Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Classes Taught:
z
z
Paper recycling
Utilization of forest/agricultural materials for new applications
Process Control
Unit Operations for Pulp and Paper
Paper Recycling (Distance)
Ultrasonic deinking
Supercritical carbon dioxide to extract wax from OCC
Course Outline
The Paper Recycling US Industry
z Contaminants
z Effect of Recycling on Fibers/Paper
z Unit Operations
z
Pulping,
Course Activities
z
z
z
z
Course Objectives
Broad understanding of paper
recycling science and technology
z Develop an expertise in a selected
research topic in paper recycling
z
Learning objectives
Understand
the industry
Identify the major grades of recovered fiber
Identify the major types of contaminants in
recovered fiber
Source: RISI
Source: RISI
Source: RISI
Source: RISI
Source: RISI
z
z
Supply1
(000
tons)
Recover
ed (000
tons)
Recover
y Rate2
1993
91,538
35,460
38.70%
1994
95,718
39,691
41.50%
1995
95,971
42,189
44.00%
1996
94,529
43,076
45.60%
1997
99,557
43,989
44.20%
1998
101,183
45,076
44.60%
1999
105,316
46,818
44.50%
2000
102,810
47,311
46.00%
2001
97,395
46,996
48.30%
2002
98,949
47,645
48.20%
2003
98,016
49,255
50.30%
2004
101,882
50,287
49.40%
2005
99,618
51,272
51.50%
2006
100,198
53,488
53.40%
Paper
Recovered
(000 tons)
Paper
Landfilled
(000 tons)
1993
35,460
38,399
1994
39,691
38,118
1995
42,189
36,118
1996
43,076
34,331
1997
43,989
37,174
1998
45,077
38,329
1999
46,818
41,255
2000
47,311
39,568
2001
46,996
35,894
2002
47,645
37,601
2003
49,255
36,032
2004
50,287
39,107
2005
51,272
36,846
2006
53,488
35,660
Pkging Material
Recovered, 2006
Paper
Glass
Metal
Plastic
Other
Total
22.9
2.8
2.2
1.3
1.3
30.5
(000,000 tons)
Exports
Imports
16
Millions of Tons
14
12
10
8
6
4
2
0
1990
1992
1994
1996
1998
2000
2002
2004
Year
2006
Mixed Paper
Super Mixed Paper
Boxboard Cuttings
Mill Wrappers
News
Special News
Special News De-ink Quality
Over-Issue News]
Magazines
Corrugated Containers
Double Sorted Corrugated
New Double-Lined Kraft Corrugated Cuttings
Used Brown Kraft
Mixed Kraft Cuttings
Carrier Stock
New Colored Kraft
Grocery Bag Scrap
Kraft Multi-Wall Bag Scrap
New Brown Kraft Envelope Cuttings
Mixed Groundwood Shavings
Telephone Directories
White Blank News
Groundwood Computer Printout
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
z
Publication Blanks
Flyleaf Shavings
Coated Soft White Shavings
Hard White Shavings
Hard White Envelope Cuttings
New Colored Envelope Cuttings
Semi Bleached Cuttings
Manila Tabulating Cards
Sorted Office Paper
Sorted Colored Ledger
Manifold Colored Ledger
Sorted White Ledger
Manifold White Ledger
