Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
7-31
January 2012
Page 1 of 48
Table of Contents
Page
1.0 SCOPE ................................................................................................................................................... 3
1.1 Changes .......................................................................................................................................... 3
2.0 LOSS PREVENTION RECOMMENDATIONS ....................................................................................... 3
2.1 Introduction ...................................................................................................................................... 3
2.1.1 Aerosol Hazard Classification ............................................................................................... 3
2.2 Construction and Location ............................................................................................................... 4
2.3 Occupancy ....................................................................................................................................... 6
2.4 Protection ......................................................................................................................................... 6
2.4.1 General .................................................................................................................................. 6
2.4.2 Warehouses ........................................................................................................................... 7
2.4.3 Small Quantities of Storage ................................................................................................ 14
2.4.4 Mercantile Locations ........................................................................................................... 14
2.4.5 Shipping/Receiving Areas ................................................................................................... 15
3.0 SUPPORT FOR RECOMMENDATIONS ............................................................................................. 15
3.1 Test Data ....................................................................................................................................... 15
3.1.1 Additional Testing ................................................................................................................ 16
3.1.2 Suppression Mode Automatic Sprinkler Testing .................................................................. 16
3.1.3 Small Containers ................................................................................................................. 18
4.0 REFERENCES ..................................................................................................................................... 18
4.1 FM Global ...................................................................................................................................... 18
4.2 Others ............................................................................................................................................ 18
APPENDIX A GLOSSARY OF TERMS ..................................................................................................... 19
APPENDIX B DOCUMENT REVISION HISTORY ..................................................................................... 19
APPENDIX C NFPA STANDARD .............................................................................................................. 19
APPENDIX D AEROSOL PRODUCTS ...................................................................................................... 19
D.1 General ......................................................................................................................................... 19
D.2 Aerosol Classification by Chemical Heat of Combustion ............................................................. 20
D.3 Previous Aerosol Classification Schemes ..................................................................................... 20
D.3.1 Aerosol Flammability Test (AFT) ........................................................................................ 20
D.3.2 12-Pallet Test ...................................................................................................................... 20
D.4 Aerosol Can Labeling ................................................................................................................... 21
D.5 Chemical Heat of Combustion Data ............................................................................................. 21
APPENDIX E IN-RACK SPRINKLER LAYOUTS AND FIRE PROTECTION SCHEMES ........................ 24
E.1 In-Rack Sprinkler Layouts ............................................................................................................. 24
E.2 Fire Protection Scheme A ............................................................................................................. 42
E.3 Aerosol Flow-Through Rack Protection Scheme .......................................................................... 47
List of Figures
Fig. 1. Aerosol classification. ......................................................................................................................... 4
Fig. 2a. Cartoned Level 2 and 3 aerosols single row racks. ................................................................. 25
Fig. 2b. Cartoned Level 2 and 3 aerosols double row racks. ............................................................... 26
Fig. 2c. Cartoned Level 2 and 3 aerosols multiple row racks. .............................................................. 27
Fig. 3a. Cartoned Level 3 aerosols single row racks up to 25 ft (7.6 m) high storage
in suppression mode protected building. ..................................................................................................... 28
Fig. 3b. Cartoned Level 3 aerosols double row racks up to 25 ft (7.6 m) high storage
in suppression mode protected building. ..................................................................................................... 29
2003 Factory Mutual Insurance Company. All rights reserved. No part of this document may be reproduced,
stored in a retrieval system, or transmitted, in whole or in part, in any form or by any means, electronic, mechanical,
photocopying, recording, or otherwise, without written permission of Factory Mutual Insurance Company.
7-31
Page 2
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
Fig.
4a.
4b.
4c.
5a.
5b.
5c.
6a.
6b.
6c.
7a.
7b.
7c.
8a.
8b.
8c.
8d.
9a.
9b.
List of Tables
Table
Table
Table
Table
Table
Table
Table
Table
Table
Table
Table
7-31
Page 3
1.0 SCOPE
This data sheet applies to the storage of Level 1, 2 and 3 aerosol products.
1.1 Changes
January 2012. Terminology related to ignitable liquids has been revised to provide increased clarity and
consistency with regard to FM Globals loss prevention recommendations for ignitable liquid hazards.
2.0 LOSS PREVENTION RECOMMENDATIONS
2.1 Introduction
2.1.1 Aerosol Hazard Classification
2.1.1.1 Classify aerosol products in accordance with Table 1. Calculate the aerosol products chemical heat
of combustion by one of the following methods.
a) Sum the chemical heat of combustion for the constituent components of the aerosol product (e.g.,
propellant, liquid products, etc.) multiplied by their weight fraction. This is represented in mathematical
notation by the following formula.
Hcht = xiHchi
Where Hcht = total chemical heat of combustion of the product, Btu/lb [kJ/g]
xi = weight fraction of component i
Hchi = chemical heat of combustion of component i
Table 1. Aerosol Classification
greater than:
If the chemical heat of
combustion is:
0
8,600 Btu/lb
(20 kJ/g)
12,900 Btu/lb
(30 kJ/g)
b) Use Figure 1 if the aerosols constituent materials are known and consist of saturated hydrocarbons,
such as propane and isobutane, alcohols such as ethanol or methanol and inert materials.
c) Conduct a 12-pallet test to determine the aerosol classification, if product compositions are not known.
d) Classify the aerosol product as Level 3, if product compositions are not known and test results are
not available.
2.1.1.2 Determine the chemical heat of combustion for the constituents of an aerosol product from one of
the following sources:
a) Use the chemical heat of combustion data compiled in Table 10, located in the Appendix D of this
document, when the exact aerosol product components and their weight percents are known.
b) Use the total heat of combustion, as determined by oxygen bomb calorimeter measurements, when
the exact aerosol product components and their weight percents are known but the chemical heat of
combustion is not available.
c) Use the values provided in Table 2 when the exact components of the aerosol product are not known
but the product can be broken down by weight percent into the generic groups of hydrocarbon (e.g.,
propellent, non-water miscible ignitable liquids), alcohol (e.g., ethanol, isopropanol, etc.), and inert (e.g.,
solids, nonignitable liquids).
d) Conduct an oxygen bomb calorimeter test on the aerosol product mixture including the propellent.
