2m(V0 E)
.
~2
(5.2)
(5.3)
(5.5)
c) Here we indeed assume that the particle is inside the potential step. Thus
the wave function associated with the particle is uII (x) = 2 cos ehx ei . As
always, it has to be normalized before calculating expectation values. The
normalization factor
Z
N =
|uII (x)|2 dx
0
Z
= 4 cos2
e2hx dx
0
2 cos2
.
h
(5.6)
Now
hxi =
=
1
N
Z 0
2h
xe2hx dx
=
=
1
2hs
~2
1
.
2 2m(V0 E)
(5.7)
d)
= eikx + Beikx ,
hx
= Ce
(5.8)
(5.9)
2k
ik(1 B) = hC
C = k+ih
10
k ih
k + ih
= e2i .
=
(5.11)
(5.12)
Now we see that the phase difference between the incoming and the scattered
wave is 2.
e) First we note that the wave function can not be normalized (due to its
form outside the step). Outside the step the probability density
(x)
= |uI (x)|2
=
eikx + eikx2i
eikx + eikx2i
2 (1 + cos(2kx + 2))
4 cos2 (kx + ) .
11
(5.13)