Computer Printout
Coated Book Stock
Coated Groundwood Sections
Printed Bleached Board Cuttings
Misprinted Bleached Board
Unprinted Bleached Board
#1 Bleached Cup Stock
#2 Printed Bleached Cup Stock
Unprinted Bleached Plate Stock
Printed Bleached Stock
Definitions
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Outthrow:
Prohibitive Material:
Prohibitive Materials
Total Outhrows may not exceed
None Permitted
of 1%
Grade-Year
At
mills
Molded Prod
OCC-1993
OCC-2006
ONP-1990
ONP-2006
13.5
20.0
3.8
5.5
2.3/0
5.2/0
0.9/0.7
2.5/1.5
Total
Total
Recov Supply
RR%
15.9
25.2
5.5
9.6
59.1
76.4
35.0
72.3
26.9
33.0
15.9
13.2
Mixed-1993
5.3
Mixed-2006
12.7
49
Pulp Sub-1993
3.3
100
Pulp Sub-2006
2.4
100
HG DI-1993
3.7
100
HG DI-2006
3.6
100
Source: AF&PA, 2006 Recovered
Paper Annual Statistics
7.0 million
4.2 million
3.5 million
1.6 million
Ctn Bd
NP
Packg
Ind Cvt
Paper Bd
Tissue
Export
Other
Total
15,153
0
398
3,946
167
5,218
303
25,185
(000 tons)
Ctn Bd
RecPBd
Tissue
News
P&W
Other
Export
Total
1
1,172
698
3,213
353
1,615
2,513
9,565
(000 tons)
Newsprint
Tissue
P&W
Other
Export
Total
380
2,680
1,200
1,000
7,300
15,690
(000 tons)
105
85
71
19
28
104
266
370
ScrapIndex.com
350
ONP
OCC
300
$/ton
Mixed Paper
250
200
150
100
50
0
1970
1975
1980
1985
1990
Year
1995
2000
2005
Cost of DIP
z
System
Quantity
Unit
Unit Cost, $
Contribution,
$/ton
1.5
ton
220
330
NaOH
0.024
ton
400
9.6
Peroxide
0.024
ton
600
14.4
Sodium Silicate
0.022
ton
500
11.0
0.0027
ton
1000
2.7
0.00115
ton
1200
1.4
Clarifier Flocculant
0.00014
ton
1600
0.2
Clarifier Bentonite
0.00085
ton
1600
1.4
Electricity
310
kWhr
0.045
14.0
0.25
mton
1.5
1.236
m3
0.53
0.7
Waste Disposal
0.984
mton
36
35.4
4.8
m3
0.53
2.5
Fiber
Flotation Aid
Process Water
Total Variable Prod. Cost
424.8
$ Per Year
$ / ton
Maintenance
4,000,000
57
Labor
2,000,000
29
Operating Materials
1,700,000
24
Depreciation (7 yr
straight line)
6,000,000
86
Business Overhead
1,100,000
16
211
636
44,532,716
600
Income, $/yr
42,000,000
-2,532,716
Taxes (25%)
Profit after taxes, $
ROI (%)
-399,537
-2,133,179
-1
Of the about 100 million tons of paper consumed in the US, ___ % is recycled
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Common Contaminants in
Waste Paper
Large Junk
Component
Particle Size
(microns)
End Products
Simple Letter
Press
Pigment +
Mineral Oil
Absorption
into Web
Weak
1-15
Penetration of
Vehicle into
Web + Resin
Oxidation
Soft Film
2-30
Letterpress
Early
Newsprint
Newsprint,
Books
Solvent
Evaporation
Hard Film
2-250
Amine
Absorption,
Evaporation
UV
Photopolymeri
zation
Heat set or
Other
Water
Resistant Film
N/A
Non swelling,
Non saponif.