7-31
Page 4
Note: Materials should be considered inert if they are liquids with a flash point that exceeds 500F (260C)
(e.g., some vegetable cooking oils), solids (e.g., powders), nonflammable gases (e.g., carbon dioxide),
or nonignitable liquids (e.g., water).
Table 2. Chemical Heat of Combustion for Various Materials
Hch
(Btu/lb)
19,000
11,000
0
Material
Hydrocarbon
Alcohol
Inert
Hch
(kJ/g)
44
25
0
7-31
Page 5
Palletized
Rack
Protection Mode
Storage Location Options
Control or Suppression Any Location is Acceptable
Control or Suppression Dedicated Building, Cutoff Room, or Dedicated Area
Defined by a Chain Link Fence
Control
Dedicated Building or Cutoff Room
Suppression
Dedicated Building, Cutoff Room, or Dedicated Area
Defined by a Chain Link Fence
Control or Suppression Dedicated Building, Cutoff Room, or Dedicated Area
Defined by a Chain Link Fence
7-31
Page 6
2.3 Occupancy
2.3.1 Maintain only aerosol storage in designated aerosol storage areas or cutoff rooms/buildings. Do not
mix aerosol storage with any ignitable liquid storage.
2.3.2 Provide minimum 8 ft (2.4 m) aisles for all rack storage of Level 2 and 3 aerosols.
2.4 Protection
2.4.1 General
2.4.1.1 Protect Level 2 or 3 aerosols with a container size of 5 fl oz (148 ml) or less using the protection
criteria provided in Data Sheet 8-9 for cartoned Group A unexpanded plastics. Products in this category may
be stored in general-purpose warehouses without any subdivision or cutoff. Basements should be avoided.
Products that are commonly found in this category include cigarette lighters, lighter refills and some small
hand-held torch cylinders.
2.4.1.2 Protect Level 1 aerosols using the protection criteria provided in Data Sheet 8-9 for a Class 3
commodity.
2.4.1.3 If storage is mixed, provide protection for the most hazardous classification of products present.
2.4.1.4 Use only wet or preaction sprinkler systems to protect aerosol storage. Dry-pipe systems do not have
adequate response time to control a fire in aerosol storage. Preaction sprinkler systems must be designed
to ensure water deliver to sprinklers before the sprinkler operates. One approach to achieve adequate
preaction system water delivery is to install heat detectors at either one-half their listed linear spacing or
the full allowable sprinkler spacing.
2.4.1.5 Install sprinklers in accordance with installation guidelines in Data Sheet 2-0, Installation Guidelines
for Automatic Sprinklers.
2.4.1.6 Base the in-rack sprinkler water demand on the simultaneous operation of the most hydraulically
remote sprinklers as follows:
a) Eight (8) sprinklers where only one level of in-rack sprinklers is provided.
b) Twelve (12) sprinklers (six [6] sprinklers on two levels) where only two (2) levels of in-rack sprinklers
are provided.
c) Eighteen (18) sprinklers (six [6] sprinklers on the top three levels) where more than two (2) levels of
in-rack sprinkler are provided.
d) In-rack design flows are provided in Tables 6 through 9. The end-sprinkler discharge pressure must
be at least 15 psi (1 bar) regardless of sprinkler type.
2.4.1.7 When required in Tables 6 through 9, install in-rack sprinklers in accordance with Figures 1 through 6.
In-rack sprinklers must be staggered vertically where indicated in the figures.
2.4.1.8 In addition to the water supply requirements for automatic sprinkler systems, provide the following
hose stream demands:
a) 500 gpm (1900 l/min) for buildings protected with control-mode sprinkler protection.
b) 250 gpm (950 l/min) for buildings protected with suppression-mode sprinkler protection.
c) 250 gpm (950 l/min) for buildings or rooms with a floor area of 2000 ft2 (185 m2) or less regardless
of the ceiling protection.
Loss experience indicates that because of rocketing cans, fire departments fight aerosol can fires from
appreciable distances with greatly reduced effects, which increases the importance of designing for hose
streams in a warehouse sprinkler design. (See Tables 4 through 9.)
2.4.1.9 Provide the following fire protection water supply durations:
a) 2 hour duration for buildings protected with control-mode sprinkler protection.
b) 1 hour duration for buildings protected with suppression-mode sprinkler protection.
7-31
Page 7
2.4.1.10 Provide small hose with combination spray nozzles and portable extinguishers suitable for fires
that involve ignitable liquids as well as ordinary combustibles.
2.4.1.11 Instruct and train operating employees and members of the Emergency Organization in the hazards
of butane and propane containers and in the emergency procedures to follow in the event of accident. Alert
the public fire department to the hazards and to the fire protection facilities provided.
2.4.2 Warehouses
2.4.2.1 Protect palletized or solid piled storage of Level 2 and 3 aerosols in accordance with Tables 4 and 5.
2.4.2.2 Protect rack storage of Level 2 and 3 aerosols in accordance with Tables 6, 7, 8, 9 and Figures 1
through 6.
7-31
Page 8
Packaging
Type
Cartoned
Uncartoned
Max
Ceiling
Height
Max
Storage
Height
25 ft
(7.6 m)
18
(5.5
20
(6.1
30 ft
(9.1 m)
5 ft
(1.5 m)
15 ft
(4.6 m)
25 ft
(7.6 m)
15 ft
(4.6 m)
30 ft
(9.1 m)
15 ft
(4.6 m)
ft
m)
ft
m)
7-31
Packaging
Type
Cartoned
Max
Ceiling
Height
Max
Storage
Height
20 ft
(6.1 m)
5 ft
(1.5 m)
10 ft
(3 m)
15 ft
(4.6 m)
25 ft
(7.6 m)
30 ft
(9.1 m)
Uncartoned
5 ft
(1.5 m)
15 ft
(4.6 m)
Page 9
Design
(density/area)
(# sprinklers @ discharge
pressure)
0.30 gpm/ft2 over 2500 ft2
(12 mm/min over 232 m2)
15 @ 75 psi (5.2 bar)
12 @ 50 psi (3.4 bar)
12 @ 35 psi (2.4 bar)
12 @ 25 psi (1.7 bar)
12 @ 25 psi (1.7 bar)
0.60 gpm/ft2 over 2500 ft2
(25 mm/min over 232 m2)
12 @ 75 psi (5.2 bar)
12 @ 52 psi (3.6 bar)
12 @ 45 psi (3.1 bar)
12 @ 25 psi (1.7 bar)
7-31
Page 10
Max
Roof
Height
Max
Storage
Height
25 ft
(7.6 m)
15 ft
(4.6 m)
30 ft
(9.1 m)
15 ft
(4.6 m)
25 ft
(7.6 m)
Layout
See Figure:
Nominal
K Factor
gpm/psi0.5
(l/min/bar0.5)
Response/
Nominal
Temperature
Rating
QR/Ordinary
NA
NA
NA
NA
16.8
(235)
QR/Ordinary
NA
NA
NA
NA
Suppressionpendent
22.4
(314)
QR/Ordinary
NA
NA
NA
NA
Suppressionpendent
25.2
(363)
QR/Ordinary
NA
NA
NA
NA
Suppressionpendent
14.0
(202)
QR/Ordinary
NA
NA
NA
NA
Suppressionpendent
16.8
(235)
QR/Ordinary
NA
NA
NA
NA
Suppressionpendent
22.4
(314)
QR/Ordinary
NA
NA
NA
NA
Suppressionpendent
25.2
(363)
QR/Ordinary
NA
NA
NA
NA
Suppressionpendent
14.0
(202)
QR/Ordinary
3a-b
8.0
(115)
QR/Ordinary
45
(170)
4a-c
5.6
(81)
SR or QR/
Ordinary
30
(114)
3a-b
8.0
(115)
QR/Ordinary
45
(170)
4a-c
5.6
(81)
SR or QR/
Ordinary
30
(114)
3a-b
8.0
(115)
QR/Ordinary
45
(170)
4a-c
5.6
(81)
SR or QR/
Ordinary
30
(114)
3a-b
8.0
(115)
QR/Ordinary
45
(170)
4a-c
5.6
(81)
SR or QR/
Ordinary
30
(114)
4a-c
5.6
(81)
SR or QR/
Ordinary
30
(114)
4a-c
5.6
(81)
SR or QR/
Ordinary
30
(114)
5a-c
5.6
(81)
SR or QR/
Ordinary
30
(114)
Response/
Nominal
Temperature
Rating
Suppressionpendent
14.0
(202)
Suppressionpendent
Protection
Mode
Suppressionpendent
Suppressionpendent
25 ft
(7.6 m)
>40 ft
(12.2 m)
25 ft
(7.6 m)
Unlimited
Unlimited
Sprinkler Type
Design
(density/area)
(# sprinklers @
discharge pressure)
Nominal
K Factor
gpm/psi0.5
(l/min/bar0.5)
16.8
(235)
22.4
(314)
QR/Ordinary
QR/Ordinary
Suppressionpendent
25.2
(363)
ControlDensity/Area
8.0
(115)
ControlDensity/Area
11.2
(161)
ControlDensity/Area
8.0
(115)
SR/High
Any
Any
See Scheme A
Any
QR/Ordinary
SR/High
SR/High
0.60 gpm/ft over 1500 ft to 2500 ft (25 mm/min over 140 m ) to 232 m
Interpolate area for clearances between 5 ft (1.5 m) and 15 ft (4.6 m)
Discharge
Flow
gpm
(l/min)
7-31
Sprinkler Type
Page 11
See Scheme A
Suppressionpendent
Suppressionpendent
Suppressionpendent
Suppressionpendent
20 ft
Suppressionpendent
Suppressionpendent
Suppressionpendent
Suppressionpendent
ControlDensity/Area
ControlDensity/Area
25 ft
Suppressionpendent
Suppressionpendent
Suppressionpendent
Suppressionpendent
ControlDensity/Area
Unlimited
Any
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Fig. 6a-c
Fig. 6a-c
Fig. 6a-c
Fig. 6a-c
Fig. 7a-c
Fig. 6a-c
Fig. 7a-c
Fig. 7a-c
Fig. 7a-c
Fig. 7a-c
Fig. 7a-c
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
8.0
QR/Ordinary
(115)
See Scheme A
Protection
Mode
Discharge
flow
gpm
(l/min)
7-31
Unlimited
Max
Storage
Height
15 ft
Layout
Max
Roof
Height
30 ft
Page 12
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
Suppressionpendent
Suppressionpendent
Suppressionpendent
Suppressionpendent
ControlDensity/Area
ControlDensity/Area
25 ft
Suppressionpendent
Suppressionpendent
Suppressionpendent
Suppressionpendent
ControlDensity/Area
Unlimited
Any
Fig. 6a-c
Fig. 6a-c
Fig. 6a-c
Fig. 6a-c
Fig. 6a-c
Fig. 7a-c
Fig. 7a-c
Fig. 7a-c
Fig. 7a-c
Fig. 7a-c
Fig. 7a-c
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
45
(170)
7-31
Protection
Mode
Discharge
flow
gpm
(l/min)
Unlimited
Max
Storage
Height
20 ft
Layout
Page 13
Max
Roof
Height
30 ft
7-31
Page 14
2.4.2.3 Protect picking areas that contain Level 2 and 3 aerosols as follows:
a) For picking in standard configuration single and double row racks, locate aerosol storage on the first
and second tier of the rack. Install Fire Protection Scheme A over the picking area. Provide chain link
fence or similar restraint at the edges of the aerosol storage area. For example, if the aerosols storage
is located only on one side of a double row rack, install chain link fencing down the longitudinal flue space
and at each end of the storage.
b) For picking in flow-through racks (those with shelves consisting of slanted rollers spaced less than
1 ft apart so that product loaded on one side rolls to the other), store and protect the aerosols in accordance
with the Aerosol Flow Through Rack Protection Scheme described and illustrated in Section E.3.