Hard Film
Hard,
Coherent
Films
50-100
Rotogravure
Flexographic
UV Cured
Specialty
Pigment
+Hard Resin &
Solvent
Pigment +
Resin & Water
Emulsification
Pigment
+Monomer
Various
Pgiments and
Rosins
Hard Film
40+
We Offset,
Letter Press
Magazines,
Catalogues
Newsprint
inserts,
Corrugated
High Speed
Coated
Papers
Xerography
Laser Printers
Electronic
Forms
Stickies
z
z
z
Coatings as a Contaminant
z
Fillers as a Contaminant
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Common fillers:
clay
CaCO3
TiO2
Fillers
Papermaking Additives
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z
Contaminant Removal
Learning objectives
Understand
less
fiber conformability
less absorptive
loss of hemicellulose
z
Decreased cleanliness
Hornification: Irreversible
A
B
C
D
Hornification: Irreversible
Never Dried
Fiber
Rewetting
Fiber Swollen
With Water
Dried Collapsed
Fiber - Hornified
have the ability to swell with water which makes the fibers flexible
can be mechanically treated (refining) to increase the flexibility
The flexible never dried fibers are able to conform in the paper
sheet which increases the fiber bonded area making strong
paper
When dried, the fibers become rigid, termed hornification
Flexible Fibers
Stiff fibers
1st Use
80 %
70 %
60 %
20%
30%
40%
2nd Use
3rd Use
z
z
z
z
10
9
8
7
6
5
4
2
1
0
0
Number of Recycles
Learning objectives
Identify
Contaminates vary by
z
z
size
density
shape
surface properties
solubility
strength
Pulping
Cleaning
Screening
Deinking
Washing
Flotation
z
z
z
z
In the next section, we will take a look at the suboperations in an OCC recycling process
The process has the following operations:
Pulping
High Density Cleaning
Screening
Forward Cleaning
Through Flow Cleaning
Thickening
Dispersion
Water Clarification
Pulping
Main Function : Disperse recovered paper into separated fibers.
solids wt
=%K
solids wt + liquid wt
z
z
z
z
z
z
z
Forces in a Pulper
z
Mechanical Forces
These are caused when
the fast moving rotor
impacts material in the
relatively slower body of
pulp stock around it.
Faster rotor speeds
cause more intense
mechanical forces in the
pulper.
Pulper Forces
z
z
Hydraulic Forces :
These are caused by the
motion of fluid that is caused by
the spinning rotor (not by the
direct impact of the rotors).
When two adjacent portions of
a fluid are moving in different
directions ( or at different
speeds) a shear force is
present. An example in the
picture would be at point A.
Forces in a Pulper
z
Attrition
Consistency from 3 -6 %.
Low profile rotor that
rotates at high speeds.
Motion of rotor causes a
vortex of pulp stock. The
baffles are used to
improve mixing.
High mechanical force due
to impacts of rotor can
damage fiber and break
contaminants.
Typically 8-18 %.
High profile rotor used. The
helical screw type rotor is
needed to pull down the
non-fluid like high % K
stock, from the top to the
bottom of the pulper.
At the high % K, fiber-fiber
(solid-solid) rubbing
dominates the forces
experienced in the pulper.
z
z
z
z
z
wood
wet-strength paper
plastics
baling wire
nails and bolts
z
z
Pulper conveyor
Pulper
Junker Claw
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z
Heavy
rejects
Accepts
Drum Pulping
z
z
z
A continuos, high
consistency pulping method.
Most often used for pulping
old newsprint.
Consists of an inclined
rotating drum 11 -17 rpm
through which the paper/
pulp travel down. The drum
is very large approximately
10 feet high and 100 feet
long.
High % K
Zone
Screening
Zone
Rejects
Conveyor
Accept
Pulp
Drum Pulping
Two Zones
z
High Consistency pulping zone
z
Low consistency pulping zone.
High Consistency Pulping Zone
z
Paper ,water and chemicals
added to ^ 15% K.
z
Baffles on the walls of the drum
lift the paper and drop causing
defibering in a gentle manner.
Low Consistency Screening zone
z
Water is added to dilute stock 34% K.
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Pulped fibers pass through 6
mm holes and are accepted
from the pulper.
z
Large rejects continue through
the pulper and are4 discharged
at the end.
Drum Pulping
Two Zones
High Consistency pulping zone
Low consistency pulping zone.
High Consistency Pulping Zone
Paper ,water and chemicals added to ^ 15% K.
Baffles on the walls of the drum lift the paper and drop causing
defibering in a gentle manner.