2.4.2.4 Protect aerosol storage in automated rack storage warehouses that are higher than 30 ft (9.1 m)
with aisle widths of 4 ft (1.2 m) or more as follows:
a) Limit aerosol storage to the bottom tiers of the racks.
b) Provide chain link fencing or noncombustible vertical barriers around the limits of the aerosol storage.
The rack face does not need to be enclosed.
c) Provide Fire Protection Scheme A over all aerosol storage within the racks. If aerosols are stored above
the bottom two rack tiers, protect all tiers below the aerosol storage using Fire Protection Scheme A as
well.
7-31
Page 15
2.4.4.3 Remove the cans from the shipping cartons and store in noncombustible bins or shopping carts as
described in Recommendation 2.4.3.4. Locate in sprinklered areas at least 5 ft (1.5 m) from other combustible
storages.
2.4.5 Shipping/Receiving Areas
In many warehouses, the receiving area often is separate from the shipping area. Pallet loads of aerosol
would be expected to be found in the receiving area but not necessarily in shipping areas where pallet loads
of mixed commodities are assembled for shipment to stores. At smaller locations, the shipping and receiving
may be combined in one area. (Even though the shipping areas at large warehouses may not have pallet
loads of aerosols present, the term shipping/receiving areas is used in the data sheet for simplicity.) The
process of receiving and distributing aerosols requires staging them in shipping/receiving areas and
transporting them through the warehouse. This is unavoidable, but the exposure can be minimized by proper
handling. Among the suggested procedures are:
2.4.5.1 In-process, non-rack storage of Level 2 and 3 aerosols may be present in shipping/receiving areas
when limited to one pallet load high and protected as follows:
a) Level 2 aerosols. Ceiling sprinklers should be capable of providing a minimum density of 0.30 gpm/ft2
over 2500 ft2 (12 mm/min over 230 m2) using 286F (141C) heads.
b) Level 3 aerosols. Ceiling sprinklers should be capable of providing a minimum density of 0.60 gpm/ft2
over 2500 ft2 (24 mm/min over 230 m2) using 1732 in. (14 mm) orifice 286F (141C) heads.
2.4.5.2 To minimize the exposure the aerosols present to other storage in the warehouse during transport
to and from the assigned area, locate the aerosol storage areas as close as possible to shipping/receiving
areas. This is especially important if the ceiling sprinkler systems everywhere in the warehouse are not
capable of providing the minimum density of 0.30 gal/min/ft2 for Level 2 aerosols or 0.60 gpm/ft2 for Level 3
aerosols over 2500 ft2 (12 or 24 mm/min over 230 m2) using 286F (141C) heads.
Quantities in shipping/receiving areas should be the minimum necessary for efficient operations. Shipping/
receiving areas should not be used for storage.
3.0 SUPPORT FOR RECOMMENDATIONS
3.1 Test Data
FM Global Research conducted large scale tests on all levels of flammable products. Level 2 flammable
aerosols produced intense fires, and ruptured cans were propelled throughout the test site. Sprinklers
confined the fire to the aerosol storage with no sustained fire propagation to the target storage arrays. Some
of the rocketing cans actually trailed burning liquid, and burning packaging material or plastic caps also were
occasionally propelled beyond the test array. Product sprayed from the cans and occasionally splashed onto
the target arrays, but it was quickly diluted and extinguished by the sprinkler discharge.
Tests on Level 3 products resulted in high heat release rates and rocketing cans with trailing fires. These
products produced copious quantities of dense black smoke. Visibility during tests was often completely
obscured after only four or five minutes. A single pallet load of a Level 3 aerosol in a 30 ft (9.1 m) high test
bay with a 40F (4C) flash point opened 36 high temperature sprinkler heads discharging at a density of
0.30 gpm/ft2 (12 mm/min). Ceiling temperatures reached 1900F (1040C) and exceeded 1000F (540C) for
one minute. Consumption of the aerosols caused the eventual reduction in ceiling temperatures. Burning
material was spread by rocketing cans and insoluble burning liquid floating on the sprinkler water.
In the rack storage tests of both types of aerosols, the fire spread quickly up the ignition flue and reached
the top of the array in about one minute. The fire also advanced to the face of the second, third, and fourth
tiers of storage. The heat input of the burning packaging caused cans on the aisle to rupture. The fireball
and burning liquid often impinged on the face of the target rack. The aisle jump started at the top of the storage
and spread downward. Aisle jump occurred in tests on Level 3 aerosols even when the ceiling sprinkler
density was 0.6 gpm/ft2 (24 mm/min), but the fire was controlled.
A test, co-sponsored by an insured, was conducted using face sprinklers in addition to longitudinal flue
sprinklers to determine whether face sprinklers would stop the fire spread up the face of the rack. Clearance
between ceiling and storage was reduced to 5 ft (1.5 m) and ceiling density was reduced from 0.60 gpm/ft2
(24 mm/min) to 0.30 gpm/ft2 (12 mm/min).
7-31
Page 16
The in-rack sprinklers were staggered horizontally and vertically. A Level 3 paint product was the test
commodity. The results indicated that the face sprinklers do interrupt the fire spread, prevent aisle jump, and
reduce the number of operating ceiling sprinklers. Two in-rack sprinklers, one at the face and one in the
longitudinal flue, and four ceiling sprinklers operated. In comparison, the two tests without face sprinklers
and with the 0.60 gpm/ft2 ceiling density opened 5 and 12 ceiling sprinklers and 5 and 6 in-rack sprinklers.
Aisle jump also occurred in these two tests, but was controlled by the high ceiling sprinkler density.
In both palletized and rack storage tests, the can ruptures dislodged surrounding cans and exposed other
cans inside the load to the fire, further increasing the severity.
The major mechanism of fire control during the test program was prompt extinguishment of the water-miscible
Level 2 product. Control of the non-water-miscible Level 2 and 3 aerosols was achieved by wetting and
cooling with a combination of high ceiling sprinkler density and in-rack sprinklers.
The testing revealed that in the absence of adequate sprinkler protection:
1. The rocketing cans, regardless of contents, could severely hamper manual fire fighting efforts.
2. Some of the Level 3 aerosols generated thick black smoke and visibility was completely obscured in five
minutes. If adequate protection is provided, the amount of smoke generated will be significantly less because
less product is released and consumed.
3. A single pallet load of a Level 3 aerosol in a general purpose warehouse as they are usually protected
constitutes a potential serious loss.
3.1.1 Additional Testing
Initial testing revealed that palletized storage of Level 2 and 3 aerosol products in excess of one high could
not be protected even with a 0.60 gpm/ft2 (24 mm/min) density. It was recognized that the one-high palletized
height limitation was a severe restriction for locations that handled large quantities of aerosols (e.g., aerosol
manufacturing plants and large distribution warehouses). Additional tests, sponsored by an aerosol trade
group and conducted by FM Global Research, were made to determine whether large-drop sprinklers could
be used to protect palletized storage that exceeded one pallet high. Tests showed that four-high (18 ft [5.5 m])
palletized storage of Level 2 aerosols and two-high (10 ft [3 m]) palletized storage of Level 3 aerosols could
be adequately protected by using 160F (71C) rated large-drop sprinklers installed on a maximum 100 ft2
(9.3 m2) spacing and with ceiling clearances specified in the recommendations.
Except for the four-high palletized Level 2 aerosol test, all tests were conducted with a 20 ft (6.1 m) ceiling
height. The test with four-high palletized storage was conducted with a 25 ft (7.6 m) ceiling height. The
end-head pressure for the Level 2 test was 50 psi (344 kPa) which produced a flow of about 79 gpm (5 l/min).
The end-head pressure for the Level 3 test was 75 psi (517 kPa) which produced a flow of 97 gpm (6 l/min).
Additional tests were conducted to determine whether packaging or product changes would reduce the
hazard. Five concepts were tested: 1) rim vent release (RVR) cans, which are designed to vent the contents
and relieve the internal pressure without catastrophic can failure; 2) plastic shrink wrap which replaced the
cardboard cartons; 3) fire retardant cartons; 4) metal overcaps instead of the plastic overcaps; and 5)
substitution of 30% of the toluene in the Level 3 product with less flammable methylene chloride. The results
of these tests did not warrant further investigation of these concepts. The results of the testing on shrink
wrapped aerosol product (i.e., uncartoned aerosols) indicated that the lack of cardboard packaging materials
may negatively impact the sprinkler protection effectiveness for rack and palletized storage arrangements.
3.1.2 Suppression Mode Automatic Sprinkler Testing
3.1.2.1 Level 1 Aerosols
Level 1 aerosols were tested under the Fire Products Collector with the same protection that was developed
for Data Sheet 2-2, Installation Rules for Suppression Mode Automatic Sprinklers. The results indicated that
Level 1 aerosols could be adequately protected with this criteria.
7-31
Page 17
7-31
Page 18
1
HS
2
R
18.8
(5.7)
25
(7.6)
6.2
(1.9)
4
1:02
1:11
4
1045
(560)
1:03
2
Pt
3
R
13.8
(4.2)
25
(7.6)
11.2
(3.4)
4
0:42
1:06
4
565
(296)
1:01
3
Pt
3
P
15.5
(4.7)
25
(7.6)
9.5
(2.9)
4
0:49
1:36
4
713
(378)
1:29
4
Pt
3
R
13.6
(4.1)
19
(5.8)
4.2
(1.3)
2
0:55
6:33
5
1421
(771)
0:52
5
Pt
3
R
13.8
(4.2)
25
(7.6)
11.2
(3.4)
1
0:35
0:35
1
256
(124)
None
6
Pt
3
R
13.8
(4.2)
30
(9)
15
(4.5)
1
0:36
2:06
61
1447
(785)
0:44
7
HS
2
R
13.8
(4.2)
30
(9)
15
(4.5)
1
0:34
0:34
1
233
(106)
0:46
8
HS
2
R
18.8
(5.7)
30
(9)
10
(3)
2
0:56
3:34
14
995
(535)
1:01
9
Pt
3
R
13.8
(4.2)
30
(9)
15
(4.5)
1
1:15
1
200
(93)
1:10
10
Pt
3
R
13.8
(4.2)
19
(5.8)
4.2
(1.3)
2
1:10
1:12
6
1590
(866)
1:05
Sheet
Sheet
Sheet
Sheet
4.2 Others
SFPE Handbook of Fire Protection Engineers.
Perrys Chemical Engineering Handbook.
NFPA 30B Code for Manufacture and Storage of Aerosol Products.
7-31
Page 19
7-31
Page 20
Aerosols have been grouped into Levels 1, 2 and 3. Level 1 aerosols represent the lowest fire hazard; Level 3
represents the highest fire hazard.
Level I aerosol products include shaving cream, spray starch, window cleaners, alkaline oven cleaners, rug
shampoos, some air fresheners, and some insecticides. The storage hazard of Level I aerosols is about
the same as ordinary combustible goods in cartons. Storage should be arranged and protected accordingly.
When a Level I aerosol can fails, the nonflammable product has a quenching effect on the flammable
contents. Some products have very small quantities of flammable product. These products will have an overall
chemical heat of combustion that is low.
Level 2 products include many personal care products such as deodorants (except for oil-based
antiperspirants), hair sprays, antiseptics, and anesthetics. Other products may include some furniture
polishes, windshield de-icers, etc.
Level 3 products include many automotive products (engine and carburetor cleaners, undercoats), home
products (some wood polishes), paints and lacquers, lubricants, some insecticides, and oil-based
antiperspirants.