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Overview
Rejects
Drum Pulping
Paper Feed
Advantages
Gentle pulping
keeps contaminants
large and minimizes
fiber degradation.
Simple operation
that includes
screening.
Disadvantages
High capital cost.
Not an aggressive
pulping method
(example: cannot
pulp wet strength
papers).
z
z
z
rejects exit
Pulping Summary
z
z
z
Light weight
Rejects
Detrasher
Heavy
Rejects out
the back
Feed
Accepts
Top View
Deflakers
Screening
z
Screening separates
contaminants based
mainly on size, but
also on shape and
deformability
Performed by
presenting a barrier
for large
contaminants (slots
or holes) that allow
fibers to pass through
Screening
Modes of Removal
1.
2.
Rejection Probability, %
100%
0%
1
Screen
Rotor
Openings, circumference
mm
speed,m/s
Consistency Range
MC
<6%
Disk
MC
<4.5%
Hole
2-3
20-30
Cylindrical
Hole
0.8-1.5
10-30
Yes
Cylindrical
Slot
0.1-0.4
10-30
Yes
LC
<1.5%
Yes
Yes
Screening
z
Types of perforations
coarse holes .110 in or 2.7 mm
fine holes
.060 in or 1.52 mm
coarse slots
.010 in or .254 mm
fine slots
.006 in or .152 mm
Pressure screen
Screen Plates
Holes
Slots
Contoured
Screening Factors
Stock characteristics
Screen design
Operating variables
Screening
Screen Layout:
Always have cascaded screens to save fiber.
Primary Screen
Accepts
Secondary Screen
Tertiary Screen
Rejects
Cleaning
Centrifugal Cleaning
Remove impurities from the pulp stream
z Centrifugal cleaners remove
z
metals
inks
sand
bark
dirt
etc.,
Centrifugal Cleaning
z
Principles of operation
z
z
z
z
Consistency
HC cleaner: 2-4.5% K, MC: 1-2, LC: 0.5-1.5
Centrifugal Acceleration (acceleration due to gravity =9.8 m/s2)
HC cleaner: <60 g, MC: <100g, LC: <1000 g
Reject Rate by mass/stage
HC cleaner: 0.1-1% , MC: 0.1-1, LC: 3-30
Accepts Header
Feed Header
Rejects Header
Forward Cleaners
Cleaners
z
Canister
Cleaners Pump
ACCEPTS
FEED
Primary
Cleaners
Secondary
Cleaners
Dilution Water
Tertiary
Cleaners
Dilution Water
REJECTS
Effective
Separation
Separation Ratio:
m(in) m(acc) / m(in)
Equal
Distribution
Rejects
Accepts
Thru-flow cleaners
Stock Characteristics
fiber type
contaminant characteristics (size, shape, density),
dirt level
Cleaner Design
Cleanliness
Efficiency
Sensitivity to
Variable
Incr/Decr
Incr/Decr
Decrease
Decrease
Decrease
Increase
Increase
Decrease
High
Medium
High
High
Medium
Low
Medium
Medium
Fundamentals
Force balance on a single particle in a hydrocyclone
axial
Fd
Fd
Fc
Fg
radial
Radial direction:
Net centrifugal force Drag force
Axial direction:
Fundamentals
z
Fc (or Fg)
Assume the time for particle to reach
its terminal velocity is very brief
dU s
= Fc (or Fg ) Fd
m
dt
0
= Fc (or Fg ) Fd
Fc (or Fg ) = Fd
velocity of particle
Drag force
ut2
ut2
1
2
l
p
V p = lU s Ap Cd
2
r
r
ut2 V p p l
Us = 2
r Ap l
Cd
Cd = drag coefficient
r = radial position
Vp = volume of particle
Fundamentals
Why is the slip velocity important ?
Cd
For high Us
Us
ut2 V p p l
Us = 2
r Ap l
Reject stream
For low Us
Us
Accept stream
Cleaner Summary
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z
z
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