D.2 Aerosol Classification by Chemical Heat of Combustion
Test data indicates the overall fire hazard of an aerosol product is a function of the chemical heat of
combustion. The chemical heat of combustion is the product of the theoretical heat of combustion and a
combustion efficiency. Typical chemical heats of combustion are provided in Table 2. A typical combustion
efficiency is 95%. Research conducted at FM Global Research correlated the chemical heat of combustion
with results of 12-pallet tests to provide a classification methodology based exclusively on chemical heat
of combustion. Figure 1 is based on this methodology.
Based on the results of the 12-pallet testing and aerosol flammability testing, liquids with a flash point that
exceeds 500F (260C) (e.g., some vegetable cooking oils) can be considered inert when classifying an
aerosol product. In addition solids (e.g., powders), nonflammable gases (e.g., carbon dioxide), or liquids
that do not support combustion (e.g., water) are also considered inert.
D.3 Previous Aerosol Classification Schemes
D.3.1 Aerosol Flammability Test (AFT)
This test involves two procedures: a single can test and a pan fire test. The single can procedure exposes
a restrained can to a predetermined heat source until it ruptures. The time to rupture is noted, and the fireball
energy is measured in the Fire Products Collector (FPC) located at the FM Global Technology Center. This
data is combined to produce a single-can index that allows the results to be compared with data produced
by large-scale tests on known Level 1, 2 or 3 aerosols.
Large scale tests, conducted to check the validity of the single can test, showed that the small scale test
accurately predicted the large scale fire behavior for most formulae. There was an indication, however, that
the single can test was inadequate for aerosols containing material that pooled on the floor and flash
vaporized when hit by sprinkler discharge. As a result, the pan fire test was devised, consisting of burning
a sample of aerosol contents for a set time period before applying water. This test shows whether the burning
rate increases or whether the water extinguishes the fire.
D.3.2 12-Pallet Test
The 12-pallet test was developed as part of the Aerosol Flammability Test (AFT) program to confirm the
accuracy of the AFT methodology. It is conducted using a 223 pallet array under a 25 ft (7.6 m) high ceiling
with large-drop sprinklers designed to discharge at 50 psi (3.45 bar). Data collected during this test include
the number of operating sprinklers, maximum steel and air temperatures, plume temperature and plume
velocity. This data is used to objectively determine the hazard classification.
7-31
Page 21
7-31
Page 22
14807-96-6
67-56-1
78-93-3
563-80-4
110-43-0
75-09-2
Material Name
1,1,1-Trichloroethane
1,1-Diflouroethane (HFC 152a)
1,1,1-Trimethylbenzene (Pseudocumene)
1,1-Dichloro-1-Fluoroethane
1,2-Dimethoxyethane
1-Chloro-1,1-Diflouroethane (HCFC 142b)
1-Methoxy-2-Propanol Acetate
2-Butoxyethanol
2-Ethoxyethanol
2-Ethoxyethyl Acetate
2-Methylpropane (Isobutane)
Acetone
Acrylic Resin
Alkyd Resin
Aluminum
Asphalt
Barium Sulfate
Benzidine (Yellow)
Butane
Butyl Benzl Phthalate
Calcium Carbonate
Carbon Dioxide
Carbon Black
Chrominum Hydroxide
Corn Oil
d-Limonene
Diacetone Alcohol
Diethylene Glycol Methyl Ether
Dimethyl Ether
Dipropylene Glycol Methyl Ether
Ethanol (95.6 Azeotrope)
Ethanol
Ethyl 3-Ethoxypropionate
Ethylbenzene
Ethylene Glycol
Ethylene Glycol Diacetate
Graphite
Hexylene Glycol
Iron Oxide
Isobutyl Alcohol
Isopropyl Acetate
Isopropyl Alcohol
Isopropyl Palmitate
Isopropyl Myristate
Kaolin Clay (Aluminum Silicate Hydroxide)
Kerosene (Kerosine)
Liquids, Non-Contributory
Liquids, Nonignitable
Magnesium Silicate (Talc)
Methanol
Methyl Ethyl Ketone
Methyl Isopropyl Ketone
Methyl n-Amyl Ketone
Methylene Chloride
Hc1
(kJ/g)
18.1
41.0
8.4
26.72
9.3
32.22
30.82
26.72
32.22
45.5
28.6
30.24
0.0
45.6
37.12
0.0
0.0
0.0
36.84
45.2
37.32
34.42
28.8
33.52
25.6
26.8
33.32
40.9
16.9
33.32
29.7
0.0
32.7
26.0
30.1
38.82
38.22
0.0
46.04
0.0
0.0
20.0
31.5
33.1
37.22
6.0
ch2
0.353
0.673
0.353
0.97
0.353
0.96
0.96
0.97
0.96
0.94
0.973
0.75
0.953
0.85
0.96
0.88
0.94
0.96
0.92
0.96
0.92
0.92
0.96
0.71
0.97
0.96
0.96
0.91
0.98
0.91
0.96
0.95
0.905
0.953
0.973
0.94
0.94
0.353
Hch
(kJ/g)
a
6.3
27.5
2.9
25.9
3.3
30.9
29.6
25.9
30.9
42.8
27.7
a
a
a
22.7
0.0
a
43.3
3.15
0.0
0.0
a
0.0
353
39.8
35.1
33.0
26.5
32.2
23.6
24.7
32.0
29.0
16.4
32.0
a
28.5
0.0
29.8
25.5
27.4
37.2
36.2
0.0
41.4
a
0.0
0.0
19.0
30.6
31.1
35.0
2.1
7-31
Page 23
CAS#
12001-26-2
64742-47-8
8012-95-1
64742-88-7
134-62-3
123-86-4
142-82-5
110-54-3
113-48-4
64742-48-9
8030-30-6
8052-41-3
64742-95-6
64742-94-5
7727-37-9
8002-74-2
109-66-0
127-18-4
64741-65-7
147-14-8
1328-53-6
51-03-6
9005-65-6
9005-64-5
74-68-6
57-55-6
78-92-2
7631-86-9
63148-58-3
63148-62-9
1338-39-2
26266-57-9
25038-32-8
16252-10-5
13463-67-7
108-88-3
102-76-1
79-01-6
7732-18-5
1330-20-7
1314-13-2
Material Name
Mica (Mica Silicate)
Mineral Spirits (Petroleum Distillate)
Mineral Oil
Mineral Spirits (Petroleum Distillate)
N,N-Diethyl-m-Toluamide (Deet)
n-Butyl Acetate
n-Heptane
n-Hexane
n-Octyl Bicyclopheptane Dicarboximide
Naphtha, VM&P (Petroleum Distillate)
Naphtha (Petroleum Distillate)
Naphtha (High Flash)
Naphtha, VM&P (Petroleum Distillate)
Naphtha, VM&P (Petroleum Distillate)
Nitrogen
Paraffin (Wax)
Pentane
Perchloroethylene (Tetrachloroethylene)
Petroleum Distillate
Phthalocyanine Blue
Phthalocyanine Green
Piperonyl Butoxide
Polyoxyethylene Sorbitan Oleate
Polyoxyethylene (20)Sorbitan Monolaurate
Propane
Propylene Glycol
sec-Butyl Alcohol
Silica (Crystalline)
Silica, Amorphous Hydrated
Silicone Oil
Silicone Oil
Solids, Non-Contributory
Solids, Noncombustible
Sorbitan Monolaurate
Sorbitan Monopalmitate
Styrene Butadiene Rubber
Tin Oxide
Titanium Dioxide
Toluene
Triacetin
Trichloroethylene
Water
Xylene
Zinc Oxide
Hc1
(kJ/g)
0.0
44.8
41.54
44.8
38.12
28.2
44.6
44.7
38.02
44.8
44.8
44.8
44.8
44.8
0.0
45.0
44.8
37.22
46.3
21.4
32.9
0.0
0.0
0.0
39.52
39.52
0.0
0.0
40.5
36.9
0.0
40.9
0.0
ch2
0.92
0.765
0.92
0.74
0.98
0.923
0.923
0.79
0.92
0.92
0.92
0.92
0.92
0.932
0.92
0.86
0.953
0.96
0.91
0.96
0.96
0.70
0.96
0.673
Hch
(kJ/g)
0.0
41.2
31.5
41.2
28.2
27.6
41.0
41.1
30.0
41.2
41.2
41.2
41.2
41.2
0.0
a
41.9
a
41.2
a
a
32.0
a
a
44.0
20.5
39.9
0.0
0.0
a
a
a
0.0
37.9
37.9
a
0.0
0.0
28.4
35.4
a
0.0
27.4
0.0
a Materials with closed cup flash points greater than 500F (D92-90 Test Method for Flash and Fire Points by Cleveland Open Cup, ASTM,
Philadelphia, Pennsylvania).
1
Except as noted, theoretical heat of complete combustion (net) determined from heat of formation or heat of combustion data assuming
all products in the vapor phase (CRC Handbook of Chemistry and Physics, 73th ed., David R. Lide, ed., CRC Press, Boca Raton, Florida,
1992).
Except as noted, chemical combustion efficiency determined by correlations based on chemical structure as given in: Tewarson, A., Smoke
Point Height and Fire Properties of Materials, May 1988, available from NTIS P889-141089.
Chemical combustion efficiency reported in: Tewarson, A, Generation of Heat and Chemical Compounds in Fires, Chapter 1-13 in SFPE
Handbook of Fire Protection Engineering, P. J. DiNenno, ed., 1st ed., National Fire Protection Association, Quincy, Massachusetts, 1988.
Heat of complete combustion (net) as measured by oxygen bomb calorimetry (D240-92 Test Method for Heat of Combustion of Liquid
Hydrocarbon Fuels by Bomb Calorimeter, ASTM, Philadelphia, Pennsylvania).
Chemical combustion efficiency measured under simulated fire conditions using the method described in: Tewarson, A, Generation of
Heat and Chemical Compounds in Fires, op. cit., ref.3.
7-31
Page 24
7-31
Page 25
5 ft. (1.5 m)
Approx.
8 ft (2.4 m)
Approx.
Plan View
NOTE:
In-Rack Sprinklers must be Staggered Vertically
Line-up In-Rack Sprinklers with Transverse Flue Spaces
10 ft (3.0 m) Approx
15 ft (4.6 m) Approx
5 ft. (1.5 m)
Approx.
Elevation View
Flue Sprinkler
7-31
Page 26
9 ft. (2.7 m)
Approx.
8 ft (2.4 m)
Approx.
Plan View
Deflector Clearance Minimum of 6 in. (15 cm)
NOTE:
In-Rack Sprinklers Must be Staggered Vertically
Line-up In-Rack Sprinklers with Transverse Flue Spaces
5 ft. (1.5 m)
Approx.
Flue Sprinkler
Elevation View
7-31
Page 27
Loading Aisle
8 ft (2.4 m)
Approx.
8 ft (2.4 m)
Approx.
Loading Aisle
Plan View
@ 15 ft (4.6 m) Level
15 ft (4.6 m) Approx.
Flue Sprinkler
Elevation View
(Aisle View)
Face Sprinklers
NOTE:
Line-up In-Rack Sprinklers with Transverse Flue Spaces
Provide Face Sprinklers at 15 ft (4.6 m) Vertical Level
Stagger In-rack Sprinklers Vertically and Horizontally
7-31
Page 28
5 ft. (1.5 m)
Approx.
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
5 ft. (1.5 m)
Approx.
Flue Sprinkler
Elevation View
Fig. 3a. Cartoned Level 3 aerosols single row racks up to 25 ft (7.6 m) high storage
in suppression mode protected building.
7-31
Page 29
9 ft. (2.7 m)
Approx.
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
(typical tier)
NOTE:
Line-up In-Rack Sprinklers with Transverse Flue
Spaces
5 ft. (1.5 m)
Approx.
Elevation View
Flue Sprinkler
Fig. 3b. Cartoned Level 3 aerosols double row racks up to 25 ft (7.6 m) high storage
in suppression mode protected building.
7-31
Page 30
5 ft. (1.5 m)
Approx.
8 ft (2.4 m)
Approx.
Plan View
NOTE:
In-Rack Sprinklers must be Staggered Vertically
Line-up In-Rack Sprinklers with Transverse Flue Spaces
5 ft. (1.5 m)
Approx.
Flue Sprinkler
Elevation View
7-31
Page 31
8 ft (2.4 m)
Approx.
NOTE:
All In-Rack Sprinklers Must be Staggered Vertically
Line-up In-Rack Sprinklers with Transverse Flue Spaces
9 ft. (2.7 m)
Approx.
8 ft (2.4 m)
Approx.
Plan View
(typical tier)
Deflector Clearance Minimum of 6 in. (15 cm)
5 ft. (1.5 m)
Approx.
Face Sprinkler
Flue Sprinkler
Elevation View
7-31
Page 32
7-31
Page 33
5 ft. (1.5 m)
Approx.
8 ft (2.4 m)
Approx.
NOTE:
In-Rack Sprinklers must be Staggered Vertically
Line-up In-Rack Sprinklers with Transverse Flue Spaces
5 ft. (1.5 m)
Approx.
Flue Sprinkler
Elevation View
Fig. 5a. Cartoned Level 2 and 3 aerosols, clearance > 15 ft (4.6 m) single row racks.
7-31
Page 34
8 ft (2.4 m)
Approx.
9 ft. (2.7 m)
Approx.
8 ft (2.4 m)
Approx.
NOTE:
Plan View
All In-Rack Sprinklers Must be Staggered
(Typical
Tier
& Below Barrier)
Vertically
Line-up In-Rack Sprinklers with Transverse
Flue Spaces
Deflector Clearance Minimum of 6 in. (15 cm)
Barrier Over Top Level of Storage
5 ft. (1.5 m)
Approx.
Face Sprinkler
Elevation View
Flue Sprinkler
Fig. 5b. Cartoned Level 2 and 3 aerosols, clearance > 15 ft (4.6 m) double row racks.
7-31
Page 35
Fig. 5c. Cartoned Level 2 and 3 aerosols, clearance > 15 ft (4.6 m) multiple row racks.
7-31
Page 36
5 ft. (1.5 m)
Approx.
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
NOTE: Line-up In-Rack Sprinklers with Transverse Flue Spaces
5 ft. (1.5 m)
Approx.
Flue Sprinkler
Elevation View
Fig. 6a. Uncartoned Level 2 and 3 aerosols single row racks up to 20 ft (6.1 m) high storage.
7-31
Page 37
8 -10 ft.
(2.4 - 3 m)
9 ft. (2.7 m)
Approx.
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
(typical tier)
NOTE:
Face Sprinklers Are NOT Staggered Vertically
Line-up In-Rack Sprinklers with Transverse Flue Spaces
Deflector Clearance Minimum of 6 in. (15 cm)
5 ft. (1.5 m)
Approx.
Face Sprinkler
Elevation View
Flue Sprinkler
Fig. 6b. Uncartoned Level 2 and 3 aerosols double row racks up to 20 ft (6.1 m) high storage.
7-31
Page 38
Fig. 6c. Uncartoned Level 2 and 3 aerosols multiple row racks up to 20 ft (6.1 m) high storage.
7-31
Page 39
5 ft. (1.5 m)
Approx.
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
5 ft. (1.5 m)
Approx.
Flue Sprinkler
Elevation View
Fig. 7a. Uncartoned Level 2 and 3 aerosols single row racks up to 25 ft (7.6 m) high storage.
7-31
Page 40
8 -10 ft.
(2.4 - 3 m)
9 ft. (2.7 m)
Approx.
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
(typical tier)
NOTE:
Face Sprinklers Must be Staggered Vertically
Line-up In-Rack Sprinklers with Transverse Flue
Spaces
5 ft. (1.5 m)
Approx.
Face Sprinkler
Elevation View
Flue Sprinkler
Fig. 7b. Uncartoned Level 2 and 3 aerosols double row racks up to 25 ft (7.6 m) high storage.
7-31
Page 41
Fig. 7c. Uncartoned Level 2 and 3 aerosols multiple row racks up to 25 ft (7.6 m) high storage.
7-31
Page 42
7-31
Page 43
Solid Barrier
5 ft. (1.4 m)
Maximum
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
Deflector a Maximum of 7 in. (23 cm) Below Barrier
10 ft. (3 m)
10 ft. (3 m)
In-Rack Sprinkler
Elevation View
Fig. 8a. Single row rack in-rack sprinkler layout Fire Protection Scheme A.
7-31
Page 44
Solid Barrier
5 ft. (1.4 m)
Maximum
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
Deflector a Maximum of 7 in. (23 cm) Below Barrier
10 ft. (3 m)
10 ft. (3 m)
In-Rack Sprinkler
Elevation View
Fig. 8b. Single row rack in-rack sprinkler layout Fire Protection Scheme A.
7-31
Page 45
Solid Barrier
(no gap at longitudinal flue)
8 -10 ft.
(2.4 - 3 m)
9 ft. (2.7 m)
Maximum
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
Face Sprinkler
10 ft. (3 m)
10 ft. (3 m)
Elevation View
Fig. 8c. Double row rack in-rack sprinkler layout Fire Protection Scheme A.
7-31
Page 46
Solid Barrier
(no gap at flue)
4 - 5 ft.
(1.2 - 1.5 m)
Plan View
Deflector a Maximum of 7 in. (23 cm) Below Barrier
10 ft. (3 m)
In-Rack Sprinkler
Fig. 8d. Multiple row rack in-rack sprinkler layout Fire Protection Scheme A.
7-31
Page 47
7-31
Page 48